Request Account    |    Login

National Distributor of Quality Maintenance Supplies Since 1958

1-800-558-2808

Track Order Status
Order No:
Zip Code:

MSDS Sheet 0051190

Printer Friendly View
        

Material Safety Data Sheet                                                
Date of issue:      |Revision Date: March 2015    |Revision Number:       
Imperial Supplies Part Number: 0051190                                    
1. PRODUCT AND COMPANY IDENTIFICATION                                     
Manufacturer:                                                             
Energizer Battery Manufacturing, Inc.                                     
25225 Detroit Rd.                                                         
Westlake, OH 44145                                                        
Telephone: 800-383-7323 (USA / CANADA)                                    
Emergency  Phone                                                          
                                                                          
                                                                          
Product Name: Energizer Battery                                           
Product Code(s):                                                          
Recommended Use:                                                          
UN-Number:                                                                
Product Type:                                                             
                                                                          
2.  HAZARDS IDENTIFICATION                                                
                                                                          
                                                                          
                                                                          
Appearance: Solid    |Physical State:          |Odor: No odor             
object               |                         |                          
                                                                          
Potential Health Effects                                                  
Principle Routes of Exposure                                              
                                                                          
Acute Effects:                                                            
Eyes                 |Contents of an open battery can cause severe        
                     |irritation.                                         
Skin                 |Contents of an open battery can cause skin          
                     |irritation.                                         
Inhalation           |Contents of an open battery can cause respiratory   
                     |irritation.                                         
Ingestion            |Swallowing may lead to serious injury or death in as
                     |little as 2 hours due to chemical burns and         
                     |potential perforation of the esophagus. Immediately 
                     |see doctor; have doctor phone (202) 625-3333. Do not
                     |induce vomiting or give food or drink.              
Notes: Under normal conditions of use, the battery is hermetically sealed.
                                                                          
Chronic Effects:                                                          
Eyes                 |                                                    
Skin                 |                                                    
Inhalation           |                                                    
Ingestion            |                                                    
Notes:                                                                    
                                                                          
Aggravated Medical Conditions                                             
                                                                          
Environmental Hazard                                                      
                                                                          
3.  COMPOSITION/INFORMATION ON INGREDIENTS                                
                                                                          
Chemical/Ingredient Name |CAS-No     |Weight%   |ACGIH,    |OSHA-PE|Other 
                         |           |          |TLV-TWA   |L      |      
Carbon Black             |1333-86-4  |0-1       |3.5 mg/m3 |3.5    |      
                         |           |          |TWA       |mg/m3  |      
                         |           |          |          |TWA    |      
1,2-Dimethoxyethane      |110-71-4   |0-6       |None      |None   |      
                         |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
1,3-Dioxolane            |646-06-0   |0-8       |None      |None   |      
                         |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Graphite                 |7782-42-5  |0-3       |2 mg/m3   |15     |      
                         |           |          |TWA       |mg/m3  |      
                         |           |          |(respirabl|TWA    |      
                         |           |          |e         |(total |      
                         |           |          |fraction) |dust)  |      
                         |           |          |          |5 mg/m3|      
                         |           |          |          |TWA    |      
                         |           |          |          |(respir|      
                         |           |          |          |able   |      
                         |           |          |          |fractio|      
                         |           |          |          |n)     |      
Lithium or Lithium Alloy |7439-93-2  |1-6       |None      |None   |      
                         |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Lithium Perchlorate      |7791-03-9  |0-3       |None      |None   |      
                         |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Lithium                  |33454-82-9 |0-3       |None      |None   |      
Trifluoromethanesulfonate|           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Lithium                  |90076-65-6 |0-3       |None      |None   |      
Trifluoromethanesulfonimi|           |          |establishe|establi|      
de                       |           |          |d         |shed   |      
Manganese Dioxide        |1313-13-9  |12-42     |0.2 mg/m3 |5 mg/m3|      
                         |           |          |TWA (as   |Ceiling|      
                         |           |          |Mn)       |(as Mn)|      
Propylene Carbonate      |108-32-7   |0-8       |None      |None   |      
                         |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Non-Hazardous Components:|65997-19-5 |20        |None      |None   |      
Steel                    |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Plastic and Other        |           |Balance   |None      |None   |      
                         |           |          |establishe|establi|      
                         |           |          |d         |shed   |      
Notes                                                                     
                                                                          
