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SDS Sheet 0055920Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 3M(TM) SUPER DUTY RUBBING COMPOUND PN 5954 5955 5956 39004 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Automotive, Painted surface defect repair 1.3. Name, Address, and Telephone of the Responsible Party Company: 3M Automotive Aftermarket 3M Center, St. Paul, MN 55144-1000, USA Phone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency Telephone Number Emergency | 1-800-364-3577 or (651) 737-6501 (24 hours) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 4. Liquid | Carcinogenicit|Category 1A. y | Specific |Category 1. Target Organ | Toxicity | (repeated | exposure) | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Health Hazard Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Combustible liquid. |May cause cancer. |Causes damage to organs through prolonged or |repeated exposure: respiratory system Precautionary Statements |General: (GHS-US) |Keep out of reach of children. |Prevention: |Obtain special instructions before use. |Do not handle until all safety precautions have been |read and understood. |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. |Do not breathe dust/fume/gas/mist/vapors/spray. |Wear protective gloves and eye/face protection. |Do not eat, drink or smoke when using this product. |Wash thoroughly after handling. |Response: |IF exposed or concerned: Get medical |advice/attention. |In case of fire: Use a fire fighting agent suitable |for flammable liquids and solids such as dry |chemical or carbon dioxide to extinguish. |Storage: |Store in a well-ventilated place. Keep cool. |Store locked up. |Disposal: |Dispose of contents/container in accordance with |applicable local/regional/national/international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Tripoli |1317-95-9 |30 - 60 | | |Trade | | |Secret *| Kerosene |8008-20-6 |10 - 30 | | |Trade | | |Secret *| Water |7732-18-5 |10 - 30 | | |Trade | | |Secret *| Oleic Acid |112-80-1 |1 - 5 | | |Trade | | |Secret *| Pine Oil |8002-09-3 |1 - 5 | | |Trade | | |Secret *| Solvent-Refined Heavy Paraffinic|64741-88-4 |1 - 5 | Petroleum Distillates | |Trade | | |Secret *| Hydrotreated Light Petroleum |64742-47-8 |< 2 | Distillates | |Trade | | |Secret *| Mineral Oil |64741-89-5 |< 2 | | |Trade | | |Secret *| Polyethylene Glycol Sorbitan |9005-65-6 |0.1 - | Monooleate | |1.0 | | |Trade | | |Secret *| *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. First-aid Measures After Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. First-aid Measures After Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. First-aid Measures After Ingestion: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Not applicable SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry chemical or carbon dioxide to extinguish. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Closed containers exposed to heat from fire may build pressure and explode. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in a well-ventilated place. Keep cool. Store away from heat. Store away from acids. Store away from oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Ingredient C.A.S. No. Agency Limit type Additional Comments Tripoli 1317-95-9 Amer Conf of Gov. Indust. Hyg. TWA(respirable fraction):0.025 mg/m3 Mineral oils (untreated and mildly treated) 64741-88-4 Amer Conf of Gov. Indust. Hyg. Limit value not established: Cntrl all exposr-low as possib MINERAL OILS, HIGHLYREFINED OILS 64741-88-4 Amer Conf of Gov. Indust. Hyg. TWA(inhalable fraction):5 mg/m3 Paraffin oil 64741-88-4 US Dept of Labor - OSHA TWA(as mist):5 mg/m3 PETROLEUM DISTILLATES 64741-88-4 US Dept of Labor - OSHA TWA:2000 mg/m3(500 ppm) Solvent-Refined Heavy Paraffinic Petroleum Distillates 64741-88-4 Chemical Manufacturer Rec Guid TWA:5 mg/m3 Mineral oils (untreated and mildly treated) 64741-89-5 Amer Conf of Gov. Indust. Hyg. Limit value not established: Cntrl all exposr-low as possib MINERAL OILS, HIGHLYREFINED OILS 64741-89-5 Amer Conf of Gov. Indust. Hyg. TWA(inhalable fraction):5 mg/m3 Paraffin oil 64741-89-5 US Dept of Labor - OSHA TWA(as mist):5 mg/m3 Hydrotreated Light Petroleum Distillates 64742-47-8 Chemical Manufacturer Rec Guid TWA:165 ppm Kerosine (petroleum) 64742-47-8 Amer Conf of Gov. Indust. Hyg. TWA(as total hydrocarbon vapor, non aerosol):200 mg/m3 Skin Notation Pine Oil 8002-09-3 Chemical Manufacturer Rec Guid TWA:100 ppm Kerosene 8008-20-6 Amer Conf of Gov. Indust. Hyg. TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 Skin Notation Kerosene 8008-20-6 Chemical Manufacturer Rec Guid TWA:500 ppm(2000 mg/m3) 8.2. Exposure Controls Appropriate Engineering |Use general dilution ventilation and/or local Controls |exhaust ventilation to control airborne exposures to |below relevant Exposure Limits and/or control |dust/fume/gas/mist/vapors/spray. If ventilation