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Safety Data Sheet Date of Issue: 04/08/2015 |Revision Date: 04/08/2015 |Revision Number: 1.0 Imperial Supplies Part Number: 0043330 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: GOJOÂ® Cherry Gel Pumice Hand Cleaner CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Skin-care 1.3. Name, Address, and Telephone of the Responsible Party Company : GOJO Industries, Inc. One GOJO Plaza, Suite 500 Akron OH 44311 Telephone: 1 (330) 255-6000 1.4. Emergency Telephone Number Emergency | 1-800-424-9300 CHEMTREC number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 4 liquids | Serious eye |Category 1 damage | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Corrosion Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H227 Combustible liquid |H318 Causes serious eye damage. Precautionary Statements |Prevention: P210 Keep away from heat/sparks/open (GHS-US) |flames/hot surfaces. No smoking. P280 Wear |protective gloves/ eye protection/ face protection. |Response: P305 + P351 + P338 + P310 IF IN EYES: |Rinse cautiously with water for several minutes. |Remove contact lenses, if present and easy to do. |Continue rinsing. Immediately call a POISON CENTER |or doctor/ physician. |Storage: P403 + P235 Store in a well-ventilated |place. Keep cool. |Disposal: P501 Dispose of contents/ container to an |approved waste disposal plant. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Repeated exposure may cause skin dryness or cracking. Vapors may form explosive mixture with air. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Distillates (petroleum), |64742-47-8 |>= 20- <| hydrotreated light | |30 | Ethoxylated branched C11-14, |78330-21-9 |>= 5- < | C13-rich alcohols | |10 | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. First-aid Measures After Inhalation: If inhaled, remove to fresh air. Get medical attention if symptoms occur. First-aid Measures After Skin Contact: Wash with water and soap as a precaution. Get medical attention if symptoms occur. First-aid Measures After Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention immediately. First-aid Measures After Ingestion: If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Prolonged or repeated contact may dry skin and cause irritation. Symptoms/Injuries After Eye Contact: Causes serious eye damage. Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Protection of first-aiders: First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician: Treat symptomatically and supportively. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2) Unsuitable Extinguishing Media: High volume water jet 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Explosion Hazard: Hazardous combustion products: Carbon oxides Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Protection During Firefighting: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations. 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Non-sparking tools should be used. Soak up with inert absorbent material.Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Hygiene Measures: Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Storage Conditions: Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid: Do not store with the following product types: Strong oxidizing agents, Explosives, Gases. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Ingredients CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Distillates (petroleum), hydrotreated light 64742-47-8 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL Hazardous components without workplace control parameters Ingredients CAS No. Ethoxylated branched C11-14, C13-rich alcohols 78330-21-9 8.2. Exposure Controls Appropriate Engineering |Ensure adequate ventilation, especially in confined Controls |areas. Minimize workplace exposure concentrations. |Use only in an area equipped with explosion proof |exhaust ventilation. Dust formation may be relevant |in the processing of this product. In addition to |substance-specific OELs, general limitations of |concentrations of particulates in the air at |workplaces have to be considered in workplace risk |assessment. Relevant limits include: OSHA PEL for |Particulates Not Otherwise Regulated of 15 mg/m3 - |total dust, 5 mg/m3 - respirable fraction; and ACGIH |TWA for Particles (insoluble or poorly soluble) Not |Otherwise Specified of 3 mg/m3 - respirable |particles, 10 mg/m3 - inhalable particles. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Material: Impervious gloves. |Material: Flame retardant gloves. |Remarks: Choose gloves to protect hands against |chemicals depending on the concentration specific to |place of work. Breakthrough time is not determined |for the product. Change gloves often! For special |applications, we recommend clarifying the resistance |to chemicals of the aforementioned protective gloves |with the glove manufacturer. Wash hands before |breaks and at the end of workday. Eye Protection |Wear the following personal protective equipment: |Chemical resistant goggles must be worn. If splashes |are likely to occur, wear: Face-shield. Skin and Body Protection |Select appropriate protective clothing based on |chemical resistance data and an assessment of the |local exposure potential. Wear the following |personal protective equipment: Flame retardant |anti-static protective clothing. Skin contact must |be avoided by using impervious protective clothing |(gloves, aprons, boots, etc). Respiratory Protection |General and local exhaust ventilation is recommended |to maintain vapor exposures below recommended |limits. Where concentrations are above recommended |limits or are unknown, appropriate respiratory |protection should be worn. Follow OSHA respirator |regulations (29 CFR 1910.134) and use NIOSH/MSHA |approved respirators. Protection provided by air |purifying respirators against exposure to any |hazardous chemical is limited. Use a positive |pressure air supplied respirator if there is any |potential for uncontrolled release, exposure levels |are unknown, or any other circumstance where air |purifying respirators may not provide adequate |protection. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |gel Odor |fruity Odor Threshold |No data available pH |6.5 - 8.0 Relative Evaporation Rate |No data available (butylacetate=1) | Melting Point |No data available Freezing Point | Boiling Point |No data available Flash Point |93 Â°C Auto-ignition Temperature |No data available Decomposition Temperature |The substance or mixture is not classified |self-reactive. Flammability (solid, gas) |Not applicable Vapor Pressure |No data available Relative Vapor Density at 20 Â°C |No data available Relative Density | Specific Gravity | Solubility | Partition coefficient: |Not applicable n-octanol/water | Viscosity |Viscosity, kinematic: 5,000 - 7,500 mm2/s Lower Flammable Limit |No data available Upper Flammable Limit |No data available 9.2. Other Information Explosive properties: Not explosive SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Not classified as a reactivity hazard. 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions Combustible liquid. Vapors may form explosive mixture with air. Can react with strong oxidizing agents. 10.4 Conditions to Avoid Heat, flames and sparks. 10.5 Incompatible Materials Oxidizing agents 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Not classified based on available information. Product: Acute oral toxicity: Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Skin Corrosion/Irritation: Not classified based on available information. Product: Result: No skin irritation. Serious Eye Damage/Irritation: Causes serious eye damage. Respiratory or Skin Sensitization: Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Germ Cell Mutagenicity: Not classified based on available information. Carcinogenicity: Not classified based on available information. Reproductive Toxicity: Not classified based on available information. Specific Target Organ Toxicity (Single Exposure): Not classified based on available information. Specific Target Organ Toxicity (Repeated Exposure): Not classified based on available information. Aspiration Hazard: Not classified based on available information. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ingredients: Distillates (petroleum), hydrotreated light: Toxicity to fish: LL50 (Danio rerio (zebra fish)): > 250 mg/l Exposure time: 96 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates: EL50 (Acartia tonsa): > 3,193 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction Toxicity to algae: EL50 (Skeletonema costatum (marine diatom)): > 3,200 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction NOELR (Skeletonema costatum (marine diatom)): 993 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Toxicity to daphnia and other: aquatic invertebrates( Chronic toxicity) NOELR (Ceriodaphnia dubia (water flea)): > 70 mg/l Exposure time: 8 d Test substance: Water Accommodated Fraction Toxicity to bacteria: EC50: > 100 mg/l Exposure time: 3 h Ethoxylated branched C11-14, C13-rich alcohols: Toxicity to fish: LC50 (Oncorhynchus mykiss (rainbow trout)): 5.6 mg/l Exposure time: 96 h Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates: EC50 (Daphnia magna (Water flea)): > 1 - 10 mg/l Exposure time: 48 h Remarks: Based on data from similar materials Toxicity to algae: EC50: > 1 - 10 mg/l Exposure time: 96 h Remarks: Based on data from similar materials Toxicity to fish (Chronic toxicity): NOEC (Lepomis macrochirus (Bluegill sunfish)): > 0.33 mg/l Exposure time: 30 d Remarks: Based on data from similar materials Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity): NOEC (Daphnia magna (Water flea)): 0.77 mg/l Exposure time: 21 d Remarks: Based on data from similar materials 12.2. Persistence and Degradability Ingredients: Distillates (petroleum), hydrotreated light: Biodegradability: Result: Readily biodegradable. Biodegradation: 82 % Exposure time: 24 d Method: OECD Test Guideline 301F Ethoxylated branched C11-14, C13-rich alcohols: Biodegradability: Result: Readily biodegradable. Biodegradation: 95 % Exposure time: 28 d Method: OECD Test Guideline 301F Remarks: Based on data from similar materials 12.3. Bioaccumulative Potential No data available 12.4. Mobility in Soil No data available 12.5. Other Adverse Effects No data available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of in accordance with local regulations. Additional Information: Contaminated packaging: Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not regulated as a dangerous good Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not regulated as a dangerous good Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes |Fire Hazard |Acute Health Hazard Toxic Substances Control Act (TSCA) |All chemical substances in this product are |either listed on the TSCA Inventory or are in |compliance with a TSCA Inventory exemption. 15.2 US State Regulations <COMPONENT> CERCLA Reportable Quantity Ingredients CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Sodium hydroxide 1310-73-2 1000 * *: Calculated RQ exceeds reasonably attainable upper limit. Pennsylvania Right To Know Water 7732-18-5 30 - 50 % Distillates (petroleum), hydrotreated light 64742-47-8 20 - 30 % Fatty acids, tall-oil 61790-12-3 10 - 20 % Ethoxylated branched C11-14, C13-rich alcohols 78330-21-9 5-10% Pumice 1332-09-8 5-10% 2-phenoxyethanol 122-99-6 0.1-1% Sodium hydroxide 1310-73-2 0.1-1% New Jersey Right To Know Water 7732-18-5 30 - 50 % Distillates (petroleum), hydrotreated light 64742-47-8 20 - 30 % Fatty acids, tall-oil 61790-12-3 10 - 20 % Ethoxylated branched C11-14, C13-rich alcohols 78330-21-9 5-10% Pumice 1332-09-8 5-10% California Prop 65: This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |04/08/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.