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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: AUTORF +LSPR 6PK AUTO TRUCK BED COATING CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Topcoat/ Aerosol 1.3. Name, Address, and Telephone of the Responsible Party Company Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA Phone 1.4. Emergency Telephone Number Emergency | 24 Hour Hotline: 847-367-7700 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |category 1 Aerosol | Flammable |category 1 Liquid | Acute |category 5 Toxicity, Oral| Acute |category 5 Toxicity, | Dermal | Skin |category 2 Irritation | Eye Irritation|category 2 Acute |category 4 Toxicity, | Inhalation | STOT, single |category 3, exposure |RTI STOT, single |category 3, NE exposure | Aspiration |category 2 Hazard | Eye Irritation|category 2B Flammable |category 1 Aerosol | Germ Cell |category 1B Mutagenicity | Carcinogenicit|category 1A y | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Health Hazard |Flame Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H222: Extremely flammable aerosol. |H224: Extremely flammable liquid and vapour. |H303: May be harmful if swallowed. |H313: May be harmful in contact with skin. |H315: Causes skin irritation. |H319: Causes serious eye irritation. |H332: Harmful if inhaled. |H335: May cause respiratory irritation. |H336: May cause drowsiness or dizziness. |H305: May be harmful if swallowed and enters |airways. |H320: Causes eye irritation. |H280: Contains gas under pressure; may explode if |heated |H340: May cause genetic defects. Classified as |mutagenic Category 1 if one |ingredient is present at or above 0.1%. Applies to |liquids, solids (w/w units) and gases (v/v). The |substance may also have its own exposure limit. |Routes of exposure are dependent on ingredient form. | |H350: May cause cancer. Classified as carcinogenic |Category 1 on the basis of |epidemiological and/or animal data. Mixtures are |classified as carcinogenic when at least 1 |ingredient has been classified as carcinogenic and |is present at 0.1% or above Routes of exposure are |dependant on ingredient form.May cause cancer <state |route of exposure if it is conclusively proven that |no other routes of exposure cause the hazard>. Precautionary Statements |P211: Do not spray on an open flame or other (GHS-US) |ignition source. |P220: Keep/Store away from clothing/.../combustible |materials. |P235: Keep cool. |P251: Pressurized container: Do not pierce or burn, |even after use. |P375: Fight fire remotely due to the risk of |explosion. |P102: Keep out of reach of children. |P103: Read label before use. |P202: Do not handle until all safety precautions |have been read and understood. |P234: Keep only in original container. |P260: Do not breathe |dust/fume/gas/mist/vapours/spray. |P261: Avoid breathing |dust/fume/gas/mist/vapours/spray. |P262: Do not get in eyes, on skin, or on clothing. |P264: Wash ... thoroughly after handling. |P270: Do not eat, drink or smoke when using this |product. |P271: Use only outdoors or in a well-ventilated |area. |P273: Avoid release to the environment. |P280: Wear protective gloves/protective clothing/eye |protection/face protection. |P281: Use personal protective equipment as required. | |P285: In case of inadequate ventilation wear |respiratory protection. |P312: Call a POISON CENTER or doctor/physician if |you feel unwell. |P351: Rinse cautiously with water for several |minutes. |P374: Fight fire with normal precautions from a |reasonable distance. |P402: Store in a dry place. |P210: Keep away from heat/sparks/open flames/hot |surfaces. - No smoking. |P410+P412: Protect from sunlight. Do no expose to |temperatures exceeding 50�C/ 122�F. |P240: Ground/bond container and receiving equipment. | |P241: Use explosion-proof |electrical/ventilating/lighting/.../ equipment. |P242: Use only non-sparking tools. |P243: Take precautionary measures against static |discharge. |P303+P361+P353: IF ON SKIN (or hair): Remove/Take |off immediately all contaminated clothing. Rinse |skin |with water/shower. |P370+P378: In case of fire: Use ... for extinction. |P403+P235: Store in a well-ventilated place. Keep |cool. |P501: Dispose of contents/container to ... |P321: Specific treatment (see ... on this label). |P352: Wash with plenty of soap and water. |P362: Take off contaminated clothing and wash before |reuse. |P332+P313: If skin irritation occurs: Get medical |advice/attention. |P305+P351+P338: IF IN EYES: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. |P337+P313: If eye irritation persists: Get medical |advice/attention. |P304+P340: IF INHALED: Remove victim to fresh air |and keep at rest in a position comfortable for |breathing. |P405: Store locked up. |P403+P233: Store in a well-ventilated place. Keep |container tightly closed. |P201: Obtain special instructions before use. |P308+P313: IF exposed or concerned: Get medical |advice/attention. |P302+P350: IF ON SKIN: Gently wash with plenty of |soap and water. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. First-aid Measures After Skin Contact: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed. First-aid Measures After Ingestion: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: FLASH POINT IS LESS THAN 20 �. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. Closed containers may explode when exposed to extreme heat due to buildup of steam. No unusual fire or explosion hazards noted. Explosion Hazard: FLASH POINT IS LESS THAN 20 �. F. - EXTREMELY FLAMMABLE LIQUID AND VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. Closed containers may explode when exposed to extreme heat due to buildup of steam. No unusual fire or explosion hazards noted. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Evacuate area and fight fire from a safe distance. Full protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and nonsparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 � F. Store large quantities in buildings designed and protected for storage of NFPA Class I flammable liquids. Contents under pressure. Do not expose to heat or store above 120 � F. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep away from heat, sparks, flame and sources of ignition. Avoid excess heat. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Chemical Name CAS-No. Weight % Less Than ACGIH TLVTWA ACGIH TLVSTEL OSHA PEL-TWA OSHA PEL-CEILING Acetone 67-64-1 35.0 500 ppm 750 ppm 1000 ppm N.E. Liquefied Petroleum Gas 68476-86-8 30.0 N.E. N.E. N.E. N.E. Xylene (mixed isomers) 1330-20-7 10.0 100 ppm 150 ppm 100 ppm N.E. n-Butyl Acetate 123-86-4 10.0 150 ppm 200 ppm 150 ppm N.E. Ethylbenzene 100-41-4 5.0 20 ppm 125 ppm 100 ppm N.E. Propylene Glycol Monobutyl Ether 5131-66-8 5.0 N.E. N.E. N.E. N.E. Carbon Black 1333-86-4 1.0 3 mg/m3 (Inhalable Dust) N.E. 3.5 mg/m3 N.E. 8.2. Exposure Controls Appropriate Engineering |Use process enclosures, local exhaust ventilation, Controls |or other engineering controls to control airborne |levels below recommended exposure limits. Use |explosion-proof ventilation equipment. Prevent |build-up of vapors by opening all doors and windows |to achieve cross-ventilation. Provide general |dilution of local exhaust ventilation in volume and |pattern to keep TLV of hazardous ingredients below |acceptable limits. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Use safety eyewear designed to protect against |splash of liquids. Skin and Body Protection |SKIN PROTECTION: Use impervious gloves to prevent |skin contact and absorption of this material through |the skin. Nitrile or Neoprene gloves may afford |adequate skin protection. Use gloves to prevent |prolonged skin contact. |OTHER PROTECTIVE EQUIPMENT: Refer to safety |supervisor or industrial hygienist for further |information regarding personal protective equipment |and its application. Refer to safety supervisor or |industrial hygienist for further guidance regarding |types of personal protective equipment and their |applications. Respiratory Protection |A respiratory protection program that meets OSHA |1910.134 and ANSI Z88.2 requirements must be |followed whenever workplace conditions warrant a |respirator's use. A NIOSH/MSHA approved air |purifying respirator with organic vapor cartridge or |canister may be permissible under certain |circumstances where airborne concentrations are |expected to exceed exposure limits. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Aerosolized Mist Odor |Solvent Like Odor Threshold |N.E. pH |N.A. Relative Evaporation Rate |Faster than Ether (butylacetate=1) | Melting Point | Freezing Point |N.D. Boiling Point, �C |-34 - 415 Flash Point |>93 �C Auto-ignition Temperature |No Information Decomposition Temperature | Flammability (solid, gas) |Does not Support Combustion Vapor Pressure |N.D. Relative Vapor Density at 20 �C |Heavier than Air Relative Density |0.751 Specific Gravity | Solubility |Slight in Water Partition coefficient: |No Information n-octanol/water | Viscosity |N.D. Lower Flammable Limit, vol% |0.7 Upper Flammable Limit, vol% |13.0 9.2. Other Information VOLATILE ORGANIC COMPOUNDS, g/L: 528 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability This product is stable under normal storage conditions. 