is |not adequate, use respiratory protection equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Select and use gloves and/or protective clothing |approved to relevant local standards to prevent skin |contact based on the results of an exposure |assessment. Selection should be based on use factors |such as exposure levels, concentration of the |substance or mixture, frequency and duration, |physical challenges such as temperature extremes, |and other use conditions. Consult with your glove |and/or protective clothing manufacturer for |selection of appropriate compatible |gloves/protective clothing. Wear protective gloves. |Gloves made from the following material(s) are |recommended: Nitrile Rubber. Eye Protection |Wear eye/face protection. Select and use eye/face |protection to prevent contact based on the results |of an exposure assessment. The following eye/face |protection(s) are recommended: Safety Glasses with |side shields Indirect Vented Goggles. Skin and Body Protection |Select and use gloves and/or protective clothing |approved to relevant local standards to prevent skin |contact based on the results of an exposure |assessment. Selection should be based on use factors |such as exposure levels, concentration of the |substance or mixture, frequency and duration, |physical challenges such as temperature extremes, |and other use conditions. Consult with your glove |and/or protective clothing manufacturer for |selection of appropriate compatible |gloves/protective clothing. Wear protective gloves. |Gloves made from the following material(s) are |recommended: Nitrile Rubber. Respiratory Protection |An exposure assessment may be needed to decide if a |respirator is required. If a respirator is needed, |use respirators as part of a full respiratory |protection program. Based on the results of the |exposure assessment, select from the following |respirator type(s) to reduce inhalation exposure: |Half facepiece or full facepiece air-purifying |respirator suitable for organic vapors and |particulates. For questions about suitability for a |specific application, consult with your respirator |manufacturer. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid, Emulsion Appearance | Odor |Petroleum odor, brown viscous liquid. Odor Threshold |No Data Available pH |7.5 - 8.5 Relative Evaporation Rate |No Data Available (butylacetate=1) | Melting Point |Not Applicable Freezing Point | Boiling Point |> 95 Deg F Flash Point |160 Deg F [Test Method: Closed Cup] Auto-ignition Temperature |No Data Available Decomposition Temperature |No Data Available Flammability (solid, gas) |Not Applicable Vapor Pressure |No Data Available Relative Vapor Density at 20 Â°C |No Data Available Relative Density | Specific Gravity |1.33 [Ref Std: WATER=1] Solubility |Negligible Partition coefficient: |No Data Available n-octanol/water | Viscosity |14,000 - 18,000 centipoise Lower Flammable Limit |No Data Available Upper Flammable Limit |No Data Available 9.2. Other Information Volatile Organic Compounds 239 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 16.0 % weight [Test Method: calculated per CARB title 2] Percent volatile 44.2 % weight VOC Less H2O & Exempt Solvents 367 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Heat 10.5 Incompatible Materials Strong acids Strong oxidizing agents 10.6 Hazardous Decomposition Products Substance Condition None known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Prolonged or repeated exposure may cause: Silicosis: Signs/symptoms may include breathlessness, weakness, chest pain, persistent cough, increased amounts of sputum, and heart disease. Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Value Kerosene Solvent-Refined Heavy Paraffinic Petroleum Distillates Hydrotreated Light Petroleum Distillates Mineral Oil Symptoms/Injuries After Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Symptoms/Injuries After Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Symptoms/Injuries After Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Symptoms/Injuries After Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause target organ effects after ingestion. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Contact 3M for more information. SARA Section 311/312 Hazard Classes |Fire Hazard - Yes |Pressure Hazard - Yes |Reactivity Hazard - No |Immediate Hazard - Yes |Delayed Hazard - Yes Toxic Substances Control Act (TSCA) |The components of this product are in |compliance with the chemical notification |requirements of TSCA. |Contact 3M for more information. 15.2 US State Regulations <COMPONENT> Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification SILICA, CRYSTALLINE (AIRBORNE None Carcinogen PARTICLES OF RESPIRABLE SIZE) Benzene 71-43-2 Male reproductive toxin Benzene 71-43-2 Carcinogen Benzene 71-43-2 Developmental Toxin WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.