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SDS Sheet 0065690

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: SP705 Non-Chlorinated Brake & Parts Cleaner Aerosol               
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Not applicable.                                   
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Sprayon Products                                                                
 
Cleveland, OH 44115                                                             
 
Phone: (800)247-3266, (216)566-2902                                             
 


1.4.  Emergency Telephone Number
Emergency     |(216) 566-2917, (800)424-9300                                    
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
FLAMMABLE     |Category 1    
AEROSOLS      |              
GASES UNDER   |Compressed gas
PRESSURE      |              
ACUTE TOXICITY|Category 4    
(oral)        |              
SKIN          |Category 2    
CORROSION/IRRI|              
TATION        |              
SERIOUS EYE   |Category 2A   
DAMAGE/ EYE   |              
IRRITATION    |              
TOXIC TO      |Category 2    
REPRODUCTION  |              
(Unborn child)|              
SPECIFIC      |Category 1    
TARGET ORGAN  |              
TOXICITY      |              
(SINGLE       |              
EXPOSURE)     |              
SPECIFIC      |Category 3    
TARGET ORGAN  |              
TOXICITY      |              
(SINGLE       |              
EXPOSURE)     |              
(Narcotic     |              
effects)      |              
SPECIFIC      |Category 2    
TARGET ORGAN  |              
TOXICITY      |              
(REPEATED     |              
EXPOSURE)     |              
ASPIRATION    |Category 1    
HAZARDq       |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame |Gas Cylinder |Health Hazard |Exclamation
Mark
       
Signal Word (GHS-US)         |Danger                                            
 
Hazard Statements (GHS-US)   |Extremely flammable aerosol.                      
 
                             |Contains gas under pressure; may explode if
heated. 
                             |Harmful if swallowed.                             
 
                             |Causes serious eye irritation.                    
 
                             |Causes skin irritation.                           
 
                             |Suspected of damaging the unborn child.           
 
                             |May be fatal if swallowed and enters airways.     
 
                             |Causes damage to organs.                          
 
                             |May cause drowsiness and dizziness.               
 
                             |May cause damage to organs through prolonged or   
 
                             |repeated exposure.                                
 
Precautionary Statements     |Prevention                                        
 
(GHS-US)                     |Obtain special instructions before use. Do not    
 
                             |handle until all safety precautions have been read
 
                             |and understood. Use personal protective equipment
as
                             |required. Wear protective gloves. Wear eye or face
 
                             |protection. Keep away from heat, hot surfaces,    
 
                             |sparks, open flames and other ignition sources. No
 
                             |smoking. Pressurized container: Do not pierce or  
 
                             |burn, even after use. Do not spray on an open
flame 
                             |or other ignition source. Use only outdoors or in
a 
                             |well-ventilated area. Do not breathe dust or mist.
 
                             |Do not eat, drink or smoke when using this
product. 
                             |Wash hands thoroughly after handling.             
 
                             |Response                                          
 
                             |Get medical attention if you feel unwell. IF      
 
                             |exposed: Call a POISON CENTER or physician. IF    
 
                             |INHALED: Remove victim to fresh air and keep at
rest
                             |in a position comfortable for breathing. Call a   
 
                             |POISON CENTER or physician if you feel unwell IF  
 
                             |SWALLOWED: Immediately call a POISON CENTER or    
 
                             |physician. Rinse mouth. Do NOT induce vomiting. IF
 
                             |ON SKIN: Wash with plenty of soap and water. Take 
 
                             |off contaminated clothing. Wash contaminated      
 
                             |clothing before reuse. If skin irritation occurs: 
 
                             |Get medical attention. IF IN EYES: Rinse
cautiously 
                             |with water for several minutes. Remove contact    
 
                             |lenses, if present and easy to do. Continue
rinsing.
                             |If eye irritation persists: Get medical attention.
 
                             |Storage                                           
 
                             |Store locked up. Protect from sunlight. Do not    
 
                             |expose to temperatures exceeding 50 °C/122 °F.
Store
                             |in a well-ventilated place.                       
 
