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SDS Sheet 0055210

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Safety Data Sheet | |
Date of Issue:             |Revision Date: 09/15/2014  |Revision Number:          
Imperial Supplies Part Number: 0055210                                            

SECTION 1: IDENTIFICATION                                                         


1.1.  Product Identifier
Product Form:                                                                     
Product Name: JOHNSEN'S WINDSHIELD WASH CONCENTRATION 12 FL.OZ.                   
CAS No:                                                                           
Synonyms:                                                                         


1.2.  Intended Use of the Product
Use of the substance/mixture: Windshield Washer Concentrate                       


1.3.  Name, Address, and Telephone of the Responsible Party
Company:                                                                          
Technical Chemical Company                                                        
P.O. BOX 139                                                                      
Cleburne,                                                                         
Texas 76033                                                                       
Phone: T 817-645-6088                                                             
                                                                                  
Supplier: Imperial Supplies LLC                                                   


1.4.  Emergency Telephone Number
Emergency     |  1-800-424-9300, 1-703-527-3887 (International)                   
number        |                                                                   

SECTION 2: HAZARDS IDENTIFICATION                                                 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flam. Liq. 2  |H225          
Acute Tox. 3  |H301          
(Oral)        |              
Acute Tox. 3  |H311          
(Dermal)      |              
Acute Tox. 3  |H331          
(Inhalation:du|              
st,mist)      |              
STOT SE 1     |H370          


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame   |Skulls  |Health  |        |        |        
                             |        |and     |hazard  |        |        |        
                             |        |crossbon|        |        |        |        
                             |        |es      |        |        |        |        
Signal Word (GHS-US)         |Danger                                              
Hazard Statements (GHS-US)   |H225 - Highly flammable liquid and vapor            
                             |H301+H311+H331 - Toxic if swallowed, in contact with
                             |skin or if inhaled                                  
                             |H370 - Causes damage to organs                      
Precautionary Statements     |P210 - Keep away from heat,sparks,open flames,hot   
(GHS-US)                     |surfaces. - No smoking                              
                             |P233 - Keep container tightly closed                
                             |P240 - Ground/bond container and receiving equipment
                             |                                                    
                             |P241 - Use explosion-proof electrical, ventilating, 
                             |lighting equipment                                  
                             |P242 - Use only non-sparking tools                  
                             |P243 - Take precautionary measures against static   
                             |discharge                                           
                             |P260 - Do not breathe dust,fumes,gas,mist,vapor     
                             |spray                                               
                             |P261 - Avoid breathing dust,fume,gas,mist,vapor     
                             |spray                                               
                             |P264 - Wash affected areas thoroughly after handling
                             |                                                    
                             |P270 - Do not eat, drink or smoke when using this   
                             |product                                             
                             |P271 - Use only outdoors or in a well-ventilated    
                             |area                                                
                             |P280 - Wear protective gloves,protective            
                             |clothing,eye protection,face protection             
                             |P301+P310 - If swallowed: Immediately call a poison 
                             |control center, doctor,physician,                   
                             |P302+P352 - If on skin: Wash with plenty of soap and
                             |water                                               
                             |P303+P361+P353 - If on skin (or hair): Take off     
                             |immediately all contaminated clothing. Rinse        
                             |skin with water/shower                              
                             |P304+P340 - If inhaled: Remove person to fresh air  
                             |and keep comfortable for breathing                  
                             |P307+P311 - If exposed: Call a poison center/doctor 
                             |P311 - Call a poison center,doctor                  
                             |P312 - Call a POISON CONTROL CENTER, doctor, if you 
                             |feel unwell.                                        
                             |P321 - Specific treatment: See section 4.1 on SDS   
                             |P330 - Rinse mouth                                  
                             |P361 - Take off immediately all contaminated        
                             |clothing                                            
                             |P363 - Wash contaminated clothing before reuse      
                             |P370+P378 - In case of fire: See Section 5.1        
                             |Extinguishing Media                                 
                             |P403+P233 - Store in a well-ventilated place. Keep  
                             |container tightly closed                            
                             |P403+P235 - Store in a well-ventilated place. Keep  
                             |cool                                                
                             |P405 - Store locked up                              
                             |P501 - Dispose of contents/container to appropriate 
                             |waste disposal facility, in accordance with         
                             |local, regional, national, international            
                             |regulations.                                        


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: None under normal           
conditions.                                                                       


2.4.  Unknown Acute Toxicity (GHS-US)
No data available                                                                 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                                 


3.1.  Substance
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  
                                |                     |        |                  


