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MSDS Sheet 0052780

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Material Safety Data Sheet                                                      
          
Date of Issue:             |Revision Date: Apr. 1, 2013|Revision Number:        
 
                           |                           |CYCRE-PSDS--01          
 
Imperial Supplies Part Number: 0052780                                          
 

SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: Manganese dioxide lithium battery                                 
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture:                                                   
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Panasonic Corporation, Automotive & Industrial Systems Company                  
 
Energy Device Business Division                                                 
 
1-1 Matsushita-cho, Moriguchi City, Osaka, 570-8511, Japan                      
 
Phone: +81-6-6994-4537                                                          
 


1.4.  Emergency Telephone Number
Emergency     | +81-6-6991-1141                                                 
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Not           |              
applicable.   |              
              |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |        |        |        |        |        |     
  
Signal Word (GHS-US)         |                                                  
 
Hazard Statements (GHS-US)   |                                                  
 
Precautionary Statements     |                                                  
 
(GHS-US)                     |                                                  
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                           
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Positive electrode              |1313-13-9            |25~45   |                
 
Manganese dioxide               |                     |        |                
 
Negative electrode              |7439-93-2            |2~ 5    |                
 
Lithium metal                   |                     |        |                
 
Electrolyte                     |                     |        |                
 
1,2- dimethoxyethane            |110-71-4             |3~ 5    |                
 
Organic electrolyte             |-                    |5~17    |                
 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Remove to fresh air immediately. Take a    
 
medical treatment.                                                              
 
First-aid Measures After Skin Contact: Wash the contact areas off immediately
with
plenty of water and soap. If appropriate procedures are not taken, this may
cause 
sores on the skin.                                                              
 
First-aid Measures After Eye Contact: Flush the eyes with plenty of clean water 
 
for at least 15 minutes immediately, without rubbing. Take a medical treatment.
If
appropriate procedures are not taken, this may cause an eye irritation.         
 
First-aid Measures After Ingestion:                                             
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
                                                                                
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Alcohol-resistant foam and dry sand are effective.
 
Unsuitable Extinguishing Media:                                                 
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:                                                                    
 
Explosion Hazard:                                                               
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting:                                                 
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Take up with absorbent cloth. Move the battery away from the  
 
fire.                                                                           
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
                                                                                
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up:                                                        
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: When packing the batteries, do not allow     
 
battery terminals to contact each other, or contact with other metals. Be sure
to 
pack batteries by providing partitions in the packaging box, or in a separate   
 
plastic bag so that the single batteries are not mixed together. Use strong     
 
material for packaging boxes so that they will not be damaged by vibration,     
 
impact, dropping and stacking during their transportation. Do not recharge      
 
batteries. Do not deform batteries. Do not mix different type of batteries. Do
not
solder directly onto batteries. Do not let water penetrate into packaging boxes 
 
during their storage and transportation.                                        
 
Hygiene Measures:                                                               
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Do not store the battery in places of the high temperature
or 
under direct sunlight or in front of a stove.                                   
 
Please also avoid the places of high humidity. Be sure not to expose the battery
 
to condensation, water drop or not to store it under frozen condition. Fire     
 
fighting apparatus should be installed.                                         
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
(In case of electrolyte leakage from the battery).                              
 
Acceptable concentration: Not specified in ACGIH.                               
 
Facilities: Provide appropriate ventilation system such as local ventilator in
the
storage Place.                                                                  
 
Protective clothing: Gas mask for organic gases, safety goggle, and safety
glove. 


8.2.  Exposure Controls
Appropriate Engineering      |                                                  
 
Controls                     |                                                  
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |                                                  
 
Skin and Body Protection     |                                                  
 
Respiratory Protection       |                                                  
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |                                           
 
Appearance                          |Cylindrical shape                          
 
Odor                                |                                           
 
Odor Threshold                      |                                           
 
pH                                  |                                           
 
Relative Evaporation Rate           |                                           
 
(butylacetate=1)                    |                                           
 
Melting Point                       |                                           
 
Freezing Point                      |                                           
 
Boiling Point                       |                                           
 
Flash Point                         |                                           
 
Auto-ignition Temperature           |                                           
 
Decomposition Temperature           |                                           
 
Flammability (solid, gas)           |                                           
 
Vapor Pressure                      |                                           
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |                                           
 
Specific Gravity                    |                                           
 
Solubility                          |                                           
 
Partition coefficient:              |                                           
 
n-octanol/water                     |                                           
 
Viscosity                           |                                           
 
Lower Flammable Limit               |                                           
 
Upper Flammable Limit               |                                           
 


9.2.  Other Information
                                                                                
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
Since batteries utilize a chemical reaction they are actually considered a      
 
chemical product. As such, battery performance will deteriorate over time even
if 
stored for a long period of time without being used. In addition, the various   
 
usage conditions such as discharge, ambient temperature, etc. are not maintained
 
within the specified ranges the life expectancy of the battery may be shortened
or
the device in which the battery is used may be damaged by electrolyte leakage.  
 


10.2      Chemical Stability
                                                                                
 


10.3      Possibility of Hazardous Reactions
                                                                                
 


10.4      Conditions to Avoid
                                                                                
 


10.5      Incompatible Materials
                                                                                
 


10.6      Hazardous Decomposition Products
                                                                                
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity: Oral(rat) LD50 > 2,000mg/kg (estimated) .                       
 
Skin Corrosion/Irritation: Irritating to skin.                                  
 
Serious Eye Damage/Irritation: Irritating to eye.                               
 
Respiratory or Skin Sensitization:                                              
 
Germ Cell Mutagenicity:                                                         
 
Carcinogenicity:                                                                
 
Reproductive Toxicity:                                                          
 
Specific Target Organ Toxicity (Single Exposure):                               
 
Specific Target Organ Toxicity (Repeated Exposure):                             
 
Aspiration Hazard:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms: Not specified.                                                
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
In case of the worn-out battery was disposed in land, the battery case may be   
 
corroded, and leak electrolyte. But, we have no ecological information.         
 


12.2. Persistence and Degradability
                                                                                
 


12.3. Bioaccumulative Potential
                                                                                
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
                                                                                
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: When the battery is worn out, dispose of it
under 
the ordinance of each local government or the law issued by relating government.
 
Additional Information:                                                         
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |                                                          
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |                                                          
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Lithium metal batteries                                   
 
Identification Number|UN3090                 |<PICTOGRAM PHRASE>                
  
Hazard Class         |Class9                 |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
IATA Dangerous Goods Regulations                                                
 
ICAO Technical Instructions for the safe transport of dangerous goods by air.   
 
SARA Section 311/312 Hazard Classes |                                           
 
Toxic Substances Control Act (TSCA) |                                           
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |Apr. 1, 2013                                                   
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.

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