                             |Disposal                                          
 
                             |Dispose of contents and container in accordance
with
                             |all local, regional, national and international   
 
                             |regulations.                                      
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                           
 
Supplemental label elements: DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE.
Contains
solvents which can cause permanent brain and nervous system damage. Intentional 
 
misuse by deliberately concentrating and inhaling the contents can be harmful or
 
fatal. WARNING: This product contains chemicals known to the State of California
 
to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE
 
ONLY. Please refer to the SDS for additional information. Keep upright in a
cool, 
dry place. Do not discard empty can in trash compactor.                         
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Acetone                         |67-64-1              |74.0    |                
 
Toluene                         |108-88-3             |15.0    |                
 
Methanol                        |67-56-1              |5.0     |                
 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest
 
in a position comfortable for breathing. If it                                  
 
is suspected that fumes are still present, the rescuer should wear an
appropriate 
mask or self-contained breathing apparatus. If not breathing, if breathing is   
 
irregular or if respiratory arrest occurs, provide artificial respiration or    
 
oxygen by trained personnel. It may be dangerous to the person providing aid to 
 
give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a  
 
poison center or physician. If unconscious, place in recovery position and get  
 
medical attention immediately. Maintain an open airway. Loosen tight clothing
such
as a collar, tie, belt or waistband.                                            
 
First-aid Measures After Skin Contact: Flush contaminated skin with plenty of   
 
water. Remove contaminated clothing and shoes. Continue to rinse for at least 10
 
minutes. Get medical attention. If necessary, call a poison center or physician.
 
Wash clothing before reuse. Clean shoes thoroughly before reuse.                
 
First-aid Measures After Eye Contact: Immediately flush eyes with plenty of
water,
occasionally lifting the upper and lower                                        
 
eyelids. Check for and remove any contact lenses. Continue to rinse for at least
 
10 minutes. Get medical attention. If necessary, call a poison center or        
 
physician.                                                                      
 
First-aid Measures After Ingestion: Get medical attention immediately. Call a   
 
poison center or physician. Wash out mouth with water. Remove dentures if any.  
 
Remove victim to fresh air and keep at rest in a position comfortable for       
 
breathing. If material has been swallowed and the exposed person is conscious,  
 
give small quantities of water to drink. Stop if the exposed person feels sick
as 
vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and  
 
cause damage. Do not induce vomiting. If vomiting occurs, the head should be
kept 
low so that vomit does not enter the lungs. Never give anything by mouth to an  
 
unconscious person. If unconscious, place in recovery position and get medical  
 
attention immediately. Maintain an open airway. Loosen tight clothing such as a 
 
collar, tie, belt or waistband.                                                 
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation: Can cause central nervous system (CNS)      
 
depression. May cause drowsiness and dizziness.                                 
 
Over-exposure signs/symptoms: Adverse symptoms may include the following:       
 
respiratory tract irritation Coughing nausea or vomiting Headache               
 
drowsiness/fatigue dizziness/vertigo Unconsciousness reduced fetal weight
increase
in fetal deaths skeletal malformations.                                         
 
Symptoms/Injuries After Skin Contact: Causes skin irritation.                   
 
Over-exposure signs/symptoms: Adverse symptoms may include the following:       
 
Irritation Redness reduced fetal weight increase in fetal deaths skeletal       
 
malformations.                                                                  
 
Symptoms/Injuries After Eye Contact: Causes serious eye irritation.             
 
Over-exposure signs/symptoms: Adverse symptoms may include the following: pain
or 
irritation Watering redness.                                                    
 
Symptoms/Injuries After Ingestion: Harmful if swallowed. Can cause central
nervous
system (CNS) depression. May be fatal if swallowed and enters airways.
Irritating 
to mouth, throat and stomach.                                                   
 
Over-exposure signs/symptoms: Adverse symptoms may include the following: nausea
 
or vomiting reduced fetal weight increase in fetal deaths skeletal
malformations. 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Notes to physician: Treat symptomatically. Contact poison treatment specialist  
 
immediately if large quantities have been ingested or inhaled.                  
 
