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MSDS Sheet 0052770

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Material Safety Data Sheet                                                
Date of issue:      |Revision Date: March 2015    |Revision Number:       
Imperial Supplies Part Number: 0052770                                    
1. PRODUCT AND COMPANY IDENTIFICATION                                     
Manufacturer:                                                             
Energizer Battery Manufacturing, Inc.                                     
25225 Detroit Rd.                                                         
Westlake, OH 44145                                                        
Telephone: 800-383-7323 (USA / CANADA)                                    
Emergency  Phone                                                          
                                                                          
                                                                          
Product Name: Energizer Battery                                           
Product Code(s):                                                          
Recommended Use:                                                          
UN-Number:                                                                
Product Type:                                                             
                                                                          
2.  HAZARDS IDENTIFICATION                                                
                                                                          
                                                                          
                                                                          
Appearance: Solid    |Physical State:          |Odor: No odor             
object               |                         |                          
                                                                          
Potential Health Effects                                                  
Principle Routes of Exposure                                              
                                                                          
Acute Effects:                                                            
Eyes                 |Contents of an open battery can cause severe        
                     |irritation.                                         
Skin                 |Contents of an open battery can cause skin          
                     |irritation.                                         
Inhalation           |Contents of an open battery can cause respiratory   
                     |irritation.                                         
Ingestion            |Swallowing a battery can be harmful.                
Notes: Under normal conditions of use, the battery is hermetically sealed.
                                                                          
Chronic Effects:                                                          
Eyes                 |                                                    
Skin                 |                                                    
Inhalation           |                                                    
Ingestion            |                                                    
Notes:                                                                    
                                                                          
Aggravated Medical Conditions                                             
                                                                          
Environmental Hazard                                                      
                                                                          
3.  COMPOSITION/INFORMATION ON INGREDIENTS                                
                                                                          
Chemical/Ingredient Name |CAS-No     |Weight%   |ACGIH,    |OSHA-PE|Other 
                         |           |          |TLV-TWA   |L      |      
Carbon Black             |1333-86-4  |0-1       |3.5 mg/m3 |3.5    |      
                         |           |          |TWA       |mg/m3  |      
                         |           |          |          |TWA    |      
1,2-Dimethoxyethane      |110-71-4   |0-6       |None      |None   |      
                         |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
1,3-Dioxolane            |646-06-0   |0-8       |None      |None   |      
                         |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Graphite                 |7782-42-5  |0-3       |2 mg/m3   |15     |      
                         |           |          |TWA       |mg/m3  |      
                         |           |          |(respirabl|TWA    |      
                         |           |          |e         |(total |      
                         |           |          |fraction) |dust)  |      
                         |           |          |          |5 mg/m3|      
                         |           |          |          |TWA    |      
                         |           |          |          |(respir|      
                         |           |          |          |able   |      
                         |           |          |          |fractio|      
                         |           |          |          |n)     |      
Lithium or Lithium Alloy |7439-93-2  |1-6       |None      |None   |      
                         |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Lithium                  |33454-82-9 |0-3       |None      |None   |      
Trifluoromethanesulfonate|           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Lithium                  |90076-65-6 |0-3       |None      |None   |      
Trifluoromethanesulfonimi|           |          |establishe|establi|      
de                       |           |          |d         |shed   |      
Manganese Dioxide        |1313-13-9  |12-42     |0.2 mg/m3 |5 mg/m3|      
                         |           |          |TWA (as   |Ceiling|      
                         |           |          |Mn)       |(as Mn)|      
Propylene Carbonate      |108-32-7   |0-8       |None      |None   |      
                         |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Non-Hazardous Components:|           |20        |None      |None   |      
                         |           |          |establishe|establi|      
Steel                    |           |          |d         |shed   |      
(iron CAS# 65997-19-5)   |           |Balance   |None      |None   |      
Plastic and Other        |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Notes: The battery should not be opened or burned. Exposure to the        
ingredients contained within or their combustion products could be        
harmful.                                                                  
                                                                          
4.  FIRST AID MEASURES                                                    
                                                                          
General Advice                                                            
Eyes               |Immediately flush eyes thoroughly with water for at  
                   |least 15 minutes, lifting upper and lower lids, until
                   |no evidence of the chemical remains. Seek medical    
                   |attention.                                           
Skin               |Remove contaminated clothing and wash skin with soap 
                   |and water.                                           
Inhalation         |Provide fresh air and seek medical attention.        
Ingestion          |Do not induce vomiting or give food or drink.        
Notes to Physician |                                                     
Protection of      |                                                     
First-aiders       |                                                     
Notes              |Carbon black is listed as a possible carcinogen by   
                   |International Agency for Research on Cancer (IARC).  
                                                                          
