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MSDS Sheet 0052770Printer Friendly View
Material Safety Data Sheet Date of issue: |Revision Date: March 2015 |Revision Number: Imperial Supplies Part Number: 0052770 1. PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Energizer Battery Manufacturing, Inc. 25225 Detroit Rd. Westlake, OH 44145 Telephone: 800-383-7323 (USA / CANADA) Emergency Phone Product Name: Energizer Battery Product Code(s): Recommended Use: UN-Number: Product Type: 2. HAZARDS IDENTIFICATION Appearance: Solid |Physical State: |Odor: No odor object | | Potential Health Effects Principle Routes of Exposure Acute Effects: Eyes |Contents of an open battery can cause severe |irritation. Skin |Contents of an open battery can cause skin |irritation. Inhalation |Contents of an open battery can cause respiratory |irritation. Ingestion |Swallowing a battery can be harmful. Notes: Under normal conditions of use, the battery is hermetically sealed. Chronic Effects: Eyes | Skin | Inhalation | Ingestion | Notes: Aggravated Medical Conditions Environmental Hazard 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical/Ingredient Name |CAS-No |Weight% |ACGIH, |OSHA-PE|Other | | |TLV-TWA |L | Carbon Black |1333-86-4 |0-1 |3.5 mg/m3 |3.5 | | | |TWA |mg/m3 | | | | |TWA | 1,2-Dimethoxyethane |110-71-4 |0-6 |None |None | | | |establishe|establi| | | |d |shed | 1,3-Dioxolane |646-06-0 |0-8 |None |None | | | |establishe|establi| | | |d |shed | Graphite |7782-42-5 |0-3 |2 mg/m3 |15 | | | |TWA |mg/m3 | | | |(respirabl|TWA | | | |e |(total | | | |fraction) |dust) | | | | |5 mg/m3| | | | |TWA | | | | |(respir| | | | |able | | | | |fractio| | | | |n) | Lithium or Lithium Alloy |7439-93-2 |1-6 |None |None | | | |establishe|establi| | | |d |shed | Lithium |33454-82-9 |0-3 |None |None | Trifluoromethanesulfonate| | |establishe|establi| | | |d |shed | Lithium |90076-65-6 |0-3 |None |None | Trifluoromethanesulfonimi| | |establishe|establi| de | | |d |shed | Manganese Dioxide |1313-13-9 |12-42 |0.2 mg/m3 |5 mg/m3| | | |TWA (as |Ceiling| | | |Mn) |(as Mn)| Propylene Carbonate |108-32-7 |0-8 |None |None | | | |establishe|establi| | | |d |shed | Non-Hazardous Components:| |20 |None |None | | | |establishe|establi| Steel | | |d |shed | (iron CAS# 65997-19-5) | |Balance |None |None | Plastic and Other | | |establishe|establi| | | |d |shed | Notes: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful. 4. FIRST AID MEASURES General Advice Eyes |Immediately flush eyes thoroughly with water for at |least 15 minutes, lifting upper and lower lids, until |no evidence of the chemical remains. Seek medical |attention. Skin |Remove contaminated clothing and wash skin with soap |and water. Inhalation |Provide fresh air and seek medical attention. Ingestion |Do not induce vomiting or give food or drink. Notes to Physician | Protection of | First-aiders | Notes |Carbon black is listed as a possible carcinogen by |International Agency for Research on Cancer (IARC). 5. FIRE-FIGHTING MEASURES Flammability/Flammable | properties | Flash point | Recommended Extinguishing | Media | Special Fire-Fighting |In case of fire where lithium batteries are Procedures |present, flood area with water or smother with |a Class D fire extinguishant appropriate for |lithium metal, such as Lith-X. Water may not |extinguish burning batteries but will cool the |adjacent batteries and control the spread of |fire. Burning batteries will burn themselves |out. Virtually all fires involving lithium |batteries can be controlled by flooding with |water. However, the contents of the battery |will react with water and form hydrogen gas. |In a confined space, hydrogen gas can form an |explosive mixture. In this situation, |smothering agents are recommended. A |smothering agent will extinguish burning |lithium batteries. | Explosion Data | Sensitivity to Mechanical | Impact | Sensitivity to Static | Discharge | | Specific Hazards from | Chemical | | Protective Equipment |Emergency Responders should wear |self-contained breathing apparatus. Burning |lithium manganese dioxide batteries produce |toxic and corrosive lithium hydroxide fumes. NFPA |Health Hazard: |Flammability: |Instability:|Physical Hazard HMIS |Health Hazard: |Flammability: |Physical |PPE: | | |Hazard: | 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: To cleanup leaking batteries: Eye Protection: Wear safety glasses with side shields if handling an open or leaking