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MSDS Sheet 0051190Printer Friendly View
Material Safety Data Sheet Date of issue: |Revision Date: March 2015 |Revision Number: Imperial Supplies Part Number: 0051190 1. PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Energizer Battery Manufacturing, Inc. 25225 Detroit Rd. Westlake, OH 44145 Telephone: 800-383-7323 (USA / CANADA) Emergency Phone Product Name: Energizer Battery Product Code(s): Recommended Use: UN-Number: Product Type: 2. HAZARDS IDENTIFICATION Appearance: Solid |Physical State: |Odor: No odor object | | Potential Health Effects Principle Routes of Exposure Acute Effects: Eyes |Contents of an open battery can cause severe |irritation. Skin |Contents of an open battery can cause skin |irritation. Inhalation |Contents of an open battery can cause respiratory |irritation. Ingestion |Swallowing may lead to serious injury or death in as |little as 2 hours due to chemical burns and |potential perforation of the esophagus. Immediately |see doctor; have doctor phone (202) 625-3333. Do not |induce vomiting or give food or drink. Notes: Under normal conditions of use, the battery is hermetically sealed. Chronic Effects: Eyes | Skin | Inhalation | Ingestion | Notes: Aggravated Medical Conditions Environmental Hazard 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical/Ingredient Name |CAS-No |Weight% |ACGIH, |OSHA-PE|Other | | |TLV-TWA |L | Carbon Black |1333-86-4 |0-1 |3.5 mg/m3 |3.5 | | | |TWA |mg/m3 | | | | |TWA | 1,2-Dimethoxyethane |110-71-4 |0-6 |None |None | | | |establishe|establi| | | |d |shed | 1,3-Dioxolane |646-06-0 |0-8 |None |None | | | |establishe|establi| | | |d |shed | Graphite |7782-42-5 |0-3 |2 mg/m3 |15 | | | |TWA |mg/m3 | | | |(respirabl|TWA | | | |e |(total | | | |fraction) |dust) | | | | |5 mg/m3| | | | |TWA | | | | |(respir| | | | |able | | | | |fractio| | | | |n) | Lithium or Lithium Alloy |7439-93-2 |1-6 |None |None | | | |establishe|establi| | | |d |shed | Lithium Perchlorate |7791-03-9 |0-3 |None |None | | | |establishe|establi| | | |d |shed | Lithium |33454-82-9 |0-3 |None |None | Trifluoromethanesulfonate| | |establishe|establi| | | |d |shed | Lithium |90076-65-6 |0-3 |None |None | Trifluoromethanesulfonimi| | |establishe|establi| de | | |d |shed | Manganese Dioxide |1313-13-9 |12-42 |0.2 mg/m3 |5 mg/m3| | | |TWA (as |Ceiling| | | |Mn) |(as Mn)| Propylene Carbonate |108-32-7 |0-8 |None |None | | | |establishe|establi| | | |d |shed | Non-Hazardous Components:|65997-19-5 |20 |None |None | Steel | | |establishe|establi| | | |d |shed | Plastic and Other | |Balance |None |None | | | |establishe|establi| | | |d |shed | Notes 4. FIRST AID MEASURES | General Advice | Eyes |Immediately flush eyes thoroughly with water for at |least 15 minutes, lifting upper and lower lids, until |no evidence of the chemical remains. Seek medical |attention. Skin |Remove contaminated clothing and wash skin with soap |and water. Inhalation |Provide fresh air and seek medical attention. Ingestion |Swallowing may lead to serious injury or death in as |little as 2 hours due to chemical burns and potential |perforation of the esophagus. Immediately see doctor; |have doctor phone (202) 625-3333. Do not induce |vomiting or give food or drink. Notes to Physician | Protection of | First-aiders | Notes 5. FIRE-FIGHTING MEASURES | Flammability/Flammable |Not applicable for an Article properties | Flash point |Not applicable for an Article Recommended Extinguishing | Media | Special Fire-Fighting |In case of fire where lithium batteries are Procedures |present, flood area with water or smother with |a Class D fire extinguishant appropriate for |lithium metal, such as Lith-X. Water may not |extinguish burning batteries but will cool the |adjacent batteries and control the spread of |fire. Burning batteries will burn themselves |out. Virtually all fires involving lithium |batteries can be controlled by flooding with |water. However, the contents of the battery |will react with water and form hydrogen gas. |In a confined space, hydrogen gas can form an |explosive mixture. In this situation, |smothering agents are recommended. A |smothering agent will extinguish burning |lithium batteries. Emergency Responders should |wear self-contained breathing apparatus. |Burning lithium manganese dioxide batteries |produce toxic and corrosive lithium hydroxide |fumes. | Explosion Data | Sensitivity to Mechanical | Impact | Sensitivity to Static | Discharge | | Specific Hazards from | Chemical | | Protective Equipment | NFPA |Health Hazard: |Flammability: |Instability:|Physical Hazard HMIS |Flammability: |Instability: |Physical |PPE: | | |Hazard: | 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions Methods for Containment Methods for Cleaning Up Notes: Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries. Respiratory Protection: Avoid exposure to electrolyte fumes from open or leaking batteries. Eye Protection: Wear safety glasses with side shields if handling an open or leaking battery. Gloves: Use neoprene or natural rubber gloves if handling an open or leaking battery. Battery materials should be collected in a leak-proof container. 