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SDS Sheet 0065351Printer Friendly View
Safety Data Sheet Date of Issue: 03-Jun-2015 |Revision Date: 03-Jun-2015 |Revision Number: 2 Imperial Supplies Part Number: 0065350 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 6535 CITRUS DEGREASER-12 PK CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Degreaser. 1.3. Name, Address, and Telephone of the Responsible Party Company American Jetway Corporation 34136 Myrtle Street Wayne, MI 48184-0126 Phone 1.4. Emergency Telephone Number Emergency | Chemtrec 1-800-262-8200, 734-721-5930 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2A damage/eye | irritation | Skin |Category 1 Sensitization | Specific |Category 3 target organ | toxicity | (single | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 1 aerosols | Gases under |Compressed Gas pressure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamat|Health |Flame |Gas | | |ion Mark|Hazard | |Cylinder| | Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Causes skin irritation |Causes serious eye irritation |May cause an allergic skin reaction |May cause drowsiness or dizziness |May be fatal if swallowed and enters airways |Extremely flammable aerosol |Contains gas under pressure; may explode if heated Precautionary Statements |Prevention (GHS-US) |Wash face, hands and any exposed skin thoroughly |after handling |Wear protective gloves/protective clothing/eye |protection/face protection |Avoid breathing dust/fume/gas/mist/vapors/spray |Contaminated work clothing should not be allowed out |of the workplace |Use only outdoors or in a well-ventilated area |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use |Response |Specific treatment (see first aid on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention |IF ON SKIN: Wash with plenty of soap and water. |Take off contaminated clothing and wash before reuse | |If skin irritation or rash occurs: Get medical |advice/attention |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician if you feel |unwell |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |Storage |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Protect from sunlight. Do not expose to temperatures |exceeding 50 Â°C/122 Â°F |Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Toxic to aquatic life with long lasting effects 3E-05% of the mixture consists of ingredient(s) of unknown toxicity 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) ACETONE |67-64-1 |50-60 | METHYL ACETATE |79-20-9 |20-30 | PROPANE/ISOBUTANE/N-BUTANE |68476-86-8 |10-20 | HYDROTREATED LIGHT DISTILLATES |64742-47-8 |1-10 | D-LIMONENE |5989-27-5 |1-10 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Artificial respiration and/or oxygen may be necessary. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. First-aid Measures After Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. Call a physician or Poison Control Center immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: May be harmful if swallowed. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes eye irritation. Symptoms/Injuries After Ingestion: May cause respiratory irritation. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media: Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: No information available. Explosion Hazard: Sensitivity to Mechanical Impact none. Sensitivity to Static Discharge Yes. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Absorb with sand, clay, or other suitable material. Hard surfaces may be mopped with water. Remove all sources of ignition. Avoid contact with the skin and the eyes. Evacuate personnel to be safe areas.Keep people away from and upwind of spill/leak. Contents under pressure. Do not puncture or incinerate cands. Wear protective gloves/clothing and eye/face protection. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Clean contaminated surface thoroughly. After cleaning, flush away traces with water. Take precautionary measures against static discharges. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible products: Strong acids, alkalis, or oxidizing agents. Aerosol Level: 2 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 METHYL ACETATE 79-20-9 STEL: 250 ppm TWA: 200 ppm TWA: 200 ppm TWA: 610 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 610 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 760 mg/m3 IDLH: 3100 ppm TWA: 200 ppm TWA: 610 mg/m3 STEL: 250 ppm STEL: 760 mg/m3 PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 74-98-6: TWA: 1000 ppm 106-97-8: STEL: 1000 ppm 75-28-5: STEL: 1000 ppm 74-98-6:TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 106-97-8: (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 74-98-6:IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 106-97-8:TWA: 800 ppm TWA: 1900 mg/m3 75-28-5:TWA: 800 ppm TWA: 1900 