Specific treatments: No specific treatment.                                     
 
Protection of first-aiders: No action shall be taken involving any personal risk
 
or without suitable training. If it is suspected that fumes are still present,
the
rescuer should wear an appropriate mask or self-contained breathing apparatus.
It 
may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation.

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use an extinguishing agent suitable for the       
 
surrounding fire.                                                               
 
Unsuitable Extinguishing Media: None known.                                     
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Extremely flammable aerosol. In a fire or if heated, a pressure    
 
increase will occur and the container may burst, with the risk of a subsequent  
 
explosion. Gas may accumulate in low or confined areas or travel a considerable 
 
distance to a source of ignition and flash back, causing fire or explosion.     
 
Bursting aerosol containers may be propelled from a fire at high speed. Runoff
to 
sewer may create fire or explosion hazard.                                      
 
Explosion Hazard: Decomposition products may include the following materials:   
 
carbon dioxide, carbon monoxide.                                                
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions: Promptly isolate the scene by removing all persons
from
the vicinity of the incident if there is a fire. No action shall be taken       
 
involving any personal risk or without suitable training. Move containers from  
 
fire area if this can be done without risk. Use water spray to keep fire-exposed
 
containers cool.                                                                
 
Protection During Firefighting: Fire-fighters should wear appropriate protective
 
equipment and self-contained breathing apparatus (SCBA) with a full face-piece  
 
operated in positive pressure mode.                                             
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:                                                               
 


6.1.1.      For Non-emergency Personnel
Protective Equipment: No action shall be taken involving any personal risk or   
 
without suitable training. Evacuate surrounding areas. Keep unnecessary and     
 
unprotected personnel from entering. In the case of aerosols being ruptured,
care 
should be taken due to the rapid escape of the pressurized contents and         
 
propellant. If a large number of containers are ruptured, treat as a bulk
material
spillage according to the instructions in the clean-up section. Do not touch or 
 
walk through spilled material. Shut off all ignition sources. No flares, smoking
 
or flames in hazard area. Avoid breathing vapor or mist. Provide adequate       
 
ventilation. Wear appropriate respirator when ventilation is inadequate. Put on 
 
appropriate personal protective equipment.                                      
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment: If specialised clothing is required to deal with the      
 
spillage, take note of any information in Section 8 on suitable and unsuitable  
 
materials. See also the information in "For non-emergency personnel".           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Avoid dispersal of spilled material and runoff and contact with soil, waterways,
 
drains and sewers. Inform the relevant authorities if the product has caused    
 
environmental pollution (sewers, waterways, soil or air).                       
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up:                                                        
 
Small spill: Stop leak if without risk. Move containers from spill area. Use    
 
spark-proof tools and explosion-proof equipment. Dilute with water and mop up if
 
water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry   
 
material and place in an appropriate waste disposal container. Dispose of via a 
 
licensed waste disposal contractor.                                             
 
Large spill: Stop leak if without risk. Move containers from spill area. Use    
 
spark-proof tools and explosion-proof equipment. Approach release from upwind.  
 
Prevent entry into sewers, water courses, basements or confined areas. Wash     
 
spillages into an effluent treatment plant or proceed as follows. Contain and   
 
collect spillage with non-combustible, absorbent material e.g. sand, earth,     
 
vermiculite or diatomaceous earth and place in container for disposal according
to
local regulations (see Section 13). Dispose of via a licensed waste disposal    
 
contractor. Contaminated absorbent material may pose the same hazard as the     
 
spilled product. Note: see Section 1 for emergency contact information and
Section
13 for waste disposal.                                                          
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Put on appropriate personal protective       
 
equipment (see Section 8). Pressurized container: protect from sunlight and do
not
expose to temperatures exceeding 50°C. Do not pierce or burn, even after use.   
 
Avoid exposure - obtain special instructions before use. Avoid exposure during  
 
pregnancy. Do not handle until all safety precautions have been read and        
 
understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or  
 
mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation.  
 