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification    
                                |                     |        |(GHS-US)          
Methanol                        |(CAS No) 67-56-1     |>= 95   |Flam. Liq. 2, H225
                                |                     |        |                  
                                |                     |        |Acute Tox. 3      
                                |                     |        |(Oral), H301      
                                |                     |        |Acute Tox. 3      
                                |                     |        |(Dermal), H311    
                                |                     |        |Acute Tox. 3      
                                |                     |        |(Inhalation:dust,m
                                |                     |        |ist),             
                                |                     |        |H331              
                                |                     |        |STOT SE 1, H370   
Polyethylene Glycol 200-600     |(CAS No) 25322-68-3  |<=      |Not classified    
                                |                     |0.0045  |                  
Nonyl Nonoxynol-5               |(CAS No) 9014-93-1   |<= 0.003|Not classified    
Hydrogen                        |(CAS No) 129-17-9    |~       |Not classified    
[4-[4-(Diethylamino)-2',4'-     |                     |0.000001|                  
Disulphonatobenzhydrylidene]    |                     |        |                  
Cyclohexa-2,5-Dien-1-ylidene]   |                     |        |                  
Diethylammonium, Sodium Salt    |                     |        |                  
                                |                     |        |                  


SECTION 4: FIRST AID MEASURES                                                     


4.1.  Description of First Aid Measures
First-aid Measures General: IF exposed or concerned: Get medical advice/attention.
Never give anything by mouth to an                                                
unconscious person. If you feel unwell, seek medical advice (show the label where 
possible). Call a POISON CENTER or doctor/physician.                              
First-aid Measures After Inhalation: Remove to fresh air and keep at rest in a    
position comfortable for breathing. Immediately call a POISON CENTER or           
doctor/physician.                                                                 
First-aid Measures After Skin Contact: Rinse skin with water/shower. Remove/Take  
off immediately all contaminated clothing.                                        
Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap and
water. Wash contaminated clothing before reuse.                                   
First-aid Measures After Eye Contact: Remove contact lenses, if present and easy  
to do. Continue rinsing. Rinse cautiously with water for several minutes.         
Immediately call a POISON CENTER or doctor/physician. Obtain medical attention if 
pain, blinking or redness persist.                                                
First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain   
emergency medical attention. Immediately call a POISON CENTER or doctor/physician.


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                                
Symptoms/Injuries After Inhalation: Toxic if inhaled. Danger of serious damage to 
health by prolonged exposure through inhalation.                                  
Symptoms/Injuries After Skin Contact: Repeated exposure to this material can      
result in absorption through skin causing significant health hazard. Toxic in     
contact with skin.                                                                
Symptoms/Injuries After Eye Contact: Causes serious eye damage. Irritation of the 
eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue.     
Symptoms/Injuries After Ingestion: Fatal if swallowed. Toxic if swallowed.        
Swallowing a small quantity of this material will result in serious health hazard.
Chronic Symptoms:                                                                 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
No additional information available.                                              

SECTION 5: FIRE-FIGHTING MEASURES                                                 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable Extinguishing Media: Do not use a heavy water stream.                  


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Highly flammable liquid and vapor.                                   
Explosion Hazard: May form flammable/explosive vapor-air mixture.                 
Reactivity:                                                                       


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                      
Firefighting Instructions: Use water spray or fog for cooling exposed containers. 
Exercise caution when fighting any                                                
chemical fire. Prevent fire-fighting water from entering environment.             
Protection During Firefighting: Do not enter fire area without proper protective  
equipment, including respiratory protection.                                      

SECTION 6: ACCIDENTAL RELEASE MEASURES                                            


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Remove ignition sources. Use special care to avoid static       
electric charges. No naked lights. No                                             
smoking.                                                                          


6.1.1.      For Non-emergency Personnel
Protective Equipment:  Gloves. Safety glasses.                                    
Emergency Procedures: Evacuate unnecessary personnel.                             


6.1.2.      For Emergency Responders
Protective Equipment: Equip cleanup crew with proper protection. Avoid breathing  
dust,fume,gas,mist,vapor spray.                                                   
Emergency Procedures: Ventilate area.                                             


6.2.  Environmental Precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters    
sewers or public waters.                                                          


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Dam up the liquid spill. Contain released substance, pump into   
suitable containers. Plug the leak,                                               
cut off the supply.                                                               
Methods for Cleaning Up: Soak up spills with inert solids, such as clay or        
diatomaceous earth as soon as possible. Collect                                   
spillage. Store away from other materials.                                        


