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SDS Sheet 0057830

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Safety Data Sheet | |
Date of Issue:             |Revision Date: 09-Apr-2015 |Revision Number: 1        
Imperial Supplies Part Number: 0057830                                            

SECTION 1: IDENTIFICATION                                                         


1.1.  Product Identifier
Product Form:                                                                     
Product Name: Rain-X Original Glass Treatment                                     
CAS No:                                                                           
Synonyms: None                                                                    


1.2.  Intended Use of the Product
Use of the substance/mixture: Glass Treatment Consumer Use.                       


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                           
ITW Global Brands                                                                 
6925 Portwest Dr., Suite 100                                                      
Houston, TX 77024                                                                 
Phone: 1-855-888-1988                                                             


1.4.  Emergency Telephone Number
Emergency     |(CHEMTREC) 1-800-424-9300 or 1-703-527-3887 (U.S.)                 
number        |(RMPDC) 1-877-504-9352 (U.S.)                                      

SECTION 2: HAZARDS IDENTIFICATION                                                 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Serious eye   |Category 2    
damage/eye    |              
irritation    |              
Carcinogenicit|Category 1B   
y             |              
Specific      |Category 3    
target organ  |              
toxicity      |              
(single       |              
exposure)     |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamat|Health  |        |        |        |        
                             |ion mark|hazard  |        |        |        |        
Signal Word (GHS-US)         |Danger                                              
Hazard Statements (GHS-US)   |Flammable Liquid                                    
                             |Causes serious eye irritation                       
                             |May cause cancer                                    
                             |May cause drowsiness or dizziness                   
Precautionary Statements     |Precautionary Statements - Prevention               
(GHS-US)                     |Obtain special instructions before use              
                             |Do not handle until all safety precautions have been
                             |read and understood                                 
                             |Use personal protective equipment as required       
                             |Wash face, hands and any exposed skin thoroughly    
                             |after handling                                      
                             |Wear eye/face protection                            
                             |Avoid breathing dust/fume/gas/mist/vapors/spray     
                             |Use only outdoors or in a well-ventilated area      
                             |                                                    
                             |Precautionary Statements - Response                 
                             |IF exposed or concerned: Get medical                
                             |advice/attention                                    
                             |IF SWALLOWED: Rinse mouth. DO NO induce vomiting    
                             |IF SKIN irritation occurs: rinse thoroughly and get 
                             |medical advice                                      
                             |IF IN EYES: Rinse cautiously with water for several 
                             |minutes. Remove contact lenses, if present and easy 
                             |to do. Continue rinsing                             
                             |If eye irritation persists: Get medical             
                             |advice/attention                                    
                             |IF INHALED: Remove victim to fresh air and keep at  
                             |rest in a position comfortable for breathing        
                             |                                                    
                             |Precautionary Statements - Storage                  
                             |Store locked up                                     
                             |Store in a well-ventilated place. Keep container    
                             |tightly closed                                      
                             |Keep out of reach of children                       
                             |                                                    
                             |Precautionary Statements - Disposal                 
                             |Dispose of contents/container to an approved waste  
                             |disposal plant                                      


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Not applicable.             


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                  

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
ETHANOL                         |64-17-5              |30 - 60 |                  
ACETONE                         |67-64-1              |10 - 30 |                  
ISOPROPYL ALCOHOL               |67-63-0              |10 - 30 |                  
Sulfuric acid                   |7664-93-9            |0.1 - 1 |                  
                                |                     |        |                  


*The exact percentage (concentration) of composition has been withheld as a
trade secret.

SECTION 4: FIRST AID MEASURES                                                     


4.1.  Description of First Aid Measures
First-aid Measures General: Get medical advice/attention if you feel unwell.      
First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and   
keep at rest in a position comfortable for                                        
breathing. If symptoms persist, call a physician.                                 
First-aid Measures After Skin Contact: IF ON SKIN:. Wash skin with soap and water.
If skin irritation persists, call a physician.                                    
Wash contaminated clothing before reuse.                                          
First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for 
several minutes. Remove contact lenses, if                                        
present and easy to do. Continue rinsing. If eye irritation persists: Get medical 
advice/attention.                                                                 
First-aid Measures After Ingestion: IF SWALLOWED:. Do NOT induce vomiting. Never  
give anything by mouth to an unconscious person. Call a physician.                