Wear appropriate respirator when ventilation is inadequate. Store and use away  
 
from heat, sparks, open flame or any other ignition source. Use explosion-proof 
 
electrical (ventilating, lighting and material handling) equipment. Use only    
 
non-sparking tools. Empty containers retain product residue and can be
hazardous. 
Hygiene Measures: Eating, drinking and smoking should be prohibited in areas
where
this material is handled, stored and processed. Workers should wash hands and
face
before eating, drinking and smoking. Remove contaminated clothing and protective
 
equipment before entering eating areas. See also Section 8 for additional       
 
information on hygiene measures. Wash hands, forearms and face thoroughly after 
 
handling chemical products, before eating, smoking and using the lavatory and at
 
the end of the working period. Appropriate techniques should be used to remove  
 
potentially contaminated clothing. Wash contaminated clothing before reusing.   
 
Ensure that eyewash stations and safety showers are close to the workstation    
 
location.                                                                       
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Store in accordance with local regulations. Store away from 
 
direct sunlight in a dry, cool and well-ventilated area, away from incompatible 
 
materials (see Section 10) and food and drink. Protect from sunlight. Store
locked
up. Eliminate all ignition sources. Use appropriate containment to avoid        
 
environmental contamination.                                                    
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Occupational exposure limits:                                                   
 
Ingredient name                                                                 
 
Exposure limits                                                                 
 
                                                                                
 
Acetone                                                                         
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
Toluene                                                                         
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
Methanol                                                                        
 
ACGIH TLV (United States, 4/2014).                                              
 
TWA: 500 ppm 8 hours.                                                           
 
TWA: 1188 mg/m³ 8 hours.                                                        
 
STEL: 750 ppm 15 minutes.                                                       
 
STEL: 1782 mg/m³ 15 minutes.                                                    
 
NIOSH REL (United States, 10/2013).                                             
 
TWA: 250 ppm 10 hours.                                                          
 
TWA: 590 mg/m³ 10 hours.                                                        
 
OSHA PEL (United States, 2/2013).                                               
 
TWA: 1000 ppm 8 hours.                                                          
 
TWA: 2400 mg/m³ 8 hours.                                                        
 
                                                                                
 
OSHA PEL Z2 (United States, 2/2013).                                            
 
TWA: 200 ppm 8 hours.                                                           
 
CEIL: 300 ppm                                                                   
 
AMP: 500 ppm 10 minutes.                                                        
 
NIOSH REL (United States, 10/2013).                                             
 
TWA: 100 ppm 10 hours.                                                          
 
TWA: 375 mg/m³ 10 hours.                                                        
 
STEL: 150 ppm 15 minutes.                                                       
 
STEL: 560 mg/m³ 15 minutes.                                                     
 
ACGIH TLV (United States, 4/2014).                                              
 
TWA: 20 ppm 8 hours.                                                            
 
                                                                                
 
ACGIH TLV (United States, 4/2014).                                              
 
Absorbed through skin.                                                          
 
TWA: 200 ppm 8 hours.                                                           
 
TWA: 262 mg/m³ 8 hours.                                                         
 
STEL: 250 ppm 15 minutes.                                                       
 
STEL: 328 mg/m³ 15 minutes.                                                     
 
NIOSH REL (United States, 10/2013).                                             
 
Absorbed through skin.                                                          
 
TWA: 200 ppm 10 hours.                                                          
 
TWA: 260 mg/m³ 10 hours.                                                        
 
STEL: 250 ppm 15 minutes.                                                       
 
STEL: 325 mg/m³ 15 minutes.                                                     
 
OSHA PEL (United States, 2/2013).                                               
 
TWA: 200 ppm 8 hours.                                                           
 
TWA: 260 mg/m³ 8 hours.                                                         
 
                                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Use only with adequate ventilation. Use process   
 
Controls                     |enclosures, local exhaust ventilation or other    
 
                             |engineering controls to keep worker exposure to   
 
                             |airborne contaminants below any recommended or    
 
                             |statutory limits. The engineering controls also
need
                             |to keep gas, vapor or dust concentrations below
any 
                             |lower explosive limits. Use explosion proof       
 
