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Safety Data Sheet Date of Issue: 18-May-2015 |Revision Date: 18-May-2015 |Revision Number: 1 Imperial Supplies Part Number: 0065070 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 6507 DRY GRAPHITE LUBE-12 PK CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Dry lubricant. 1.3. Name, Address, and Telephone of the Responsible Party Company: Imperial Supplies LLC 789 Armed Forces Drive P.O. Box 11008 Green Bay, WI 53407-1038 Phone: 1.4. Emergency Telephone Number Emergency | Chemtrec 1-800-424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2A damage/eye | irritation | Specific |Category 3 target organ | toxicity | (single | exposure) | Aspiration |Category 1 toxicity | Flammable |Category 1 aerosols | Gases under |Compressed Gas pressure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamat|Health |Flame |Gas | | |ion Mark|Hazard | |Cylinder| | Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Causes skin irritation |Causes serious eye irritation |May cause drowsiness or dizziness |May be fatal if swallowed and enters airways |Extremely flammable aerosol |Contains gas under pressure; may explode if heated Precautionary Statements |Prevention: (GHS-US) |Wash face, hands and any exposed skin thoroughly |after handling |Wear protective gloves/protective clothing/eye |protection/face protection |Avoid breathing dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking |Do not spray on an open flame or other ignition |source |Pressurized container: Do not pierce or burn, even |after use |Response: |Specific treatment (see first aid on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention |IF ON SKIN: Wash with plenty of soap and water. |Take off contaminated clothing and wash before reuse | |If skin irritation occurs: Get medical |advice/attention |IF INHALED: Remove person to fresh air and keep |comfortable for breathing. |Call a POISON CENTER or doctor/physician if you feel |unwell |IF SWALLOWED: Immediately call a POISON CENTER or |doctor/physician |Do NOT induce vomiting |Storage: |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Protect from sunlight. Do not expose to temperatures |exceeding 50 Â°C/122 Â°F |Disposal: |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None 2.4. Unknown Acute Toxicity (GHS-US) 6.6E-06% of the mixture consists of ingredient(s) of unknown toxicity SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) HEPTANE |64742-49-0 |40-50 | PROPANE/ISOBUTANE/N-BUTANE |68476-86-8 |20-30 | ISOPROPYL ALCOHOL |67-63-0 |20-30 | GRAPHITE |7782-42-5 |1-10 | N-BUTYL ALCOHOL |71-36-3 |0.1-1 | 1-METHYOXY-2-PROPANOL |107-98-2 |0.1-1 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Artificial respiration and/or oxygen may be necessary. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. First-aid Measures After Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. Call a physician or Poison Control Center immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: May cause respiratory irritation. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes eye irritation. Symptoms/Injuries After Ingestion: May be harmful if swallowed. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog.Dry chemical. Carbon dioxide (CO2). Cool containers/tanks with water spray. Unsuitable Extinguishing Media: Keep away from sources of ignition - No smoking. Cool containers / tanks with water spray. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Extremely flammable. Keep product and empty container away from heat and sources of ignition. Risk of ignition. In the event of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with water spray. Explosion Hazard: Sensitivity to Mechanical Impact: none. Sensitivity to Static Discharge: Yes. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Absorb with sand, clay, or other suitable material. Hard surfaces may be mopped with water. Remove all sources of ignition. Avoid contact with the skin and the eyes. Evacuate personnel to be safe areas.Keep people away from and upwind of spill/leak. Contents under pressure. Do not puncture or incinerate cands. Wear protective gloves/clothing and eye/face protection. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Absorb spill with inert material (e.g. dry sand or earth), the place in a chemical waste container. Methods for Cleaning Up: Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Clean contaminated surface thoroughly. After cleaning, flush away traces with water. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep in properly labeled containers. Keep out of the reach of children. Store locked up. Incompatible products: Strong acids, alkalis, or oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL OSHA PEL HEPTANE 64742-49-0 TLV: 400 ppm STEL: 500 ppm TWA: 500 ppm - PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 74-98-6: TWA: 1000 ppm 106-97-8: STEL: 1000 ppm 75-28-5: STEL: 1000 ppm 74-98-6:TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 106-97-8: (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 74-98-6:IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 106-97-8:TWA: 800 ppm TWA: 1900 mg/m3 75-28-5:TWA: 800 ppm TWA: 1900 mg/m3 ISOPROPYL ALCOHOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 GRAPHITE 7782-42-5 TWA: 2 mg/m3 respirable fraction all forms except graphite fibers TWA: 15 mg/m3 total dust synthetic TWA: 5 mg/m3 respirable fraction synthetic (vacated) TWA: 2.5 mg/m3 respirable dust natural (vacated) TWA: 