battery. Gloves: Use neoprene or natural rubber gloves if handling an open or leaking battery. Battery materials should be collected in a leak-proof container. Labeling: If the Energizer label or package warnings are not visible, it is important to provide a package and/or device label stating: WARNING: Battery can explode or leak and cause burns if installed backwards, disassembled, charged, or exposed to water, fire or high temperature. Where accidental ingestion of small batteries is possible, the label should include: (1) KEEP OUT OF REACH OF CHILDREN. Swallowing may lead to serious injury or death in as little as 2 hours due to chemical burns and potential perforation of the esophagus. Immediately see doctor; have doctor phone (202) 625-3333. Keep in original package until ready to use. Dispose of used batteries immediately. Environmental Precautions Methods for Containment Methods for Cleaning Up Notes: Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries. Respiratory Protection: Avoid exposure to electrolyte fumes from open or leaking batteries. 7. HANDLING AND STORAGE Handling: Accidental short circuit for a few seconds will not seriously affect the battery. Prolonged short circuit will cause the battery to lose energy, generate significant heat and can cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk containers, metal jewelry, metal covered tables or metal belts used for assembly of batteries into devices. Damaging a lithium battery may result in an internal short circuit. The contents of an open battery, including a vented battery, when exposed to water, may result in a fire and/or explosion. Crushed or damaged batteries may result in a fire. If soldering or welding to the battery is required, consult your Energizer representative for proper precautions to prevent seal damage or short circuit. Charging: This battery is manufactured in a charged state. It is not designed for recharging. Recharging can cause battery leakage or, in some cases, high pressure rupture. Inadvertent charging can occur if a battery is installed backwards. Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life. In locations that handle large quantities of lithium batteries, such as warehouses, lithium batteries should be isolated from unnecessary combustibles. Mechanical Containment: If potting or sealing the battery in an airtight or watertight container is required, consult your Energizer Battery Manufacturing, Inc. representative for precautionary suggestions. Do not obstruct safety release vents on batteries. Encapsulation of batteries will not allow cell venting and can cause high pressure rupture. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name |ACGIH TLV |OSHA PEL |NIOSH IDLH |OTHER | | | | | | | | | | | | Engineering Measures Personal Protective Equipment Eyes/Face |Not necessary under normal conditions. Protection | Skin and Body |Gloves: Not necessary under normal conditions. Protection | Respiratory |Not necessary under normal conditions. Protection | Ventilation/Other |Not necessary under normal conditions. Hygiene Measures 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance |Solid object |Odor |No odor Odor Threshold |No odor |Physical State | Color | |Viscosity |Not applicable for | | |an Article pH |Not |Percent Volatile, | |applicable |wt. % | |for an | | |Article | | Flash Point |Not |Auto-ignition |Not applicable for |applicable |Temperature |an Article |for an | | |Article | | Decomposition |Not |Boiling Point/ Range|Not applicable for Temp |applicable | |an Article |for an | | |Article | | Melting |Not |Freezing Point |Not applicable for Point/Range |applicable | |an Article |for an | | |Article | | Flammability | |Explosion Limits |Not applicable for | | |an Article Specific Gravity | |Water Solubility | Solubility | |Evaporation Rate | Vapor Pressure |Not |Vapor Density |Not applicable for |applicable | |an Article |for an | | |Article | | VOC content, wt. | | | % | | | | | | Notes 10. STABILITY AND REACTIVITY Chemical Stability | Incompatible Products | Conditions to avoid | Hazardous Decomposition | Products | Hazardous Polymerization | Notes: Lithium manganese dioxide batteries contain no sulfides or cyanides and they do not meet any other reactivity criteria including "reacts violently with water" and therefore do not meet any of the criteria established in 40 CFR 261.2 for reactivity. 