                             |ventilation equipment.                            
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Chemical-resistant, impervious gloves complying
with
                             |an approved standard should be worn at all times  
 
                             |when handling chemical products if a risk
assessment
                             |indicates this is necessary. Considering the      
 
                             |parameters specified by the glove manufacturer,   
 
                             |check during use that the gloves are still
retaining
                             |their protective properties. It should be noted
that
                             |the time to breakthrough for any glove material
may 
                             |be different for different glove manufacturers. In
 
                             |the case of mixtures, consisting of several       
 
                             |substances, the protection time of the gloves
cannot
                             |be accurately estimated.                          
 
Eye Protection               |Safety eyewear complying with an approved standard
 
                             |should be used when a risk assessment indicates
this
                             |is necessary to avoid exposure to liquid splashes,
 
                             |mists, gases or dusts. If contact is possible, the
 
                             |following protection should be worn, unless the   
 
                             |assessment indicates a higher degree of
protection: 
                             |chemical splash goggles.                          
 
Skin and Body Protection     |Body protection: Personal protective equipment for
 
                             |the body should be selected based on the task
being 
                             |performed and the risks involved and should be    
 
                             |approved by a specialist before handling this     
 
                             |product. When there is a risk of ignition from    
 
                             |static electricity, wear antistatic protective    
 
                             |clothing. For the greatest protection from static 
 
                             |discharges, clothing should include anti-static   
 
                             |overalls, boots and gloves.                       
 
                             |Other skin protection: Appropriate footwear and
any 
                             |additional skin protection measures should be     
 
                             |selected based on the task being performed and the
 
                             |risks involved and should be approved by a        
 
                             |specialist before handling this product.          
 
Respiratory Protection       |Use a properly fitted, air-purifying or air-fed   
 
                             |respirator complying with an approved standard if
a 
                             |risk assessment indicates this is necessary.      
 
                             |Respirator selection must be based on known or    
 
                             |anticipated exposure levels, the hazards of the   
 
                             |product and the safe working limits of the
selected 
                             |respirator.                                       
 
Thermal Hazard Protection    |Emissions from ventilation or work process
equipment
                             |should be checked to ensure they comply with the  
 
                             |requirements of environmental protection          
 
                             |legislation. In some cases, fume scrubbers,
filters 
                             |or engineering modifications to the process       
 
                             |equipment will be necessary to reduce emissions to
 
                             |acceptable levels.                                
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid.                                    
 
Appearance                          |                                           
 
Odor                                |Not available.                             
 
Odor Threshold                      |Not available.                             
 
pH                                  |7                                          
 
Relative Evaporation Rate           |5.6 (butyl acetate = 1)                    
 
(butylacetate=1)                    |                                           
 
Melting Point                       |Not available.                             
 
Freezing Point                      |                                           
 
Boiling Point                       |Not available.                             
 
Flash Point                         |Closed cup: -8°C (17.6°F) [Pensky-Martens  
 
                                    |Closed Cup]                                
 
Auto-ignition Temperature           |Not available.                             
 
Decomposition Temperature           |Not available.                             
 
Flammability (solid, gas)           |Not available.                             
 
Vapor Pressure                      |13.5 kPa (101.325 mm Hg) [at 20°C]         
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |0.81                                       
 
Specific Gravity                    |                                           
 
Solubility                          |Not available.                             
 
Partition coefficient:              |Not available.                             
 
n-octanol/water                     |                                           
 
Viscosity                           |Kinematic (room temperature): <0.07 cm2/s
(<7
                                    |cSt)                                       
 
                                    |Kinematic (40°C (104°F)): <0.07 cm2/s (<7  
 
                                    |cSt)                                       
 
Lower Flammable Limit               |Lower: 1%                                  
 
Upper Flammable Limit               |Upper: 36.5%                               
 


9.2.  Other Information
                                                                                
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No specific test data related to reactivity available for this product or its   
 
ingredients.                                                                    
 


10.2      Chemical Stability
The product is stable.                                                          
 


10.3      Possibility of Hazardous Reactions
Under normal conditions of storage and use, hazardous reactions will not occur. 
 


