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SDS Sheet 0065160

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: CBD Citrus-Based Degreaser                                        
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: General Purpose Degreaser                         
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company:                                                                        
 
The Blaster Corporation                                                         
 
8500 Sweet Valley Drive                                                         
 
Valley View, Ohio 44125 - USA                                                   
 
Phone: (216) 901-5800                                                           
 


1.4.  Emergency Telephone Number
Emergency     | Chemtrec (800) 424-9300                                         
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flammable     |1             
Aerosol       |              
Gases Under   |Dissolved Gas 
Pressure      |              
Skin          | 2            
Irritation    |              
Eye Irritation|2A            
Skin          |1             
Sensitization |              
Aspiration    |1             
Hazard        |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame |Gas Cylinder |Exclamation Mark |Health
Hazard
         
Signal Word (GHS-US)         |Danger                                            
 
Hazard Statements (GHS-US)   |Extremely flammable aerosol. Contains gas under   
 
                             |pressure; may explode if heated. Causes skin      
 
                             |irritation. Causes serious eye irritation. May
cause
                             |an allergic skin reaction. May be fatal if
swallowed
                             |and enters airways.                               
 
Precautionary Statements     |Keep away from heat/sparks/open flames/hot
surfaces.
(GHS-US)                     |-No smoking. Do not spray on an open flame or
other 
                             |ignition source. Pressurized container: Do not    
 
                             |pierce or burn, even after use. Avoid breathing   
 
                             |dust/fume/gas/mist/vapors/spray. Wash hands       
 
                             |thoroughly after handling. Contaminated work      
 
                             |clothing must not be allowed out of the workplace.
 
                             |Wear protective gloves/eye protection/face        
 
                             |protection. If swallowed: Immediately call a
poison 
                             |center/doctor. Do NOT induce vomiting. If on skin:
 
                             |Wash with plenty of water. Take off contaminated  
 
                             |clothing and wash it before reuse. If skin        
 
                             |irritation or rash occurs: Get medical            
 
                             |advice/attention. If in eyes: Rinse cautiously
with 
                             |water for several minutes. Remove contact lenses,
if
                             |present and easy to do. Continue rinsing. If eye  
 
                             |irritation persists: Get medical advice/attention.
 
                             |Store locked up. Protect from sunlight. Store in a
 
                             |wellventilated place. Do not expose to
temperatures 
                             |exceeding 50 ºC/122 ºF. Dispose of contents and   
 
                             |container in accordance with all local, regional, 
 
                             |national and international regulations.           
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: No additional information 
 
available                                                                       
 


2.4.  Unknown Acute Toxicity (GHS-US)
3 percent of the mixture consists of ingredient(s) of unknown acute toxicity.   
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Not applicable                  |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Petroleum distillates,          |64742-47-8           |60 - 100|Flam. Liq. 3    
 
hydrotreated light              |                     |        |Asp. Tox. 1     
 
D-Limonene                      |5989-27-5            |7 - 13  |Flam. Liq. 3    
 
                                |                     |        |Skin Irrit. 2   
 
                                |                     |        |Skin Sens. 1    
 
                                |                     |        |Asp. Tox. 1     
 
Alcohols, C11-15-secondary,     |68131-40-8           |3 - 7   |Eye Irrit. 2A   
 
ethoxylated                     |                     |        |                
 
Dipropylene glycol monomethyl   |34590-94-8           |1 - 5   |Flam. Liq. 4    
 
ether                           |                     |        |                
 
Carbon dioxide                  |124-38-9             |1 - 5   |Compressed gas  
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: If breathing is difficult, remove victim to
 
fresh air and keep at rest in a position comfortable for breathing. Get medical 
 
advice/attention if you feel unwell.                                            
 
First-aid Measures After Skin Contact: In case of contact, immediately flush
skin 
with plenty of water. Remove contaminated clothing and shoes. Wash clothing
before
reuse. Call a physician if irritation develops and persists.                    
 
First-aid Measures After Eye Contact: In case of contact, immediately flush eyes
 
with plenty of water for at least 15 minutes. If easy to do, remove contact     
 
lenses, if worn. If irritation persists, get medical attention.                 
 
First-aid Measures After Ingestion: Do NOT induce vomiting. Never give anything
by
mouth to an unconscious person. Get                                             
 
immediate medical advice/attention.                                             
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation: May cause respiratory tract irritation.     
 
Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms may
include
redness, edema, drying, defatting and cracking of the skin. May cause           
 
sensitization by skin contact.                                                  
 
Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms may
 
include discomfort or pain, excess blinking and tear production, with marked    
 
redness and swelling of the conjunctiva.                                        
 
Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways.
 
This product may be aspirated into the lungs and cause chemical pneumonitis. May
 
cause stomach distress, nausea or vomiting.                                     
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, 
 
seek medical advice immediately (show the label or SDS where possible).         
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Carbon dioxide, dry chemical, halons, foam.       
 
