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SDS Sheet 0043350

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: 4335 PINT DEGREASER                                               
 
CAS No:                                                                         
 
Synonyms:  None                                                                 
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Degreaser.                                        
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company:                                                                        
 
Imperial Supplies LLC                                                           
 
789 Armed Forces Drive                                                          
 
P.O. Box 11008                                                                  
 
Green Bay, WI 53407-1038                                                        
 


1.4.  Emergency Telephone Number
Emergency     | Chemtrec 1-800-424-9300                                         
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Skin          |Category 2    
corrosion/irri|              
tation        |              
Serious eye   |Category 2A   
damage/eye    |              
irritation    |              
Skin          |Category 1    
Sensitization |              
Flammable     |Category 4    
Liquids       |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamation Mark
        
Signal Word (GHS-US)         |Warning                                           
        
Hazard Statements (GHS-US)   |Causes skin irritation                            
 
                             |Causes serious eye irritation                     
 
                             |May cause an allergic skin reaction               
 
                             |Combustible liquid                                
 
Precautionary Statements     |Precautionary Statements - Prevention             
 
(GHS-US)                     |Wash face, hands and any exposed skin thoroughly  
 
                             |after handling                                    
 
                             |Wear protective gloves/protective clothing/eye    
 
                             |protection/face protection                        
 
                             |Avoid breathing dust/fume/gas/mist/vapors/spray   
 
                             |Contaminated work clothing should not be allowed
out
                             |of the workplace                                  
 
                             |Keep away from heat/sparks/open flames/hot
surfaces.
                             |- No smoking                                      
 
                             |Precautionary Statements - Response               
 
                             |Specific treatment (see first aid on this label)  
 
                             |IF IN EYES: Rinse cautiously with water for
several 
                             |minutes. Remove contact lenses, if present and
easy 
                             |to do. Continue rinsing.                          
 
                             |If eye irritation persists: Get medical           
 
                             |advice/attention                                  
 
                             |IF ON SKIN: Wash with plenty of soap and water.   
 
                             |Take off contaminated clothing and wash before
reuse
                             |                                                  
 
                             |If skin irritation or rash occurs: Get medical    
 
                             |advice/attention                                  
 
                             |In case of fire: Use CO2, dry chemical, or foam
for 
                             |extinction                                        
 
                             |Precautionary Statements - Storage                
 
                             |Store in a well-ventilated place. Keep cool       
 
                             |Precautionary Statements - Disposal               
 
                             |Dispose of contents/container to an approved waste
 
                             |disposal plant                                    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:  None                     
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%*      |Classification  
 
                                |                     |        |(GHS-US)        
 
ETHOXYLATED ALCOHOL             |68439-46-3           |1-10    |                
 
SODIUM METASILICATE PENTAHYDRATE|6834-92-0            |1-10    |                
 
D-LIMONENE                      |5989-27-5            |0.1-1   |                
 
                                |                     |        |                
 
*The exact percentage           |                     |        |                
 
(concentration) of composition  |                     |        |                
 
has been withheld as a trade    |                     |        |                
 
secret.                         |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: Move to fresh air. If breathing is
difficult,
give oxygen. Artificial respiration and/or oxygen may be necessary. If breathing
 
has stopped, contact emergency medical services immediately.                    
 
First-aid Measures After Skin Contact: Wash off immediately with soap and plenty
 
of water while removing all contaminated clothes and shoes. If symptoms persist,
 
call a physician.                                                               
 
First-aid Measures After Eye Contact: Rinse immediately with plenty of water,
also
under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If
 
symptoms persist, call a physician.                                             
 
First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Never  
 
give anything by mouth to an unconscious person. Drink plenty of water. Call a  
 
physician or Poison Control Center immediately.                                 
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact: Causes skin irritation.                   
 
Symptoms/Injuries After Eye Contact: Causes eye irritation.                     
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Notes to physician: Treat symptomatically.                                      
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use extinguishing measures that are appropriate to
 
local circumstances and the surrounding environment.                            
 
