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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: GREEN STUFFÂ® ABSORBENT CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Spill absorbent for liquids & semi-liquids 1.3. Name, Address, and Telephone of the Responsible Party Company: D2L Products, 801 Port America Place, Suite A, Grapevine, TX 76051 1.4. Emergency Telephone Number Emergency | CHEMTREC: 800-424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Not classified| | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |None | | | | | Signal Word (GHS-US) |None Hazard Statements (GHS-US) |None Precautionary Statements |Prevention: Observe good industrial hygiene (GHS-US) |practices. |Response: Wash hands after handling. |Disposal: Considered RCRA non-hazardous and can be |disposed as residential or commercial waste sent to |a permitted solid waste landfill. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Fine-Celled Thermoset Phenolic |Not applicable to | | Resin Material |mixtures. | | | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove to fresh air. Dust/vapor may be a nuisance. Unlikely that material can be ingested in large amounts. First-aid Measures After Skin Contact: Generally the product should not irritate the skin. First-aid Measures After Eye Contact: Immediately flush eyes with large amount of water for 15 minutes. If discomfort persists, get medical attention. First-aid Measures After Ingestion: DO NOT induce vomiting. Keep respiratory passages clear. Unlikely that material can be ingested in large amounts. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Fugitive dust may cause eye discomfort. Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Treat the symptoms and call the emergency number. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Foam, Carbon Dioxide, Dry Chemical or Water. Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: No specific explosion hazard. Finished material is not flammable, in that it does not burn with an open flame. It will support combustion if it is ignited by direct contact with an open flame or exposed to temperatures in the range of 600 F. If material is placed in a microwave for an extended period, it will begin to burn. Hazardous Decomposition Products: Not determined. Under fire conditions, product may decompose to give off fumes of carbon dioxide, carbon monoxide and sulfur dioxide. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Firefighters should wear full protective gear used in fighting fires, including self-contained breathing apparatus. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Stop spill at source. Wear appropriate personal protective equipment (Sec. 8). Contain the spill to facilitate clean up with absorbent. Transfer to disposal containers. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: Stop spill at source. Wear appropriate personal protective equipment (Sec. 8). Contain the spill to facilitate clean up with absorbent. Transfer to disposal containers. 6.2. Environmental Precautions Do not release into sewers or waterways. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Note: See Section 13 for waste disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures. Hygiene Measures: Practice good personal hygiene. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters No exposure limit value known. 8.2. Exposure Controls Appropriate Engineering |Provide general or local exhaust ventilation Controls |systems. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear standard work gloves. Eye Protection |Wear safety glasses. Dust may irritate contact |lenses. Skin and Body Protection | Respiratory Protection |Respiratory protection not required if working in |well-ventilated area. Use only NIOSH/MSHA approved |equipment, if exposure is excessive. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Solid. Fine-Celled Thermoset Phenolic Resin |Material. Appearance | Odor |None Odor Threshold |None pH |None (solid) Relative Evaporation Rate | (butylacetate=1) | Melting Point | Freezing Point | Boiling Point | Flash Point |N/A Auto-ignition Temperature |Product is not self-igniting. Decomposition Temperature |N/A Flammability (solid, gas) |Finished material is not flammable, in that |it does not burn with an |open flame. It will support combustion if it |is ignited by direct contact |with an open flame or exposed to temperatures |in the range of 600 F. Vapor Pressure | Relative Vapor Density at 20 Â°C | Relative Density |N/A Specific Gravity | Solubility |N/A Partition coefficient: |N/A n-octanol/water | Viscosity |N/A Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information % Volatile: 0 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity None expected. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions No known dangerous reactions. 10.4 Conditions to Avoid Use method that does not create dust. Also, see Incompatible Materials below. 10.5 Incompatible Materials Cyanide solutions, concentrated nitric acid (>40%), sodium hypochlorite (>8%) and organic peroxides. 10.6 Hazardous Decomposition Products Under fire conditions, product may decompose to give off fumes.of carbon dioxide, carbon monoxide and sulfur dioxide. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Not determined. LC50 results of 5.84 g/L (aquatic life unaffected in normal conditions). Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Dust could enter the eye and cause discomfort. Respiratory or Skin Sensitization: No known significant effects or critical hazards., No sensitizing effects known. Germ Cell Mutagenicity: No further relevant information available. Carcinogenicity: IARC, NTP and OSHA do not list any component of this product as a carcinogen. Reproductive Toxicity: None. Specific Target Organ Toxicity (Single Exposure): No further relevant information available. Specific Target Organ Toxicity (Repeated Exposure): No further relevant information available. Aspiration Hazard: No further relevant information available. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Eye soreness or redness and coughing. Symptoms/Injuries After Ingestion: No known significant effects or critical hazards. Unlikely that material can be ingested in large amounts. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity IARC, NTP and OSHA do not list any component of this product as a carcinogen. LC50 results on mysidopsis bahia (gulf shrimp) over 96-hours were 5.84 g/L (aquatic life were unaffected in normal conditions). 12.2. Persistence and Degradability ASTM G-21 Method (Fungal Resistance) - No growth, non-biodegradable ASTM G-22 Method (Bacterial Resistance) - No growth, non-biodegradable 12.3. Bioaccumulative Potential No further relevant information available. 12.4. Mobility in Soil Passes Paint Filter Test, Liquid Release Test, TCLP Metals, TCLP Volatiles, California W.E.T. (Waste Extraction Test) CAM17. No further relevant information available. 12.5. Other Adverse Effects No Known significant effects or critical hazards. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Product has a unique tendency to not leach. Contact your supplier or a licensed contractor for detailed recommendations. Follow applicable Federal, State and local regulations. Do not release into sewers or waterways. Waste packaging should be recycled. Excess material can be incinerated. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |N/A Hazard Class |Not Regulated |<PICTOGRAM PHRASE> Identification Number|N/A | Label Codes |Part Number(s): 200, | |201, 202, 203, 204, | |205, 206, 210, 211, | |212, 213, 214, 217, | |218, 219, 245, 251, | |252, 261, 275 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT>SARA TITLE III SECTION 313 SUPPLIER NOTIFICATION This product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the Emergency Planning & Community Right-To-Know-Act of 1986 & of 40CFR 372: None. Clean Air Act Sections 112/602: Not listed. DEA List I/II Chemicals: Not listed. SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) |All components are listed or exempt from |listing. 15.2 US State Regulations <COMPONENT> California Proposition 65: This product contains the following chemicals known to the state of California to cause cancer and/or reproductive toxicity: None. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |5/11/15 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.