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Safety Data Sheet Date of Issue: |Revision Date: 10/21/2013 |Revision Number: 1 Imperial Supplies Part Number: 0055960 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Freylube Prema CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Lubricating Grease 1.3. Name, Address, and Telephone of the Responsible Party Company Freylube Division 805 Rein Rd. Cheektowaga, NY 14225 Phone: CHEMTREC: 1-800-424-9300, 703-527-3887 1.4. Emergency Telephone Number Emergency | (800) 523-7010, Outside of US call (703) 527-3887 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | Signal Word (GHS-US) |CAUTION Hazard Statements (GHS-US) | Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Mineral Oil* |8012-95-1 |90-100% | Graphite |7782-42-5 |1-5% | | | | | | | | | | * May include one or more of the following CAS #: 64741-88-4, 64741-89-5, 64741-44-2, 64741-96-4, 64741-97-5, 64742-46-7, 64742-52-5, 64742-53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-62-7, 64742-65-0, 72623-84-8, 72623-85-9, 72623-86-0, 72623-87-1, 69029-75-0, 64742-01-4, and 64741-95-3 SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Show this safety data sheet to the doctor in attendance. If symptoms persist, call a physician. Remove contaminated clothing and shoes. Wash contaminated clothing before re-use. First-aid Measures After Inhalation: Move to fresh air in case of accidental inhalation of vapors. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Consult a physician if necessary. First-aid Measures After Skin Contact: Wash off with soap and plenty of water. Remove and wash contaminated clothing before re-use. First-aid Measures After Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. First-aid Measures After Ingestion: If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Inhalation of vapor (generated at high temperatures only) or oil mist from this product may cause mild irritation of the upper respiratory tract. Symptoms/Injuries After Skin Contact: Repeated or prolonged contact with base product may cause irritation leading to various skin disorders such as dermatitis, oil acne, or foliculitis. Symptoms/Injuries After Eye Contact: Irritating to eyes. Symptoms/Injuries After Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Note to physician: Treat symptomatically. Medical condition aggravated by exposure: Dermatitis. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use dry chemical, CO2, water spray or `alcohol` foam. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Do not allow material to contaminate ground water system. None known. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Water mist may be used to cool closed containers. Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Ensure adequate ventilation. Use personal protective equipment. Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Do not flush into surface water or sanitary sewer system. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up and shovel into suitable containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Technical measures/precautions: Provide sufficient air exchange and/or exhaust in work rooms. Safe handling advice: In case of insufficient ventilation, wear suitable respiratory equipment. Wear personal protective equipment. Avoid contact with skin and eyes. Wash thoroughly after handling. Hygiene Measures: Avoid contact with skin, eyes and clothing. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Store at room temperature in the original container. Storage Conditions: Store at room temperature in the original container. Incompatible products: Strong oxidizing agents Safe storage temperature: 5-35 �C Shelf life: 2 years 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components OSHA Ceiling Limits OSHA TWA (final) ACGIH Ceiling Limits ACGIH Exposure Limits NIOSH - Pocket Guide Vendor Exposure Limits Mineral Oil* None 5mg/m� None 5 mg/m� 5mg/m� None Graphite None 15 mg/m3 None 2 mg/m3 (TWA) 2.5 mg/m3 (TWA) None 8.2. Exposure Controls Appropriate Engineering |Ensure adequate ventilation. Controls | Personal Protective Equipment|General: Eye Wash and Safety Shower Materials for Protective | Clothing | Hand Protection |Recommended: neoprene, latex, nitrile, butyl rubber |and polyethylene type. Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Long sleeved clothing. Respiratory Protection |If engineering controls do not maintain airborne |concentrations to a level which is adequate to |protect worker health, a NIOSH-certified respirator |with organic vapor/P100 filter should be worn. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Semi-solid Appearance | Odor |Characteristic Odor Threshold | pH |NA Relative Evaporation Rate |Not determined (butylacetate=1) | Melting Point | Freezing Point | Boiling Point | Flash Point |(�C): 281 |(�F): 538 Auto-ignition Temperature |Not determined Decomposition Temperature |Not determined Flammability (solid, gas) | Vapor Pressure |Not determined Relative Vapor Density at 20 �C |Not determined Relative Density | Specific Gravity | Solubility |InsolubleNot determined Partition coefficient: |Not determined n-octanol/water | Viscosity | Lower Flammable Limit |No data available Upper Flammable Limit |No data available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions Not applicable. 10.4 Conditions to Avoid None known. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides. Not applicable. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: MINERAL OIL INFORMATION: Any product containing a substance for which OSHA has established a permissible exposure limit (PEL) is considered hazardous. OSHA has established a PEL of 5 mg/m3 for worker exposure to air borne mists of mineral oils. Therefore, the presence of mineral oils brings this product within the provisions of the OSHA Hazard Communication Standard where the PEL reaches or exceeds 5 mg/m3. Health studies have shown that many petroleum hydrocarbons pose potential human health risks which may vary from person to person. As a precaution, exposure to liquids, vapors, mists or fumes should be minimized. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Not Determined. 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential Not available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No data available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste disposal must be in accordance with appropriate Federal, State, and local regulations. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority. Additional Information: Contaminated packaging: Do not re-use empty containers. Methods for cleaning up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up and shovel into suitable containers for disposal. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not Regulated Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not Regulated Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not Regulated Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> OSHA Hazard Communication Standard: This product is considered to be hazardous under the OSHA Hazard Communication Standard. CERCLA/SARA 313 Emission reporting: This product contains no components subject to the reporting requirements of SARA 313.: Components Hazardous Substances and RQs Extremely Hazardous Substances and TPQs SARA 313 Emission Reporting Mineral Oil* Not listed Not listed Not listed Graphite Not listed Not listed Not listed Clean Air and Clean Water Acts: Components Hazardous Air Pollutants CWA - Hazardous Substances CWA - Toxic Pollutants CWA - Priority Pollutants Mineral Oil* Not listed Not listed Not listed Not listed Graphite Not listed Not listed Not listed Not listed RCRA Status: Not regulated. SARA Section 311/312 Hazard Classes |Immediate Health (Acute): Yes |Delayed Health (Chronic): No |Flammability: No |Pressure: No |Reactivity: No Toxic Substances Control Act (TSCA) |This product complies with TSCA. 15.2 US State Regulations <COMPONENT> U.S. STATE REGULATIONS (RTK): Components California Proposition 65 PARTK MI Critical Materials NJRTK MARTK Mineral Oil* Not Listed Present Not Listed 1437 Present Graphite Not Listed Present Not Listed 1437 Present SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |10/21/2013 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.