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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Foaming Crystal Simple GreenÂ® Industrial Cleaner & Degreaser CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Cleaner & Degreaser for water tolerant surfaces. 1.3. Name, Address, and Telephone of the Responsible Party Company Sunshine Makers, Inc. 15922 Pacific Coast Highway Huntington Beach, CA 92649 USA Phone: 800-228-0709, 562-795-6000 1.4. Emergency Telephone Number Emergency | Chem-Tel 24-Hour Emergency Service: 800-255-3924 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Aerosols |Category 3 Eye |Category 2B Corrosive/Irri| tant | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |None Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |H229 - Pressurized container: may burst if heated. |H320 - Causes eye irritation. Precautionary Statements |P210 - Keep away from heat/sparks/open flames/hot (GHS-US) |surfaces. No smoking. |P251 - Do not pierce or burn, even after use. |P264 - Wash hands thoroughly after handling. |P305 + P351 + P338 - IF IN EYS: Rinse cautiously |with water for several minutes. Remove contact |lenses, if present and easy to do. Continue rinsing. | |P337 + P313 - If eye irritation persists: Get |medical advice/attention. |P410 + P412 - Protect from sunlight. Do not expose |to temperatures exceeding 50 Deg. C/122 Deg. F. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None Known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Water |7732-18-5 |> 82%* | Ethoxylated Alcohol |68439-46-3 |< 5%* | Sodium Citrate |68-04-2 |< 5%* | Tetrasodium |51981-21-6 |< 1%* | N,N-bis(carboxymethyl)-L-glutama| | | te | | | Sodium Carbonate |497-19-8 |< 1%* | Citric Acid |77-92-9 |< 1%* | Butane |106-97-8 |3.7%* | Propane |74-98-6 |1.3%* | *specific percentages of composition are being withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Not expected to cause respiratory irritation. If adverse effect occurs, move to fresh air. First-aid Measures After Skin Contact: Not expected to cause skin irritation. If adverse effect occurs, rinse skin with water. First-aid Measures After Eye Contact: Causes eye irritation. IF IN EYS: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: May cause upset stomach. Drink plenty of water to dilute. See section 11. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: None known. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: None known. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use Dry chemical, CO2, water spray or "alcohol" foam. Avoid high volume jet water. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: In event of fire, fire created carbon oxides may be formed. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Wear positive pressure self-contained breathing apparatus; Wear full protective clothing. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: For non-emergency and emergency personnel: See section 8 - personal protection. Avoid eye contact. Wear safety goggles. Emergency Procedures: 6.2. Environmental Precautions Do not allow into open waterways and ground water systems. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Dike or soak up with inert absorbent material. See section 13 for disposal considerations. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Ensure adequate ventilation. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not pierce or burn, even after use. Do not mix or contaminate with any other chemical. Do not eat, drink or smoke while using this product. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed. Keep in cool dry area. Protect from sunlight. Do not expose to temperatures exceeding 50oC/122oF If separation occurs, mix the product for reconstitution. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters TWA/PEL STEL Butane 800 ppm; 1900 mg/m3 1000 ppm Propane 1000 ppm; 1800 mg/m3 1250 ppm 8.2. Exposure Controls Appropriate Engineering |Showers, eyewash stations, ventilation systems. Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Use protective glasses or safety goggles if |splashing or spray-back is likely. Skin and Body Protection |Use protective gloves (any material) when used for |prolonged periods or dermally sensitive. Respiratory Protection |Use in well ventilated areas or local exhaust |ventilations when cleaning small spaces. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |White Foam Odor |No added odor Odor Threshold |Not determined pH |10.5 - 11.5 Relative Evaporation Rate |Not determined (butylacetate=1) | Melting Point | Freezing Point |0 Deg.C (32 Deg.F) Boiling Point |101 Deg.C (213.8 Deg.F) Flash Point |> 212 Deg.F Auto-ignition Temperature |Non-flammable Decomposition Temperature |109 Deg.F Flammability (solid, gas) |Not applicable Vapor Pressure |Not determined Relative Vapor Density at 20 Â°C | Relative Density |8.34 - 8.44 lb/gal Specific Gravity |1.00 - 1.02 Solubility |100% in water Partition coefficient: |Not determined n-octanol/water | Viscosity |Not determined Lower Flammable Limit |Not applicable Upper Flammable Limit |Not applicable 9.2. Other Information VOCs: **Water & fragrance exemption in calculation SCAQMD 304-91 / EPA 24: Not tested CARB Method 310**: <54 g/L <0.451 lb/gal <5.4% SCAQMD Method 313: Not tested VOC Composite Partial Pressure: Not determined SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Non-reactive. 10.2 Chemical Stability Stable under normal conditions 70oF (21oC) and 14.7 psig (760 mmHg). 10.3 Possibility of Hazardous Reactions None known. 10.4 Conditions to Avoid Excessive heat or cold. 10.5 Incompatible Materials Do not mix with oxidizers, acids, bathroom cleaners, or disinfecting agents. 10.6 Hazardous Decomposition Products Normal products of combustion - CO, CO2. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Oral LD50 (rat) > 5 g/kg body weight Dermal LD50 (rabbit) > 5 g/kg body weight Calculated via OSHA HCS 2012 / Globally Harmonized System of Classification and Labelling of Chemicals Skin Corrosion/Irritation: No ingredients trigger or classify under this category. Serious Eye Damage/Irritation: Causes eye irritation (GHS hazard category 2B). Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Mixture does not classify under this category. Carcinogenicity: Mixture does not classify under this category. Reproductive Toxicity: Mixture does not classify under this category. Specific Target Organ Toxicity (Single Exposure): Mixture does not classify under this category. Specific Target Organ Toxicity (Repeated Exposure): Mixture does not classify under this category. Aspiration Hazard: Mixture does not classify under this category. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Volume of ingredients used does not trigger toxicity classifications under the Globally Harmonized System of Classification and Labelling of Chemicals. 12.2. Persistence and Degradability Based on similar formulations, foam is expected to be readily biodegradable. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No data available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: May be considered hazardous in your area depending on usage and tonnage of disposal - check with local, regional, and or national regulations for appropriate methods of disposal. Additional Information: Dispose of in accordance with local regulations. Never dispose of used degreasing rinsates into lakes, streams, and open bodies of water or storm drains. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Sections 313 Superfunds Amendments and Reauthorizations Act of 1986 - Not applicable. Sections 302 - Not applicable. Clean Air Act (CAA): Butane (106-97-8) CAA 112(r) TQ 10,000 lbs Propane (74-98-6) CAA 112 (r) TQ 10,000 lbs Clean Water Act (CWA): Not applicable. State Right To Know Lists: Butane (106-97-8) Massachusetts, New Jersey, Pennsylvania Propane (74-98-6) Massachusetts, New Jersey, Pennsylvania SARA Section 311/312 Hazard Classes |Not applicable. Toxic Substances Control Act (TSCA) |All components are listed on: TSCA. 15.2 US State Regulations <COMPONENT> California Proposition 65: No ingredients listed Texas ESL: Ethoxylated Alcohol 68439-46-3 60 ?g/m3 long term 600 ?g/m3 short term Sodium Citrate 68-04-2 5 ?g/m3 long term 50 ?g/m3 short term Sodium Carbonate 497-19-8 5 ?g/m3 long term 50 ?g/m3 short term Citric Acid 77-92-9 10 ?g/m3 long term 100 ?g/m3 short term Butane 106-97-8 1000 ppb, 2375 ?g/m3 long term 10000 ppb, 23750 ?g/m3 short term SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.