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Safety Data Sheet | | Date of Issue: |Revision Date: 09/15/2014 |Revision Number: Imperial Supplies Part Number: 0055210 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ. CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Windshield Washer Concentrate 1.3. Name, Address, and Telephone of the Responsible Party Company: Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 Phone: T 817-645-6088 Supplier: Imperial Supplies LLC 1.4. Emergency Telephone Number Emergency | 1-800-424-9300, 1-703-527-3887 (International) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flam. Liq. 2 |H225 Acute Tox. 3 |H301 (Oral) | Acute Tox. 3 |H311 (Dermal) | Acute Tox. 3 |H331 (Inhalation:du| st,mist) | STOT SE 1 |H370 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Skulls |Health | | | | |and |hazard | | | | |crossbon| | | | | |es | | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H225 - Highly flammable liquid and vapor |H301+H311+H331 - Toxic if swallowed, in contact with |skin or if inhaled |H370 - Causes damage to organs Precautionary Statements |P210 - Keep away from heat,sparks,open flames,hot (GHS-US) |surfaces. - No smoking |P233 - Keep container tightly closed |P240 - Ground/bond container and receiving equipment | |P241 - Use explosion-proof electrical, ventilating, |lighting equipment |P242 - Use only non-sparking tools |P243 - Take precautionary measures against static |discharge |P260 - Do not breathe dust,fumes,gas,mist,vapor |spray |P261 - Avoid breathing dust,fume,gas,mist,vapor |spray |P264 - Wash affected areas thoroughly after handling | |P270 - Do not eat, drink or smoke when using this |product |P271 - Use only outdoors or in a well-ventilated |area |P280 - Wear protective gloves,protective |clothing,eye protection,face protection |P301+P310 - If swallowed: Immediately call a poison |control center, doctor,physician, |P302+P352 - If on skin: Wash with plenty of soap and |water |P303+P361+P353 - If on skin (or hair): Take off |immediately all contaminated clothing. Rinse |skin with water/shower |P304+P340 - If inhaled: Remove person to fresh air |and keep comfortable for breathing |P307+P311 - If exposed: Call a poison center/doctor |P311 - Call a poison center,doctor |P312 - Call a POISON CONTROL CENTER, doctor, if you |feel unwell. |P321 - Specific treatment: See section 4.1 on SDS |P330 - Rinse mouth |P361 - Take off immediately all contaminated |clothing |P363 - Wash contaminated clothing before reuse |P370+P378 - In case of fire: See Section 5.1 |Extinguishing Media |P403+P233 - Store in a well-ventilated place. Keep |container tightly closed |P403+P235 - Store in a well-ventilated place. Keep |cool |P405 - Store locked up |P501 - Dispose of contents/container to appropriate |waste disposal facility, in accordance with |local, regional, national, international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None under normal conditions. 2.4. Unknown Acute Toxicity (GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Methanol |(CAS No) 67-56-1 |>= 95 |Flam. Liq. 2, H225 | | | | | |Acute Tox. 3 | | |(Oral), H301 | | |Acute Tox. 3 | | |(Dermal), H311 | | |Acute Tox. 3 | | |(Inhalation:dust,m | | |ist), | | |H331 | | |STOT SE 1, H370 Polyethylene Glycol 200-600 |(CAS No) 25322-68-3 |<= |Not classified | |0.0045 | Nonyl Nonoxynol-5 |(CAS No) 9014-93-1 |<= 0.003|Not classified Hydrogen |(CAS No) 129-17-9 |~ |Not classified [4-[4-(Diethylamino)-2',4'- | |0.000001| Disulphonatobenzhydrylidene] | | | Cyclohexa-2,5-Dien-1-ylidene] | | | Diethylammonium, Sodium Salt | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: IF exposed or concerned: Get medical advice/attention. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Call a POISON CENTER or doctor/physician. First-aid Measures After Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. First-aid Measures After Skin Contact: Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap and water. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. Immediately call a POISON CENTER or doctor/physician. Obtain medical attention if pain, blinking or redness persist. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Toxic if inhaled. Danger of serious damage to health by prolonged exposure through inhalation. Symptoms/Injuries After Skin Contact: Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Symptoms/Injuries After Eye Contact: Causes serious eye damage. Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/Injuries After Ingestion: Fatal if swallowed. Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed No additional information available. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable Extinguishing Media: Do not use a heavy water stream. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Highly flammable liquid and vapor. Explosion Hazard: May form flammable/explosive vapor-air mixture. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Remove ignition sources. Use special care to avoid static electric charges. No naked lights. No smoking. 6.1.1. For Non-emergency Personnel Protective Equipment: Gloves. Safety glasses. Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Responders Protective Equipment: Equip cleanup crew with proper protection. Avoid breathing dust,fume,gas,mist,vapor spray. Emergency Procedures: Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for Cleaning Up: Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Handle empty containers with care because residual vapors are flammable. Do not handle until all safety precautions have been read and understood. Obtain special instructions . Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No naked lights. No smoking. Use only non-sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing dust, fume, gas, mist, vapor spray. Do not breathe dust, fumes, gas, mist, vapor spray. Hygiene Measures: Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting equipment. Storage Conditions: Keep only in the original container in a cool, well ventilated place away from : Keep in fireproof place. Keep container tightly closed. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Methanol (67-56-1) USA ACGIH ACGIH TWA (mg/m�) 262 mg/m� USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (mg/m�) 328 mg/m� USA ACGIH ACGIH STEL (ppm) 250 ppm USA OSHA OSHA PEL (TWA) (mg/m�) 260 mg/m� USA OSHA OSHA PEL (TWA) (ppm) 200 ppm 8.2. Exposure Controls Appropriate Engineering |Local exhaust ventilation, vent hoods. Controls | Personal Protective Equipment|Safety glasses. Gloves. Avoid all unnecessary |exposure. |Other information : Do not eat, drink or smoke |during use. |Avoid contact during pregnancy/while nursing. Materials for Protective | Clothing | Hand Protection |Wear protective gloves. Eye Protection |Chemical goggles or safety glasses. Skin and Body Protection |Wear suitable protective clothing. Respiratory Protection |Where exposure through inhalation may occur from |use, respiratory protection equipment is |recommended. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance | Odor |Mild . Odourless. Odor Threshold |4.2 - 5960 ppm pH |? 7 Relative Evaporation Rate |4.1 (butylacetate=1) | Melting Point |No data available Freezing Point |-97.8 Boiling Point |64.7 �C Flash Point |11 �C Auto-ignition Temperature |464 �C Decomposition Temperature |Not Determined Flammability (solid, gas) |No data available Vapor Pressure |12.8 kPa @ 20 deg C Relative Vapor Density at 20 �C |No data available Relative Density |0.792 Specific Gravity | Solubility |Soluble in alcohols. Soluble in water. Partition coefficient: | n-octanol/water | Viscosity |No data available Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information VOC content : > 98 % Explosive limits : 36.5 vol % Upper Explosive Limit (UEL) SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No additional information available 10.2 Chemical Stability Highly flammable liquid and vapor. May form flammable/explosive vapor-air mixture. 10.3 Possibility of Hazardous Reactions Not established. 10.4 Conditions to Avoid Direct sunlight. Extremely high or low temperatures. Open flame. 10.5 Incompatible Materials Sources of ignition. Direct sunlight. Heat sources. Strong acids. Strong bases. 10.6 Hazardous Decomposition Products Toxic fume. . Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Skin Corrosion/Irritation: Not classified. pH: ? 7. Serious Eye Damage/Irritation: Not classified. pH: ? 7. Respiratory or Skin Sensitization: Not classified. Germ Cell Mutagenicity: Not classified Based on available data, the classification criteria are not met. Carcinogenicity: Not classified. Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Causes damage to organs. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: Toxic if inhaled. Danger of serious damage to health by prolonged exposure through inhalation. Symptoms/Injuries After Skin Contact: Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Symptoms/Injuries After Eye Contact: Causes serious eye damage. Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/Injuries After Ingestion: Fatal if swallowed. Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Other information : Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Additional Information: Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Methanol Solution Hazard Class |3 |<PICTOGRAM PHRASE> Identification Number|UN1230 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Methanol Solution Hazard Class |3 (6.1) Identification Number|UN1230 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Methanol Solution Identification Number|UN1230 |<PICTOGRAM PHRASE> Hazard Class |3 (6.1) | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Methanol (67-56-1) Listed on United States SARA Section 313 SARA Section 311/312 Hazard Classes |Immediate (acute) health hazard |Delayed (chronic) health hazard |Fire hazard Toxic Substances Control Act (TSCA) |Methanol (67-56-1) |Listed on the United States TSCA (Toxic |Substances Control Act) inventory 15.2 US State Regulations <COMPONENT> SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |09/15/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Acute Tox. 3 (Dermal) |Acute toxicity (dermal) Category 3 -- | | ----|Acute Tox. 3 |Acute toxicity (inhalation:dust,mist) -- |(Inhalation:dust,mist) |Category 3 ----|Acute Tox. 3 (Oral) |Acute toxicity (oral) Category 3 -- | | ----|Flam. Liq. 2 |Flammable liquids Category 2 -- | | ----|STOT SE 1 |Specific target organ toxicity (single -- | |exposure) Category 1 |H225 |Highly flammable liquid and vapor |H301 |Toxic if swallowed |H311 |Toxic in contact with skin |H331 |Toxic if inhaled |H370 |Causes damage to organs Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.