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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 3-IN-ONE� Professional Garage Door Lube CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Aerosol Lubricant 1.3. Name, Address, and Telephone of the Responsible Party Company WD-40 Company 1061 Cudahy Place (92110) P.O. Box 80607 San Diego, California, USA Phone: 92138-0607 1.4. Emergency Telephone Number Emergency | 1-888-324-7596 (PROSAR) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 1 Aerosol | Gas Under |Compressed Gas Pressure: | Aspiration |Category 1 Toxicity | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Gas Cylinder |Health Hazard | Signal Word (GHS-US) |DANGER! Hazard Statements (GHS-US) |Extremely Flammable Aerosol. |Contains gas under pressure; may explode if heated. |May be fatal if swallowed and enters airways. Precautionary Statements |Prevention (GHS-US) |Keep away from heat, sparks, open flames, hot |surfaces - No smoking. |Do not spray on an open flame or other ignition |source. |Pressurized container: Do not pierce or burn, even |after use. |Response |IF SWALLOWED: Immediately call a POISON CENTER or |physician. Do NOT induce vomiting. |Storage |Store locked up. |Protect from sunlight. Do not expose to temperatures |exceeding 50�C/122�F. Store in a well-ventilated |place. |Disposal |Dispose of contents and container in accordance with |local and national regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Aliphatic Petroleum Distillates |64742-47-8 |50-60 |Aspiration | | |Toxicity Category | | |1 Polydimethylsiloxane |63148-62-9 |2-4 |Not Hazardous White Mineral Oil |8042-47-5 |2-4 |Aspiration | | |Toxicity Category | | |1 Liquefied Petroleum Gas |68476-86-8 |35-45 |Flammable Gas (propane, n-butane) | | |Category 1 | | |Gas Under | | |Pressure, | | |Compressed Gas Note: The exact percentages are | | | a trade secret. | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms develop and persist. First-aid Measures After Skin Contact: Wash with soap and water. If irritation develops and persists, get medical attention. First-aid Measures After Eye Contact: Flush thoroughly with water for 15 minutes. Remove contact lenses if present after the first 5 minutes and continue flushing. Get medical attention if irritation persists. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or Poison Control Center immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Immediate medical attention is needed for ingestion. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire. Unsuitable Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Contents under pressure. Keep away from ignition sources and open flames. Exposure of containers to extreme heat and flames can cause them to rupture often with violent force. Combustible liquid and vapor. This material can release flammable vapors when heated above ambient temperatures. Vapors can cause a flash fire. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. A vapor and air mixture can create an explosion hazard in confined spaces. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Firefighters should always wear positive pressure self-contained breathing apparatus and full protective clothing in areas where chemicals are used and stored. Cool fire-exposed containers with water. Use shielding to protect against bursting containers. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and ventilate area. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Leaking cans should be placed in a plastic bag or open pail until the pressure has dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report spills to authorities as required. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes. Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use only with adequate ventilation. Keep away from heat, sparks, pilot lights, hot surfaces and open flames. Unplug electrical tools, motors and appliances before spraying or bringing the can near any source of electricity. Electricity can burn a hole in the can and cause contents to burst into flames. To avoid serious burn injury, do not let the can touch battery terminals, electrical connections on motors or appliances or any other source of electricity. Wash thoroughly with soap and water after handling. Keep containers closed when not in use. Keep out of the reach of children. Do not puncture, crush or incinerate containers, even when empty. Intentional misuse by deliberately concentrating vapors and inhaling can be harmful or fatal. Hygiene Measures: Wash with soap and water after handling. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Do not store above 120�F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol. Do not place can in hot water or near radiators, stoves or other sources of heat. Protect from physical damage. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Chemical Occupational Exposure Limits Aliphatic Hydrocarbon 1200 mg/m3 TWA (manufacturer recommended) Polydimethylsiloxane None Established White mineral oil 5 mg/m3 (inhalable) TWA ACGIH TLV 5 mg/m3 TWA OSHA PELquefied Petroleum Gas Liquefied Petroleum Gas 1000 ppm STEL ACGIH TLV (as butane) 1000 ppm TWA OSHA PEL (as propane) 8.2. Exposure Controls Appropriate Engineering |Use in a well-ventilated area. Controls: | Personal Protective Equipment| Material for Protective | Equipment | Hand Protection | Eye Protection |The Following Controls are Recommended for Normal |Consumer Use of this Product: Avoid eye contact. |Always spray away from your face. |For Bulk Processing or Workplace Use the Following |Controls are Recommended: Safety goggles recommended |where eye contact is possible. Skin and Body Protection |The Following Controls are Recommended for Normal |Consumer Use of this Product: Avoid prolonged skin |contact. Chemical resistant gloves recommended for |operations where skin contact is likely. |For Bulk Processing or Workplace Use the Following |Controls are Recommended: Wear chemical resistant |gloves. Respiratory Protection |The Following Controls are Recommended for Normal |Consumer Use of this Product: None needed for normal |use with adequate ventilation. |For Bulk Processing or Workplace Use the Following |Controls are Recommended: None required if |ventilation is adequate. If the occupational |exposure limits are exceeded, wear a NIOSH approved |respirator. Respirator selection and use should be |based on contaminant type, form and concentration. |Follow OSHA 1910.134, ANSI Z88.2 and good Industrial |Hygiene practice. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Clear, aerosol spray Odor |Petroleum odor Odor Threshold |Not established pH |Not Applicable Relative Evaporation Rate |Not established (butylacetate=1) | Melting Point |Not established Freezing Point |Not established Boiling Point |161-257�C (322-495�F) (Petroleum Solvent) Flash Point |-29.2�F (closed cup) liquid Auto-ignition Temperature |Not established Decomposition Temperature |Not established Flammability (solid, gas) |Flammable Aerosol Vapor Pressure |40-60 psig @ 70�F Relative Vapor Density at 20 �C |Greater than 1 (air=1) Relative Density |0.81 Specific Gravity | Solubility |Insoluble in water Partition coefficient: |Not established n-octanol/water | Viscosity |Not established Lower Flammable Limit |0.6% Upper Flammable Limit |9.5% 9.2. Other Information VOC: 49% SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Not reactive under normal conditions. 10.2 Chemical Stability Stable. 10.3 Possibility of Hazardous Reactions May react with strong oxidizers generating heat. 10.4 Conditions to Avoid Avoid heat, sparks, flames and other sources of ignition. Do not puncture or incinerate containers. 10.5 Incompatible Materials Strong oxidizing agents. 10.6 Hazardous Decomposition Products Carbon monoxide, carbon dioxide, silicon oxides, formaldehyde, smoke, fumes and unburned hydrocarbons. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an assessment of the ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard. Skin Corrosion/Irritation: Irritating to skin. Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Germ Cell Mutagenicity: Carcinogenicity: None of the components are listed as a carcinogen or suspect carcinogen by IARC, NTP, ACGIH or OSHA. Reproductive Toxicity: None of the components is considered a reproductive hazard. Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: High concentrations may cause nasal and respiratory irritation and central nervous system effects such as headache, dizziness and nausea. Intentional abuse may be harmful or fatal. Symptoms/Injuries After Skin Contact: May cause skin irritation with short-term exposure with redness, itching and burning of the skin. Prolonged and/or repeated contact may produce defatting and possible dermatitis. Repeated contact may cause an allergic skin reaction and/or a photosensitization (sensitivity to sunlight). Symptoms/Injuries After Eye Contact: Contact may be irritating to eyes. May cause redness, stinging, swelling and tearing. Symptoms/Injuries After Ingestion: This product has low oral toxicity. If swallowed, this material may cause irritation of the mouth, throat and esophagus. Swallowing may cause gastrointestinal irritation, nausea, vomiting, diarrhea, dizziness drowsiness, loss of consciousness, delirium and other central nervous system effects. This product is an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis, severe lung damage and death. Chronic Symptoms: None expected. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity No specific aquatic toxicity data is currently available, however components of this product are not expected to be harmful to aquatic organisms. 12.2. Persistence and Degradability The majority of component are readily biodegradable. 12.3. Bioaccumulative Potential Bioaccumulation is not expected based on an assessment of the ingredients. 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects None known. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: If this product becomes a waste, it would be expected to meet the criteria of a RCRA ignitable hazardous waste (D001). However, it is the responsibility of the generator to determine at the time of disposal the proper classification and method of disposal. Do not puncture or incinerate containers, even empty. Dispose in accordance with federal, state, and local regulations. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Aerosols Hazard Class |2.1 |<PICTOGRAM PHRASE> Identification Number|UN1950 | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Aerosols Hazard Class |2.1 Identification Number|UN1950 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills are reportable to the National Response Center under the Clean Water Act and many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: None. Section 302 Extremely Hazardous Substances (TPQ): None. SARA Section 311/312 Hazard Classes |Acute Health, Fire Hazard, Sudden Release of |Pressure Toxic Substances Control Act (TSCA) |All of the components of this product are |listed on the TSCA inventory. 15.2 US State Regulations <COMPONENT> California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product does not contain chemicals regulated under California Proposition 65. VOC Regulations: This product complies with the consumer product VOC limits of CARB, the US EPA and states adopting the OTC VOC rules. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |July 31, 2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.