10.4      Conditions to Avoid
Avoid all possible sources of ignition (spark or flame).                        
 


10.5      Incompatible Materials
No specific data.                                                               
 


10.6      Hazardous Decomposition Products
Under normal conditions of storage and use, hazardous decomposition products    
 
should not be produced.                                                         
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation:                                                      
 
Serious Eye Damage/Irritation: Causes serious eye irritation.                   
 
Respiratory or Skin Sensitization: Not available.                               
 
Germ Cell Mutagenicity: Not available.                                          
 
Carcinogenicity: Not available.                                                 
 
Reproductive Toxicity: Not available.                                           
 
Specific Target Organ Toxicity (Single Exposure):                               
 
Specific Target Organ Toxicity (Repeated Exposure):                             
 
Aspiration Hazard:                                                              
 
Symptoms/Injuries After Inhalation: Can cause central nervous system (CNS)      
 
depression. May cause drowsiness and                                            
 
Dizziness. Adverse symptoms may include the following:  respiratory tract       
 
irritation Coughing nausea or vomiting Headache drowsiness/fatigue              
 
dizziness/vertigo Unconsciousness reduced fetal weight increase in fetal deaths 
 
skeletal malformations.                                                         
 
Symptoms/Injuries After Skin Contact: Causes skin irritation. Adverse symptoms
may
include the following: Irritation Redness reduced fetal weight increase in fetal
 
deaths skeletal malformations                                                   
 
Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Adverse     
 
symptoms may include the following: pain or irritation Watering  redness        
 
Symptoms/Injuries After Ingestion: Harmful if swallowed. Can cause central
nervous
system (CNS) depression. May be                                                 
 
fatal if swallowed and enters airways. Irritating to mouth, throat and stomach. 
 
Adverse symptoms may include the following: nausea or vomiting reduced fetal    
 
weight increase in fetal deaths skeletal malformations                          
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
                                                                                
 
Product/ingredient name                                                         
 
Result                                                                          
 
Species                                                                         
 
Exposure                                                                        
 
                                                                                
 
Acetone                                                                         
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
Toluene                                                                         
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
                                                                                
 
Methanol                                                                        
 
Acute EC50 20.565 mg/l Marine water                                             
 
Acute LC50 6000000 ?g/l Fresh water                                             
 
Acute LC50 10000 ?g/l Fresh water                                               
 
Acute LC50 5600 ppm Fresh water                                                 
 
Chronic NOEC 4.95 mg/l Marine water                                             
 
Chronic NOEC 0.016 ml/L Fresh water                                             
 
Chronic NOEC 0.1 ml/L Fresh water                                               
 
                                                                                
 
Chronic NOEC 5 ?g/l Marine water                                                
 
                                                                                
 
Acute EC50 12500 ?g/l Fresh water                                               
 
                                                                                
 
Acute EC50 11600 ?g/l Fresh water                                               
 
                                                                                
 
Acute EC50 6000 ?g/l Fresh water                                                
 
                                                                                
 
                                                                                
 
Acute LC50 5500 ?g/l Fresh water                                                
 
Chronic NOEC 1000 ?g/l Fresh water                                              
 
Acute EC50 16.912 mg/l Marine water                                             
 
Acute LC50 2500000 ?g/l Marine water                                            
 
                                                                                
 
Acute LC50 3289 mg/l Fresh water                                                
 
                                                                                
 
Acute LC50 290 mg/l Fresh water                                                 
 
Chronic NOEC 9.96 mg/l Marine water                                             
 
Algae - Ulva pertusa                                                            
 
Crustaceans - Gammarus pulex                                                    
 
Daphnia - Daphnia magna                                                         
 
Fish - Poecilia reticulata                                                      
 
Algae - Ulva pertusa                                                            
 
Crustaceans - Daphniidae                                                        
 
Daphnia - Daphnia magna -                                                       
 
Neonate                                                                         
 
Fish - Gasterosteus aculeatus - Larvae                                          
 
Algae - Pseudokirchneriella                                                     
 
Subcapitata                                                                     
 
Crustaceans - Gammarus                                                          
 
pseudolimnaeus - Adult                                                          
 
Daphnia - Daphnia magna -                                                       
 
Juvenile (Fledgling,Hatchling, Weanling)                                        
 
