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SDS Sheet 0046000

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: 4600-0 GALLON PENETRATING OIL                                     
 
CAS No:                                                                         
 
Synonyms: None                                                                  
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Penetrating Oil.                                  
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Imperial Supplies LLC                                                           
 
789 Armed Forces Drive                                                          
 
P.O. Box 11008                                                                  
 
Green Bay, WI 53407-1008                                                        
 
Phone                                                                           
 


1.4.  Emergency Telephone Number
Emergency     | Chemtrec 1-800-424-9300                                         
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Aspiration    |Category 1    
toxicity      |              
Flammable     |Category 4    
Liquids       |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Health Hazard
       
Signal Word (GHS-US)         |DANGER                                            
 
Hazard Statements (GHS-US)   |May be fatal if swallowed and enters airways      
 
                             |Combustible liquid                                
 
Precautionary Statements     |Prevention                                        
 
(GHS-US)                     |Keep away from heat/sparks/open flames/hot
surfaces.
                             |- No smoking                                      
 
                             |Wear protective gloves/eye protection/face        
 
                             |protection.                                       
 
                             |Response                                          
 
                             |IF SWALLOWED: Immediately call a POISON CENTER or 
 
                             |doctor/physician                                  
 
                             |Do NOT induce vomiting                            
 
                             |In case of fire: Use CO2, dry chemical, or foam
for 
                             |extinction                                        
 
                             |Storage                                           
 
                             |Store locked up                                   
 
                             |Store in a well-ventilated place. Keep cool       
 
                             |Disposal                                          
 
                             |Dispose of contents/container to an approved waste
 
                             |disposal plant                                    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification: 0% of the mixture consists
 
of ingredient(s) of unknown toxicity.                                           
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%*      |Classification  
 
                                |                     |        |(GHS-US)        
 
NAPHTHENIC OIL, SEVERELY        |64742-52-5           |70-80   |                
 
HYDROTREATED                    |                     |        |                
 
HYDROTREATED MIDDLE DISTILLATE  |64742-46-7           |20-30   |                
 
                                |                     |        |                
 
                                |                     |        |                
 
*The exact percentage           |                     |        |                
 
(concentration) of composition  |                     |        |                
 
has been withheld as a trade    |                     |        |                
 
secret.                         |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Move to fresh air. If breathing is
difficult,
give oxygen. Artificial respiration and/or oxygen may be necessary. If breathing
 
has stopped, contact emergency medical services immediately.                    
 
First-aid Measures After Skin Contact: Wash off immediately with soap and plenty
 
of water while removing all contaminated clothes and shoes. If symptoms persist,
 
call a physician.                                                               
 
First-aid Measures After Eye Contact: Rinse immediately with plenty of water,
also
under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If
 
symptoms persist, call a physician.                                             
 
First-aid Measures After Ingestion: Rinse mouth. Never give anything by mouth to
 
an unconscious person. Drink plenty of water. Call a physician or Poison Control
 
Center immediately.                                                             
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion: Ingestion causing lung damage.               
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Notes to physician: Treat symptomatically.                                      
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Water fog.Dry chemical. Carbon dioxide (CO2). Cool
 
containers/tanks with water spray.                                              
 
Unsuitable Extinguishing Media: Keep away from heat and sources of ignition. Do 
 
not smoke. Cool containers / tanks with water spray.                            
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Extremely flammable. Keep product and empty container away from
heat 
and sources of ignition. Risk of ignition. In the event of fire and/or explosion
 
do not breathe fumes. In the event of fire, cool tanks with water spray.        
 
Explosion Hazard:                                                               
 
Sensitivity to Mechanical Impact: none.                                         
 
Sensitivity to Static Discharge: none.                                          
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: As in any fire, wear self-contained breathing   
 
