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SDS Sheet 0065270

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: Foaming Crystal Simple Green® Industrial Cleaner & Degreaser      
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Cleaner & Degreaser for water tolerant surfaces.  
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Sunshine Makers, Inc.                                                           
 
15922 Pacific Coast Highway                                                     
 
Huntington Beach, CA 92649 USA                                                  
 
Phone: 800-228-0709, 562-795-6000                                               
 


1.4.  Emergency Telephone Number
Emergency     | Chem-Tel 24-Hour Emergency Service: 800-255-3924                
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Aerosols      |Category 3    
Eye           |Category 2B   
Corrosive/Irri|              
tant          |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |None
        
Signal Word (GHS-US)         |Warning                                           
 
Hazard Statements (GHS-US)   |H229 - Pressurized container: may burst if heated.
 
                             |H320 - Causes eye irritation.                     
 
Precautionary Statements     |P210 - Keep away from heat/sparks/open flames/hot 
 
(GHS-US)                     |surfaces. No smoking.                             
 
                             |P251 - Do not pierce or burn, even after use.     
 
                             |P264 - Wash hands thoroughly after handling.      
 
                             |P305 + P351 + P338 - IF IN EYS: Rinse cautiously  
 
                             |with water for several minutes. Remove contact    
 
                             |lenses, if present and easy to do. Continue
rinsing.
                             |                                                  
 
                             |P337 + P313 - If eye irritation persists: Get     
 
                             |medical advice/attention.                         
 
                             |P410 + P412 - Protect from sunlight. Do not expose
 
                             |to temperatures exceeding 50  Deg. C/122 Deg. F.  
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None Known.               
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Water                           |7732-18-5            |> 82%*  |                
 
Ethoxylated Alcohol             |68439-46-3           |< 5%*   |                
 
Sodium Citrate                  |68-04-2              |< 5%*   |                
 
Tetrasodium                     |51981-21-6           |< 1%*   |                
 
N,N-bis(carboxymethyl)-L-glutama|                     |        |                
 
te                              |                     |        |                
 
Sodium Carbonate                |497-19-8             |< 1%*   |                
 
Citric Acid                     |77-92-9              |< 1%*   |                
 
Butane                          |106-97-8             |3.7%*   |                
 
Propane                         |74-98-6              |1.3%*   |                
 


*specific percentages of composition are being withheld as a trade secret.

SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Not expected to cause respiratory
irritation.
If adverse effect occurs, move to fresh air.                                    
 
First-aid Measures After Skin Contact: Not expected to cause skin irritation. If
 
adverse effect occurs, rinse skin with water.                                   
 
First-aid Measures After Eye Contact: Causes eye irritation. IF IN EYS: Rinse   
 
cautiously with water for several minutes. Remove contact lenses, if present and
 
easy to do. Continue rinsing. If eye irritation persists: Get medical           
 
advice/attention.                                                               
 
First-aid Measures After Ingestion: May cause upset stomach. Drink plenty of
water
to dilute. See section 11.                                                      
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries: None known.                                                  
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms: None known.                                                   
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Treat symptomatically.                                                          
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use Dry chemical, CO2, water spray or "alcohol"   
 
foam. Avoid high volume jet water.                                              
 
Unsuitable Extinguishing Media:                                                 
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: In event of fire, fire created carbon oxides may be formed.        
 
Explosion Hazard:                                                               
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: Wear positive pressure self-contained breathing 
 
apparatus; Wear full protective clothing.                                       
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:                                                               
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment: For non-emergency and emergency personnel: See section 8 -
 
personal protection. Avoid eye contact. Wear safety goggles.                    
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Do not allow into open waterways and ground water systems.                      
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up: Dike or soak up with inert absorbent material. See     
 
section 13 for disposal considerations.                                         
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Ensure adequate ventilation. Keep out of
reach 
of children. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do
 
not pierce or burn, even after use. Do not mix or contaminate with any other    
 
chemical. Do not eat, drink or smoke while using this product.                  
 
Hygiene Measures:                                                               
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Keep container tightly closed. Keep in cool dry area.
Protect 
from sunlight. Do not expose to temperatures exceeding 50oC/122oF If separation 
 
occurs, mix the product for reconstitution.                                     
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
                                TWA/PEL                                         
 
STEL                                                                            
 
Butane                   800 ppm; 1900 mg/m3                       1000 ppm     
 
Propane                 1000 ppm; 1800 mg/m3                    1250 ppm        
 


8.2.  Exposure Controls
Appropriate Engineering      |Showers, eyewash stations, ventilation systems.   
 
Controls                     |                                                  
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Use protective glasses or safety goggles if       
 
                             |splashing or spray-back is likely.                
 
Skin and Body Protection     |Use protective gloves (any material) when used for
 
                             |prolonged periods or dermally sensitive.          
 
