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Safety Data Sheet Date of Issue: |Revision Date: |Revision Number: |09/September/2015 | Imperial Supplies Part Number: 0055080 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Liquid Product Name: Gas Treatment and FI Cleaner CAS No: Synonyms: 590292 1.2. Intended Use of the Product Use of the substance/mixture: Gasoline fuel additive. 1.3. Name, Address, and Telephone of the Responsible Party Company Gold Eagle Co. 4400 S. Kildare Avenue Chicago, IL 606324372 United States Phone: 7733764400 1.4. Emergency Telephone Number Emergency | 18005355053 - (INFOTRAC #22283) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |2 Liquids | Skin |2 Irritation | Eye Irritation|2 Specific |3: Narcotic Target Organ |Effects Toxicity | Single | Exposure | Reproductive |2 Toxicity | Specific |1 Target Organ | Toxicity | Single | Exposure | Specific |1 Target Organ | Toxicity | Repeated | Exposure | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | |Flame |Exclamat|Health | | | | |ion Mark|Hazard | | | Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Highly flammable liquid and vapour |Causes skin irritation |Causes serious eye irritation |May cause drowsiness or dizziness |Suspected of damaging fertility or the unborn child. | |Causes damage to organs Eyes |Causes damage to organs Eyes through prolonged or |repeated exposure Precautionary Statements |Prevention (GHS-US) |Obtain special instructions before use. |Do not handle until all safety precautions have been |read and understood. |Keep away from heat, sparks, open flames and/or hot |surfaces. No smoking. |Keep container tightly closed. |Ground and/or bond container and receiving |equipment. |Use explosion-proof |electrical/ventilating/lighting/equipment. |Use only non-sparking tools. |Take precautionary measures against static |discharge. |Do not breathe mist/vapours/spray. |Wash thoroughly after handling. |Do not eat, drink or smoke when using this product. |Use only outdoors or in a well-ventilated area. |Wear protective gloves and eye/face protection , . |Response |In case of fire: Use appropriate media for |extinction. |IF INHALED: Remove victim to fresh air and keep at |rest in a position comfortable for breathing. |Call a POISON CENTER or doctor/physician if you feel |unwell. |IF ON SKIN (or hair): Take off immediately all |contaminated clothing. Rinse skin with water/shower. | |Wash contaminated clothing before reuse. |If skin irritation occurs: Get medical |advice/attention. |Specific treatment, see supplemental first aid |information. |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |If eye irritation persists: Get medical |advice/attention. |Get medical advice/attention if you feel unwell. |IF exposed: Call POISON CENTER or doctor/physician. |Storage/Disposal |Store in a well-ventilated place. Keep container |tightly closed. |Keep cool. |Store locked up. |Dispose of content and/or container in accordance |with local, regional, national, and/or international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: OSHA HCS 2012: Under United States Regulations (29 CFR 1910.1200 Hazard Communication Standard), this product is considered hazardous. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Methanol |67-56-1 |0% TO |OSHA HCS 2012: | |95% |Flam. Liq. 2? Eye | | |Irrit. 2? Skin | | |Irrit. 2? STOT SE | | |1 (Eyes)? STOT SE | | |3: Narc.? STOT RE | | |1 (Eyes)? Repr. 2 Proprietary |Proprietary |0% TO |OSHA HCS 2012: | |5% |Exposure limit(s) | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Move victim to fresh air. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. First-aid Measures After Skin Contact: In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Remove and isolate contaminated clothing. Wash skin with soap and water. First-aid Measures After Eye Contact: Hold eye open and rinse slowly and gently with water for 1520 minutes. Remove contact lenses, if present, after the first five minutes, then continue rinsing eye. Get medical attention immediately. First-aid Measures After Ingestion: Induce vomiting (only in conscious persons) Then give 2 teaspoons of baking soda in a glass of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Refer to Section 11 Toxicological Information. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to Physician: All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use halon replacement or carbon dioxide extinguishers or alcohol foam for small fires. Large fires should be extinguished with alcohol foam. Unsuitable Extinguishing Media: Water spray or fog can cool fire but may not be effective in extinguishing fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Containers may explode when heated. Vapor explosion hazard indoors, outdoors or in sewers. HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Many liquids are lighter than water. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Runoff to sewer may create fire or explosion hazard. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Explosion Hazard: Hazardous Combustion Products: No data available Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Structural firefighters' protective clothing will only provide limited protection. Wear positive pressure self-contained breathing apparatus (SCBA). Move containers from fire area if you can do it without risk. LARGE FIRES: Cool containers with flooding quantities of water until well after fire is out. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Ventilate the area. Do not walk through spilled material. Use appropriate Personal Protective Equipment (PPE) Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Do not breathe mist, vapours and/or spray. Avoid contact with skin, eyes, and clothing. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions? also, consider initial evacuation for 800 meters (1/2 mile) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet) ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. 6.2. Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Stop leak if you can do it without risk. Absorb or cover with dry earth, sand or other noncombustible material and transfer to Containers. Use clean non-sparking tools to collect absorbed material. A vapor suppressing foam may be used to reduce vapors. All equipment used when handling the product must be grounded. LARGE SPILLS: Dike far ahead of liquid spill for later disposal. LARGE SPILLS: Water spray may reduce vapor? but may not prevent ignition in closed spaces. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Use only with adequate ventilation. Keep away from heat, sparks, and flame. All equipment used when handling the product must be grounded. Take precautionary measures against static charges. Do not use sparking tools. Contact lenses should not be worn when working with this chemical. Wear appropriate personal protective equipment, avoid direct contact. Do not breathe mist, vapours and/or spray. Avoid contact with skin, eyes, and clothing. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed. Keep away from sources of ignition - No Smoking. Store in a cool, dry, well-ventilated place. Empty containers contain product residues, assume emptied containers to have same hazards as full containers. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Limits/Guidelines Result ACGIH NIOSH OSHA Methanol (67561) TWAs 200 ppm TWA 200 ppm TWA? 260 mg/m3 TWA 200 ppm TWA? 260 mg/m3 TWA STELs 250 ppm STEL 250 ppm STEL? 325 mg/m3 STEL Not established Proprietary (Proprietary) TWAs 100 ppm TWA Not established 100 ppm TWA? 435 mg/m3 TWA STELs 150 ppm STEL Not established Not established 8.2. Exposure Controls Appropriate Engineering |Good general ventilation should be used. Ventilation Controls |rates should be matched to |conditions. If applicable, use process enclosures, |local exhaust ventilation, or other engineering |controls to maintain airborne levels below |recommended exposure limits. If exposure limits have |not been established, maintain airborne levels to an |acceptable level. Use only appropriately classified |electrical equipment. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Wear chemical splash safety goggles. Skin and Body Protection |Wear appropriate gloves. Wear protective clothing. Respiratory Protection |In case of insufficient ventilation, wear suitable |respiratory equipment. Follow the OSHA respirator |regulations found in 29 CFR 1910.134. Use a |NIOSH/MSHA approved respirator if exposure limits |are exceeded or symptoms are experienced. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Water-white to pale yellow liquid. Odor |No data available Odor Threshold |No data available pH |No data available Relative Evaporation Rate |No data available (butylacetate=1) | Melting Point |No data available Freezing Point |No data available Boiling Point |147 F(63.8889 C) Flash Point |56 F(13.3333 C) Auto-ignition Temperature |No data available Decomposition Temperature |No data available Flammability (solid, gas) |Not relevant. Vapor Pressure |96 mmHg (torr) Relative Vapor Density at 20 Â°C | Relative Density |0.791 Water=1 Specific Gravity |0.791 Solubility |Soluble 100 % Water Partition coefficient: | n-octanol/water | Viscosity |3 to 5 Centistoke (cSt, cS) or |mm2/sec @ 40 C(104 F) Lower Flammable Limit |2 % Upper Flammable Limit |12.7 % 9.2. Other Information VOC (Vol.): 100 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical Stability Stable under normal temperatures and pressures. 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Keep away from heat, sparks, and flame. 10.5 Incompatible Materials Strong oxidizing agents, aluminum, zinc, or metals that displace hydrogen, rubber and rubber based coatings, chromic anhydride, lead perchlorate and perchloric acids. 10.6 Hazardous Decomposition Products Excessive heating and/or incomplete combustion will produce carbon monoxide. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: This product does not contain any components above de minimus concentrations that are considered carcinogenic by OSHA , IARC or NTP. Reproductive Toxicity: Animal tests for components have shown adverse reproductive effects. Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Acute (Immediate): May affect the central nervous system. Symptoms may include dizziness, drowsiness, lethargy, coma and death. Chronic (Delayed): No data available. Symptoms/Injuries After Skin Contact: Acute (Immediate): Causes skin irritation. Chronic (Delayed): No data available. Symptoms/Injuries After Eye Contact: Acute (Immediate): Causes serious eye irritation. Chronic (Delayed): No data available. Symptoms/Injuries After Ingestion: Acute (Immediate): May cause headache, dizziness, weakness, euphoria, drowsiness, shortness of breath, vomiting, and loss of voluntary muscle control. Can also cause blindness and death. Chronic (Delayed): No data available. Chronic Symptoms: Chronic (Delayed): Chronic poisoning from repeated exposure to methanol vapor were manifested by conjunctivitis, headache, giddiness, insomnia, gastric disturbances, and bilateral blindness. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Nonmandatory section - information about this substance not complied for this reason. 12.2. Persistence and Degradability Nonmandatory section - information about this substance not complied for this reason. 12.3. Bioaccumulative Potential Nonmandatory section - information about this substance not complied for this reason. 12.4. Mobility in Soil Nonmandatory section - information about this substance not complied for this reason. 12.5. Other Adverse Effects Nonmandatory section - information about this substance not complied for this reason. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Additional Information: Product waste: Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste: Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Consumer commodity Hazard Class |NDA |<PICTOGRAM PHRASE> Identification Number|ORMD | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Labor U.S. OSHA Process Safety Management Highly Hazardous Chemicals Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed U.S. OSHA Specifically Regulated Chemicals Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed Environment U.S. CAA (Clean Air Act) 1990 Hazardous Air Pollutants Methanol 67-56-1 Not Listed Proprietary Proprietary (isomers and mixtures) U.S. CAA (Clean Air Act) Accidental Release Prevention Flammable Substances Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed U.S. CAA (Clean Air Act) Accidental Release Prevention Toxic Substances Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed U.S. CERCLA/ SARA Hazardous Substances and their Reportable Quantities Methanol 67-56-1 5000 lb final RQ? 2270 kg final RQ Proprietary Proprietary 100 lb final RQ? 45.4 kg final RQ U.S. CERCLA/ SARA Section 302 Extremely Hazardous Substances EPCRA RQs Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed U.S. CERCLA/ SARA Section 302 Extremely Hazardous Substances TPQs Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed U.S. CERCLA/ SARA Section 313 Emission Reporting Methanol 67-56-1 1.0 % de minimis concentration Proprietary Proprietary 1.0 % de minimis concentration U.S. CERCLA/ SARA Section 313 PBT Chemical Listing Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed U.S. CWA (Clean Water Act) Hazardous Substances Methanol 67-56-1 Not Listed Proprietary Proprietary U.S. CWA (Clean Water Act) Toxic Pollutants Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed SARA Section 311/312 Hazard Classes |Acute, Chronic, Fire Toxic Substances Control Act (TSCA) |Inventory |Component |CAS |TSCA | |Methanol |67561 |Yes | |Proprietary |Proprietary |Yes | 15.2 US State Regulations <COMPONENT> United States California U.S. California Proposition 65 Carcinogens List Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed U.S. California Proposition 65 Developmental Toxicity Methanol 67-56-1 developmental toxicity, initial date 3/16/12 Proprietary Proprietary Not Listed U.S. California Proposition 65 Maximum Allowable Dose Levels (MADL) Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed U.S. California Proposition 65 No Significant Risk Levels (NSRL) Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed U.S. California Proposition 65 Reproductive Toxicity Female Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed U.S. California Proposition 65 Reproductive Toxicity Male Methanol 67-56-1 Not Listed Proprietary Proprietary Not Listed Other Information: WARNING: This product contains a chemical known to the State of California to cause cancer, birth defects, or other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |09/September/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.