Unsuitable Extinguishing Media: Water may be ineffective.                       
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Extremely flammable aerosol. Products of combustion may include,
and 
are not limited to: oxides of carbon, hydrocarbons.                             
 
Explosion Hazard:Heat may build pressure, rupturing closed containers, spreading
 
fire and increasing risk of burns and injuries.                                 
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions: Cool closed containers exposed to fire with water.   
 
Protection During Firefighting: Keep upwind of fire. Wear full fire fighting    
 
turn-out gear (full Bunker gear) and respiratory protection (SCBA).             
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Use personal protection recommended in Section 8. Isolate the 
 
hazard area and deny entry to unnecessary and unprotected personnel. Eliminate  
 
sources of ignition.                                                            
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
                                                                                
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Contain and/or absorb spill with inert material (e.g. sand,    
 
vermiculite), then place in a suitable                                          
 
container. Do not flush to sewer or allow to enter waterways. Use appropriate   
 
Personal Protective Equipment (PPE).                                            
 
Methods for Cleaning Up: Scoop up material and place in a disposal container.   
 
Vapours may be heavier than air and may travel along the ground to a distant    
 
ignition source and flash back. Provide ventilation.                            
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Keep away from sources of ignition. - No     
 
smoking. Avoid contact with skin and eyes. Avoid                                
 
breathing dust/fume/gas/mist/vapors/spray. Do not swallow. When using do not
eat, 
drink or smoke. Do not spray on an open flame or other ignition source. Use only
 
outdoors or in a wellventilated area. Pressurized container: Do not pierce or   
 
burn, even after use.                                                           
 
Hygiene Measures: Launder contaminated clothing before reuse. Wash hands before 
 
eating, drinking, or smoking.                                                   
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Proper grounding procedures to avoid static electricity
should
be followed.                                                                    
 
Storage Conditions: Keep locked up and out of reach of children. Do not expose
to 
temperatures exceeding 50 °C/ 122 °F. Store away from direct sunlight or other  
 
heat sources. Keep dry.                                                         
 
Storage area: Store in a well-ventilated place.                                 
 


7.3.  Specific End Use(s)
Not available.                                                                  
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Petroleum distillates, hydrotreated light (64742-47-8)                          
 
USA ACGIH                      ACGIH TWA            Not applicable              
 
USA OSHA                       OSHA PEL (TWA)    Not applicable                 
 
                                                                                
 
D-Limonene (5989-27-5)                                                          
 
USA ACGIH                       ACGIH TWA          Not applicable               
 
USA OSHA                        OSHA PEL (TWA)  Not applicable                  
 
                                                                                
 
Alcohols, C11-15-secondary, ethoxylated (68131-40-8)                            
 
USA ACGIH                     ACGIH TWA              Not applicable             
 
USA OSHA                     OSHA PEL (TWA)      Not applicable                 
 
                                                                                
 
Dipropylene glycol monomethyl ether (34590-94-8)                                
 
USA ACGIH                     ACGIH TWA (ppm)                  100 ppm          
 
USA ACGIH                     ACGIH STEL (ppm)                  150 ppm         
 
USA OSHA                 OSHA PEL (TWA) (mg/m³)          600 mg/m³              
 
USA OSHA                     OSHA PEL (TWA) (ppm)          100 ppm              
 
                                                                                
 
Carbon dioxide (124-38-9)                                                       
 
USA ACGIH               ACGIH TWA (ppm)                      5000 ppm           
 
USA ACGIH               ACGIH STEL (ppm)                      30000 ppm         
 
USA OSHA                OSHA PEL (TWA) (mg/m³)         9000 mg/m³               
 
USA OSHA                OSHA PEL (TWA) (ppm)             5000 ppm               
 


8.2.  Exposure Controls
Appropriate Engineering      |Use ventilation adequate to keep exposures
(airborne
Controls                     |levels of dust, fume, vapor, etc.) below
recommended
                             |exposure limits. Ensure that eyewash stations and 
 
                             |safety showers are close to the workstation       
 
                             |location.                                         
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Wear chemically resistant protective gloves.      
 
Eye Protection               |Wear eye protection.                              
 
Skin and Body Protection     |Wear suitable protective clothing.                
 
Respiratory Protection       |In case of insufficient ventilation, wear suitable
 
                             |respiratory equipment. Respirator selection must
be 
                             |based on known or anticipated exposure levels, the
 
                             |hazards of the product and the safe working limits
 
                             |of the selected respirator.                       
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Gas / Pressurized Liquid.                  
 
Appearance                          |Clear.                                     
 
Odor                                |Citrus.                                    
 
Odor Threshold                      |No data available.                         
 
pH                                  |No data available.                         
 
Relative Evaporation Rate           |> 1                                        
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No data available.                         
 
Freezing Point                      |No data available.                         
 