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                                
Symptoms/Injuries After Inhalation: May cause irritation of respiratory tract. May
be harmful if inhaled.                                                            
Symptoms/Injuries After Skin Contact: May cause skin irritation and/or dermatitis.
Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May  
cause redness and tearing of the eyes.                                            
Symptoms/Injuries After Ingestion: Ingestion may cause irritation to mucous       
membranes. May be harmful if swallowed.                                           
Chronic Symptoms: No information available.                                       


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Note to physicians: Treat symptomatically.                                        

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Dry chemical, CO2, sand, earth, water spray or      
regular foam.                                                                     
Unsuitable Extinguishing Media: CAUTION: All these products have a very low flash 
point. Use of water spray when fighting fire may be inefficient.                  


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: CAUTION: All these products have a very low flash point. Use of water
spray when fighting fire may be inefficient.                                      
Explosion Hazard:                                                                 
Sensitivity to Mechanical Impact: No information available.                       
Sensitivity to Static Discharge: May be ignited by heat, sparks or flames.        
Reactivity:                                                                       


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions:                                                        
Protection During Firefighting: As in any fire, wear self-contained breathing     
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective
gear.                                                                             

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Ensure adequate ventilation, especially in confined areas. Avoid
contact with skin, eyes and inhalation of vapors. Use personal protective         
equipment as required. ELIMINATE all ignition sources (no smoking, flares, sparks 
or flames in immediate area).                                                     


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.1.2.      For Emergency Responders
Protective Equipment:                                                             
Emergency Procedures:                                                             


6.2.  Environmental Precautions
See Section 12 for additional ecological information.                             


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Prevent further leakage or spillage if safe to do so.            
Methods for Cleaning Up: Ensure adequate ventilation. Soak up with inert absorbent
material. Sweep up and shovel into suitable containers for disposal.              


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        


SECTION 7: HANDLING AND STORAGE                                                   


7.1.  Precautions for Safe Handling
Additional Hazards When Processed:                                                
Advice on safe handling: Handle in accordance with good industrial hygiene and    
safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or
clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse.
Use personal protective equipment as required.                                    
Hygiene Measures: Handle in accordance with good industrial hygiene and safety    
practice. Regular cleaning of equipment, work area and clothing is recommended.   


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                               
Storage Conditions: Keep containers tightly closed in a cool, well-ventilated     
place. Keep away from heat, sparks, flame and other sources of ignition (i.e.,    
pilot lights, electric motors and static electricity). Keep out of the reach of   
children.                                                                         


7.3.  Specific End Use(s)
                                                                                  

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  


8.1.  Control Parameters
Exposure Guidelines                                                               
Chemical Name                                                                     
ACGIH TLV                                                                         
OSHA PEL                                                                          
NIOSH IDLH                                                                        
                                                                                  
ETHANOL                                                                           
64-17-5                                                                           
STEL: 1000 ppm                                                                    
TWA: 1000 ppm                                                                     
TWA: 1900 mg/m3                                                                   
(vacated) TWA: 1000 ppm                                                           
(vacated) TWA: 1900 mg/m3                                                         
IDLH: 3300 ppm                                                                    
TWA: 1000 ppm                                                                     
TWA: 1900 mg/m3                                                                   
                                                                                  
ACETONE                                                                           
67-64-1                                                                           
STEL: 750 ppm                                                                     
TWA: 500 ppm                                                                      
TWA: 1000 ppm                                                                     
TWA: 2400 mg/m3                                                                   
(vacated) TWA: 750 ppm                                                            
(vacated) TWA: 1800 mg/m3                                                         
(vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose       
acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000
ppm                                                                               
IDLH: 2500 ppm                                                                    
TWA: 250 ppm                                                                      
TWA: 590 mg/m3                                                                    
                                                                                  