Unsuitable Extinguishing Media: Decomposition by contact with water may generate
 
vapors which can be ignited by heat or open flame.                              
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard:  No information available.                                         
 
Explosion Hazard:                                                               
 
Sensitivity to Mechanical Impact: none.                                         
 
Sensitivity to Static Discharge: none                                           
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: As in any fire, wear self-contained breathing   
 
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective
gear.                                                                           
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Evacuate personnel to safe areas. Absorb with sand ,clay, or  
 
other suitable material. Hard surfaces may be mopped with water. Avoid contact  
 
with skin, eyes and clothing. Ensure adequate ventilation. Avoid dust formation.
 
Keep people away from and upwind of spill/leak.                                 
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Prevent further leakage or spillage if safe to do so. Do not allow material to  
 
contaminate ground water system. Prevent product from entering drains.          
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Absorb with earth, sand or other non-combustible material and  
 
transfer to containers for later disposal. Prevent further leakage or spillage
if 
safe to do so.                                                                  
 
Methods for Cleaning Up: Pick up and transfer to properly labeled containers.
Soak
up with inert absorbent material. Clean contaminated surface thoroughly. After  
 
cleaning, flush away traces with water.                                         
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid contact with skin, eyes and clothing.  
 
Handle in accordance with good industrial                                       
 
hygiene and safety practice. Remove and wash contaminated clothing before
re-use. 
Hygiene Measures:  Handle in accordance with good industrial hygiene and safety 
 
practice.                                                                       
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Keep container tightly closed in a dry and well-ventilated  
 
place. Keep in properly labeled containers. Keep out of the reach of children.  
 
Store locked up.                                                                
 
Storage Conditions: Incompatible products Strong acids, alkalis, or oxidizing   
 
agents.                                                                         
 
Aerosol Level: 1                                                                
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Exposure Guidelines: This product does not contain any hazardous materials with 
 
occupational exposure limits established by the region specific regulatory
bodies.


8.2.  Exposure Controls
Appropriate Engineering      |Showers, Eyewash stations, Ventilation systems.   
 
Controls                     |                                                  
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Safety glasses with side-shields.                 
 
Skin and Body Protection     |Chemical resistant apron. Protective gloves.      
 
Respiratory Protection       |If exposure limits are exceeded or irritation is  
 
                             |experienced, NIOSH/MSHA approved respiratory      
 
                             |protection should be worn. Positive-pressure      
 
                             |supplied air respirators may be required for high 
 
                             |airborne contaminant concentrations. Respiratory  
 
                             |protection must be provided in accordance with    
 
                             |current local regulations.                        
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                     
 
Appearance                          |Slightly Hazy                              
 
Odor                                |Fragrance                                  
 
Odor Threshold                      |No information available                   
 
pH                                  |No information available                   
 
Relative Evaporation Rate           |No information available                   
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No information available                   
 
Freezing Point                      |No information available                   
 
Boiling Point                       |No information available                   
 
Flash Point                         |No information available                   
 
Auto-ignition Temperature           |No information available                   
 
Decomposition Temperature           |No information available                   
 
Flammability (solid, gas)           |No information available                   
 
Vapor Pressure                      |No information available                   
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |                                           
 
Specific Gravity                    |1.01                                       
 
Solubility                          |                                           
 
Partition coefficient:              |No information available                   
 
n-octanol/water                     |                                           
 
Viscosity                           |No information available                   
 
Lower Flammable Limit               |No information available                   
 
Upper Flammable Limit               |No information available                   
 


9.2.  Other Information
VOC Content(%)  0.49                                                            
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No data available                                                               
 


10.2      Chemical Stability
Stable under recommended storage conditions.                                    
 


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                   
 


10.4      Conditions to Avoid
Extremes of temperature and direct sunlight.                                    
 


10.5      Incompatible Materials
Strong acids, alkalis, or oxidizing agents.                                     
 


10.6      Hazardous Decomposition Products
None known based on information supplied.                                       
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation: Irritating to skin. May cause an allergic skin       
 
reaction.                                                                       
 
Serious Eye Damage/Irritation: Irritating to eyes. Irritating to eyes and skin. 
 
Respiratory or Skin Sensitization: May cause sensitization by skin contact.     
 
Germ Cell Mutagenicity: None known.                                             
 
Carcinogenicity: There are no known carcinogenic chemicals in this product.     
 