Fish - Oncorhynchus kisutch -Fry                                                
 
Daphnia - Daphnia magna                                                         
 
Algae - Ulva pertusa                                                            
 
Crustaceans - Crangon crangon - Adult                                           
 
Daphnia - Daphnia magna -                                                       
 
Neonate                                                                         
 
Fish - Danio rerio - Egg                                                        
 
Algae - Ulva pertusa                                                            
 
96 hours                                                                        
 
48 hours                                                                        
 
48 hours                                                                        
 
96 hours                                                                        
 
96 hours                                                                        
 
21 days                                                                         
 
21 days                                                                         
 
                                                                                
 
42 days                                                                         
 
                                                                                
 
72 hours                                                                        
 
                                                                                
 
48 hours                                                                        
 
                                                                                
 
48 hours                                                                        
 
                                                                                
 
                                                                                
 
96 hours                                                                        
 
96 hours                                                                        
 
96 hours                                                                        
 
48 hours                                                                        
 
                                                                                
 
48 hours                                                                        
 
                                                                                
 
96 hours                                                                        
 
96 hours                                                                        
 
                                                                                
 


12.2. Persistence and Degradability
                                                                                
 
Product/ingredient name                                                         
 
Aquatic half-life                                                               
 
Photolysis                                                                      
 
Biodegradability                                                                
 
                                                                                
 
Acetone                                                                         
 
Toluene                                                                         
 
-                                                                               
 
-                                                                               
 
-                                                                               
 
-                                                                               
 
Readily                                                                         
 
Readily                                                                         
 
                                                                                
 


12.3. Bioaccumulative Potential
                                                                                
 
Product/ingredient name                                                         
 
LogPow                                                                          
 
BCF                                                                             
 
Potential                                                                       
 
                                                                                
 
Toluene                                                                         
 
Methanol                                                                        
 
-                                                                               
 
-                                                                               
 
90                                                                              
 
<10                                                                             
 
Low                                                                             
 
low                                                                             
 
                                                                                
 


12.4. Mobility in Soil
Soil/water partition coefficient (KOC) : Not available.                         
 


12.5. Other Adverse Effects
No known significant effects or critical hazards.                               
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: The generation of waste should be avoided or    
 
minimized wherever possible. Disposal of this product, solutions and any        
 
by-products should at all times comply with the requirements of environmental   
 
protection and waste disposal legislation and any regional local authority      
 
requirements. Dispose of surplus and non-recyclable products via a licensed
waste 
disposal contractor. Waste should not be disposed of untreated to the sewer
unless
fully compliant with the requirements of all authorities with jurisdiction.
Waste 
packaging should be recycled. Incineration or landfill should only be considered
 
when recycling is not feasible. This material and its container must be disposed
 
of in a safe way. Empty containers or liners may retain some product residues.
Do 
not puncture or incinerate container.                                           
 
Additional Information:                                                         
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |AEROSOLS                                                  
 
Hazard Class         |2.1                    |<PICTOGRAM PHRASE>                
 
                     |                       |[pic]                             
 
Identification Number|UN1950                 |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |AEROSOLS                                                  
 
Hazard Class         |2.1                                                       
 
Identification Number|UN1950                                                    
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |[pic]                              
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |F-D                   |                                   
 
EmS-No. (Spillage)   |S-U                   |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |AEROSOLS, flammable                                       
 
Identification Number|UN1950                 |<PICTOGRAM PHRASE>                
  
                     |                       |[pic]                             
  
Hazard Class         |2.1                    |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA Section 311/312 Hazard Classes |                                           
 
Toxic Substances Control Act (TSCA) |                                           
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Prop. 65: WARNING: This product contains chemicals known to the State
 
of California to cause cancer and birth defects or other reproductive harm.     
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |3/13/2015                                                      
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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