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SDS Sheet 0046010

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: 4601-0 GALLON 4-WAY LUBE                                          
 
CAS No:                                                                         
 
Synonyms: None                                                                  
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Penetrating lubricant.                            
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Imperial Supplies LLC                                                           
 
789 Armed Forces Drive                                                          
 
P.O. Box 11008                                                                  
 
Green Bay, WI 53407-1038                                                        
 
Phone                                                                           
 


1.4.  Emergency Telephone Number
Emergency     | Chemtrec 1-800-262-8200 ID 1195                                 
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Skin          |Category 2    
corrosion/irri|              
tation        |              
Serious eye   |Category 2B   
damage/eye    |              
irritation    |              
Specific      |Category 3    
target organ  |              
toxicity      |              
(single       |              
exposure)     |              
Aspiration    |Category 1    
toxicity      |              
Flammable     |Category 3    
Liquids       |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamation Mark |Health Hazard |Flame
        
Signal Word (GHS-US)         |DANGER                                            
 
Hazard Statements (GHS-US)   |Causes skin irritation                            
 
                             |Causes eye irritation                             
 
                             |May cause respiratory irritation. May cause       
 
                             |drowsiness or dizziness                           
 
                             |May be fatal if swallowed and enters airways      
 
                             |Flammable liquid and vapor                        
 
Precautionary Statements     |Prevention                                        
 
(GHS-US)                     |Wash face, hands and any exposed skin thoroughly  
 
                             |after handling                                    
 
                             |Wear protective gloves/protective clothing/eye    
 
                             |protection/face protection                        
 
                             |Avoid breathing dust/fume/gas/mist/vapors/spray   
 
                             |Use only outdoors or in a well-ventilated area    
 
                             |Keep away from heat/sparks/open flames/hot
surfaces.
                             |- No smoking                                      
 
                             |Keep container tightly closed                     
 
                             |Ground/Bond container and receiving equipment     
 
                             |Use explosion-proof electrial/ventilating/lighting
 
                             |/equipment.                                       
 
                             |Use only non-sparking tools                       
 
                             |Take precautionary measures against static
discharge
                             |                                                  
 
                             |Response                                          
 
                             |Specific treatment (see first aid on this label)  
 
                             |IF IN EYES: Rinse cautiously with water for
several 
                             |minutes. Remove contact lenses, if present and
easy 
                             |to do. Continue rinsing.                          
 
                             |If eye irritation persists: Get medical           
 
                             |advice/attention                                  
 
                             |IF ON SKIN (or hair): Remove/Take off immediately 
 
                             |all contaminated clothing. Rinse skin with        
 
                             |water/shower                                      
 
                             |Wash contaminated clothing before reuse           
 
                             |If skin irritation occurs: Get medical            
 
                             |advice/attention                                  
 
                             |IF INHALED: Remove person to fresh air and keep   
 
                             |comfortable for breathing.                        
 
                             |Call a POISON CENTER or doctor/physician if you
feel
                             |unwell                                            
 
                             |IF SWALLOWED: Immediately call a POISON CENTER or 
 
                             |doctor/physician                                  
 
                             |Do NOT induce vomiting                            
 
                             |In case of fire: Use CO2, dry chemical, or foam
for 
                             |extinction                                        
 
                             |Storage                                           
 
                             |Store locked up                                   
 
                             |Store in a well-ventilated place. Keep container  
 
                             |tightly closed                                    
 
                             |Keep cool.                                        
 
                             |Disposal                                          
 
                             |Dispose of contents/container to an approved waste
 
                             |disposal plant                                    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: Toxic to aquatic life with
 
long lasting effects                                                            
 
0.001% of the mixture consists of ingredient(s) of unknown toxicity.            
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
HYDROTREATED LIGHT DISTALLATES  |64742-47-8           |30-40   |                
 
NAPHTHENIC OIL, SEVERLY HYDROT  |64742-52-5           |10-20   |                
 
KEROSENE                        |8008-20-6            |10-20   |                
 
PETROLEUM DISTILLATES           |64742-47-8           |10-20   |                
 
MINERAL OIL, DEWAXED            |64742-65-0           |1-10    |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General: If symptoms persist, call a physician.              
 
