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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Air Brake Anti-Freeze & Conditioner CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Air brake anti-freeze 1.3. Name, Address, and Telephone of the Responsible Party Company: CRC Industries, Inc. 885 Louis Dr. Warminster, PA 18974 US Phone: 215-674-4300, 800-521-3168, 800-272-4620 1.4. Emergency Telephone Number Emergency | 800-424-9300, 703-527-3887 (International) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 2 liquids | Acute |Category 3 toxicity, oral| Acute |Category 3 toxicity, | dermal | Acute |Category 3 toxicity, | inhalation | Reproductive |Category 2 toxicity | Specific |Category 1 target organ | toxicity, | single | exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Skull and Crossbones |Health Hazard Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Highly flammable liquid and vapor. Toxic if |swallowed. Toxic in contact with skin. Toxic if |inhaled. Suspected of damaging fertility or the |unborn child. Causes damage to organ (eyes, central |nervous system). Precautionary Statements |Prevention: (GHS-US) |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Keep away from heat/sparks/open |flames/hot surfaces. - No smoking. Keep container |tightly closed. Use explosion-proof |electrical/ventilating/lighting equipment. Use only |non-sparking tools. Take precautionary measures |against static discharge. Use only with adequate |ventilation; maintain ventilation during use and |until all vapors are gone. Open doors and windows or |use other means to ensure a fresh air supply during |use and while product is drying. If you experience |any symptoms listed on this label, increase |ventilation or leave the area. Do not breathe mist |or vapor. Wash thoroughly after handling. Do not |eat, drink or smoke when using this product. Wear |protective gloves/protective clothing/eye |protection/face protection. |Response: |If swallowed: Immediately call a poison |center/doctor. Rinse mouth. If on skin (or hair): |Take off immediately all contaminated clothing. |Rinse skin with water/shower. If inhaled: Remove |person to fresh air and keep comfortable for |breathing. Call a poison center/doctor. Wash |contaminated clothing before reuse. If exposed or |concerned: Get medical attention. In case of fire: |Do not use water jet as an extinguisher, as this |will spread the fire. |Storage: |Keep cool. Store in a well-ventilated place. Keep |container tightly closed. Store locked up. |Disposal: |Dispose of contents/container in accordance with |local/regional/national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) Methanol |67-56-1 |90 - 100| | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: General information Take off immediately all contaminated clothing. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a POISON CENTER or doctor/physician. First-aid Measures After Skin Contact: Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical advice/attention if you feel unwell. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Dizziness. Headache. Nausea, vomiting. Irritation of eyes and mucous membranes. Upper respiratory tract irritation. Skin irritation. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Explosion Hazard: Highly flammable liquid and vapor. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Protection During Firefighting: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Emergency Procedures: 6.2. Environmental Precautions Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Clean surface thoroughly to remove residual contamination. Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary measures against static discharges. Use non-sparking tools and explosion-proof equipment. Do not breathe mist or vapor. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. When using, do not eat, drink or smoke. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Wash contaminated clothing before reuse. For product usage instructions, please see the product label. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep away from heat, sparks and open flame. Eliminate sources of ignition. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Keep container tightly closed. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Methanol (CAS 67-56-1) PEL 260 mg/m3 200 ppm US. ACGIH Threshold Limit Values Components Type Value Methanol (CAS 67-56-1) STEL 250 ppm TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Methanol (CAS 67-56-1) STEL 325 mg/m3 250 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value TWA 260 mg/m3 200 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Methanol (CAS 67-56-1) 15 mg/l Methanol Urine * * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Methanol (CAS 67-56-1) Skin designation applies. US - Tennessee OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. 8.2. Exposure Controls Appropriate Engineering |Explosion-proof general and local exhaust Controls |ventilation. Good general ventilation (typically 10 |air changes per hour) should be used. Ventilation |rates should be matched to conditions. If |applicable, use process enclosures, local exhaust |ventilation, or other engineering controls to |maintain airborne levels below recommended exposure |limits. If exposure limit have not been established, |maintain airborne levels to an acceptable level. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Wear protective gloves such as: Nitrile. Rubber. |Wear appropriate chemical resistant clothing. Use of |an impervious apron is recommended. Eye Protection |Wear safety glasses with side shields (or goggles). Skin and Body Protection | Respiratory Protection |If engineering controls are not feasible or if |exposure exceeds the applicable exposure limits, use |a NIOSH-approved cartridge respirator with an |organic vapor cartridge. Use a self contained |breathing apparatus in confined spaces and for |emergencies. Air monitoring is needed to determine |actual employee exposure levels. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. Appearance | Odor |Pungent. Alcoholic. Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |Fast. (butylacetate=1) | Melting Point |-144 �F (-97.8 �C) estimated Freezing Point |-144 �F (-97.8 �C) estimated Boiling Point |148.5 �F (64.7 �C) estimated Flash Point |54 �F (12.2 �C) Tag Closed Cup Auto-ignition Temperature |725 �F (385 �C) estimated Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |133.2 hPa estimated Relative Vapor Density at 20 �C | Relative Density |0.79 Specific Gravity | Solubility |Completely soluble. Partition coefficient: |Not available. n-octanol/water | Viscosity |Not available. Lower Flammable Limit |2.6 % estimated Upper Flammable Limit |36 % estimated 9.2. Other Information Percent volatile: 99.9 % estimated Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 100 % Consumer products (40 CFR 59, Subpt. C): Not regulated State Consumer products Not regulated VOC content (CA) 100 % VOC content (OTC) 100 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides. Formaldehyde. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Toxic if inhaled. Toxic in contact with skin. Toxic if swallowed. Skin Corrosion/Irritation: Prolonged skin contact may cause temporary irritation. Serious Eye Damage/Irritation: Direct contact with eyes may cause temporary irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive Toxicity: Suspected of damaging fertility or the unborn child. Specific Target Organ Toxicity (Single Exposure): Causes damage to organs: Eyes. Central nervous system. Even small amounts (30-250 ml methanol) may be fatal. Symptoms are stomach ache, nausea, vomiting, dullness, visual disorder and blindness. Specific Target Organ Toxicity (Repeated Exposure): Not classified. Aspiration Hazard: May be an aspiration hazard. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Upper respiratory tract irritation. Skin irritation. Symptoms/Injuries After Eye Contact: Irritation of eyes and mucous membranes. Symptoms/Injuries After Ingestion: Toxic if swallowed. Even small amounts (30-250 ml methanol) may be fatal. Symptoms are stomach ache, nausea, vomiting, dullness, visual disorder and blindness. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Product Species Test Results Air Brake Anti-Freeze & Conditioner Aquatic Acute Crustacea EC50 Daphnia 16121.3125 mg/l, 48 hours estimated Fish LC50 Fish 22749.9609 mg/l, 96 hours estimated Components Species Test Results Methanol (CAS 67-56-1) Aquatic Fish LC50 Rainbow trout,donaldson trout 18000 - 20000 mg/l, 96 hours (Oncorhynchus mykiss) Acute Crustacea EC50 Water flea (Daphnia magna) > 10000 mg/l, 48 hours Fish LC50 Rainbow trout,donaldson trout 18000 - 20000 mg/l, 96 hours (Oncorhynchus mykiss) * Estimates for product may be based on additional component data not shown. 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data available. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations. Hazardous waste code: D001: Waste Flammable material with a flash point <140 F F003: Waste Non-halogenated Solvent - Spent Non-halogenated Solvent Additional Information: US RCRA Hazardous Waste U List: Reference Methanol (CAS 67-56-1) U154 Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Methanol, Limited Quantity Hazard Class |3 |<PICTOGRAM PHRASE> Identification Number|UN1230 | Label Codes |3 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |METHANOL, LIMITED QUANTITY Hazard Class |3 Identification Number|UN1230 Label Codes |3 |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |E | EmS-No. (Spillage) |D | 14.3 In Accordance with IATA Proper Shipping Name |Methanol, Limited Quantity Identification Number|UN1230 |<PICTOGRAM PHRASE> Hazard Class |3 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |3L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. SARA 304 Emergency release notification: Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Methanol (CAS 67-56-1) CERCLA Hazardous Substance List (40 CFR 302.4) Methanol (CAS 67-56-1) CERCLA Hazardous Substances: Reportable quantity Methanol (CAS 67-56-1) 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Methanol (CAS 67-56-1) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA): Not regulated. Food and Drug Administration (FDA): Not regulated. SARA 302 Extremely hazardous substance: No. SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - Yes |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |All components are on the U.S. EPA TSCA |Inventory List. |TSCA Section 12(b) Export Notification (40 |CFR 707, Subpt. D): Not regulated. 15.2 US State Regulations <COMPONENT> US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Methanol (CAS 67-56-1) US. Massachusetts RTK - Substance List Methanol (CAS 67-56-1) US. Pennsylvania Worker and Community Right-to-Know Law Methanol (CAS 67-56-1) US. Rhode Island RTK Methanol (CAS 67-56-1) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive Harm. US - California Proposition 65 - CRT: Listed date/Developmental toxin Methanol (CAS 67-56-1) Listed: March 16, 2012 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.