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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 79DA RUST TREATMENT 10.25OZ AE CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Aerosol Rust preventative 1.3. Name, Address, and Telephone of the Responsible Party Company ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Phone: (877) 376-2839 1.4. Emergency Telephone Number Emergency | Chem-Tel: 800-255-3924 number |International Emergency: 00+1+ 813-248-0585 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2 damage/eye | irritation | Specific |Category 3 target organ | toxicity | (single | exposure) | Flammable |Category 1 aerosols | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Flame Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Causes skin irritation |Causes serious eye irritation |May cause drowsiness or dizziness |Extremely flammable aerosol Precautionary Statements |Prevention: (GHS-US) |Wash face, hands and any exposed skin thoroughly |after handling |Wear eye/face protection |Avoid breathing dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use |Response: |IF exposed or concerned: Get medical |advice/attention |Specific treatment (see supplemental first aid |instructions on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing |If eye irritation persists: Get medical |advice/attention |IF ON SKIN: Wash with plenty of soap and water |If skin irritation occurs: Get medical |advice/attention |Take off contaminated clothing and wash before reuse | |IF INHALED: Remove victim to fresh air and keep at |rest in a position comfortable for breathing |Storage: |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Protect from sunlight. Do not expose to temperatures |exceeding 50 Â°C/122 Â°F |Disposal: |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: -The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1 % w/w 1,3-butadiene (EINECS No. 203-450-8). If the substance is not classified as a carcinogen or mutagen, at least the S-phrases (2-)9-16 (Table 3.2) should apply. This note applies only to certain complex oil-derived substances in Part 3. 2.4. Unknown Acute Toxicity (GHS-US) 26.13 % of the mixture consists of ingredient(s) of unknown toxicity. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) ACETONE |67-64-1 |15 - 40 | PETROLEUM GASES, LIQUEFIED, |68476-86-8 |10 - 30 | SWEETENED | | | 2-BUTOXYETHANOL |111-76-2 |10 - 30 | FORMIC ACID |64-18-6 |1 - 5 | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Get medical advice/attention if you feel unwell. First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. First-aid Measures After Skin Contact: IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: See section 2 for more information. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Self-protection of the first aider: Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Note to physicians: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Carbon dioxide (CO2), Dry chemical, Foam. Unsuitable Extinguishing Media: None. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Explosion Hazard: Sensitivity to Mechanical Impact: None. Sensitivity to Static Discharge: None. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Remove all sources of ignition. Contents under pressure. Do not puncture or incinerate cans. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards: Clean contaminated objects and areas thoroughly observing environmental regulations. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Do not expose to temperatures exceeding 50 Â°C/122 Â°F. Store locked up. Incompatible materials: Strong oxidizing agents, Acids, Alkalis, Chlorinated compounds. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines: Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 2-BUTOXYETHANOL 111-76-2 TWA: 20 ppm TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S* IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3 FORMIC ACID 64-18-6 STEL: 10 ppm TWA: 5 ppm TWA: 5 ppm TWA: 9 mg/m3 (vacated) TWA: 5 ppm (vacated) TWA: 9 mg/m3 IDLH: 30 ppm TWA: 5 ppm TWA: 9 mg/m3 Other Information: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear protective gloves and protective clothing. Respiratory Protection |Use NIOSH-approved air-purifying respirator with |organic vapor cartridge or canister, as appropriate. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid; Aerosol Appearance |Gray Odor |Acidic Odor Threshold |No information available pH |No information available Relative Evaporation Rate |> 1, Butyl acetate = 1 (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |> 38 Â°C / >100 Â°F Flash Point |No information available, Gives a flame |projection at full valve opening or flashback |at any degree of valve opening Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C | Relative Density |0.845-0.855 Specific Gravity | Solubility |Soluble in water Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information Softening point: No information available Molecular weight: No information available VOC Content: (%) 33.1% Density: No information available Bulk density: No information available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Heat, flames and sparks. Temperatures >50 Â°C / 122 Â°F. 10.5 Incompatible Materials Strong oxidizing agents, Acids, Alkalis, Chlorinated compounds. 10.6 Hazardous Decomposition Products Carbon oxides Aldehydes Ketones and their derivatives. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: No information available. Germ Cell Mutagenicity: No information available. Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Blood, Central nervous system, Eyes, Hematopoietic System, kidney, Liver, Respiratory system, Skin. Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: May cause irritation of respiratory tract. May cause drowsiness or dizziness. Symptoms/Injuries After Skin Contact: May cause skin irritation and/or dermatitis. Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Symptoms/Injuries After Ingestion: Ingestion may cause irritation to mucous membranes. Chronic Symptoms: May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: 54.2 % of the mixture consists of components(s) of unknown hazards to the aquatic environment. Chemical Name Algae/aquatic plants Fish Crustacea ACETONE 67-64-1 - 4.74 - 6.33: 96 h Oncorhynchus mykiss mL/L LC50 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 2-BUTOXYETHANOL 111-76-2 - 1490: 96 h Lepomis macrochirus mg/L LC50 static 2950: 96 h Lepomis macrochirus mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 1698 - 1940: 24 h Daphnia magna mg/L EC50 FORMIC ACID 64-18-6 25: 96 h Desmodesmus subspicatus mg/L EC50 26.9: 72 h Desmodesmus subspicatus mg/L EC50 175: 24 h Lepomis macrochirus mg/L LC50 static 120: 48 h Daphnia magna mg/L EC50 138 - 165.6: 48 h Daphnia magna mg/L EC50 Static 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil No information available. Chemical Name Partition coefficient ACETONE 67-64-1 -0.24 PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 <=2.8 2-BUTOXYETHANOL 111-76-2 0.81 FORMIC ACID 64-18-6 -0.54 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal should be in accordance with applicable regional, national and local laws and regulations. Additional Information: Contaminated packaging: Do not reuse container. US EPA Waste Number: D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes ACETONE 67-64-1 - Included in waste stream: F039 - U002 FORMIC ACID 64-18-6 U123 Included in waste streams: K009, K010 - U123 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ACETONE 67-64-1 Ignitable FORMIC ACID 64-18-6 Toxic Corrosive SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, Limited Quantity (LQ) Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols, Limited Quantity (LQ) Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |Consumer commodity Identification Number|ID 8000 |<PICTOGRAM PHRASE> Hazard Class |9 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |9L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Chemical Name SARA 313 - Threshold Values % 2-BUTOXYETHANOL - 111-76-2 1.0 FORMIC ACID - 64-18-6 1.0 CWA (Clean Water Act): This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances FORMIC ACID 64-18-6 5000 lb - - X CERCLA: This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302). Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ FORMIC ACID 64-18-6 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ SARA Section 311/312 Hazard Classes |Acute health hazard |Yes |Chronic Health Hazard |No |Fire hazard |Yes |Sudden release of pressure hazard No |Reactive Hazard |No Toxic Substances Control Act (TSCA) |Complies 15.2 US State Regulations <COMPONENT> California Proposition 65: This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations: Chemical Name New Jersey Massachusetts Pennsylvania ACETONE 67-64-1 X X X 2-BUTOXYETHANOL 111-76-2 X X X WATER 7732-18-5 - - X FORMIC ACID 64-18-6 X X X SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |23-Jun-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.