First-aid Measures After Inhalation: Immediate medical attention is not
required. 
If symptoms persist, call a physician. Move to fresh air in case of accidental  
 
inhalation of vapors or decomposition products.                                 
 
First-aid Measures After Skin Contact: Immediate medical attention is not       
 
required. Wash off immediately with soap and plenty of water while removing all 
 
contaminated clothes and shoes. If skin irritation persists, call a physician.  
 
First-aid Measures After Eye Contact: Immediately flush with plenty of water.   
 
After initial flushing, remove any contact lenses and continue flushing for at  
 
least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a 
 
physician.                                                                      
 
First-aid Measures After Ingestion: Clean mouth with water and drink afterwards 
 
plenty of water. Never give anything by mouth to an unconscious person. Consult
a 
physician. Do NOT induce vomiting.                                              
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation: Inhalation causing Central Nervous System   
 
effects.                                                                        
 
Symptoms/Injuries After Skin Contact: Causes skin irritation.                   
 
Symptoms/Injuries After Eye Contact: Causes eye irritation.                     
 
Symptoms/Injuries After Ingestion: Ingestion causing lung damage.               
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Protection of First-aiders: Absorb with sand ,clay, or other suitable material. 
 
Hard surfaces may be mopped with water.                                         
 
Notes to physician: Treat symptomatically.                                      
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use:. Dry chemical. Carbon dioxide (CO 2). Water  
 
spray. Alcohol-resistant foam.                                                  
 
Unsuitable Extinguishing Media: Decomposition by contact with water may generate
 
vapors which can be ignited by heat or open flame.                              
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Keep product and empty container away from heat and sources of     
 
ignition. Risk of ignition.                                                     
 
Explosion Hazard:                                                               
 
Sensitivity to Mechanical Impact: none.                                         
 
Sensitivity to Static Discharge: Yes.                                           
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: As in any fire, wear self-contained breathing   
 
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective
gear.                                                                           
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Evacuate personnel to safe areas. Keep people away from and   
 
upwind of spill/leak. Remove all sources of ignition. Pay attention to
flashback. 
Take precautionary measures against static discharges. Absorb with sand ,clay,
or 
other suitable material. Hard surfaces may be mopped with water.                
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Prevent further leakage or spillage if safe to do so. Prevent product from      
 
entering drains. Beware of vapors accumulating to form explosive concentrations.
 
Vapors can accumulate in low areas.                                             
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Prevent further leakage or spillage if safe to do so.          
 
Methods for Cleaning Up: Dam up. Soak up with inert absorbent material. Pick up 
 
and transfer to properly labeled containers. Take precautionary measures against
 
static discharges.                                                              
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Use only in area provided with appropriate   
 
exhaust ventilation. To avoid ignition of vapors by static electricity
discharge, 
all metal parts of the equipment must be grounded. Keep away from heat, sparks
and
open flame. No smoking. Wear personal protective equipment. Do not breathe
vapors 
or spray mist. Take necessary action to avoid static electricity discharge
(which 
might cause ignition of organic vapors).                                        
 
Hygiene Measures: When using, do not eat, drink or smoke. Provide regular
cleaning
of equipment, work area and clothing.                                           
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Keep containers tightly closed in a cool, well-ventilated   
 
place. Keep away from heat. Keep in properly labeled containers.                
 
Incompatible products: None known based on information supplied.                
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Exposure Guidelines                                                             
 
Chemical Name                                                                   
 
ACGIH TLV                                                                       
 
OSHA PEL                                                                        
 
NIOSH IDLH                                                                      
 
                                                                                
 
HYDROTREATED LIGHT DISTALLATES 64742-47-8                                       
 
TWA: 200 PPM 8 hours                                                            
 
-                                                                               
 
-                                                                               
 
                                                                                
 
KEROSENE                                                                        
 
8008-20-6                                                                       
 
TWA: 200 mg/m3 total hydrocarbon vapor application restricted to conditions in  
 
which there are negligible aerosol Exposures Skin - potential significant       
 
contribution to overall exposure by the cutaneous route                         
 
-                                                                               
 
TWA: 100 mg/m3                                                                  
 
                                                                                
 
MINERAL OIL, DEWAXED                                                            
 
64742-65-0                                                                      
 
ACGIH TLV: 5 mg/m3 (oil mist)                                                   
 
OSHA PEL: 5 mg/m3 (oil mist)                                                    
 
-                                                                               
 
                                                                                
 
Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals
decision
in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).                             
 


