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SDS Sheet 0046764Printer Friendly View
SECTION 1: IDENTIFICATION | |1.1. Product Identifier Product Form: Product Name: Chain and Cable; Chain and Cable Heavy CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Petroleum lubricating oil 1.3. Name, Address, and Telephone of the Responsible Party Company LUBRIPLATEÂ® Lubricants Co. 129 Lockwood St. Newark, NJ 07105 Telephone no.: 1-973-589-9150 1.4. Emergency Telephone Number Emergency | CHEM-TEL 1-800-255-3924 (24 hour) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | Hazard Statements (GHS-US) |No known significant effects or critical hazards. Precautionary Statements |Prevention: Not applicable. (GHS-US) |Response: Not applicable. |Storage: Not applicable. |Disposal: Not applicable 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Prolonged or repeated contact may dry skin and cause irritation 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) Distillates (petroleum), |64742-52-5 | |60-100 hydrotreated heavy | | | Naphthenic | | | Residual oils (petroleum), |64742-62-7 | |30-60 solvent-dewaxed | | | Distillates (petroleum), |64742-53-6 | |10-30 hydrotreated light | | | Naphthenic | | | 2-Butoxyethanol |111-76-2 | |1-5 | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. First-aid Measures After Skin Contact: Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove contaminated clothing and shoes. Get medical attention if symptoms occur First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention. First-aid Measures After Ingestion: Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: No known significant effects or critical hazards. Symptoms/Injuries After Skin Contact: Defatting to the skin. May cause skin dryness and irritation. Adverse symptoms may include the following: irritation dryness cracking Symptoms/Injuries After Eye Contact: No known significant effects or critical hazards. Symptoms/Injuries After Ingestion: No known significant effects or critical hazards. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments: No specific treatment. Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use an extinguishing agent suitable for the surrounding fire. Unsuitable Extinguishing Media: None Known 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: In a fire or if heated, a pressure increase will occur and the container may burst. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". 6.2. Environmental Precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 6.3. Methods and Material for Containment and Cleaning Up For Containment: Small spill: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill: Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Methods for Cleaning Up: 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Hygiene Measures: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Do not store above the following temperature: 40Â°C (104Â°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Chemical-resistant, impervious gloves complying with |an approved standard should be worn at all times |when handling chemical products if a risk assessment |indicates this is necessary. Eye Protection |Safety eyewear complying with an approved standard |should be used when a risk assessment indicates this |is necessary to avoid exposure to liquid splashes, |mists, gases or dusts. If contact is possible, the |following protection should be worn, unless the |assessment indicates a higher degree of protection: |safety glasses with side-shields. Skin and Body Protection |Personal protective equipment for the body should be |selected based on the task being performed and the |risks involved and should be approved by a |specialist before handling this product. |Other skin protection: Appropriate footwear and any |additional skin protection measures should be |selected based on the task being performed and the |risks involved and should be approved by a |specialist before handling this product. Respiratory Protection |Use a properly fitted, air-purifying or air-fed |respirator complying with an approved standard if a |risk assessment indicates this is necessary. |Respirator selection must be based on known or |anticipated exposure levels, the hazards of the |product and the safe working limits of the selected |respirator. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid. [Transparent / Oily liquid.] Appearance | Odor |Sweet. Odor Threshold |Not available pH |Not available Relative Evaporation Rate |Not available (butylacetate=1) | Melting Point |Pour point: -40 to -23Â°C (-40 to -9.4Â°F) Freezing Point | Boiling Point |>288Â°C (>550.4Â°F) Flash Point |Open cup: 154 to 199Â°C (309.2 to 390.2Â°F) |[Cleveland.] Auto-ignition Temperature |177Â°C (350.6Â°F) Decomposition Temperature |Not available Flammability (solid, gas) |Not applicable Vapor Pressure |<0.67 kPa (<5 mm Hg) [room temperature] Relative Vapor Density at 20 Â°C |<5 [Air = 1] Relative Density |0.93 [Water = 1] Specific Gravity | Solubility |Insoluble in the following materials: cold |water and hot water. Partition coefficient: |Not available. n-octanol/water | Viscosity |Kinematic (40Â°C (104Â°F)): 0.32 to 1.35 cm2/s |(32 to 135 cSt) Lower Flammable Limit |Lower: 0.9% Upper Flammable Limit |Upper: 7% 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No specific test data related to reactivity available for this product or its ingredients. 10.2 Chemical Stability The product is stable. 10.3 Possibility of Hazardous Reactions Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous polymerization will not occur 10.4 Conditions to Avoid Keep away from heat, sparks and flame. Keep away from all sources of ignition. 10.5 Incompatible Materials Reactive or incompatible with the following materials: oxidizing materials. Chlorine 10.6 Hazardous Decomposition Products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Product/ingredient name Result Species Dose Exposure Distillates (petroleum), LD50 Oral Rat >5000 mg/kg - hydrotreated heavy naphthenic Distillates (petroleum), LD50 Oral Rat >5000 mg/kg - hydrotreated light naphthenic 2-butoxyethanol LC50 Inhalation Vapor Rat 450 ppm 4 Hours LD50 Oral Rat 917 mg/kg Skin Corrosion/Irritation: Species Exposure Distillates (petroleum), Skin - Severe irritant Rabbit 500 milligrams hydrotreated heavy Skin - Mild irritant naphthenic 2-butoxyethanol Serious Eye Damage/Irritation: Species Exposure Distillates (petroleum), Eyes - Moderate irritant Rabbit 24 hours 100 miligrams hydrotreated heavy Eyes - Severe irritant 100 milligrams naphthenic 2-butoxyethanol Respiratory or Skin Sensitization: Not available. Germ Cell Mutagenicity: Carcinogenicity: Not available. Reproductive Toxicity: Not available. Specific Target Organ Toxicity (Single Exposure): 2-butoxyethanol Category 3 Route of exposure--Not applicable. Target organs: Respiratory tract irritation Specific Target Organ Toxicity (Repeated Exposure): Not available. Aspiration Hazard: Name Result Distillates (petroleum), hydrotreated heavy naphthenic ASPIRATION HAZARD - Category 1 Residual oils (petroleum), solvent-dewaxed ASPIRATION HAZARD - Category 1 Distillates (petroleum), hydrotreated light naphthenic ASPIRATION HAZARD - Category 1 Symptoms/Injuries After Inhalation: No known significant effects or critical hazards. Symptoms/Injuries After Skin Contact: Defatting to the skin. May cause skin dryness and irritation. Adverse symptoms may include the following: irritation dryness cracking Symptoms/Injuries After Eye Contact: No known significant effects or critical hazards. Symptoms/Injuries After Ingestion: No known significant effects or critical hazards. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 2-butoxyethanol Result Species Exposure Acute EC50 >1000 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 800000 ?g/l Marine water Crustaceans - Crangon crangon 48 hours Acute LC50 1250000 ?g/l Marine water Fish - Menidia beryllina 96 hours 12.2. Persistence and Degradability Test Result Dose Inoculum Residual oils (petroleum), OECD 301B 6% - 28 Days solvent-dewaxed Ready Biodegradability - CO Evolution Test 2-butoxyethanol 301E Ready 95%-28 Days Biodegradability - Modified OECD Screening Test 12.3. Bioaccumulative Potential 2-butoxyethanol LogPow: 0.81 BCF: <100, Potential: Low 12.4. Mobility in Soil Soil/water partition coefficient (KOC): Not available. 12.5. Other Adverse Effects No known significant effects or critical hazards. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not regulated. Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not regulated. Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not regulated. Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations Form R - Reporting Requirements, Supplier notification Product name cas No % 2-Butoxyethanol 111-76-2 3-7% SARA Section 311/312 Hazard Classes |Immediate (acute) health hazard Toxic Substances Control Act (TSCA) |All components are listed or exempted. 15.2 US State Regulations Massachusetts: The following components are listed: MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED LIGHT NAPHTHENIC; 2-BUTOXYETHANOL New York: None of the components are listed. New Jersey: The following components are listed: MINERAL OIL; 2-BUTOXY ETHANOL; BUTYL CELLOSOLVE Pennsylvania: The following components are listed: ETHANOL, 2-BUTOXY- California Prop. 65: None of the components are listed. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |03/16/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer. To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.