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective
gear.                                                                           
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Absorb with sand, clay, or other suitable material. Hard      
 
surfaces may be mopped with water. Remove all sources of ignition. Avoid contact
 
with the skin and the eyes. Evacuate personnel to be safe areas.Keep people away
 
from and upwind of spill/leak. Contents under pressure. Do not puncture or      
 
incinerate cands. Wear protective gloves/clothing and eye/face protection.      
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Prevent further leakage or spillage if safe to do so. Do not allow material to  
 
contaminate ground water system. Prevent product from entering drains. Local    
 
authorities should be advised if significant spillages cannot be contained.
Beware
of vapors accumulating to form explosive concentrations. Vapors can accumulate
in 
low areas.                                                                      
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Prevent further leakage or spillage if safe to do so. Soak up  
 
condensate with inert absorbent material and collect in ventilated waste
container
for disposal.                                                                   
 
Methods for Cleaning Up: Pick up and transfer to properly labeled containers.
Soak
up with inert absorbent material. Clean contaminated surface thoroughly. After  
 
cleaning, flush away traces with water.                                         
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid contact with skin, eyes and clothing.  
 
Handle in accordance with good industrial hygiene and safety practice. Remove
and 
wash contaminated clothing before re-use. Keep away from open flames, hot
surfaces
and sources of ignition. Take precautionary measures against static discharges. 
 
Hygiene Measures:  Handle in accordance with good industrial hygiene and safety 
 
practice.                                                                       
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Keep container tightly closed in a dry and well-ventilated  
 
place. Keep away from open flames, hot surfaces and sources of ignition. Keep in
 
properly labeled containers. Keep out of the reach of children. Store locked up.
 
Incompatible Products: Strong acids, alkalis, or oxidizing agents.              
 
Aerosol Level:  3                                                               
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Exposure Guidelines: This product does not contain any hazardous materials with 
 
occupational exposure limits established by the region specific regulatory
bodies.


8.2.  Exposure Controls
Appropriate Engineering      |Showers, Eyewash stations, Ventilation systems.   
 
Controls                     |                                                  
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Safety glasses with side-shields.                 
 
Skin and Body Protection     |Chemical resistant apron. Protective gloves.      
 
Respiratory Protection       |If exposure limits are exceeded or irritation is  
 
                             |experienced, NIOSH/MSHA approved respiratory      
 
                             |protection should be worn. Positive-pressure      
 
                             |supplied air respirators may be required for high 
 
                             |airborne contaminant concentrations. Respiratory  
 
                             |protection must be provided in accordance with    
 
                             |current local regulations.                        
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                     
 
Appearance                          |Clear                                      
 
Odor                                |Solvent                                    
 
Odor Threshold                      |No information available                   
 
pH                                  |No information available                   
 
Relative Evaporation Rate           |No information available                   
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No information available                   
 
Freezing Point                      |No information available                   
 
Boiling Point                       |No information available                   
 
Flash Point                         |No information available                   
 
Auto-ignition Temperature           |No information available                   
 
Decomposition Temperature           |No information available                   
 
Flammability (solid, gas)           |No information available                   
 
Vapor Pressure                      |No information available                   
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |                                           
 
Specific Gravity                    |.892                                       
 
Solubility                          |Practically insoluble                      
 
Partition coefficient:              |No information available                   
 
n-octanol/water                     |                                           
 
Viscosity                           |No information available                   
 
Lower Flammable Limit               |No information available                   
 
Upper Flammable Limit               |No information available                   
 


9.2.  Other Information
VOC Content(%): 10.03                                                           
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No data available.                                                              
 


10.2      Chemical Stability
Stable under recommended storage conditions.                                    
 


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                   
 


10.4      Conditions to Avoid
Extremes of temperature and direct sunlight.                                    
 


10.5      Incompatible Materials
Strong acids, alkalis, or oxidizing agents.                                     
 


10.6      Hazardous Decomposition Products
None known based on information supplied.                                       
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity: 0% of the mixture consists of ingredient(s) of unknown toxicity.
 
Skin Corrosion/Irritation:                                                      
 
Serious Eye Damage/Irritation: Avoid contact with eyes.                         
 
Respiratory or Skin Sensitization: Sensitization: None known.                   
 
Germ Cell Mutagenicity: None known.                                             
 
Carcinogenicity: The table below indicates whether each agency has evaluated a  
 
listed ingredient as a carcinogen.                                              
 
Reproductive Toxicity: This product does not contain any known or suspected     
 
reproductive hazards.                                                           
 
Specific Target Organ Toxicity (Single Exposure): None under normal use         
 
conditions.                                                                     
 
Specific Target Organ Toxicity (Repeated Exposure): None under normal use       
 
conditions.                                                                     
 
Aspiration Hazard: May be fatal if swallowed and enters airways.                
 