Reproductive Toxicity: This product does not contain any known or suspected     
 
reproductive hazards.                                                           
 
Specific Target Organ Toxicity (Single Exposure): None under normal use         
 
conditions.                                                                     
 
Specific Target Organ Toxicity (Repeated Exposure): None under normal use       
 
conditions.                                                                     
 
Aspiration Hazard: Not applicable.                                              
 
Symptoms/Injuries After Inhalation: Avoid breathing vapors or mists.            
 
Symptoms/Injuries After Skin Contact: Irritating to skin. Repeated exposure may 
 
cause skin dryness or cracking. Prolonged skin                                  
 
contact may defat the skin and produce dermatitis. May cause sensitization by
skin
contact.  Avoid contact with skin.                                              
 
Avoid contact with skin.                                                        
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion: May be harmful or fatal if swallowed         
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Chemical Name                                                                   
 
Toxicity to algae                                                               
 
Toxicity to fish                                                                
 
Toxicity to                                                                     
 
microorganisms                                                                  
 
Toxicity to daphnia and other aquatic invertebrates                             
 
                                                                                
 
SODIUM METASILICATE                                                             
 
PENTAHYDRATE                                                                    
 
6834-92-0                                                                       
 
-                                                                               
 
210 mg/L LC50 Brachydanio rerio 96h 210 mg/L LC50 Brachydanio rerio 96h         
 
semi-static                                                                     
 
-                                                                               
 
-                                                                               
 
                                                                                
 
D-LIMONENE                                                                      
 
5989-27-5                                                                       
 
-                                                                               
 
0.619 - 0.796 mg/L LC50 Pimephales promelas 96h flow-through 35 mg/L LC50       
 
Oncorhynchus mykiss 96h                                                         
 
-                                                                               
 
-                                                                               
 
                                                                                
 


12.2. Persistence and Degradability
No information available.                                                       
 


12.3. Bioaccumulative Potential
No information available.                                                       
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
                                                                                
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: This material, as supplied, is a hazardous waste
 
according to federal regulations (40 CFR261).                                   
 
Additional Information: Contaminated packaging: Do not re-use empty containers. 
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |CONSUMER COMMODITY ORM-D                                  
 
                     |or LIMITED QUANTITY                                       
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |CORROSIVE LIQUID, N.O.S.(SODIUM METASILICATE)             
 
Hazard Class         |UN1760                                                    
 
Identification Number|8                                                         
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |CORROSIVE LIQUID, N.O.S.(SODIUM METASILICATE)             
 
Identification Number|UN1760                 |<PICTOGRAM PHRASE>                
  
Hazard Class         |8                      |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA 313: Section 313 of Title III of the Superfund Amendments and              
 
Re-authorization Act of 1986 (SARA). This product does not contain any chemicals
 
which are subject to the reporting requirements of the Act and Title 40 of the  
 
Code of Federal Regulations, Part 372.                                          
 
                                                                                
 
Clean Water Act: This product does not contain any substances regulated as      
 
pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).   
 
                                                                                
 
CERCLA: This material, as supplied, does not contain any substances regulated as
 
hazardous substances under the Comprehensive Environmental Response Compensation
 
and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and         
 
Re-authorization Act (SARA) (40 CFR 355). There may be specific reporting       
 
requirements at the local, regional, or state level pertaining to releases of
this
material.                                                                       
 
SARA Section 311/312 Hazard Classes |Acute Health Hazard                        
 
                                    |Yes                                        
 
                                    |Chronic Health Hazard                      
 
                                    |Yes                                        
 
                                    |Fire Hazard                                
 
                                    |Yes                                        
 
                                    |Sudden Release of Pressure Hazard        no
 
                                    |Reactive Hazard                            
 
                                    |no                                         
 
Toxic Substances Control Act (TSCA) |Chemical Name                     TSCA     
 
                                    |ETHOXYLATED                                
 
                                    |ALCOHOL                              X     
 
                                    |                                           
 
                                    |SODIUM                                     
 
                                    |METASILICATE                               
 
                                    |PENTAHYDRATE                 X             
 
                                    |                                           
 
                                    |D-LIMONENE                      X          
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Proposition 65: This product does not contain any known Proposition
65 
chemicals.                                                                      
 
U.S. State Right-to-Know Regulations                                            
 
EPA Pesticide Registration Number Not applicable                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |26-May-2015                                                    
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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