5.  FIRE-FIGHTING MEASURES                                                
                                                                          
Flammability/Flammable     |                                              
properties                 |                                              
Flash point                |                                              
Recommended Extinguishing  |                                              
Media                      |                                              
Special  Fire-Fighting     |In case of fire where lithium batteries are   
Procedures                 |present, flood area with water or smother with
                           |a Class D fire extinguishant appropriate for  
                           |lithium metal, such as Lith-X. Water may not  
                           |extinguish burning batteries but will cool the
                           |adjacent batteries and control the spread of  
                           |fire. Burning batteries will burn themselves  
                           |out. Virtually all fires involving lithium    
                           |batteries can be controlled by flooding with  
                           |water. However, the contents of the battery   
                           |will react with water and form hydrogen gas.  
                           |In a confined space, hydrogen gas can form an 
                           |explosive mixture. In this situation,         
                           |smothering agents are recommended. A          
                           |smothering agent will extinguish burning      
                           |lithium batteries.                            
                           |                                              
Explosion Data             |                                              
Sensitivity to Mechanical  |                                              
Impact                     |                                              
Sensitivity to Static      |                                              
Discharge                  |                                              
                           |                                              
Specific Hazards from      |                                              
Chemical                   |                                              
                           |                                              
Protective Equipment       |Emergency Responders should wear              
                           |self-contained breathing apparatus. Burning   
                           |lithium manganese dioxide batteries produce   
                           |toxic and corrosive lithium hydroxide fumes.  
                                                                          
NFPA |Health Hazard: |Flammability:  |Instability:|Physical Hazard        
                                                                          
HMIS |Health Hazard: |Flammability:  |Physical      |PPE:                 
     |               |               |Hazard:       |                     
                                                                          
6.  ACCIDENTAL RELEASE MEASURES                                           
                                                                          
Personal Precautions: To cleanup leaking batteries: Eye Protection: Wear  
safety glasses with side shields if handling an open or leaking battery.  
Gloves: Use neoprene or natural rubber gloves if handling an open or      
leaking battery. Battery materials should be collected in a leak-proof    
container.                                                                
                                                                          
Labeling: If the Energizer label or package warnings are not visible, it  
is important to provide a package and/or device label stating:            
                                                                          
WARNING: Battery can explode or leak and cause burns if installed         
backwards, disassembled, charged, or exposed to water, fire or high       
temperature.                                                              
Where accidental ingestion of small batteries is possible, the label      
should include:                                                           
(1) KEEP OUT OF REACH OF CHILDREN. Swallowing may lead to serious injury  
or death in as little as 2 hours due to chemical burns and potential      
perforation of the esophagus. Immediately see doctor; have doctor phone   
(202) 625-3333. Keep in original package until ready to use. Dispose of   
used batteries immediately.                                               
Environmental Precautions                                                 
Methods for Containment                                                   
Methods for Cleaning Up                                                   
Notes: Ventilation Requirements: Room ventilation may be required in areas
where there are open or leaking batteries.                                
Respiratory Protection: Avoid exposure to electrolyte fumes from open or  
leaking batteries.                                                        
                                                                          
7.  HANDLING AND STORAGE                                                  
                                                                          
Handling: Accidental short circuit for a few seconds will not seriously   
affect the battery. Prolonged short circuit will cause the battery to lose
energy, generate significant heat and can cause the safety release vent to
open. Sources of short circuits include jumbled batteries in bulk         
containers, metal jewelry, metal covered tables or metal belts used for   
assembly of batteries into devices. Damaging a lithium battery may result 
in an internal short circuit.                                             
The contents of an open battery, including a vented battery, when exposed 
to water, may result in a fire and/or explosion. Crushed or damaged       
batteries may result in a fire.                                           
If soldering or welding to the battery is required, consult your Energizer
representative for proper precautions to prevent seal damage or short     
circuit.                                                                  
Charging: This battery is manufactured in a charged state. It is not      
designed for recharging. Recharging can cause battery leakage or, in some 
cases, high pressure rupture. Inadvertent charging can occur if a battery 
is installed backwards.                                                   
Storage: Store in a cool, well ventilated area. Elevated temperatures can 
result in shortened battery life. In locations that handle large          
quantities of lithium batteries, such as warehouses, lithium batteries    
should be isolated from unnecessary combustibles.                         
Mechanical Containment: If potting or sealing the battery in an airtight  
or watertight container is required, consult your Energizer Battery       
Manufacturing, Inc. representative for precautionary suggestions. Do not  
obstruct safety release vents on batteries. Encapsulation of batteries    
will not allow cell venting and can cause high pressure rupture.          
                                                                          