8.2.  Exposure Controls
Appropriate Engineering      |Showers, Eyewash stations, Ventilation systems.   
 
Controls                     |                                                  
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Tightly fitting safety goggles.                   
 
Skin and Body Protection     |Chemical resistant apron. Protective gloves.      
 
Respiratory Protection       |If exposure limits are exceeded or irritation is  
 
                             |experienced, NIOSH/MSHA approved respiratory      
 
                             |protection should be worn. Positive-pressure      
 
                             |supplied air respirators may be required for high 
 
                             |airborne contaminant concentrations. Respiratory  
 
                             |protection must be provided in accordance with    
 
                             |current local regulations.                        
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                     
 
Appearance                          |Opaque                                     
 
Odor                                |Solvent                                    
 
Odor Threshold                      |No information available                   
 
pH                                  |No information available                   
 
Relative Evaporation Rate           |No information available                   
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No information available                   
 
Freezing Point                      |No information available                   
 
Boiling Point                       |No information available                   
 
Flash Point                         |41 °C / 106 °F (based on components)       
 
Auto-ignition Temperature           |No information available                   
 
Decomposition Temperature           |No information available                   
 
Flammability (solid, gas)           |No information available                   
 
Vapor Pressure                      |No information available                   
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |                                           
 
Specific Gravity                    |0.84                                       
 
Solubility                          |Practically insoluble                      
 
Partition coefficient:              |No information available                   
 
n-octanol/water                     |                                           
 
Viscosity                           |No information available                   
 
Lower Flammable Limit               |No information available                   
 
Upper Flammable Limit               |No information available                   
 


9.2.  Other Information
VOC Content(%): 35.45                                                           
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No data available.                                                              
 


10.2      Chemical Stability
Stable under recommended storage conditions.                                    
 


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                   
 


10.4      Conditions to Avoid
Heat, flames and sparks.                                                        
 


10.5      Incompatible Materials
None known based on information supplied.                                       
 


10.6      Hazardous Decomposition Products
None known based on information supplied.                                       
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation: Irritating to skin. Repeated exposure may cause skin 
 
dryness or cracking. Prolonged skin contact may defat the skin and produce      
 
dermatitis. Avoid contact with skin.                                            
 
Serious Eye Damage/Irritation: Irritating to eyes. Avoid contact with eyes.     
 
Respiratory or Skin Sensitization: None known. Irritating to respiratory system.
 
Germ Cell Mutagenicity: None known.                                             
 
Carcinogenicity: There are no known carcinogenic chemicals in this product.     
 
Reproductive Toxicity: Product is or contains a chemical which is a known or    
 
suspected reproductive hazard.                                                  
 
Specific Target Organ Toxicity (Single Exposure): May cause respiratory         
 
irritation. May cause drowsiness and dizziness.                                 
 
Specific Target Organ Toxicity (Repeated Exposure): None under normal use       
 
conditions.                                                                     
 
Aspiration Hazard: May be fatal if swallowed and enters airways.                
 
Symptoms/Injuries After Inhalation: Vapors may irritate throat and respiratory  
 
system. May cause drownsiness and dizziness based on components. May cause      
 
irritation of respiratory tract. Avoid breathing vapors or mists.               
 
May be fatal if swallowed and enters airways.                                   
 
Symptoms/Injuries After Skin Contact: Skin corrosion/irritation: Irritating to  
 
skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
 
vomiting. Irritating to skin.                                                   
 
Symptoms/Injuries After Eye Contact: Eye damage/irritation: Irritating to eyes. 
 
Symptoms/Injuries After Ingestion: Aspiration into the lungs during swallowing
may
cause serious lung damage which may be fatal.                                   
 
