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SAFETY DATA SHEET SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 6528 BATTERY PROTECTOR GREASE-12 PK CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Battery Protectant. 1.3. Name, Address, and Telephone of the Responsible Party Company: Imperial Supplies LLC 789 Armed Forces Drive P.O. Box 11008 Green Bay, WI 53407-1008 Phone: 1.4. Emergency Telephone Number Emergency | Chemtrec 1-800-424-9300, 1-800-558-2808 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2B damage/eye | irritation | Specific |Category 3 target organ | toxicity | (single | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 1 aerosols | Gases under |Compressed Gas pressure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark |Health Hazard |Flame |Gas Cylinder Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Causes skin irritation |Causes eye irritation |May cause respiratory irritation. May cause |drowsiness or dizziness |May be fatal if swallowed and enters airways |Extremely flammable aerosol |Contains gas under pressure; may explode if heated Precautionary Statements |Prevention (GHS-US) |Wash face, hands and any exposed skin thoroughly |after handling |Wear protective gloves/eye protection/face |protection. |Avoid breathing dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use |Response |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention |IF ON SKIN: Wash with plenty of soap and water. |If skin irritation occurs: Get medical |advice/attention |Take off contaminated clothing and wash before reuse | |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician if you feel |unwell |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |Storage |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Protect from sunlight. Do not expose to temperatures |exceeding 50 Â°C/122 Â°F |Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Harmful to aquatic life with long lasting effects 0.2641179% of the mixture consists of ingredient(s) of unknown toxicity 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) NAPHTHENIC OIL, SEVERLY HYDROT |64742-52-5 |30-40 | HEPTANE |64742-49-0 |30-40 | PROPANE/ISOBUTANE/N-BUTANE |68476-86-8 |10-20 | BRIGHT STOCK, SEVERELY HYDROTR |64742-57-0 |1-10 | HYDROTREATED LIGHT DISTALLATES |64742-47-8 |1-10 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Avoid contact with eyes,skin, and clothing.Avoid breathing, vapors,mist,or gas. First-aid Measures After Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water . Remove and wash contaminated clothing before re-use. Get medical attention immediately if symptoms occur. First-aid Measures After Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes. Consult a physician if irritation persists. Seek immediate medical attention/advice. First-aid Measures After Ingestion: Do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. Risk of product entering the lungs on vomiting after ingestion. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Inhalation causing Central Nervous System effects. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes eye irritation. Symptoms/Injuries After Ingestion: Ingestion causing lung damage. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Dry chemical. Carbon dioxide (CO2). Cool containers / tanks with water spray. Unsuitable Extinguishing Media: Do not use a solid water stream as it may scatter and spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Flammable . Keep product and empty container away from heat and sources of ignition. Explosion Hazard: Sensitivity to Mechanical Impact: none. Sensitivity to Static Discharge: Yes. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Use shielding to protect fire-fighters from bursting containers. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use with adequate ventiliation to keep the exposure levels below the OELS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Report spills as required by local and federal regulations. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Contain liquid and collect with an inter,non-combustible material. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Avoid skin contact. Use with adequate ventilation. Keep container away from heat, flames,and all other sources of ignition.Keep can away from all sources of electricity such as electric motors and batteries. Do not spray on hot surfaces. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep containers tightly closed in a cool, well-ventilated place. Incompatible products: Store away from strong acids,alkalis, or oxidizing agents. Aerosol Level: 3 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines: Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH HEPTANE 64742-49-0 TLV: 400 ppm STEL: 500 ppm TWA: 500 ppm - PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 74-98-6: TWA: 1000 ppm 106-97-8: STEL: 1000 ppm 75-28-5: STEL: 1000 ppm 74-98-6:TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 106-97-8: (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 74-98-6:IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 106-97-8:TWA: 800 ppm TWA: 1900 mg/m3 75-28-5:TWA: 800 ppm TWA: 1900 mg/m3 HYDROTREATED LIGHT DISTALLATES 64742-47-8 TWA: 200 PPM 8 hours - - Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Ventilation systems. Use adequate ventilation to Controls |keep the exposure levels below the OELs. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Aerosol Appearance |Opaque Odor |Solvent Odor Threshold |No information available pH |No information available Relative Evaporation Rate | (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |-96.4 Â°C / -141 Â°F Based on propellant Auto-ignition Temperature |No information available, Not applicable Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |0.765 Solubility |Practically insoluble Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information VOC Content(%): 49.35 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable under recommended storage conditions. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Store away from strong acids,alkalis, or oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides. Fumes. Hydrocarbons. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Product Information: Product does not present an acute toxicity hazard based on known information. Not acutely toxic. Skin Corrosion/Irritation: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Symptoms of overexposure may be headache,dizziness, tiredness, nausea,and vomiting. Serious Eye Damage/Irritation: Irritating to eyes. Respiratory or Skin Sensitization: No information available. Germ Cell Mutagenicity: No information available. Carcinogenicity: There are no known carcinogenic chemicals in this product. Reproductive Toxicity: The ingredients are not reproductive hazards. Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. may cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): None known. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Exposure to high vapour concentrations may cause nervous systems effects such as headache, nausea, and dizziness. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes eye irritation. Symptoms/Injuries After Ingestion: Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Chronic Symptoms: Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Chronic hydrocarbon abuse has been associated with irregular heart rhythms and potential cardiac arrest. Prolonged skin contact may defat the skin and produce dermatitis. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to Microorganisms Toxicity to daphnia and other aquatic invertebrates NAPHTHENIC OIL, SEVERLY HYDROT 64742-52-5 - 5000 mg/L LC50 Oncorhynchus mykiss 96h - 1000 mg/L EC50 Daphnia magna 48h PROPANE/ISOBUTANE/NBUTANE 68476-86-8 - - - - HYDROTREATED LIGHT DISTALLATES 64742-47-8 - 45 mg/L LC50 Pimephales promelas 96h flow through 2.2 mg/L LC50 Lepomis macrochirus 96h static 2.4 mg/L LC50 Oncorhynchus mykiss 96h static - - 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential Chemical Name log Pow PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 <=2.8 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste Disposal Methods: Dispose of in accordance with federal, state, and local regulations. Contaminated packaging: Do not re-use empty containers. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |CONSUMER COMMODITY ORM-D or LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Clean Water Act: This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA: This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. SARA Section 311/312 Hazard Classes |Acute Health Hazard |Yes |Chronic Health Hazard |Yes |Fire Hazard |Yes |Sudden Release of Pressure Hazard Yes |Reactive Hazard |no Toxic Substances Control Act (TSCA) |Chemical Name |TSCA |NAPHTHENIC OIL, SEVERLY HYDROT |X |HEPTANE X |PROPANE/ISOBUTA NE/N-BUTANE X |BRIGHT STOCK, SEVERELY HYDROTR X |HYDROTREATED LIGHT DISTALLATES X 15.2 US State Regulations <COMPONENT> California Proposition 65: This product does not contain any known Proposition 65 chemicals. U.S. State Right-to-Know Regulations: EPA Pesticide Registration Number: Not applicable. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |08-Sep-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.