10 mg/m3 total dust synthetic (vacated) TWA: 5 mg/m3 respirable fraction synthetic TWA: 15 mppcf natural IDLH: 1250 mg/m3 TWA: 2.5 mg/m3 natural respirable dust N-BUTYL ALCOHOL 71-36-3 TWA: 20 ppm TWA: 100 ppm TWA: 300 mg/m3 (vacated) S* (vacated) Ceiling: 50 ppm (vacated) Ceiling: 150 mg/m3 IDLH: 1400 ppm Ceiling: 50 ppm Ceiling: 150 mg/m3 1-METHYOXY-2-PROPANOL 107-98-2 STEL: 100 ppm TWA: 50 ppm (vacated) TWA: 100 ppm (vacated) TWA: 360 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 540 mg/m3 TWA: 100 ppm TWA: 360 mg/m3 STEL: 150 ppm STEL: 540 mg/m3 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Aerosol Appearance |Opaque Odor |Solvent Odor Threshold |No information available pH |No information available Relative Evaporation Rate | (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |-97 Â°C / -142 Â°F Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity |0.72 Solubility |negligible Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |12.0 % Upper Flammable Limit |1.2 % 9.2. Other Information VOC Content(%): 98.86 MIR Value: 0.99 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Strong acids, alkalis, or oxidizing agents. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Numerical measures of toxicity - Product Information: Unknown Acute Toxicity 6.6E-06% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5569 mg/kg ATEmix (dermal) 7046 mg/kg ATEmix (inhalation-vapor) 56 mg/l Skin Corrosion/Irritation: Irritating to skin. Repeated exposure may cause skin dryness or cracking. Prolonged skin contact may defat the skin and produce dermatitis. Avoid contact with skin. Serious Eye Damage/Irritation: Irritating to eyes. Avoid contact with eyes. Respiratory or Skin Sensitization: Irritating to skin. Repeated exposure may cause skin dryness or cracking. Prolonged skin contact may defat the skin and produce dermatitis. Avoid contact with skin. Germ Cell Mutagenicity: None known. Carcinogenicity: There are no known carcinogenic chemicals in this product. Reproductive Toxicity: This product does not contain any known or suspected reproductive hazards. Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): None under normal use conditions. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: Vapors may irritate throat and respiratory system. May cause drownsiness and dizziness based on components. May cause irritation of respiratory tract. Avoid breathing vapors or mists. Symptoms/Injuries After Skin Contact: Irritating to skin. Symptoms/Injuries After Eye Contact: Irritating to eyes. Symptoms/Injuries After Ingestion: May be harmful or fatal if swallowed. Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal. Chronic Symptoms: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Irritating to skin and eyes. Causes respiratory system irritation. May be harmful or fatal if ingested. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to Microorganisms Toxicity to daphnia and other aquatic invertebrates PROPANE/ISOBUTANE/NBUTANE 68476-86-8 - - - - ISOPROPYL ALCOHOL 67-63-0 1000 mg/L EC50 Desmodesmus subspicatus 96h 1000 mg/L EC50 Desmodesmus subspicatus 72h 11130 mg/L LC50 Pimephales promelas 96h static 9640 mg/L LC50 Pimephales promelas 96h flow-through 1400000 ?g/L LC50 Lepomis macrochirus 96h - 13299 mg/L EC50 Daphnia magna 48h N-BUTYL ALCOHOL 71-36-3 N-BUTYL ALCOHOL 71-36-3 100000 - 500000 ?g/L LC50 Lepomis macrochirus 96h static 1730 - 1910 mg/L LC50 Pimephales promelas 96h static 1740 mg/L LC50 Pimephales promelas 96h flow-through 1910000 ?g/L LC50 Pimephales promelas 96h static - 1897 - 2072 mg/L EC50 Daphnia magna 48h Static 1983 mg/L EC50 Daphnia magna 48h 1-METHYOXY-2-PROPANOL 107-98-2 - 20.8 g/L LC50 Pimephales promelas 96h static - 23300 mg/L EC50 Daphnia magna 48h 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. Chemical Name log Pow PROPANE/ISOBUTANE/N-BUTANE 2.8 68476-86-8 ISOPROPYL ALCOHOL 0.05 67-63-0 N-BUTYL ALCOHOL 0.785 71-36-3 1-METHYOXY-2-PROPANOL -0.437 107-98-2 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Additional Information: Contaminated packaging: Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |CONSUMER COMMODITY ORM-D or LIMITED QUANTITY Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |AEROSOLS, FLAMMABLE Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |AEROSOLS, FLAMMABLE Identification Number|UN1950 |<PICTOGRAM PHRASE> Hazard Class |2.1 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight %* SARA 313 - Threshold Values % ISOPROPYL ALCOHOL 67-63-0 20-30 1.0 N-BUTYL ALCOHOL 71-36-3 0.1-1 1.0 Clean Water Act: This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA: This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ N-BUTYL ALCOHOL 71-36-3 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ SARA Section 311/312 Hazard Classes |Acute Health Hazard |Yes |Chronic Health Hazard |Yes |Fire Hazard |Yes |Sudden Release of Pressure Hazard Yes | |Reactive Hazard |no Toxic Substances Control Act (TSCA) |Chemical Name |TSCA |HEPTANE |X |PROPANE/ISOBUTA NE/N-BUTANE |X |ISOPROPYL ALCOHOL |X |GRAPHITE |X |N-BUTYL ALCOHOL |X |1-METHYOXY-2-PRO PANOL |X 15.2 US State Regulations <COMPONENT> California Proposition 65 This product does not contain any known Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ISOPROPYL ALCOHOL 67-63-0 X X X GRAPHITE 7782-42-5 X X X N-BUTYL ALCOHOL 71-36-3 X X X 1-METHYOXY-2-PROPANOL 107-98-2 X X X SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |18-May-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.