Causes respiratory system irritation.                                           
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Chemical Name                                                                   
 
Toxicity to algae                                                               
 
Toxicity to fish                                                                
 
Toxicity to microorganisms                                                      
 
Toxicity to daphnia and other aquatic invertebrates                             
 
                                                                                
 
HYDROTREATED LIGHT                                                              
 
DISTALLATES                                                                     
 
64742-47-8                                                                      
 
-                                                                               
 
2.2 mg/L LC50 Lepomis macrochirus 96h static 2.4 mg/L LC50 Oncorhynchus mykiss
96h
static 45 mg/L LC50 Pimephales promelas 96h flow-through                        
 
-                                                                               
 
-                                                                               
 
                                                                                
 
NAPHTHENIC OIL,                                                                 
 
SEVERLY HYDROT                                                                  
 
64742-52-5                                                                      
 
-                                                                               
 
5000 mg/L LC50 Oncorhynchus mykiss 96h                                          
 
-                                                                               
 
1000 mg/L EC50 Daphnia magna 48h                                                
 
                                                                                
 
PETROLEUM DISTILLATES                                                           
 
64742-47-8                                                                      
 
-                                                                               
 
2.2 mg/L LC50 Lepomis macrochirus 96h static 2.4 mg/L LC50 Oncorhynchus mykiss
96h
static 45 mg/L LC50 Pimephales promelas 96h flow-through                        
 
-                                                                               
 
-                                                                               
 
                                                                                
 
MINERAL OIL, DEWAXED                                                            
 
64742-65-0                                                                      
 
-                                                                               
 
5000 mg/L LC50 Oncorhynchus mykiss 96h                                          
 
-                                                                               
 
1000 mg/L EC50 Daphnia magna 48h                                                
 
                                                                                
 


12.2. Persistence and Degradability
No information available.                                                       
 


12.3. Bioaccumulative Potential
No information available.                                                       
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
No information available.                                                       
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: This material, as supplied, is a hazardous waste
 
according to federal regulations (40 CFR 261).                                  
 
Additional Information: Contaminated packaging: Do not re-use empty containers. 
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |CONSUMER COMMODITY ORM-D                                  
 
                     |or LIMITED QUANTITY                                       
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |KEROSENE SOLUTION                                         
 
Hazard Class         |3                                                         
 
Identification Number|UN1223                                                    
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |KEROSENE SOLUTION                                         
 
Identification Number|UN1223                 |<PICTOGRAM PHRASE>                
  
Hazard Class         |3                      |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA 313: Section 313 of Title III of the Superfund Amendments and              
 
Re-authorization Act of 1986 (SARA). This product does not contain any chemicals
 
which are subject to the reporting requirements of the Act and Title 40 of the  
 
Code of Federal Regulations, Part 372.                                          
 
Clean Water Act: This product contains the following substances which are       
 
regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR  
 
122.42):                                                                        
 
CERCLA:  This material, as supplied, contains one or more substances regulated
as 
a hazardous substance under the Comprehensive Environmental Response
Compensation 
and Liability Act (CERCLA) (40 CFR 302)                                         
 
SARA Section 311/312 Hazard Classes |Acute Health Hazard                        
 
                                    |Yes                                        
 
                                    |Chronic Health Hazard                      
 
                                    |Yes                                        
 
                                    |Fire Hazard                                
 
                                    |Yes                                        
 
                                    |Sudden Release of Pressure Hazard        no
 
                                    |Reactive Hazard                            
 
                                    |no                                         
 
Toxic Substances Control Act (TSCA) |Chemical Name         TSCA                 
 
                                    |HYDROTREATED            X                  
 
                                    |LIGHT DISTALLATES                          
 
                                    |                                           
 
                                    |NAPHTHENIC OIL,          X                 
 
                                    |SEVERLY HYDROT                             
 
                                    |                                           
 
                                    |KEROSENE X                                 
 
                                    |                                           
 
                                    |PETROLEUM                    X             
 
                                    |DISTILLATES                                
 
                                    |                                           
 
                                    |MINERAL OIL,                  X            
 
                                    |DEWAXED                                    
 

15.2      US State Regulations
California Proposition 65: This product contains the following Proposition 65   
 
chemicals:                                                                      
 
Chemical Name                                                                   
 
California Prop. 65                                                             
 
                                                                                
 
NAPHTHALENE - 91-20-3                                                           
 
X                                                                               
 
                                                                                
 
U.S. State Right-to-Know Regulations                                            
 
Chemical Name                                                                   
 
New Jersey                                                                      
 
Massachusetts                                                                   
 
Pennsylvania                                                                    
 
                                                                                
 
KEROSENE                                                                        
 
8008-20-6                                                                       
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
EPA Pesticide Registration Number: Not applicable.                              
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |21-May-2015                                                    
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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