11. TOXICOLOGY INFORMATION Acute Toxicity: Under normal conditions of use, lithium manganese dioxide batteries are non-toxic. Product | Information | Inhalation | Eye Contact | Skin Contact | Ingestion | Chemical Name |LD50 Oral |LD50 Dermal |LC50 Inhalation | | | | | | Chronic Toxicity| Chemical Name |ACGIH |IARC |NTP |OSHA Carbon black | | listed as| | | |a possible| | | |carcinogen| | | |by | | | |Internatio| | | |nal Agency| | | |for | | | |Research | | | |on Cancer | | | |(IARC). | | | | | | Target Organ Effects 12. ECOLOGICAL INFORMATION Ecotoxicity: Issues such as ecotoxicity, persistence and bioaccumulation are not applicable for articles. The Environmental impact of this product has been fully investigated Chemical Name|Toxicity to |Toxicity to |Tox, to |Daphnia Magna |Algea |Fish |Microorganisms|(water flea) | | | | | | | | | | | | Notes 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Lithium iron disulfide batteries are not hazardous waste per the United States Resource Conservation and Recovery Act (RCRA) - 40 CFR Part 261 Subpart C. Dispose of in accordance with all applicable federal, state and local regulations. Contaminated Packaging US EPA Waste number Notes 14. TRANSPORTATION INFORMATION In general, all batteries in all forms of transportation (ground, air, or ocean) must be packaged in a safe and responsible manner. Regulatory concerns from all agencies for safe packaging require that batteries be packaged in a manner that prevents short circuits and be contained in "strong outer packaging" that prevents spillage of contents. All original packaging for Energizer lithium batteries are compliant with these regulatory concerns. Energizer lithium manganese dioxide batteries are exempt from the classification as dangerous goods as they meet the requirements of the special provisions listed below. (Essentially, they are properly packaged and labeled, contain less than 1 gram of lithium and pass the tests defined in UN model regulation section 38.3). DOT UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description |Special Provisions: 29, A54, A100, A101 Emergency Response | Guide Number | TDG UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description |Special Provisions: 34 MEX | UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | ICAO UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description |Special Provisions: Packaging Instructions 968 - 970 IATA UN-Number | Proper Shipping name| Hazard Class | Packing Group | ERG Code | Description |Special Provisions: Packaging Instructions 968 - 970 IMDG/IMO UN-Number | Proper Shipping name| Hazard Class | Packing Group | EmS No. | Description |Special Provisions: 188, 230, 310, 957 RID UN-Number | Proper Shipping | name | Hazard Class | Packing Group | Classification Code| Description | ADR/RID-Labels | ADR UN-Number | Proper Shipping | name | Hazard Class | Packing Group | Classification Code| Description | ADR/RID-Labels | ADN UN-Number Proper Shipping name Hazard Class Packing Group Classification Code Special Provisions Description Hazard Labels Limited Quantity 15. REGULATORY INFORMATION International Inventories TSCA DSL EINECS ENCS IECSC PICCS AICS U.S. Federal Regulations SARA 313: Outside of the transportation requirements noted in Section 14, lithium manganese dioxide batteries marketed by Energizer Battery Manufacturing, Inc. are not regulated. SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency Planning and Community Right-To-Know Act. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Clean Water Act CERCLA U.S. State Regulations U.S. State Right-to-Know Regulations International Regulations Canada 16. OTHER INFORMATION Prepared By: Revision Date: March 2015 Company: Energizer Battery Manufacturing, Inc. Revision number Telephone number: 800-383-7323 (USA / CANADA) Notes Other Information: None Disclaimer information: Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different Eveready/Energizer battery systems. Batteries are articles as defined under the GHS and exempt from GHS classification criteria (Section 188.8.131.52.1 of the GHS). The information and recommendations set forth herein are made in good faith, for information only, and are believed to be accurate as of the date of preparation. However, ENERGIZER BATTERY MANUFACTURING, INC. MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMATION AND DISCLAIMS ALL LIABILITY FROM REFERENCE ON IT. END OF MATERIAL SAFETY DATA SHEET
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.