8.  EXPOSURE CONTROLS/PERSONAL PROTECTION                                 
                                                                          
Exposure Guidelines                                                       
                                                                          
Chemical Name    |ACGIH TLV    |OSHA PEL      |NIOSH IDLH     |OTHER      
                 |             |              |               |           
                 |             |              |               |           
                 |             |              |               |           
                                                                          
Engineering Measures                                                      
                                                                          
Personal Protective Equipment                                             
Eyes/Face          |Not necessary under normal conditions.               
Protection         |                                                     
Skin and Body      |Gloves: Not necessary under normal conditions.       
Protection         |                                                     
Respiratory        |Not necessary under normal conditions.               
Protection         |                                                     
Ventilation/Other  |Not necessary under normal conditions.               
Hygiene Measures                                                          
                                                                          
9.  PHYSICAL AND CHEMICAL PROPERTIES                                      
                                                                          
Appearance       |Solid object |Odor                |No odor             
Odor Threshold   |No odor      |Physical State      |                    
Color            |             |Viscosity           |Not applicable for  
                 |             |                    |an Article          
pH               |Not          |Percent  Volatile,  |                    
                 |applicable   |wt. %               |                    
                 |for an       |                    |                    
                 |Article      |                    |                    
Flash Point      |Not          |Auto-ignition       |Not applicable for  
                 |applicable   |Temperature         |an Article          
                 |for an       |                    |                    
                 |Article      |                    |                    
Decomposition    |Not          |Boiling Point/ Range|Not applicable for  
Temp             |applicable   |                    |an Article          
                 |for an       |                    |                    
                 |Article      |                    |                    
Melting          |Not          |Freezing Point      |Not applicable for  
Point/Range      |applicable   |                    |an Article          
                 |for an       |                    |                    
                 |Article      |                    |                    
Flammability     |             |Explosion Limits    |Not applicable for  
                 |             |                    |an Article          
Specific Gravity |             |Water Solubility    |                    
Solubility       |             |Evaporation Rate    |                    
Vapor Pressure   |Not          |Vapor Density       |Not applicable for  
                 |applicable   |                    |an Article          
                 |for an       |                    |                    
                 |Article      |                    |                    
VOC content, wt. |             |                    |                    
%                |             |                    |                    
                 |             |                    |                    
Notes                                                                     
                                                                          
10. STABILITY AND REACTIVITY                                              
                                                                          
Chemical Stability        |                                               
Incompatible Products     |                                               
Conditions to avoid       |                                               
Hazardous Decomposition   |                                               
Products                  |                                               
Hazardous Polymerization  |                                               
Notes: Lithium manganese dioxide batteries contain no sulfides or cyanides
and they do not meet any other reactivity criteria including "reacts      
violently with water" and therefore do not meet any of the criteria       
established in 40 CFR 261.2 for reactivity.                               
                                                                          
11. TOXICOLOGY INFORMATION                                                
                                                                          
Acute Toxicity: Under normal conditions of use, lithium manganese dioxide 
batteries are non-toxic.                                                  
                                                                          
Product          |                                                        
Information      |                                                        
Inhalation      |                                                        
Eye Contact     |                                                        
Skin Contact    |                                                        
Ingestion       |                                                        
                                                                          
Chemical Name   |LD50 Oral      |LD50 Dermal       |LC50 Inhalation      
                |               |                  |                     
                |               |                  |                     
                                                                          
Chronic Toxicity|                                                        
                                                                          
Chemical Name   |ACGIH            |IARC      |NTP          |OSHA          
Carbon black    |                 | listed as|             |              
                |                 |a possible|             |              
                |                 |carcinogen|             |              
                |                 |by        |             |              
                |                 |Internatio|             |              
                |                 |nal Agency|             |              
                |                 |for       |             |              
                |                 |Research  |             |              
                |                 |on Cancer |             |              
                |                 |(IARC).   |             |              
                |                 |          |             |              
                                                                          
Target Organ Effects                                                      
                                                                          
12.  ECOLOGICAL INFORMATION                                               
                                                                          
Ecotoxicity: Issues such as ecotoxicity, persistence and bioaccumulation  
are not applicable for articles.                                          
The Environmental impact of this product has been fully investigated      
                                                                          
Chemical Name|Toxicity to    |Toxicity to  |Tox, to       |Daphnia Magna   
             |Algea          |Fish         |Microorganisms|(water flea)    
             |               |             |              |                
             |               |             |              |                
             |               |             |              |                
                                                                          