mg/m3 HYDROTREATED LIGHT DISTILLATES 64742-47-8 TWA: 200 PPM 8 hours - - Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Aerosol Appearance |Clear Odor |Light Vanilla Scent Odor Threshold |No information available pH |No information available Relative Evaporation Rate |No information available (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |-97 Â°C / -142 Â°F Based on propellant Auto-ignition Temperature |No information available, Not applicable Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |0.818 Solubility |Practically insoluble Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information VOC Content(%): 17.73 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Strong acids, alkalis, or oxidizing agents. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Irritating to skin. Avoid contact with skin. Repeated exposure may cause skin dryness or cracking. Prolonged skin contact may defat the skin and produce dermatitis. Serious Eye Damage/Irritation: Irritating to eyes. Avoid contact with eyes. Respiratory or Skin Sensitization:Irritating to skin. Avoid contact with skin. Repeated exposure may cause skin dryness or cracking. Prolonged skin contact may defat the skin and produce dermatitis. Germ Cell Mutagenicity: None known. Carcinogenicity: The table below indicates whether each agency has evaluated a listed ingredient as a carcinogen. Reproductive Toxicity: This product does not contain any known or suspected reproductive hazards. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. May cause drowsiness and dizziness. Target Organ Effects: Central nervous system, Eyes, Respiratory system, Skin. Neurological effects: Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Specific Target Organ Toxicity (Repeated Exposure): None under normal use conditions. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Vapors may irritate throat and respiratory system. May cause drownsiness and dizziness based on components. May cause irritation of respiratory tract. Avoid breathing vapors or mists. Harmful if swallowed. May be fatal if swallowed and enters airways. May cause irritation when inhaled to respiratory system. Symptoms/Injuries After Skin Contact: Irritation to skin. Symptoms/Injuries After Eye Contact: Irritation to eyes. Symptoms/Injuries After Ingestion: May be harmful or fatal if swallowed. Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates ACETONE 67-64-1 - 4.74 - 6.33 mL/L LC50 Oncorhynchus mykiss 96h 6210 - 8120 mg/L LC50 Pimephales promelas 96h static 8300 mg/L LC50 Lepomis macrochirus 96h - 10294 - 17704 mg/L EC50 Daphnia magna 48h Static 12600 - 12700 mg/L EC50 Daphnia magna 48h METHYL ACETATE 79-20-9 120 mg/L EC50 Desmodesmus subspicatus 72h 250 - 350 mg/L LC50 Brachydanio rerio 96h static 295 - 348 mg/L LC50 Pimephales promelas 96h flow through - 1026.7 mg/L EC50 Daphnia magna 48h PROPANE/ISOBUTANE/NBUTANE 68476-86-8 - - - - HYDROTREATED LIGHT DISTILLATES 64742-47-8 - 2.2 mg/L LC50 Lepomis macrochirus 96h static 2.4 mg/L LC50 Oncorhynchus mykiss 96h static 45 mg/L LC50 Pimephales promelas 96h flow-through - - D-LIMONENE 5989-27-5 - 0.619 - 0.796 mg/L LC50 Pimephales promelas 96h flow-through 35 mg/L LC50 Oncorhynchus mykiss 96h - - 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. Chemical Name log Pow ACETONE 67-64-1 -0.24 METHYL ACETATE 79-20-9 0.18 PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 2.8 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste Disposal Methods: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging: Do not re-use empty containers. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |CONSUMER COMMODITY ORM-D or LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313:Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Clean Water Act: This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): CERCLA: This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ ACETONE 67-64-1 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ SARA Section 311/312 Hazard Classes |Acute Health Hazard |Yes |Chronic Health Hazard |Yes |Fire Hazard |Yes |Sudden Release of Pressure Hazard Yes |Reactive Hazard |no Toxic Substances Control Act (TSCA) |Chemical Name |TSCA | |ACETONE |X | |METHYL ACETATE |X | |PROPANE/ISOBUTA |NE/N-BUTANE |X | |HYDROTREATED |LIGHT DISTILLATES |X | |D-LIMONENE |X | 15.2 US State Regulations <COMPONENT> California Proposition 65: This product contains the following Proposition 65 chemicals: Chemical Name California Prop. 65 METHANOL - 67-56-1 Carcinogen ACETALDEHYDE - 75-07-0 Carcinogen U.S. State Right-to-Know Regulations: Chemical Name New Jersey Massachusetts Pennsylvania ACETONE 67-64-1 X X X METHYL ACETATE 79-20-9 X X X EPA Pesticide Registration Number: Not applicable. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |03-Jun-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.