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SDS Sheet 0065180Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: D2 SOLVENT DEGREASER CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Degreaser 1.3. Name, Address, and Telephone of the Responsible Party Company: Sprayway, Inc. 1005 S. Westgate Drive Addison, IL 60101 United States Phone: 1-630-628-3000 1.4. Emergency Telephone Number Emergency | 1-866-836-8855, 1-952-852-4646 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 aerosols | Serious eye |Category 2A damage/eye | irritation | Reproductive |Category 2 toxicity | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Causes serious eye |irritation. May cause drowsiness or dizziness. |Suspected of damaging fertility or the unborn child. Precautionary Statements |Prevention (GHS-US) |Obtain special instructions before use. Keep away |from heat/sparks/open flames/hot surfaces. - No |smoking. Do not spray on an open flame or other |ignition source. Pressurized container: Do not |pierce or burn, even after use. Avoid breathing mist |or vapor. Use only outdoors or in a well-ventilated |area. Wear protective gloves/protective clothing/eye |protection/face protection. |Response |If exposed or concerned: Get medical |advice/attention. |Storage |Store in a well-ventilated place. Keep container |tightly closed. Store locked up. Protect from |sunlight. Do not expose to temperatures exceeding |50Â°C/122Â°F. |Disposal |Dispose of contents/container in accordance wit |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None known. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Acetone |67-64-1 |80 - 90 | Carbon Dioxide |124-38-9 |2.5 - 10| n-Heptane |142-82-5 |2.5 - 10| Solvent naphtha (petroleum), |64742-89-8 |2.5 - 10| light aliph. | | | Cyclohexane |110-82-7 |0.1 - 1 | Toluene |108-88-3 |0.1 - 1 | Other components below | |0.01 - | reportable levels | |0.1 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Wash off with soap and water. Get medical attention if irritation develops and persists. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Irritation of nose and throat. Symptoms/Injuries After Eye Contact: Severe eye irritation. Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Extremely flammable aerosol. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. Firefighting Instructions: Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Protection During Firefighting: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Methods for Cleaning Up: Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not re-use empty containers. Avoid breathing mist or vapor. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Should be handled in closed systems, if possible. Pregnant or breastfeeding women must not handle this product. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Level 2 Aerosol. Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50Â°C/122 Â°F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 2 Aerosol. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Explosion-proof general and local exhaust Controls |ventilation. Good general ventilation (typically 10 |air changes per hour) should be used. Ventilation |rates should be matched to conditions. If |applicable, use process enclosures, local exhaust |ventilation, or other engineering controls to |maintain airborne levels below recommended exposure |limits. If exposure limits have not been |established, maintain airborne levels to an |acceptable level. Provide eyewash station. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear appropriate chemical resistant gloves. Eye Protection |Chemical respirator with organic vapor cartridge and |full facepiece. Skin and Body Protection |Wear appropriate chemical resistant clothing. Use of |an impervious apron is recommended. Respiratory Protection |Chemical respirator with organic vapor cartridge and |full facepiece. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Gas. Appearance |Clear. Liquid. Odor |Solvent. Odor Threshold |Not available. pH |Not applicable estimated Relative Evaporation Rate |Not available. (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |123.68 Â°F (50.93 Â°C) estimated Flash Point |-4.0 Â°F (-20.0 Â°C) Concentrate estimated Auto-ignition Temperature |474.8 Â°F (246 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |45 - 60 psig @ 70F estimated Relative Vapor Density at 20 Â°C | Relative Density |0.828 g/cm3 estimated estimated Specific Gravity |0.77 - 0.78 estimated estimated Solubility |Not available. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |1 % estimated Upper Flammable Limit |6.7 % estimated 9.2. Other Information Density: 0.09 g/cm3 estimated Flammability class: Flammable IB estimated Heat of combustion (NFPA 30B): 27.37 kJ/g estimated Percent volatile: 94 % estimated SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. Hazardous polymerization does not occur. 10.4 Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Fire or intense heat may cause violent rupture of packages. 10.5 Incompatible Materials Acids. Strong oxidizing agents. Aluminum. 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Narcotic effects. Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Skin Corrosion/Irritation: Causes mild skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Narcotic effects. Prolonged inhalation may be harmful. Not a respiratory sensitizer. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive Toxicity: May damage fertility or the unborn child. Suspected of damaging fertility or the unborn child. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness or dizziness. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: Not an aspiration hazard. Symptoms/Injuries After Inhalation: Irritation of nose and throat. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Severe eye irritation. Symptoms/Injuries After Ingestion: Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause central nervous system effects. Chronic Symptoms: Prolonged inhalation may be harmful. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Toxic to aquatic life with long lasting effects. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal instructions: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations: Dispose in accordance with all applicable regulations. Additional Information: Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols, flammable Hazard Class |2.1 |<PICTOGRAM PHRASE> | |[pic] Identification Number|UN1950 | Label Codes |2.1 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes |2.1 |<PICTOGRAM PHRASE> ntification Of The | |[pic] Substance/m | | EmS-No. (Fire) |F-D | EmS-No. (Spillage) |S-U | 14.3 In Accordance with IATA Proper Shipping Name |Aerosols, flammable Identification Number|UN1950 |<PICTOGRAM PHRASE> | |[pic] Hazard Class |2.1 | Label Codes |2.1 | ntification Of The | | Substance/m | | ERG Code (IATA) |10L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) Listed. Cyclohexane (CAS 110-82-7) Listed. Toluene (CAS 108-88-3) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 302 Extremely hazardous substance Not listed. SARA 313 (TRI reporting) Chemical name CAS number % by wt. Cyclohexane 110-82-7 0.1 - 1 Toluene 108-88-3 0.1 - 1 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Toluene (CAS 108-88-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA): Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Toluene (CAS 108-88-3) 6594 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV Toluene (CAS 108-88-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Toluene (CAS 108-88-3) 594 SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Carbon Dioxide (CAS 124-38-9) Cyclohexane (CAS 110-82-7) n-Heptane (CAS 142-82-5) Toluene (CAS 108-88-3) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Carbon Dioxide (CAS 124-38-9) Cyclohexane (CAS 110-82-7) n-Heptane (CAS 142-82-5) Toluene (CAS 108-88-3) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Carbon Dioxide (CAS 124-38-9) Cyclohexane (CAS 110-82-7) n-Heptane (CAS 142-82-5) Toluene (CAS 108-88-3) US. Rhode Island RTK Acetone (CAS 67-64-1) Cyclohexane (CAS 110-82-7) Toluene (CAS 108-88-3) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Developmental toxin Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.