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                        


SECTION 7: HANDLING AND STORAGE                                                   


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Handle empty containers with care because      
residual vapors are flammable.                                                    
Do not handle until all safety precautions have been read and understood. Obtain  
special instructions . Wash hands and other exposed areas with mild soap and water
before eating, drinking or smoking and when leaving work. Provide good ventilation
in process area to prevent formation of vapor. No naked lights. No smoking. Use   
only non-sparking tools. Use only outdoors or in a well-ventilated area. Avoid    
breathing dust, fume, gas, mist, vapor spray. Do not breathe dust, fumes, gas,    
mist, vapor spray.                                                                
Hygiene Measures: Do not eat, drink or smoke when using this product. Wash        
affected areas thoroughly after handling. Wash hands and other exposed areas with 
mild soap and water before eating, drinking or smoking and when leaving work. Wash
contaminated clothing before reuse.                                               


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Proper grounding procedures to avoid static electricity should
be followed. Ground/bond                                                          
container and receiving equipment. Use explosion-proof electrical, ventilating,   
lighting equipment.                                                               
Storage Conditions: Keep only in the original container in a cool, well ventilated
place away from : Keep in fireproof                                               
place. Keep container tightly closed.                                             


7.3.  Specific End Use(s)
                                                                                  

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                  


8.1.  Control Parameters
Methanol (67-56-1)                                                                
                                                                                  
USA ACGIH                                                                         
ACGIH TWA (mg/m³)                                                                 
262 mg/m³                                                                         
                                                                                  
USA ACGIH                                                                         
ACGIH TWA (ppm)                                                                   
200 ppm                                                                           
                                                                                  
USA ACGIH                                                                         
ACGIH STEL (mg/m³)                                                                
328 mg/m³                                                                         
                                                                                  
USA ACGIH                                                                         
ACGIH STEL (ppm)                                                                  
250 ppm                                                                           
                                                                                  
USA OSHA                                                                          
OSHA PEL (TWA) (mg/m³)                                                            
260 mg/m³                                                                         
                                                                                  
USA OSHA                                                                          
OSHA PEL (TWA) (ppm)                                                              
200 ppm                                                                           
                                                                                  


8.2.  Exposure Controls
Appropriate Engineering      |Local exhaust ventilation, vent hoods.              
Controls                     |                                                    
Personal Protective Equipment|Safety glasses. Gloves. Avoid all unnecessary       
                             |exposure.                                           
                             |Other information : Do not eat, drink or smoke      
                             |during use.                                         
                             |Avoid contact during pregnancy/while nursing.       
Materials for Protective     |                                                    
Clothing                     |                                                    
Hand Protection              |Wear protective gloves.                             
Eye Protection               |Chemical goggles or safety glasses.                 
Skin and Body Protection     |Wear suitable protective clothing.                  
Respiratory Protection       |Where exposure through inhalation may occur from    
                             |use, respiratory protection equipment is            
                             |recommended.                                        
Thermal Hazard Protection    |                                                    

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                       


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                       
Appearance                          |                                             
Odor                                |Mild . Odourless.                            
Odor Threshold                      |4.2 - 5960 ppm                               
pH                                  |? 7                                          
Relative Evaporation Rate           |4.1                                          
(butylacetate=1)                    |                                             
Melting Point                       |No data available                            
Freezing Point                      |-97.8                                        
Boiling Point                       |64.7 °C                                      
Flash Point                         |11 °C                                        
Auto-ignition Temperature           |464 °C                                       
Decomposition Temperature           |Not Determined                               
Flammability (solid, gas)           |No data available                            
Vapor Pressure                      |12.8 kPa @ 20 deg C                          
Relative Vapor Density at 20 °C     |No data available                            
Relative Density                    |0.792                                        
Specific Gravity                    |                                             
Solubility                          |Soluble in alcohols. Soluble in water.       
Partition coefficient:              |                                             
n-octanol/water                     |                                             
Viscosity                           |No data available                            
Lower Flammable Limit               |                                             
Upper Flammable Limit               |                                             


9.2.  Other Information
VOC content : > 98 %                                                              
Explosive limits : 36.5 vol % Upper Explosive Limit (UEL)                         

SECTION 10: STABILITY AND REACTIVITY                                              


10.1      Reactivity
No additional information available                                               


10.2      Chemical Stability
Highly flammable liquid and vapor. May form flammable/explosive vapor-air mixture.


10.3      Possibility of Hazardous Reactions
Not established.                                                                  


10.4      Conditions to Avoid
Direct sunlight. Extremely high or low temperatures. Open flame.                  


10.5      Incompatible Materials
Sources of ignition. Direct sunlight. Heat sources.                               
Strong acids. Strong bases.                                                       