7. HANDLING AND STORAGE Handling: Accidental short circuit for a few seconds will not seriously affect the battery. Prolonged short circuit will cause the battery to lose energy, generate significant heat and can cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk containers, metal jewelry, metal covered tables or metal belts used for assembly of batteries into devices. Damaging a lithium battery may result in an internal short circuit. The contents of an open battery, including a vented battery, when exposed to water, may result in a fire and/or explosion. Crushed or damaged batteries may result in a fire. If soldering or welding to the battery is required, consult your Energizer representative for proper precautions to prevent seal damage or short circuit. Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life. In locations that handle large quantities of lithium batteries, such as warehouses, lithium batteries should be isolated from unnecessary combustibles. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines | | | | Chemical Name |ACGIH TLV |OSHA PEL |NIOSH IDLH |OTHER | | | | | | | | | | | | Engineering Measures Personal Protective Equipment Eyes/Face |Not necessary under normal conditions. Protection | Skin and Body |Gloves: Not necessary under normal conditions. Protection | Respiratory |Not necessary under normal conditions. Protection | Ventilation/Other | Hygiene Measures 9. PHYSICAL AND CHEMICAL PROPERTIES | | | Appearance |Solid object |Odor |No odor Odor Threshold |No odor |Physical State |Solid object Color |Solid object |Viscosity |Not applicable for | | |an Article pH |Not |Percent Volatile, | |applicable |wt. % | |for an | | |Article | | Flash Point |Not |Auto-ignition |Not applicable for |applicable |Temperature |an Article |for an | | |Article | | Decomposition |Not |Boiling Point/ Range|Not applicable for Temp |applicable | |an Article |for an | | |Article | | Melting |Not |Freezing Point |Not applicable for Point/Range |applicable | |an Article |for an | | |Article | | Flammability |Not |Explosion Limits | |applicable | | |for an | | |Article | | Specific Gravity | |Water Solubility |Not applicable for | | |an Article Solubility | |Evaporation Rate |Not applicable for | | |an Article Vapor Pressure |Not |Vapor Density |Not applicable for |applicable | |an Article |for an | | |Article | | VOC content, wt. | | | % | | | Notes 10. STABILITY AND REACTIVITY | Chemical Stability | Incompatible Products | Conditions to avoid | Hazardous Decomposition | Products | Hazardous Polymerization | Notes: Lithium manganese dioxide batteries contain no sulfides or cyanides and they do not meet any other reactivity criteria including "reacts violently with water" and therefore do not meet any of the criteria established in 40 CFR 261.2 for reactivity. 11. TOXICOLOGY INFORMATION Acute Toxicity: Under normal conditions of use, lithium manganese dioxide batteries are non-toxic. | Product | Information | Inhalation | Eye Contact | Skin Contact | Ingestion | Chemical Name |LD50 Oral |LD50 Dermal |LC50 Inhalation | | | | | | Chronic Toxicity| | | | | Chemical Name |ACGIH |IARC |NTP |OSHA | | | | | | | | Target Organ Effects 12. ECOLOGICAL INFORMATION Ecotoxicity The Environmental impact of this product has been fully investigated Chemical Name|Toxicity to |Toxicity to |Tox, to |Daphnia Magna |Algea |Fish |Microorganisms|(water flea) | | | | | | | | | | | | Notes: Issues such as ecotoxicity, persistence and bioaccumulation are not applicable for articles. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Contaminated Packaging US EPA Waste number Notes: Lithium iron disulfide batteries are not hazardous waste per the United States Resource Conservation and Recovery Act (RCRA) - 40 CFR Part 261 Subpart C. Dispose of in accordance with all applicable federal, state and local regulations. 14. TRANSPORTATION INFORMATION DOT | UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description |29, A54, A100, A101 Emergency Response | Guide Number | TDG | UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | | MEX | UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description | ICAO | UN-Number | Proper Shipping name| Hazard Class | Packing Group | Description |Packaging Instructions 968 - 970 IATA | UN-Number | Proper Shipping name| Hazard Class | Packing Group | ERG Code | Description |Packaging Instructions 968 - 970 IMDG/IMO | UN-Number | Proper Shipping name| Hazard Class | Packing Group | EmS No. | Description |188, 230, 310, 957 RID | UN-Number | Proper Shipping | name | Hazard Class | Packing Group | Classification Code| Description | ADR/RID-Labels | ADR | UN-Number | Proper Shipping | name | Hazard Class | Packing Group | Classification Code| Description |188, 230, 310, 636, 656 ADR/RID-Labels | ADN UN-Number Proper Shipping name Hazard Class Packing Group Classification Code Special Provisions Description Hazard Labels Limited Quantity 15. REGULATORY INFORMATION International Inventories TSCA DSL EINECS ENCS IECSC PICCS AICS U.S. Federal Regulations SARA 313 SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Clean Water Act CERCLA U.S. State Regulations U.S. State Right-to-Know Regulations: SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency Planning and Community Right-To-Know Act. International Regulations Canada 16. OTHER INFORMATION Prepared By: Revision Date: March 2015 Company: Energizer Battery Manufacturing, Inc. Revision number Telephone number: 800-383-7323 (USA / CANADA) Notes Other Information Disclaimer information END OF MATERIAL SAFETY DATA SHEET
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.