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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: CBD Citrus-Based Degreaser CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: General Purpose Degreaser 1.3. Name, Address, and Telephone of the Responsible Party Company: The Blaster Corporation 8500 Sweet Valley Drive Valley View, Ohio 44125 - USA Phone: (216) 901-5800 1.4. Emergency Telephone Number Emergency | Chemtrec (800) 424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |1 Aerosol | Gases Under |Dissolved Gas Pressure | Skin | 2 Irritation | Eye Irritation|2A Skin |1 Sensitization | Aspiration |1 Hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Exclamation Mark |Health Hazard Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Extremely flammable aerosol. Contains gas under |pressure; may explode if heated. Causes skin |irritation. Causes serious eye irritation. May cause |an allergic skin reaction. May be fatal if swallowed |and enters airways. Precautionary Statements |Keep away from heat/sparks/open flames/hot surfaces. (GHS-US) |-No smoking. Do not spray on an open flame or other |ignition source. Pressurized container: Do not |pierce or burn, even after use. Avoid breathing |dust/fume/gas/mist/vapors/spray. Wash hands |thoroughly after handling. Contaminated work |clothing must not be allowed out of the workplace. |Wear protective gloves/eye protection/face |protection. If swallowed: Immediately call a poison |center/doctor. Do NOT induce vomiting. If on skin: |Wash with plenty of water. Take off contaminated |clothing and wash it before reuse. If skin |irritation or rash occurs: Get medical |advice/attention. If in eyes: Rinse cautiously with |water for several minutes. Remove contact lenses, if |present and easy to do. Continue rinsing. If eye |irritation persists: Get medical advice/attention. |Store locked up. Protect from sunlight. Store in a |wellventilated place. Do not expose to temperatures |exceeding 50 ÂºC/122 ÂºF. Dispose of contents and |container in accordance with all local, regional, |national and international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: No additional information available 2.4. Unknown Acute Toxicity (GHS-US) 3 percent of the mixture consists of ingredient(s) of unknown acute toxicity. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) Not applicable | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Petroleum distillates, |64742-47-8 |60 - 100|Flam. Liq. 3 hydrotreated light | | |Asp. Tox. 1 D-Limonene |5989-27-5 |7 - 13 |Flam. Liq. 3 | | |Skin Irrit. 2 | | |Skin Sens. 1 | | |Asp. Tox. 1 Alcohols, C11-15-secondary, |68131-40-8 |3 - 7 |Eye Irrit. 2A ethoxylated | | | Dipropylene glycol monomethyl |34590-94-8 |1 - 5 |Flam. Liq. 4 ether | | | Carbon dioxide |124-38-9 |1 - 5 |Compressed gas SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. First-aid Measures After Skin Contact: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid Measures After Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid Measures After Ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: May cause respiratory tract irritation. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. May cause sensitization by skin contact. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Carbon dioxide, dry chemical, halons, foam. Unsuitable Extinguishing Media: Water may be ineffective. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable aerosol. Products of combustion may include, and are not limited to: oxides of carbon, hydrocarbons. Explosion Hazard:Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Cool closed containers exposed to fire with water. Protection During Firefighting: Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for Cleaning Up: Scoop up material and place in a disposal container. Vapours may be heavier than air and may travel along the ground to a distant ignition source and flash back. Provide ventilation. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Keep away from sources of ignition. - No smoking. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not swallow. When using do not eat, drink or smoke. Do not spray on an open flame or other ignition source. Use only outdoors or in a wellventilated area. Pressurized container: Do not pierce or burn, even after use. Hygiene Measures: Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Proper grounding procedures to avoid static electricity should be followed. Storage Conditions: Keep locked up and out of reach of children. Do not expose to temperatures exceeding 50 Â°C/ 122 Â°F. Store away from direct sunlight or other heat sources. Keep dry. Storage area: Store in a well-ventilated place. 7.3. Specific End Use(s) Not available. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Petroleum distillates, hydrotreated light (64742-47-8) USA ACGIH ACGIH TWA Not applicable USA OSHA OSHA PEL (TWA) Not applicable D-Limonene (5989-27-5) USA ACGIH ACGIH TWA Not applicable USA OSHA OSHA PEL (TWA) Not applicable Alcohols, C11-15-secondary, ethoxylated (68131-40-8) USA ACGIH ACGIH TWA Not applicable USA OSHA OSHA PEL (TWA) Not applicable Dipropylene glycol monomethyl ether (34590-94-8) USA ACGIH ACGIH TWA (ppm) 100 ppm USA ACGIH ACGIH STEL (ppm) 150 ppm USA OSHA OSHA PEL (TWA) (mg/mÂ³) 600 mg/mÂ³ USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Carbon dioxide (124-38-9) USA ACGIH ACGIH TWA (ppm) 5000 ppm USA ACGIH ACGIH STEL (ppm) 30000 ppm USA OSHA OSHA PEL (TWA) (mg/mÂ³) 9000 mg/mÂ³ USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm 8.2. Exposure Controls Appropriate Engineering |Use ventilation adequate to keep exposures (airborne Controls |levels of dust, fume, vapor, etc.) below recommended |exposure limits. Ensure that eyewash stations and |safety showers are close to the workstation |location. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear chemically resistant protective gloves. Eye Protection |Wear eye protection. Skin and Body Protection |Wear suitable protective clothing. Respiratory Protection |In case of insufficient ventilation, wear suitable |respiratory equipment. Respirator selection must be |based on known or anticipated exposure levels, the |hazards of the product and the safe working limits |of the selected respirator. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Gas / Pressurized Liquid. Appearance |Clear. Odor |Citrus. Odor Threshold |No data available. pH |No data available. Relative Evaporation Rate |> 1 (butylacetate=1) | Melting Point |No data available. Freezing Point |No data available. Boiling Point |82.2 Â°C (180 Â°F) Flash Point |43.3 Â°C (110 Â°F) TCC Auto-ignition Temperature |No data available. Decomposition Temperature |No data available. Flammability (solid, gas) |No data available. Vapor Pressure |No data available. Relative Vapor Density at 20 Â°C |> 1 (Air=1) Relative Density |0.875 Specific Gravity | Solubility |Soluble. Partition coefficient: | n-octanol/water | Viscosity |No data available. Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information Flame projection length : 0 cm Heat of combustion : 47.1 kJ/g SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical Stability Stable under normal storage conditions. Extremely flammable aerosol. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Heat. Incompatible materials. Sources of ignition. Excessive water. 10.5 Incompatible Materials Strong oxidizing agents. Strong reducing agents. Water. 10.6 Hazardous Decomposition Products May include, and are not limited to: oxides of carbon, hydrocarbons. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Not classified Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: May cause an allergic skin reaction. Germ Cell Mutagenicity: Based on available data, the classification criteria are not met. Carcinogenicity: Based on available data, the classification criteria are not met. D-Limonene (5989-27-5) IARC group : 3 - Not classifiable National Toxicity Program (NTP) Status: 1 - Evidence of Carcinogenicity Reproductive Toxicity: Based on available data, the classification criteria are not met. Specific Target Organ Toxicity (Single Exposure): Based on available data, the classification criteria are not met. Specific Target Organ Toxicity (Repeated Exposure): Based on available data, the classification criteria are not met. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: May cause respiratory tract irritation. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. May cause sensitization by skin contact. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and Degradability CBD Citrus-Based Degreaser: Persistence and degradability Not established. 12.3. Bioaccumulative Potential CBD Citrus-Based Degreaser: Bioaccumulative potential Not established. 12.4. Mobility in Soil No additional information available 12.5. Other Adverse Effects Effect on ozone layer : No additional information available Effect on the global warming : No known ecological damage caused by this product. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional Information: Flammable vapors may accumulate in the container. Do not incinerate empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |AEROSOLS, flammable, limited quantities Hazard Class |2.1 |<PICTOGRAM PHRASE> | |[pic] Identification Number|UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |Dipropylene glycol monomethyl ether |(34590-94-8) |EPA TSCA Regulatory Flag: T - T - indicates a |substance that is the subject of a Section 4 |test rule under TSCA. 15.2 US State Regulations <COMPONENT> CBD Citrus-Based Degreaser State or local regulations: This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |08/22/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.