10.6      Hazardous Decomposition Products
Toxic fume. . Carbon monoxide. Carbon dioxide. May release flammable gases.       

SECTION 11: TOXICOLOGICAL INFORMATION                                             


11.1. Information on Toxicological Effects
Acute Toxicity: Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. 
Skin Corrosion/Irritation: Not classified.  pH: ? 7.                              
Serious Eye Damage/Irritation: Not classified.  pH: ? 7.                          
Respiratory or Skin Sensitization: Not classified.                                
Germ Cell Mutagenicity:  Not classified Based on available data, the              
classification criteria are not met.                                              
Carcinogenicity: Not classified.                                                  
Reproductive Toxicity: Not classified                                             
Specific Target Organ Toxicity (Single Exposure): Causes damage to organs.        
Specific Target Organ Toxicity (Repeated Exposure): Not classified.               
Aspiration Hazard: Not classified                                                 
Symptoms/Injuries After Inhalation: Toxic if inhaled. Danger of serious damage to 
health by prolonged exposure through inhalation.                                  
Symptoms/Injuries After Skin Contact: Repeated exposure to this material can      
result in absorption through skin causing significant health hazard. Toxic in     
contact with skin.                                                                
Symptoms/Injuries After Eye Contact:  Causes serious eye damage. Irritation of the
eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue.     
Symptoms/Injuries After Ingestion: Fatal if swallowed. Toxic if swallowed.        
Swallowing a small quantity of this material will result in serious health hazard.
Chronic Symptoms:                                                                 

SECTION 12: ECOLOGICAL INFORMATION                                                


12.1. Toxicity
                                                                                  


12.2. Persistence and Degradability
                                                                                  


12.3. Bioaccumulative Potential
                                                                                  


12.4. Mobility in Soil
                                                                                  


12.5. Other Adverse Effects
Other information : Avoid release to the environment.                             

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose in a safe manner in accordance with       
local/national regulations. Dispose of                                            
contents/container to appropriate waste disposal facility, in accordance with     
local, regional, national, international regulations.                             
Additional Information: Handle empty containers with care because residual vapors 
are flammable.                                                                    
Ecology - waste materials : Avoid release to the environment. Hazardous waste due 
to toxicity.                                                                      

SECTION 14: TRANSPORT INFORMATION                                                 


14.1 In Accordance with DOT
Proper Shipping Name |Methanol Solution                                           
Hazard Class         |3                      |<PICTOGRAM PHRASE>                  
Identification Number|UN1230                 |                                    
Label Codes          |                       |                                    
ERG Number           |                                                            


14.2 In Accordance with IMDG
Proper Shipping Name |Methanol Solution                                           
Hazard Class         |3 (6.1)                                                     
Identification Number|UN1230                                                      
Label Codes          |                      |<PICTOGRAM PHRASE>                   
ntification Of The   |                      |                                     
Substance/m          |                      |                                     
EmS-No. (Fire)       |                      |                                     
EmS-No. (Spillage)   |                      |                                     


14.3 In Accordance with IATA
Proper Shipping Name |Methanol Solution                                           
Identification Number|UN1230                 |<PICTOGRAM PHRASE>                   
Hazard Class         |3 (6.1)                |                                     
Label Codes          |                       |                                     
ntification Of The   |                       |                                     
Substance/m          |                       |                                     
ERG Code (IATA)      |                                                            

SECTION 15: REGULATORY INFORMATION                                                

15.1      US Federal Regulations
<COMPONENT>                                                                       
Methanol (67-56-1)                                                                
                                                                                  
Listed on United States SARA Section 313                                          
                                                                                  
SARA Section 311/312 Hazard Classes |Immediate (acute) health hazard              
                                    |Delayed (chronic) health hazard              
                                    |Fire hazard                                  
Toxic Substances Control Act (TSCA) |Methanol (67-56-1)                           
                                    |Listed on the United States TSCA (Toxic      
                                    |Substances Control Act) inventory            

15.2      US State Regulations
<COMPONENT>                                                                       
                                                                                  

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION     

Revision date   |09/15/2014                                                       
Other           |This document has been prepared in accordance with the SDS       
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR    
                |1910.1200.                                                       
GHS Full Text Phrases:                                                            
----|Acute Tox. 3 (Dermal)          |Acute toxicity (dermal) Category 3           
--  |                               |                                             
----|Acute Tox. 3                   |Acute toxicity (inhalation:dust,mist)        
--  |(Inhalation:dust,mist)         |Category 3                                   
----|Acute Tox. 3 (Oral)            |Acute toxicity (oral) Category 3             
--  |                               |                                             
----|Flam. Liq. 2                   |Flammable liquids Category 2                 
--  |                               |                                             
----|STOT SE 1                      |Specific target organ toxicity (single       
--  |                               |exposure) Category 1                         
    |H225                           |Highly flammable liquid and vapor            
    |H301                           |Toxic if swallowed                           
    |H311                           |Toxic in contact with skin                   
    |H331                           |Toxic if inhaled                             
    |H370                           |Causes damage to organs                      


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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