Respiratory Protection       |Use in well ventilated areas or local exhaust     
 
                             |ventilations when cleaning small spaces.          
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |                                           
 
Appearance                          |White Foam                                 
 
Odor                                |No added odor                              
 
Odor Threshold                      |Not determined                             
 
pH                                  |10.5 - 11.5                                
 
Relative Evaporation Rate           |Not determined                             
 
(butylacetate=1)                    |                                           
 
Melting Point                       |                                           
 
Freezing Point                      |0 Deg.C (32 Deg.F)                         
 
Boiling Point                       |101 Deg.C (213.8 Deg.F)                    
 
Flash Point                         |> 212 Deg.F                                
 
Auto-ignition Temperature           |Non-flammable                              
 
Decomposition Temperature           |109 Deg.F                                  
 
Flammability (solid, gas)           |Not applicable                             
 
Vapor Pressure                      |Not determined                             
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |8.34 - 8.44 lb/gal                         
 
Specific Gravity                    |1.00 - 1.02                                
 
Solubility                          |100% in water                              
 
Partition coefficient:              |Not determined                             
 
n-octanol/water                     |                                           
 
Viscosity                           |Not determined                             
 
Lower Flammable Limit               |Not applicable                             
 
Upper Flammable Limit               |Not applicable                             
 


9.2.  Other Information
VOCs: **Water & fragrance exemption in calculation                              
 
SCAQMD 304-91 / EPA 24: Not tested                                              
 
CARB Method 310**: <54 g/L <0.451 lb/gal <5.4%                                  
 
SCAQMD Method 313: Not tested                                                   
 
VOC Composite Partial Pressure: Not determined                                  
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
Non-reactive.                                                                   
 


10.2      Chemical Stability
Stable under normal conditions 70oF (21oC) and 14.7 psig (760 mmHg).            
 


10.3      Possibility of Hazardous Reactions
None known.                                                                     
 


10.4      Conditions to Avoid
Excessive heat or cold.                                                         
 


10.5      Incompatible Materials
Do not mix with oxidizers, acids, bathroom cleaners, or disinfecting agents.    
 


10.6      Hazardous Decomposition Products
Normal products of combustion - CO, CO2.                                        
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Oral LD50 (rat)                                  > 5 g/kg body weight           
 
Dermal LD50 (rabbit)                       > 5 g/kg body weight                 
 
Calculated via OSHA HCS 2012 / Globally Harmonized System of Classification and 
 
Labelling of Chemicals                                                          
 
Skin Corrosion/Irritation: No ingredients trigger or classify under this
category.
Serious Eye Damage/Irritation: Causes eye irritation (GHS hazard category 2B).  
 
Respiratory or Skin Sensitization:                                              
 
Germ Cell Mutagenicity: Mixture does not classify under this category.          
 
Carcinogenicity: Mixture does not classify under this category.                 
 
Reproductive Toxicity: Mixture does not classify under this category.           
 
Specific Target Organ Toxicity (Single Exposure): Mixture does not classify
under 
this category.                                                                  
 
Specific Target Organ Toxicity (Repeated Exposure): Mixture does not classify   
 
under this category.                                                            
 
Aspiration Hazard: Mixture does not classify under this category.               
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Volume of ingredients used does not trigger toxicity classifications under the  
 
Globally Harmonized System of Classification and Labelling of Chemicals.        
 


12.2. Persistence and Degradability
Based on similar formulations, foam is expected to be readily biodegradable.    
 


12.3. Bioaccumulative Potential
No data available.                                                              
 


12.4. Mobility in Soil
No data available.                                                              
 


12.5. Other Adverse Effects
No data available.                                                              
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: May be considered hazardous in your area
depending
on usage and tonnage of disposal - check with local, regional, and or national  
 
regulations for appropriate methods of disposal.                                
 
Additional Information: Dispose of in accordance with local regulations. Never  
 
dispose of used degreasing rinsates into lakes, streams, and open bodies of
water 
or storm drains.                                                                
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |                                                          
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |                                                          
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |                                                          
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
Sections 313 Superfunds Amendments and Reauthorizations Act of 1986 - Not       
 
applicable.                                                                     
 
Sections 302 - Not applicable.                                                  
 
Clean Air Act (CAA): Butane (106-97-8)         CAA 112(r) TQ 10,000 lbs         
 
Propane (74-98-6)          CAA 112 (r) TQ 10,000 lbs                            
 
Clean Water Act (CWA): Not applicable.                                          
 
State Right To Know Lists: Butane (106-97-8)                 Massachusetts, New 
 
Jersey, Pennsylvania                                                            
 
Propane (74-98-6)    Massachusetts, New Jersey, Pennsylvania                    
 
SARA Section 311/312 Hazard Classes |Not applicable.                            
 
Toxic Substances Control Act (TSCA) |All components are listed on: TSCA.        
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Proposition 65: No ingredients listed                                
 
Texas ESL:                                                                      
 
Ethoxylated Alcohol              68439-46-3                60 ?g/m3 long term   
 
600 ?g/m3 short term                                                            
 
Sodium Citrate                       68-04-2                         5 ?g/m3
long 
term                                         50 ?g/m3 short term                
 
Sodium Carbonate                497-19-8                       5 ?g/m3 long term
 
50 ?g/m3 short term                                                             
 
Citric Acid                               77-92-9                        10
?g/m3 
long term                                        100 ?g/m3 short term           
 
Butane                                    106-97-8           1000 ppb, 2375
?g/m3 
long term                      10000 ppb, 23750 ?g/m3 short term                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |                                                               
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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