4.  FIRST AID MEASURES                                                    
                                                                          
                   |                                                     
General Advice     |                                                     
Eyes               |Immediately flush eyes thoroughly with water for at  
                   |least 15 minutes, lifting upper and lower lids, until
                   |no evidence of the chemical remains. Seek medical    
                   |attention.                                           
Skin               |Remove contaminated clothing and wash skin with soap 
                   |and water.                                           
Inhalation         |Provide fresh air and seek medical attention.        
Ingestion          |Swallowing may lead to serious injury or death in as 
                   |little as 2 hours due to chemical burns and potential
                   |perforation of the esophagus. Immediately see doctor;
                   |have doctor phone (202) 625-3333. Do not induce      
                   |vomiting or give food or drink.                      
Notes to Physician |                                                     
Protection of      |                                                     
First-aiders       |                                                     
Notes                                                                     
5.  FIRE-FIGHTING MEASURES                                                
                           |                                              
Flammability/Flammable     |Not applicable for an Article                 
properties                 |                                              
Flash point                |Not applicable for an Article                 
Recommended Extinguishing  |                                              
Media                      |                                              
Special  Fire-Fighting     |In case of fire where lithium batteries are   
Procedures                 |present, flood area with water or smother with
                           |a Class D fire extinguishant appropriate for  
                           |lithium metal, such as Lith-X. Water may not  
                           |extinguish burning batteries but will cool the
                           |adjacent batteries and control the spread of  
                           |fire. Burning batteries will burn themselves  
                           |out. Virtually all fires involving lithium    
                           |batteries can be controlled by flooding with  
                           |water. However, the contents of the battery   
                           |will react with water and form hydrogen gas.  
                           |In a confined space, hydrogen gas can form an 
                           |explosive mixture. In this situation,         
                           |smothering agents are recommended. A          
                           |smothering agent will extinguish burning      
                           |lithium batteries. Emergency Responders should
                           |wear self-contained breathing apparatus.      
                           |Burning lithium manganese dioxide batteries   
                           |produce toxic and corrosive lithium hydroxide 
                           |fumes.                                        
                           |                                              
Explosion Data             |                                              
Sensitivity to Mechanical  |                                              
Impact                     |                                              
Sensitivity to Static      |                                              
Discharge                  |                                              
                           |                                              
Specific Hazards from      |                                              
Chemical                   |                                              
                           |                                              
Protective Equipment       |                                              
                                                                          
NFPA |Health Hazard: |Flammability:  |Instability:|Physical Hazard        
                                                                          
HMIS |Flammability:  |Instability:   |Physical      |PPE:                 
     |               |               |Hazard:       |                     
                                                                          
6.  ACCIDENTAL RELEASE MEASURES                                           
                                                                          
Personal Precautions                                                      
Environmental Precautions                                                 
Methods for Containment                                                   
Methods for Cleaning Up                                                   
Notes: Ventilation Requirements: Room ventilation may be required in areas
where there are open or leaking batteries.                                
Respiratory Protection: Avoid exposure to electrolyte fumes from open or  
leaking batteries.                                                        
Eye Protection: Wear safety glasses with side shields if handling an open 
or leaking battery.                                                       
Gloves: Use neoprene or natural rubber gloves if handling an open or      
leaking battery. Battery materials should be collected in a leak-proof    
container.                                                                
                                                                          
