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Safety Data Sheet Date of Issue: 17-Dec-2013 |Revision Date: 17-Dec-2013 |Revision Number: 1 Imperial Supplies Part Number: 0065090 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 6509 PEN RED GREASE-12 PK CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Penetrating lubricant. 1.3. Name, Address, and Telephone of the Responsible Party Company American Jetway Corporation 34136 Myrtle Street Wayne, MI 48184-0126 Phone 1.4. Emergency Telephone Number Emergency |Chemical Emergency Phone Number: Chemtrec 1-800-262-8200 ID 1195 number |Company Emergency Phone Number: 734-721-5930 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Germ Cell |Category 1B Mutagenicity | Carcinogenicit|Category 1B y | Aspiration |Category 1 toxicity | Flammable |Category 1 aerosols | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Health |Flame | | | | |hazard | | | | | Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |May cause genetic defects |May cause cancer |May be fatal if swallowed and enters airways |Extremely flammable aerosol Precautionary Statements |Precautionary Statements - Response: (GHS-US) |IF exposed or concerned: Get medical |advice/attention |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |Precautionary Statements - Storage: |Store locked up |Precautionary Statements - Disposal: |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Harmful to aquatic life with long lasting effects. Harmful to aquatic life. 2.4. Unknown Acute Toxicity (GHS-US) 46.77163% of the mixture consists of ingredient(s) of unknown toxicity SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) NAPHTHENIC OIL, SEVERLY HYDROT |64742-52-5 |30 - 40%| HEPTANE |64742-49-0 |30 - 40%| PROPANE/ISOBUTANE/N-BUTANE |68476-86-8 |10 - 20%| BRIGHT STOCK, SEVERELY HYDROTR |64742-57-0 |0 - 10% | HYDROTREATED LIGHT DISTALLATES |64742-47-8 |0 - 10% | ANTIMONY DIALKYLDITHIOCARBAMAT |15890-25-2 |0 - 10% | XYLENE |1330-20-7 |0 - 10% | *The exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Move to fresh air. First-aid Measures After Skin Contact: Wash skin with soap and water. First-aid Measures After Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. First-aid Measures After Ingestion: Clean mouth with water and drink afterwards plenty of water. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Not applicable. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media: Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Sensitivity to Mechanical Impact: none. Sensitivity to Static Discharge: Yes. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Ensure adequate ventilation. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Pick up and transfer to properly labeled containers. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Keep containers tightly closed in a dry, cool and well-ventilated place. Storage Conditions: Keep containers tightly closed in a dry, cool and well-ventilated place. 7.3. Specific End Use(s) Incompatible products: None known based on information supplied. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines: Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ANTIMONY DIALKYLDITHIOCARBAMAT 15890-25-2 TWA: 0.5 mg/m3 Sb TWA: 0.5 mg/m3 Sb (vacated) TWA: 0.5 mg/m3 Sb IDLH: 50 mg/m3 Sb TWA: 0.5 mg/m3 Sb XYLENE 1330-20-7 STEL: 150 ppm TWA: 100 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 655 mg/m3 ACGIH: (American Conference of Governmental Industrial Hygienists) OSHA: (Occupational Safety & Health Administration) NIOSH IDLH: Immediately Dangerous to Life or Health Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Aerosol Appearance |opaque Odor |Solvent Odor Threshold |No information available pH |0 Relative Evaporation Rate (butyl |No information available acetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |-97 Â°C / -142 Â°F Based on propellant Auto-ignition Temperature |No information available Not applicable Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C |No information available Relative Density | Specific Gravity |0.788 Solubility |Practically insoluble (Water) Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information VOC Content(%): 46.47 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available. 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials None known based on information supplied. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Product does not present an acute toxicity hazard based on known information. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: No information available. Germ Cell Mutagenicity: No information available. Carcinogenicity: The table below indicates whether each agency has evaluated a listed ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA NAPHTHENIC OIL, SEVERLY HYDROT 64742-52-5 A2 Group 1 X XYLENE 1330-20-7 Group 3 ACGIH: (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC: (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 3 - Not Classifiable as to Carcinogenicity in Humans OSHA: (Occupational Safety & Health Administration) X - Present Reproductive Toxicity: No information available. Specific Target Organ Toxicity (Single Exposure): No information available. Specific Target Organ Toxicity (Repeated Exposure): No information available. Aspiration Hazard: No information available. Symptoms/Injuries After Inhalation: There is no data available for this product. Symptoms/Injuries After Skin Contact: There is no data available for this product. Symptoms/Injuries After Eye Contact: There is no data available for this product. Symptoms/Injuries After Ingestion: There is no data available for this product. Chronic Symptoms: No information available. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates NAPHTHENIC OIL, SEVERLY HYDROT 64742-52-5 5000: 96 h Oncorhynchus mykiss mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 HEPTANE 64742-49-0 2.6: 96 h Chaetogammarus marinus mg/L LC50 HYDROTREATED LIGHT DISTALLATES 64742-47-8 45: 96 h Pimephales promelas mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h Oncorhynchus mykiss mg/L LC50 static 4720: 96 h Den-dronereides heteropoda mg/L LC50 XYLENE 1330-20-7 13.4: 96 h Pimephales promelas mg/L LC50 flow-through 2.661 - 4.093: 96 h Oncorhynchus mykiss mg/L LC50 static 13.5 - 17.3: 96 h Oncorhynchus mykiss mg/L LC50 13.1 - 16.5: 96 h Lepomis macrochirus mg/L LC50 flow-through 19: 96 h Lepomis macrochirus mg/L LC50 7.711 - 9.591: 96 h Lepomis macrochirus mg/L LC50 static 23.53 - 29.97: 96 h Pimephales promelas mg/L LC50 static 780: 96 h Cyprinus carpio mg/L LC50 semi-static 780: 96 h Cyprinus carpio mg/L LC50 30.26 - 40.75: 96 h Poecilia reticulata mg/L LC50 static 3.82: 48 h water flea mg/L EC50 0.6: 48 h Gammarus lacustris mg/L LC50 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. Chemical Name log Pow PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 2.8 XYLENE 1330-20-7 3.15 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Additional Information: Contaminated packaging: Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |CONSUMER COMMODITY ORM-D or LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42): Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances ANTIMONY DIALKYLDITHIOCARBAMAT 15890-25-2 X XYLENE 1330-20-7 100 lb X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ XYLENE 1330-20-7 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ SARA Section 311/312 Hazard Classes |Acute Health Hazard |Yes |Chronic Health Hazard |Yes |Fire Hazard |Yes |Sudden Release of Pressure Hazard no |Reactive Hazard |no Toxic Substances Control Act (TSCA) |NAPHTHENIC OIL, SEVERLY HYDROT |X |HEPTANE |X |PROPANE/ISOBUTANE/N-BUTANE X | |BRIGHT STOCK, SEVERELY HYDROTR |X |HYDROTREATED LIGHT DISTALLATES X | |ANTIMONY DIALKYLDITHIOCAR BAMAT X |XYLENE |X 15.2 US State Regulations <COMPONENT> California Proposition 65: This product does not contain any known Proposition 65 chemicals. U.S. State Right-to-Know Regulations: Chemical Name New Jersey Massachusetts Pennsylvania ANTIMONY DIALKYLDITHIOCARBAMAT 15890-25-2 X X XYLENE 1330-20-7 X X X SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |17-Dec-2013 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.