ISOPROPYL ALCOHOL                                                                 
67-63-0                                                                           
STEL: 400 ppm                                                                     
TWA: 200 ppm                                                                      
TWA: 400 ppm                                                                      
TWA: 980 mg/m3                                                                    
(vacated) TWA: 400 ppm                                                            
(vacated) TWA: 980 mg/m3                                                          
(vacated) STEL: 500 ppm                                                           
(vacated) STEL: 1225 mg/m3                                                        
IDLH: 2000 ppm                                                                    
TWA: 400 ppm                                                                      
TWA: 980 mg/m3                                                                    
STEL: 500 ppm                                                                     
STEL: 1225 mg/m3                                                                  
                                                                                  
Sulfuric acid                                                                     
7664-93-9                                                                         
TWA: 0.2 mg/m3 thoracic fraction                                                  
TWA: 1 mg/m3                                                                      
(vacated) TWA: 1 mg/m3                                                            
IDLH: 15 mg/m3                                                                    
TWA: 1 mg/m3                                                                      
                                                                                  
NIOSH IDLH Immediately Dangerous to Life or Health                                


8.2.  Exposure Controls
Appropriate Engineering      |Showers                                             
Controls                     |Eyewash stations                                    
                             |Ventilation systems                                 
Personal Protective Equipment|                                                    
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |                                                    
Eye Protection               |Wear safety glasses or goggles if splashing is      
                             |likely to occur.                                    
Skin and Body Protection     |Wear protective gloves and protective clothing.     
Respiratory Protection       |Use NIOSH-approved air-purifying respirator with    
                             |organic vapor cartridge or canister, as appropriate.
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                       
Appearance                          |Clear Colorless                              
Odor                                |Alcohol                                      
Odor Threshold                      |No information available                     
pH                                  |1.5 - 2.5                                    
Relative Evaporation Rate (butyl    |No information available                     
acetate=1)                          |                                             
Melting Point                       |No information available                     
Freezing Point                      |No information available                     
Boiling Point                       |No information available                     
Flash Point                         |-2.78 °C / 27.0 °F                           
Auto-ignition Temperature           |No information available                     
Decomposition Temperature           |No information available                     
Flammability (solid, gas)           |No information available                     
Vapor Pressure                      |No information available                     
Relative Vapor Density at 20 °C     |No information available                     
Relative Density                    |0.810 - 0.812                                
Specific Gravity                    |                                             
Solubility                          |Soluble in water                             
Partition coefficient:              |No information available                     
n-octanol/water                     |                                             
Viscosity                           |No information available                     
Lower Flammable Limit               |No information available                     
Upper Flammable Limit               |No information available                     


9.2.  Other Information
Softening point:       No information available                                   
Molecular weight:   No information available                                      
VOC Content (%):    72.5%                                                         
Density:                     0.806 - 0.808 g/cm3                                  
Bulk density:            No information available                                 

SECTION 10: STABILITY AND REACTIVITY                                              


10.1      Reactivity
Stable under normal use.                                                          


10.2      Chemical Stability
Stable under normal conditions.                                                   


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                     


10.4      Conditions to Avoid
Heat, flames and sparks. Excessive heat.                                          


10.5      Incompatible Materials
None known.                                                                       


10.6      Hazardous Decomposition Products
Carbon oxides.                                                                    

SECTION 11: TOXICOLOGICAL INFORMATION                                             


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                   
Skin Corrosion/Irritation:                                                        
Serious Eye Damage/Irritation:                                                    
Respiratory or Skin Sensitization: No information available.                      
Germ Cell Mutagenicity: No information available.                                 
Carcinogenicity: The table below indicates whether each agency has listed any     
ingredient as a carcinogen.                                                       
Reproductive Toxicity:                                                            
Specific Target Organ Toxicity (Single Exposure):                                 
Specific Target Organ Toxicity (Repeated Exposure):                               
Aspiration Hazard:                                                                
Symptoms/Injuries After Inhalation:                                               
Symptoms/Injuries After Skin Contact:                                             
Symptoms/Injuries After Eye Contact:                                              
Symptoms/Injuries After Ingestion:                                                
Chronic Symptoms: May cause adverse effects on the bone marrow and blood-forming  
system. May cause adverse liver effects. Contains a known or suspected            
reproductive toxin.                                                               