Notes                                                                     
                                                                          
13.  DISPOSAL CONSIDERATIONS                                              
                                                                          
Waste Disposal Methods: Lithium iron disulfide batteries are not hazardous
waste per the United States Resource Conservation and Recovery Act (RCRA) 
- 40 CFR Part 261 Subpart C. Dispose of in accordance with all applicable 
federal, state and local regulations.                                     
                                                                          
Contaminated Packaging                                                    
                                                                          
US EPA Waste number                                                       
                                                                          
Notes                                                                     
                                                                          
                                                                          
14.  TRANSPORTATION INFORMATION                                           
In general, all batteries in all forms of transportation (ground, air, or 
ocean) must be packaged in a safe and responsible manner. Regulatory      
concerns from all agencies for safe packaging require that batteries be   
packaged in a manner that prevents short circuits and be contained in     
"strong outer packaging" that prevents spillage of contents. All original 
packaging for Energizer lithium batteries are compliant with these        
regulatory concerns. Energizer lithium manganese dioxide batteries are    
exempt from the classification as dangerous goods as they meet the        
requirements of the special provisions listed below. (Essentially, they   
are properly packaged and labeled, contain less than 1 gram of lithium and
pass the tests defined in UN model regulation section 38.3).              
DOT                                                                       
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |Special Provisions: 29, A54, A100, A101              
Emergency Response  |                                                     
Guide Number        |                                                     
                                                                          
TDG                                                                       
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |Special Provisions: 34                               
                                                                          
MEX                 |                                                     
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
ICAO                                                                      
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |Special Provisions: Packaging Instructions 968 - 970 
                                                                          
IATA                                                                      
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
ERG Code            |                                                     
Description         |Special Provisions: Packaging Instructions 968 - 970 
                                                                          
IMDG/IMO                                                                  
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
EmS No.             |                                                     
Description         |Special Provisions: 188, 230, 310, 957               
                                                                          
RID                                                                       
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
Classification Code|                                                     
Description        |                                                     
ADR/RID-Labels     |                                                     
                                                                          
ADR                                                                       
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
Classification Code|                                                     
Description        |                                                     
ADR/RID-Labels     |                                                     
                                                                          
ADN                                                                       
UN-Number                                                                 
Proper Shipping name                                                      
Hazard Class                                                              
Packing Group                                                             
Classification Code                                                       
Special Provisions                                                        
Description                                                               
Hazard Labels                                                             
Limited Quantity                                                          
                                                                          
15.  REGULATORY INFORMATION                                               
                                                                          
International Inventories                                                 
TSCA                                                                      
DSL                                                                       
EINECS                                                                    
ENCS                                                                      
IECSC                                                                     
PICCS                                                                     
AICS                                                                      
                                                                          
U.S. Federal Regulations                                                  
SARA 313: Outside of the transportation requirements noted in Section 14, 
lithium manganese dioxide batteries marketed by Energizer Battery         
Manufacturing, Inc. are not regulated.                                    
SARA/TITLE III - As an article, this battery and its contents are not     
subject to the requirements of the Emergency Planning and Community       
Right-To-Know Act.                                                        
SARA 311/312 Hazard Categories                                            
Acute Health Hazard                                                       
Chronic Health Hazard                                                     
Fire Hazard                                                               
Sudden Release of Pressure Hazard                                         
Reactive Hazard                                                           
                                                                          
Clean Water Act                                                           
                                                                          
CERCLA                                                                    
                                                                          
U.S. State Regulations                                                    
                                                                          
U.S. State Right-to-Know Regulations                                      
                                                                          
International Regulations                                                 
                                                                          
Canada                                                                    
                                                                          
                                                                          
                                                                          
16.  OTHER INFORMATION                                                    
                                                                          
Prepared By:                                                              
Revision Date: March 2015                                                 
Company: Energizer Battery Manufacturing, Inc.                            
Revision number                                                           
Telephone number: 800-383-7323 (USA / CANADA)                             
                                                                          
Notes                                                                     
                                                                          
Other Information: None                                                   
                                                                          
Disclaimer information: Energizer has prepared copyrighted Product Safety 
Datasheets to provide information on the different Eveready/Energizer     
battery systems. Batteries are articles as defined under the GHS and      
exempt from GHS classification criteria (Section 1.3.2.1.1 of the GHS).   
The information and recommendations set forth herein are made in good     
faith, for information only, and are believed to be accurate as of the    
date of preparation. However, ENERGIZER BATTERY MANUFACTURING, INC. MAKES 
NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMATION  
AND DISCLAIMS ALL LIABILITY FROM REFERENCE ON IT.                         
                                                                          
                                                                          
END OF MATERIAL SAFETY DATA SHEET                                         




    

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.

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