7.  HANDLING AND STORAGE                                                  
                                                                          
Handling: Accidental short circuit for a few seconds will not seriously   
affect the battery. Prolonged short circuit will cause the battery to lose
energy, generate significant heat and can cause the safety release vent to
open. Sources of short circuits include jumbled batteries in bulk         
containers, metal jewelry, metal covered tables or metal belts used for   
assembly of batteries into devices. Damaging a lithium battery may result 
in an internal short circuit. The contents of an open battery, including a
vented battery, when exposed to water, may result in a fire and/or        
explosion. Crushed or damaged batteries may result in a fire. If soldering
or welding to the battery is required, consult your Energizer             
representative for proper precautions to prevent seal damage or short     
circuit.                                                                  
Storage: Store in a cool, well ventilated area. Elevated temperatures can 
result in shortened battery life. In locations that handle large          
quantities of lithium batteries, such as warehouses, lithium batteries    
should be isolated from unnecessary combustibles.                         
                                                                          
8.  EXPOSURE CONTROLS/PERSONAL PROTECTION                                 
                                                                          
Exposure Guidelines                                                       
                 |             |              |               |           
Chemical Name    |ACGIH TLV    |OSHA PEL      |NIOSH IDLH     |OTHER      
                 |             |              |               |           
                 |             |              |               |           
                 |             |              |               |           
                                                                          
Engineering Measures                                                      
                                                                          
Personal Protective Equipment                                             
Eyes/Face          |Not necessary under normal conditions.               
Protection         |                                                     
Skin and Body      |Gloves: Not necessary under normal conditions.       
Protection         |                                                     
Respiratory        |Not necessary under normal conditions.               
Protection         |                                                     
Ventilation/Other  |                                                     
Hygiene Measures                                                          
                                                                          
9.  PHYSICAL AND CHEMICAL PROPERTIES                                      
                 |             |                    |                    
Appearance       |Solid object |Odor                |No odor             
Odor Threshold   |No odor      |Physical State      |Solid object        
Color            |Solid object |Viscosity           |Not applicable for  
                 |             |                    |an Article          
pH               |Not          |Percent  Volatile,  |                    
                 |applicable   |wt. %               |                    
                 |for an       |                    |                    
                 |Article      |                    |                    
Flash Point      |Not          |Auto-ignition       |Not applicable for  
                 |applicable   |Temperature         |an Article          
                 |for an       |                    |                    
                 |Article      |                    |                    
Decomposition    |Not          |Boiling Point/ Range|Not applicable for  
Temp             |applicable   |                    |an Article          
                 |for an       |                    |                    
                 |Article      |                    |                    
Melting          |Not          |Freezing Point      |Not applicable for  
Point/Range      |applicable   |                    |an Article          
                 |for an       |                    |                    
                 |Article      |                    |                    
Flammability     |Not          |Explosion Limits    |                    
                 |applicable   |                    |                    
                 |for an       |                    |                    
                 |Article      |                    |                    
Specific Gravity |             |Water Solubility    |Not applicable for  
                 |             |                    |an Article          
Solubility       |             |Evaporation Rate    |Not applicable for  
                 |             |                    |an Article          
Vapor Pressure   |Not          |Vapor Density       |Not applicable for  
                 |applicable   |                    |an Article          
                 |for an       |                    |                    
                 |Article      |                    |                    
VOC content, wt. |             |                    |                    
%                |             |                    |                    
                                                                          
Notes                                                                     
                                                                          
10. STABILITY AND REACTIVITY                                              
                          |                                               
Chemical Stability        |                                               
Incompatible Products     |                                               
Conditions to avoid       |                                               
Hazardous Decomposition   |                                               
Products                  |                                               
Hazardous Polymerization  |                                               
Notes: Lithium manganese dioxide batteries contain no sulfides or cyanides
and they do not meet any other reactivity criteria including "reacts      
violently with water" and therefore do not meet any of the criteria       
established in 40 CFR 261.2 for reactivity.                               
                                                                          
11. TOXICOLOGY INFORMATION                                                
                                                                          
Acute Toxicity: Under normal conditions of use, lithium manganese dioxide 
batteries are non-toxic.                                                  
                 |                                                        
Product         |                                                        
Information     |                                                        
Inhalation      |                                                        
Eye Contact     |                                                        
Skin Contact    |                                                        
Ingestion       |                                                        
                                                                          
Chemical Name   |LD50 Oral      |LD50 Dermal       |LC50 Inhalation      
                |               |                  |                     
                |               |                  |                     
                                                                          