SECTION 12: ECOLOGICAL INFORMATION                                                


12.1. Toxicity
Chemical Name                                                                     
Algae/aquatic plants                                                              
Fish                                                                              
Crustacea                                                                         
                                                                                  
ETHANOL                                                                           
64-17-5                                                                           
-                                                                                 
12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 100: 96 h Pimephales       
promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50       
flow-through                                                                      
9268 - 14221: 48 h Daphnia magna                                                  
mg/L LC50 2: 48 h Daphnia magna                                                   
mg/L EC50 Static 10800: 24 h                                                      
Daphnia magna mg/L EC50                                                           
                                                                                  
ACETONE                                                                           
67-64-1                                                                           
-                                                                                 
4.74 - 6.33: 96 h Oncorhynchus                                                    
mykiss mL/L LC50 6210 - 8120: 96                                                  
h Pimephales promelas mg/L LC50                                                   
static 8300: 96 h Lepomis                                                         
macrochirus mg/L LC50                                                             
10294 - 17704: 48 h Daphnia                                                       
magna mg/L EC50 Static 12600 -                                                    
12700: 48 h Daphnia magna mg/L                                                    
EC50                                                                              
                                                                                  
ISOPROPYL ALCOHOL                                                                 
67-63-0                                                                           
1000: 96 h Desmodesmus                                                            
subspicatus mg/L EC50 1000: 72 h                                                  
Desmodesmus subspicatus mg/L                                                      
EC50                                                                              
11130: 96 h Pimephales promelas                                                   
mg/L LC50 static 9640: 96 h                                                       
Pimephales promelas mg/L LC50                                                     
flow-through 1400000: 96 h                                                        
Lepomis macrochirus ?g/L LC50                                                     
13299: 48 h Daphnia magna mg/L                                                    
EC50                                                                              
                                                                                  
Sulfuric acid                                                                     
7664-93-9                                                                         
-                                                                                 
500: 96 h Brachydanio rerio mg/L                                                  
LC50 static                                                                       
29: 24 h Daphnia magna mg/L                                                       
EC50                                                                              
                                                                                  


12.2. Persistence and Degradability
No information available.                                                         


12.3. Bioaccumulative Potential
No information available.                                                         


12.4. Mobility in Soil
Disperses in water.                                                               


12.5. Other Adverse Effects
No information available.                                                         

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Disposal of wastes: Disposal should be in         
accordance with applicable regional, national and local laws and regulations.     
Recover or recycle if possible.                                                   
Additional Information:                                                           

SECTION 14: TRANSPORT INFORMATION                                                 


14.1 In Accordance with DOT
Proper Shipping Name |ALCOHOLS, N.O.S, Limited Quantity (LQ)                      
Hazard Class         |3                      |<PICTOGRAM PHRASE>                  
Identification Number|UN 1987                |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            


14.2 In Accordance with IMDG
Proper Shipping Name |ALCOHOLS, N.O.S, Limited Quantity (LQ)                      
Hazard Class         |3                                                           
Identification Number|UN 1987                                                     
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     


14.3 In Accordance with IATA
Proper Shipping Name |Consumer commodity, Limited Quantity (LQ)                   
Identification Number|ID 8000                |<PICTOGRAM PHRASE>                   
Hazard Class         |9                      |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization
Act of 1986 (SARA). This product contains a chemical or chemicals which are       
subject to the reporting requirements of the Act and Title 40 of the Code of      
Federal Regulations, Part 372                                                     
                                                                                  