Boiling Point                       |82.2 °C (180 °F)                           
 
Flash Point                         |43.3 °C (110 °F) TCC                       
 
Auto-ignition Temperature           |No data available.                         
 
Decomposition Temperature           |No data available.                         
 
Flammability (solid, gas)           |No data available.                         
 
Vapor Pressure                      |No data available.                         
 
Relative Vapor Density at 20 °C     |> 1 (Air=1)                                
 
Relative Density                    |0.875                                      
 
Specific Gravity                    |                                           
 
Solubility                          |Soluble.                                   
 
Partition coefficient:              |                                           
 
n-octanol/water                     |                                           
 
Viscosity                           |No data available.                         
 
Lower Flammable Limit               |                                           
 
Upper Flammable Limit               |                                           
 


9.2.  Other Information
Flame projection length     : 0 cm                                              
 
Heat of combustion            : 47.1 kJ/g                                       
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No dangerous reaction known under conditions of normal use.                     
 


10.2      Chemical Stability
Stable under normal storage conditions. Extremely flammable aerosol. Contents   
 
under pressure. Container may explode if heated. Do not puncture. Do not burn.  
 


10.3      Possibility of Hazardous Reactions
No dangerous reaction known under conditions of normal use.                     
 


10.4      Conditions to Avoid
Heat. Incompatible materials. Sources of ignition. Excessive water.             
 


10.5      Incompatible Materials
Strong oxidizing agents. Strong reducing agents. Water.                         
 


10.6      Hazardous Decomposition Products
May include, and are not limited to: oxides of carbon, hydrocarbons.            
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity: Not classified                                                  
 
Skin Corrosion/Irritation: Causes skin irritation.                              
 
Serious Eye Damage/Irritation: Causes serious eye irritation.                   
 
Respiratory or Skin Sensitization: May cause an allergic skin reaction.         
 
Germ Cell Mutagenicity: Based on available data, the classification criteria are
 
not met.                                                                        
 
Carcinogenicity: Based on available data, the classification criteria are not
met.
                                                                                
 
D-Limonene (5989-27-5)                                                          
 
IARC group : 3 - Not classifiable                                               
 
National Toxicity Program (NTP) Status: 1 - Evidence of Carcinogenicity         
 
Reproductive Toxicity: Based on available data, the classification criteria are 
 
not met.                                                                        
 
Specific Target Organ Toxicity (Single Exposure): Based on available data, the  
 
classification criteria are not met.                                            
 
Specific Target Organ Toxicity (Repeated Exposure): Based on available data, the
 
classification criteria are not met.                                            
 
Aspiration Hazard: May be fatal if swallowed and enters airways.                
 
Symptoms/Injuries After Inhalation: May cause respiratory tract irritation.     
 
Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms may
include
redness, edema, drying, defatting and cracking of the skin. May cause           
 
sensitization by skin contact.                                                  
 
Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms may
 
include discomfort or pain, excess blinking and tear production, with marked    
 
redness and swelling of the conjunctiva.                                        
 
Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways.
 
This product may be aspirated into the lungs and cause chemical pneumonitis. May
 
cause stomach distress, nausea or vomiting.                                     
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Ecology - general : May cause long-term adverse effects in the aquatic          
 
environment.                                                                    
 


12.2. Persistence and Degradability
CBD Citrus-Based Degreaser:                                                     
 
Persistence and degradability                       Not established.            
 


12.3. Bioaccumulative Potential
CBD Citrus-Based Degreaser:                                                     
 
Bioaccumulative potential                             Not established.          
 


12.4. Mobility in Soil
No additional information available                                             
 


12.5. Other Adverse Effects
Effect on ozone layer : No additional information available                     
 
Effect on the global warming : No known ecological damage caused by this
product. 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: This material must be disposed of in accordance 
 
with all local, state, provincial, and federal                                  
 
regulations. The generation of waste should be avoided or minimized wherever    
 
possible.                                                                       
 
Additional Information: Flammable vapors may accumulate in the container. Do not
 
incinerate empty containers.                                                    
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |AEROSOLS, flammable, limited quantities                   
 
Hazard Class         |2.1                    |<PICTOGRAM PHRASE>                
 
                     |                       |[pic]                             
 
Identification Number|UN1950                 |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |                                                          
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |                                                          
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA Section 311/312 Hazard Classes |                                           
 
Toxic Substances Control Act (TSCA) |Dipropylene glycol monomethyl ether        
 
                                    |(34590-94-8)                               
 
                                    |EPA TSCA Regulatory Flag: T - T - indicates
a
                                    |substance that is the subject of a Section
4 
                                    |test rule under TSCA.                      
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
CBD Citrus-Based Degreaser                                                      
 
State or local regulations: This product does not contain a chemical known to
the 
State of California to cause cancer, birth                                      
 
defects or other reproductive harm.                                             
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |08/22/2014                                                     
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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