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Safety Data Sheet | | Date of Issue: |Revision Date: 09-Apr-2015 |Revision Number: 1 Imperial Supplies Part Number: 0057830 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Rain-X Original Glass Treatment CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Glass Treatment Consumer Use. 1.3. Name, Address, and Telephone of the Responsible Party Company ITW Global Brands 6925 Portwest Dr., Suite 100 Houston, TX 77024 Phone: 1-855-888-1988 1.4. Emergency Telephone Number Emergency |(CHEMTREC) 1-800-424-9300 or 1-703-527-3887 (U.S.) number |(RMPDC) 1-877-504-9352 (U.S.) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Serious eye |Category 2 damage/eye | irritation | Carcinogenicit|Category 1B y | Specific |Category 3 target organ | toxicity | (single | exposure) | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamat|Health | | | | |ion mark|hazard | | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Flammable Liquid |Causes serious eye irritation |May cause cancer |May cause drowsiness or dizziness Precautionary Statements |Precautionary Statements - Prevention (GHS-US) |Obtain special instructions before use |Do not handle until all safety precautions have been |read and understood |Use personal protective equipment as required |Wash face, hands and any exposed skin thoroughly |after handling |Wear eye/face protection |Avoid breathing dust/fume/gas/mist/vapors/spray |Use only outdoors or in a well-ventilated area | |Precautionary Statements - Response |IF exposed or concerned: Get medical |advice/attention |IF SWALLOWED: Rinse mouth. DO NO induce vomiting |IF SKIN irritation occurs: rinse thoroughly and get |medical advice |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing |If eye irritation persists: Get medical |advice/attention |IF INHALED: Remove victim to fresh air and keep at |rest in a position comfortable for breathing | |Precautionary Statements - Storage |Store locked up |Store in a well-ventilated place. Keep container |tightly closed |Keep out of reach of children | |Precautionary Statements - Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Not applicable. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) ETHANOL |64-17-5 |30 - 60 | ACETONE |67-64-1 |10 - 30 | ISOPROPYL ALCOHOL |67-63-0 |10 - 30 | Sulfuric acid |7664-93-9 |0.1 - 1 | | | | *The exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Get medical advice/attention if you feel unwell. First-aid Measures After Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. First-aid Measures After Skin Contact: IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: May cause irritation of respiratory tract. May be harmful if inhaled. Symptoms/Injuries After Skin Contact: May cause skin irritation and/or dermatitis. Symptoms/Injuries After Eye Contact: Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Symptoms/Injuries After Ingestion: Ingestion may cause irritation to mucous membranes. May be harmful if swallowed. Chronic Symptoms: No information available. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Note to physicians: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Dry chemical, CO2, sand, earth, water spray or regular foam. Unsuitable Extinguishing Media: CAUTION: All these products have a very low flash point. Use of water spray when fighting fire may be inefficient. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: CAUTION: All these products have a very low flash point. Use of water spray when fighting fire may be inefficient. Explosion Hazard: Sensitivity to Mechanical Impact: No information available. Sensitivity to Static Discharge: May be ignited by heat, sparks or flames. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes and inhalation of vapors. Use personal protective equipment as required. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions See Section 12 for additional ecological information. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Advice on safe handling: Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep out of the reach of children. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ETHANOL 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 ISOPROPYL ALCOHOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 Sulfuric acid 7664-93-9 TWA: 0.2 mg/m3 thoracic fraction TWA: 1 mg/m3 (vacated) TWA: 1 mg/m3 IDLH: 15 mg/m3 TWA: 1 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health 8.2. Exposure Controls Appropriate Engineering |Showers Controls |Eyewash stations |Ventilation systems Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Wear safety glasses or goggles if splashing is |likely to occur. Skin and Body Protection |Wear protective gloves and protective clothing. Respiratory Protection |Use NIOSH-approved air-purifying respirator with |organic vapor cartridge or canister, as appropriate. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Clear Colorless Odor |Alcohol Odor Threshold |No information available pH |1.5 - 2.5 Relative Evaporation Rate (butyl |No information available acetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |-2.78 �C / 27.0 �F Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 �C |No information available Relative Density |0.810 - 0.812 Specific Gravity | Solubility |Soluble in water Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information Softening point: No information available Molecular weight: No information available VOC Content (%): 72.5% Density: 0.806 - 0.808 g/cm3 Bulk density: No information available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable under normal use. 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Heat, flames and sparks. Excessive heat. 10.5 Incompatible Materials None known. 10.6 Hazardous Decomposition Products Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: No information available. Germ Cell Mutagenicity: No information available. Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Chemical Name Algae/aquatic plants Fish Crustacea ETHANOL 64-17-5 - 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 ACETONE 67-64-1 - 4.74 - 6.33: 96 h Oncorhynchus mykiss mL/L LC50 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 ISOPROPYL ALCOHOL 67-63-0 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 11130: 96 h Pimephales promelas mg/L LC50 static 9640: 96 h Pimephales promelas mg/L LC50 flow-through 1400000: 96 h Lepomis macrochirus ?g/L LC50 13299: 48 h Daphnia magna mg/L EC50 Sulfuric acid 7664-93-9 - 500: 96 h Brachydanio rerio mg/L LC50 static 29: 24 h Daphnia magna mg/L EC50 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. 12.4. Mobility in Soil Disperses in water. 12.5. Other Adverse Effects No information available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal of wastes: Disposal should be in accordance with applicable regional, national and local laws and regulations. Recover or recycle if possible. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |ALCOHOLS, N.O.S, Limited Quantity (LQ) Hazard Class |3 |<PICTOGRAM PHRASE> Identification Number|UN 1987 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |ALCOHOLS, N.O.S, Limited Quantity (LQ) Hazard Class |3 Identification Number|UN 1987 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Consumer commodity, Limited Quantity (LQ) Identification Number|ID 8000 |<PICTOGRAM PHRASE> Hazard Class |9 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations SARA 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % ISOPROPYL ALCOHOL - 67-63-0 1.0 CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Sulfuric acid 7664-93-9 1000 lb - - X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ Sulfuric acid 7664-93-9 1000 lb 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ SARA Section 311/312 Hazard Classes |Acute health hazard |No |Chronic Health Hazard |No |Fire hazard |No |Sudden release of pressure hazard No | |Reactive Hazard |No Toxic Substances Control Act (TSCA) |Complies 15.2 US State Regulations California Proposition 65: This product contains the following Proposition 65 chemicals Ethyl alcohol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage Sulfuric acid is only considered a Proposition 65 carcinogen hazard in the industrial processing of strong inorganic acids: Chemical Name California Proposition 65 ETHANOL - 64-17-5 Carcinogen Developmental Sulfuric acid - 7664-93-9 Carcinogen U.S. State Right-to-Know Regulations: Chemical Name New Jersey Massachusetts Pennsylvania ETHANOL 64-17-5 X X X ACETONE 67-64-1 X X X ISOPROPYL ALCOHOL 67-63-0 X X X WATER 7732-18-5 - - X Sulfuric acid 7664-93-9 X X X U.S. EPA Label Information EPA Pesticide Registration Number: Not applicable. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |09-Apr-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.