Chemical Name                                                                     
SARA 313 - Threshold Values %                                                     
                                                                                  
ISOPROPYL ALCOHOL - 67-63-0                                                       
1.0                                                                               
                                                                                  
                                                                                  
CWA (Clean Water Act)                                                             
This product contains the following substances which are regulated pollutants     
pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)                 
Chemical Name                                                                     
CWA - Reportable Quantities                                                       
CWA - Toxic Pollutants                                                            
CWA - Priority Pollutants                                                         
CWA - Hazardous Substances                                                        
                                                                                  
Sulfuric acid                                                                     
7664-93-9                                                                         
1000 lb                                                                           
-                                                                                 
-                                                                                 
X                                                                                 
                                                                                  
                                                                                  
CERCLA                                                                            
This material, as supplied, contains one or more substances regulated as a        
hazardous substance under the Comprehensive Environmental Response Compensation   
and Liability Act (CERCLA) (40 CFR 302)                                           
Chemical Name                                                                     
Hazardous Substances RQs                                                          
CERCLA/SARA RQ                                                                    
Reportable Quantity (RQ)                                                          
                                                                                  
ACETONE                                                                           
67-64-1                                                                           
5000 lb                                                                           
-                                                                                 
RQ 5000 lb final RQ                                                               
RQ 2270 kg final RQ                                                               
                                                                                  
Sulfuric acid                                                                     
7664-93-9                                                                         
1000 lb                                                                           
1000 lb                                                                           
RQ 1000 lb final RQ                                                               
RQ 454 kg final RQ                                                                
                                                                                  
SARA Section 311/312 Hazard Classes |Acute health hazard                          
                                    |No                                           
                                    |Chronic Health Hazard                        
                                    |No                                           
                                    |Fire hazard                                  
                                    |No                                           
                                    |Sudden release of pressure hazard          No
                                    |                                             
                                    |Reactive Hazard                              
                                    |No                                           
Toxic Substances Control Act (TSCA) |Complies                                     

15.2      US State Regulations
California Proposition 65:                                                        
This product contains the following Proposition 65 chemicals Ethyl alcohol is only
a considered a Proposition 65 developmental hazard when it is ingested as an      
alcoholic beverage Sulfuric acid is only considered a Proposition 65 carcinogen   
hazard in the industrial processing of strong inorganic acids:                    
                                                                                  
Chemical Name                                                                     
California Proposition 65                                                         
                                                                                  
ETHANOL - 64-17-5                                                                 
Carcinogen                                                                        
Developmental                                                                     
                                                                                  
Sulfuric acid - 7664-93-9                                                         
Carcinogen                                                                        
                                                                                  
                                                                                  
U.S. State Right-to-Know Regulations:                                             
Chemical Name                                                                     
New Jersey                                                                        
Massachusetts                                                                     
Pennsylvania                                                                      
                                                                                  
ETHANOL                                                                           
64-17-5                                                                           
X                                                                                 
X                                                                                 
X                                                                                 
                                                                                  
ACETONE                                                                           
67-64-1                                                                           
X                                                                                 
X                                                                                 
X                                                                                 
                                                                                  
ISOPROPYL ALCOHOL                                                                 
67-63-0                                                                           
X                                                                                 
X                                                                                 
X                                                                                 
                                                                                  
WATER                                                                             
7732-18-5                                                                         
-                                                                                 
-                                                                                 
X                                                                                 
                                                                                  
Sulfuric acid                                                                     
7664-93-9                                                                         
X                                                                                 
X                                                                                 
X                                                                                 
                                                                                  
                                                                                  
U.S. EPA Label Information                                                        
EPA Pesticide Registration Number: Not applicable.                                
                                                                                  

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION     

Revision date   |09-Apr-2015                                                      
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
                |1910.1200.                                                       
GHS Full Text Phrases:                                                            
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             
----|                               |                                             
--  |                               |                                             


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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