10.3 Possibility of Hazardous Reactions 10.4 Conditions to Avoid Avoid temperatures above 120 � F. Avoid all possible sources of ignition. Avoid contact with strong acid and strong bases. 10.5 Incompatible Materials Incompatible with strong oxidizing agents, strong acids and strong alkalies. 10.6 Hazardous Decomposition Products By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: The acute effects of this product have not been tested. Data on individual components are tabulated below: CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50 1330-20-7 Xylene (mixed isomers) 4300 mg/kg Rat N.I. 47635 mg/L Rat 123-86-4 n-Butyl Acetate N.I. >17600 mg/kg Rabbit N.I. 100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat 5131-66-8 Propylene Glycol 1900 mg/kg Rat N.I. N.I. Monobutyl Ether Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation. Symptoms/Injuries After Skin Contact: Substance may cause slight skin irritation. Prolonged or repeated contact may cause skin irritation. May cause skin irritation. Allergic reactions are possible. Symptoms/Injuries After Eye Contact: Causes Serious Eye Irritation. Symptoms/Injuries After Ingestion: Aspiration hazard if swallowed; can enter lungs and cause damage. Harmful if swallowed. Chronic Symptoms: IARC lists Ethylbenzene as a possible human carcinogen (group 2B). Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of time to excessive concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other animal species (i.e., mouse and hamster) under similar circumstances and study conditions. Epidemiological studies of North American workers show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black. Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified as a human carcinogen" by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of carbon black in the formula. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Product is a mixture of listed components. Product is a mixture of listed components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Paint Products in Limited Quantities Hazard Class |N.A. |<PICTOGRAM PHRASE> Identification Number|N.A. | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols Hazard Class |2.1 Identification Number|1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols Identification Number|1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Sara Section 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372: Chemical Name CAS-No. Xylene (mixed isomers) 1330-20-7 Ethylbenzene 100-41-4 SARA Section 311/312 Hazard Classes |This product has been reviewed according to |the EPA 'Hazard Categories' promulgated under |Sections 311 and 312 of the Superfund |Amendment and Reauthorization Act of 1986 |(SARA Title III) and is considered, under |applicable definitions, to meet the following |categories: |Fire Hazard, Pressure Hazard, Acute Health |Hazard, Chronic Health Hazard Toxic Substances Control Act (TSCA) |This product contains the following chemical |substances subject to the reporting |requirements of TSCA 12(B) if exported from |the United States: No TSCA components exist |in this product. 15.2 US State Regulations <COMPONENT> CALIFORNIA PROPOSITION 65: Warning: This products contains a substance known to the State of California to cause cancer. Chemical Name CAS-No. Ethylbenzene 100-41-4 Carbon Black 1333-86-4 CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS: Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive harm. Chemical Name CAS-No. Toluene 108-88-3 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |1/7/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|H225 | Highly flammable liquid and vapour. -- | | ----|H226 |Flammable liquid and vapour. -- | | ----|H251 |Self-heating: may catch fire. -- | | ----|H302 |Harmful if swallowed. -- | | ----|H312 |Harmful in contact with skin. -- | | |H315 |Causes skin irritation. |H319 |Causes serious eye irritation. |H332 |Harmful if inhaled. |H336 |May cause drowsiness or dizziness. |H340 |May cause genetic defects <state route of | |exposure if it is conclusively proven that no | |other routes of exposure cause the hazard>. |H350 |May cause cancer <state route of exposure if | |it is conclusively proven that no other | |routes of exposure cause the hazard>. Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.