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SDS Sheet 0055220Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Quick Flow Emergency Diesel-Gel Relief CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Dissolve gelled diesel fuel 1.3. Name, Address, and Telephone of the Responsible Party Company: CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168 1.4. Emergency Telephone Number Emergency |800-424-9300 (US) number |703-527-3887 (International) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 3 liquids | Carcinogenicit|Category 2 y | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Aspiration |Category 1 hazard | Hazardous to |Category 2 the aquatic | environment, | acute hazard | Hazardous to |Category 3 the aquatic | environment, | long-term | hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Flammable liquid and vapor. May be fatal if |swallowed and enters airways. May cause drowsiness |or dizziness. Suspected of causing cancer. Toxic to |aquatic life. Harmful to aquatic life with long |lasting effects. Precautionary Statements |Prevention (GHS-US) |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Keep away from heat/sparks/open |flames/hot surfaces. - No smoking. Keep container |tightly closed. Use explosion-proof |electrical/ventilating/lighting equipment. Use only |non-sparking tools. Take precautionary measures |against static discharge. Use only with adequate |ventilation; maintain ventilation during use and |until all vapors are gone. Open doors and windows or |use other means to ensure a fresh air supply during |use and while product is drying. If you experience |any symptoms listed on this label, increase |ventilation or leave the area. Avoid breathing mist |or vapor. Wear protective gloves/protective |clothing/eye protection/face protection. Avoid |release to the environment. | |Response |If swallowed: Immediately call a poison |center/doctor. Do NOT induce vomiting. If on skin |(or hair): Take off immediately all contaminated |clothing. Rinse skin with water/shower. If inhaled: |Remove person to fresh air and keep comfortable for |breathing. Call a poison center/doctor if you feel |unwell. If exposed or concerned: Get medical |attention. In case of fire: Do not use water jet as |an extinguisher, as this will spread the fire. | |Storage |Store in a well-ventilated place. Keep cool. Store |locked up. | |Disposal |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Stoddard Solvent |8052-41-3 |80 - 90 | Solvent naphtha (petroleum), |64742-94-5 |5 - 10 | heavy arom. | | | 1,2,4-Trimethylbenzene |95-63-6 |1 - 3 | Naphthalene |91-20-3 |< 1 | | | | Specific chemical identity and/or percentage of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Take off all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical attention if irritation develops and persists. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of eyes and mucous membranes. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Flammable liquid and vapor. Explosion Hazard: Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Protection During Firefighting: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Methods for Cleaning Up: Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust ventilation. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary measures against static discharges. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid prolonged exposure. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Hygiene Measures: When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep away from heat, sparks and open flame. Eliminate sources of ignition. Avoid spark promoters. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Keep container tightly closed. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Naphthalene (CAS 91-20-3) PEL 50 mg/m3 10 ppm Solvent naphtha(petroleum), heavy arom. (CAS 64742-94-5) PEL 400 mg/m3 100 ppm Stoddard Solvent (CAS 8052-41-3) PEL 2900 mg/m3 500 ppm US. ACGIH Threshold Limit Values Components Type Value Form 1,2,4-Trimethylbenzene (CAS 95-63-6) TWA 25 ppm Naphthalene (CAS 91-20-3) TWA 10 ppm Solvent naphtha (petroleum), heavy arom. (CAS 64742-94-5) TWA 200 mg/m3 Non-aerosol. Stoddard Solvent (CAS 8052-41-3) TWA 100 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value 1,2,4-Trimethylbenzene (CAS 95-63-6) TWA 125 mg/m3 25 ppm Naphthalene (CAS 91-20-3) STEL TWA 75 mg/m3 15 ppm 50 mg/m3 10 ppm Stoddard Solvent (CAS 8052-41-3) Ceiling TWA 1800 mg/m3 350 mg/m3 8.2. Exposure Controls Appropriate Engineering |Explosion-proof general and local exhaust Controls |ventilation. Good general ventilation (typically 10 |air changes per hour) should be used. Ventilation |rates should be matched to conditions. If |applicable, use process enclosures, local exhaust |ventilation, or other engineering controls to |maintain airborne levels below recommended exposure |limits. If exposure limits have not been |established, maintain airborne levels to an |acceptable level. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Nitrile. Neoprene. |Polyvinyl chloride (PVC). Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection |Wear suitable protective clothing. Use of an |impervious apron is recommended. Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Petroleum. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Slow. (butylacetate=1) | Melting Point |-94 Â°F (-70 Â°C) estimated Freezing Point |-94 Â°F (-70 Â°C) estimated Boiling Point |315 Â°F (157.2 Â°C) estimated Flash Point |110 Â°F (43.3 Â°C) Tag Closed Cup Auto-ignition Temperature |450 Â°F (232.2 Â°C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |0.9 hPa estimated Relative Vapor Density at 20 Â°C |> 4 (air = 1) Relative Density |0.79 Specific Gravity | Solubility |Negligible. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |0.7 % estimated Upper Flammable Limit |6.8 % estimated 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: May be fatal if swallowed and enters airways. Narcotic effects. Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: Suspected of causing cancer. Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Symptoms/Injuries After Inhalation: May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Symptoms/Injuries After Skin Contact: Prolonged skin contact may cause temporary irritation. Symptoms/Injuries After Eye Contact: Direct contact with eyes may cause temporary irritation. Symptoms/Injuries After Ingestion: Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Chronic Symptoms: Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Components Species Test Results 1,2,4-Trimethylbenzene (CAS 95-63-6) Aquatic Fish LC50 Fathead minnow (Pimephales promelas) 7.19 - 8.28 mg/l, 96 hours Naphthalene (CAS 91-20-3) Aquatic Acute Crustacea EC50 Water flea (Daphnia magna) 1.09 - 3.4 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 1.6 mg/l, 96 hours (Oncorhynchus mykiss) Solvent naphtha (petroleum), heavy arom. (CAS 64742-94-5) Aquatic Crustacea EC50 Water flea (Daphnia pulex) 2.7 - 5.1 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 8.8 mg/l, 96 hours (Oncorhynchus mykiss) 8.8 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Additional Information: Hazardous waste code: D001: Waste Flammable material with a flash point <140 F Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Petroleum distillates, n.o.s. or Petroleum products, n.o.s., |Limited Quantity Hazard Class |3 |<PICTOGRAM PHRASE> Identification Number|UN1268 | Label Codes |3 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S., |LIMITED QUANTITY Hazard Class |3 Identification Number|UN1268 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |E | EmS-No. (Spillage) |E | 14.3 In Accordance with IATA Proper Shipping Name |Petroleum products, n.o.s., Limited Quantity Identification Number|UN1268 |<PICTOGRAM PHRASE> Hazard Class |3 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |3L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance 1,2,4-Trimethylbenzene (CAS 95-63-6) Naphthalene (CAS 91-20-3) CERCLA Hazardous Substance List (40 CFR 302.4) Naphthalene (CAS 91-20-3) CERCLA Hazardous Substances: Reportable quantity Naphthalene (CAS 91-20-3) 100 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA): Not regulated. Food and Drug Administration (FDA): Not regulated SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not regulated. 15.2 US State Regulations <COMPONENT> US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Stoddard Solvent (CAS 8052-41-3) 1,2,4-Trimethylbenzene (CAS 95-63-6) Naphthalene (CAS 91-20-3) Solvent naphtha (petroleum), heavy arom. (CAS 64742-94-5) US. Massachusetts RTK - Substance List 1,2,4-Trimethylbenzene (CAS 95-63-6) Stoddard Solvent (CAS 8052-41-3) US. Pennsylvania Worker and Community Right-to-Know Law Naphthalene (CAS 91-20-3) 1,2,4-Trimethylbenzene (CAS 95-63-6) Stoddard Solvent (CAS 8052-41-3) US. Rhode Island RTK 1,2,4-Trimethylbenzene (CAS 95-63-6) Naphthalene (CAS 91-20-3) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004 Naphthalene (CAS 91-20-3) Listed: April 19, 2002 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.