Symptoms/Injuries After Inhalation: Avoid breathing vapors or mists.            
 
Symptoms/Injuries After Skin Contact:  Avoid contact with skin.                 
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion: May be harmful or fatal if swallowed.        
 
Aspiration into the lungs during swallowing may cause serious lung damage which 
 
may be fatal.                                                                   
 
Symptoms: Harmful if swallowed. May be fatal if swallowed and enters airways.   
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Chemical Name                                                                   
 
Toxicity to algae                                                               
 
Toxicity to fish                                                                
 
Toxicity to microorganisms                                                      
 
Toxicity to daphnia and other aquatic invertebrates                             
 
                                                                                
 
NAPHTHENIC OIL,                                                                 
 
SEVERELY                                                                        
 
HYDROTREATED                                                                    
 
64742-52-5                                                                      
 
-                                                                               
 
5000 mg/L LC50 Oncorhynchus mykiss 96h                                          
 
-                                                                               
 
1000 mg/L EC50 Daphnia magna 48h                                                
 
                                                                                
 
HYDROTREATED MIDDLE                                                             
 
DISTILLATE                                                                      
 
64742-46-7                                                                      
 
-                                                                               
 
35 mg/L LC50 Pimephales promelas 96h flow through 10000 mg/L LC50 Pimephales    
 
promelas 96h static                                                             
 
-                                                                               
 
-                                                                               
 
                                                                                
 


12.2. Persistence and Degradability
No information available.                                                       
 


12.3. Bioaccumulative Potential
No information available.                                                       
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
No information available.                                                       
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: It must undergo special treatment, e.g. at      
 
suitable disposal site, to comply with local regulations.                       
 
Additional Information: Contaminated packaging: Do not re-use empty containers. 
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |CONSUMER COMMODITY ORM-D or LIMITED QUANTITY              
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |AEROSOLS, FLAMMABLE                                       
 
Hazard Class         |2.1                                                       
 
Identification Number|UN1950                                                    
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |AEROSOLS, FLAMMABLE                                       
 
Identification Number|UN1950                 |<PICTOGRAM PHRASE>                
  
Hazard Class         |2.1                    |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA 313                                                                        
 
Section 313 of Title III of the Superfund Amendments and Re-authorization Act of
 
1986 (SARA). This product does not contain any chemicals which are subject to
the 
reporting requirements of the Act and Title 40 of the Code of Federal
Regulations,
Part 372.                                                                       
 
Clean Water Act                                                                 
 
This product does not contain any substances regulated as pollutants pursuant to
 
the Clean Water Act (40 CFR 122.21 and 40                                       
 
CFR 122.42).                                                                    
 
CERCLA                                                                          
 
This material, as supplied, does not contain any substances regulated as
hazardous
substances under the Comprehensive                                              
 
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or
the
Superfund Amendments and                                                        
 
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting        
 
requirements at the local, regional, or state level                             
 
pertaining to releases of this material.                                        
 
SARA Section 311/312 Hazard Classes |Acute Health Hazard                        
 
                                    |Yes                                        
 
                                    |Chronic Health Hazard                      
 
                                    |Yes                                        
 
                                    |Fire Hazard                                
 
                                    |Yes                                        
 
                                    |Sudden Release of Pressure Hazard          
 
                                    |Yes                                        
 
                                    |Reactive Hazard                            
 
                                    |no                                         
 
Toxic Substances Control Act (TSCA) |                                           
 
                                    |TSCA                                       
 
                                    |NAPHTHENIC OIL,                            
 
                                    |SEVERELY                            X      
 
                                    |HYDROTREATED                               
 
                                    |                                           
 
                                    |HYDROTREATED                X              
 
                                    |MIDDLE DISTILLATE                          
 

15.2      US State Regulations
California Proposition 65: This product does not contain any known Proposition
65 
chemicals.                                                                      
 
U.S. State Right-to-Know Regulations                                            
 
EPA Pesticide Registration Number: Not applicable                               
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |06-Jun-2015                                                    
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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