Chronic Toxicity|                                                        
                |                 |          |             |              
Chemical Name   |ACGIH            |IARC      |NTP          |OSHA          
                |                 |          |             |              
                |                 |          |             |              
                                                                          
Target Organ Effects                                                      
                                                                          
12.  ECOLOGICAL INFORMATION                                               
                                                                          
Ecotoxicity                                                               
The Environmental impact of this product has been fully investigated      
                                                                          
Chemical Name|Toxicity to    |Toxicity to  |Tox, to       |Daphnia Magna   
             |Algea          |Fish         |Microorganisms|(water flea)    
             |               |             |              |                
             |               |             |              |                
             |               |             |              |                
                                                                          
Notes: Issues such as ecotoxicity, persistence and bioaccumulation are not
applicable for articles.                                                  
                                                                          
13.  DISPOSAL CONSIDERATIONS                                              
                                                                          
Waste Disposal Methods:                                                   
                                                                          
Contaminated Packaging                                                    
                                                                          
US EPA Waste number                                                       
                                                                          
Notes:  Lithium iron disulfide batteries are not hazardous waste per the  
United States Resource Conservation and Recovery Act (RCRA) - 40 CFR Part 
261 Subpart C. Dispose of in accordance with all applicable federal, state
and local regulations.                                                    
                                                                          
                                                                          
14.  TRANSPORTATION INFORMATION                                           
                                                                          
DOT                 |                                                     
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |29, A54, A100, A101                                  
Emergency Response  |                                                     
Guide Number        |                                                     
                                                                          
TDG                 |                                                     
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                    |                                                     
MEX                 |                                                     
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
ICAO                |                                                     
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |Packaging Instructions 968 - 970                     
                                                                          
IATA                |                                                     
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
ERG Code            |                                                     
Description         |Packaging Instructions 968 - 970                     
                                                                          
IMDG/IMO            |                                                     
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
EmS No.             |                                                     
Description         |188, 230, 310, 957                                   
                                                                          
RID                |                                                     
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
Classification Code|                                                     
Description        |                                                     
ADR/RID-Labels     |                                                     
                                                                          
ADR                |                                                     
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
Classification Code|                                                     
Description        |188, 230, 310, 636, 656                              
ADR/RID-Labels     |                                                     
                                                                          
ADN                                                                       
UN-Number                                                                 
Proper Shipping name                                                      
Hazard Class                                                              
Packing Group                                                             
Classification Code                                                       
Special Provisions                                                        
Description                                                               
Hazard Labels                                                             
Limited Quantity                                                          
                                                                          
15.  REGULATORY INFORMATION                                               
                                                                          
International Inventories                                                 
TSCA                                                                      
DSL                                                                       
EINECS                                                                    
ENCS                                                                      
IECSC                                                                     
PICCS                                                                     
AICS                                                                      
                                                                          
U.S. Federal Regulations                                                  
SARA 313                                                                  
SARA 311/312 Hazard Categories                                            
Acute Health Hazard                                                       
Chronic Health Hazard                                                     
Fire Hazard                                                               
Sudden Release of Pressure Hazard                                         
Reactive Hazard                                                           
                                                                          
Clean Water Act                                                           
                                                                          
CERCLA                                                                    
                                                                          
U.S. State Regulations                                                    
                                                                          
U.S. State Right-to-Know Regulations: SARA/TITLE III - As an article, this
battery and its contents are not subject to the requirements of the       
Emergency Planning and Community Right-To-Know Act.                       
                                                                          
International Regulations                                                 
                                                                          
Canada                                                                    
                                                                          
                                                                          
                                                                          
16.  OTHER INFORMATION                                                    
                                                                          
Prepared By:                                                              
Revision Date: March 2015                                                 
Company: Energizer Battery Manufacturing, Inc.                            
Revision number                                                           
Telephone number: 800-383-7323 (USA / CANADA)                             
                                                                          
Notes                                                                     
                                                                          
Other Information                                                         
                                                                          
Disclaimer information                                                    
                                                                          
                                                                          
END OF MATERIAL SAFETY DATA SHEET                                         


   




    

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.

Feedback