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SDS Sheet 0043320

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Safety Data Sheet                                                               
 
Date of Issue: 04/08/2015  |Revision Date: 04/08/2015  |Revision Number: 1.0    
 
Imperial Supplies Part Number: 0043320                                          
 

SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: GOJO® Cherry Gel Pumice Hand Cleaner                              
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Skin-care                                         
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company :                                                                       
 
GOJO Industries, Inc.                                                           
 
One GOJO Plaza, Suite 500                                                       
 
Akron OH 44311                                                                  
 
Telephone: 1 (330) 255-6000                                                     
 


1.4.  Emergency Telephone Number
Emergency     | 1-800-424-9300 CHEMTREC                                         
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flammable     |Category 4    
liquids       |              
Serious eye   |Category 1    
damage        |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Corrosion        
                                    
Signal Word (GHS-US)         |Danger                                            
 
Hazard Statements (GHS-US)   |H227 Combustible liquid                           
 
                             |H318 Causes serious eye damage.                   
 
Precautionary Statements     |Prevention: P210 Keep away from heat/sparks/open  
 
(GHS-US)                     |flames/hot surfaces. No smoking. P280 Wear        
 
                             |protective gloves/ eye protection/ face
protection. 
                             |Response: P305 + P351 + P338 + P310 IF IN EYES:   
 
                             |Rinse cautiously with water for several minutes.  
 
                             |Remove contact lenses, if present and easy to do. 
 
                             |Continue rinsing. Immediately call a POISON CENTER
 
                             |or doctor/ physician.                             
 
                             |Storage: P403 + P235 Store in a well-ventilated   
 
                             |place. Keep cool.                                 
 
                             |Disposal: P501 Dispose of contents/ container to
an 
                             |approved waste disposal plant.                    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:  Repeated exposure may
cause
skin dryness or cracking. Vapors may form explosive mixture with air.           
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Distillates (petroleum),        |64742-47-8           |>= 20- <|                
 
hydrotreated light              |                     |30      |                
 
Ethoxylated branched C11-14,    |78330-21-9           |>= 5- < |                
 
C13-rich alcohols               |                     |10      |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General: In the case of accident or if you feel unwell, seek 
 
medical advice immediately. When symptoms persist or in all cases of doubt seek 
 
medical advice.                                                                 
 
First-aid Measures After Inhalation: If inhaled, remove to fresh air. Get
medical 
attention if symptoms occur.                                                    
 
First-aid Measures After Skin Contact: Wash with water and soap as a precaution.
 
Get medical attention if symptoms occur.                                        
 
First-aid Measures After Eye Contact: In case of contact, immediately flush eyes
 
with plenty of water for at least 15 minutes. If easy to do, remove contact
lens, 
if worn. Get medical attention immediately.                                     
 
First-aid Measures After Ingestion: If swallowed, DO NOT induce vomiting. Get   
 
medical attention if symptoms occur. Rinse mouth thoroughly with water.         
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact: Prolonged or repeated contact may dry skin
 
and cause irritation.                                                           
 
Symptoms/Injuries After Eye Contact: Causes serious eye damage.                 
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Protection of first-aiders: First Aid responders should pay attention to        
 
self-protection, and use the recommended personal protective equipment when the 
 
potential for exposure exists.                                                  
 
Notes to physician: Treat symptomatically and supportively.                     
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media:                                                   
 
Water spray                                                                     
 
Alcohol-resistant foam                                                          
 
Dry chemical                                                                    
 
Carbon dioxide (CO2)                                                            
 
Unsuitable Extinguishing Media: High volume water jet                           
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Do not use a solid water stream as it may scatter and spread fire. 
 
Flash back possible over considerable distance. Vapors may form explosive
mixtures
with air. Exposure to combustion products may be a hazard to health.            
 
Explosion Hazard: Hazardous combustion products: Carbon oxides                  
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions: Use extinguishing measures that are appropriate to   
 
local circumstances and the surrounding environment. Use water spray to cool    
 
unopened containers. Remove undamaged containers from fire area if it is safe to
 
do so. Evacuate area.                                                           
 
Protection During Firefighting: In the event of fire, wear self-contained       
 
breathing apparatus. Use personal protective equipment.                         
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:                                                               
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:  Remove all sources of ignition. Use personal protective  
 
equipment. Follow safe handling advice and personal protective equipment        
 
recommendations.                                                                
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Discharge into the environment must be avoided. Prevent further leakage or      
 
spillage if safe to do so. Prevent spreading over a wide area (e.g. by
containment
or oil barriers). Retain and dispose of contaminated wash water. Local
authorities
should be advised if significant spillages cannot be contained.                 
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up: Non-sparking tools should be used. Soak up with inert  
 
absorbent material.Suppress (knock down) gases/vapors/mists with a water spray  
 
jet. For large spills, provide diking or other appropriate containment to keep  
 
material from spreading. If diked material can be pumped, store recovered
material
in appropriate container. Clean up remaining materials from spill with suitable 
 
absorbent. Local or national regulations may apply to releases and disposal of  
 
this material, as well as those materials and items employed in the cleanup of  
 
releases. You will need to determine which regulations are applicable. Sections
13
and 15 of this SDS provide information regarding certain local or national      
 
requirements.                                                                   
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed:                                              
 
Hygiene Measures:  Ensure that eye flushing systems and safety showers are
located
close to the working place. When using do not eat, drink or smoke. Wash         
 
contaminated clothing before re-use.                                            
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: See Engineering measures under EXPOSURE CONTROLS/PERSONAL   
 
PROTECTION section.                                                             
 
Storage Conditions:  Keep in properly labeled containers. Keep tightly closed.  
 
Keep in a cool, well-ventilated place. Store in accordance with the particular  
 
national regulations. Keep away from heat and sources of ignition.              
 
Materials to avoid: Do not store with the following product types: Strong       
 
oxidizing agents,  Explosives, Gases.                                           
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Ingredients                                                                     
 
CAS-No.                                                                         
 
Value type                                                                      
 
(Form of exposure)                                                              
 
Control                                                                         
 
parameters / Permissible concentration                                          
 
Basis                                                                           
 
                                                                                
 
Distillates (petroleum), hydrotreated light                                     
 
64742-47-8                                                                      
 
TWA (Mist)                                                                      
 
5 mg/m3                                                                         
 
OSHA Z-1                                                                        
 
                                                                                
 
                                                                                
 
                                                                                
 
TWA (Mist)                                                                      
 
5 mg/m3                                                                         
 
NIOSH REL                                                                       
 
                                                                                
 
                                                                                
 
                                                                                
 
ST (Mist)                                                                       
 
10 mg/m3                                                                        
 
NIOSH REL                                                                       
 
                                                                                
 
Hazardous components without workplace control parameters                       
 
Ingredients                                                                   
CAS
No.                                                                             
 
Ethoxylated branched C11-14, C13-rich alcohols   78330-21-9                     
 
                                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Ensure adequate ventilation, especially in
confined 
Controls                     |areas. Minimize workplace exposure concentrations.
 
                             |Use only in an area equipped with explosion proof 
 
                             |exhaust ventilation. Dust formation may be
relevant 
                             |in the processing of this product. In addition to 
 
                             |substance-specific OELs, general limitations of   
 
                             |concentrations of particulates in the air at      
 
                             |workplaces have to be considered in workplace risk
 
                             |assessment. Relevant limits include: OSHA PEL for 
 
                             |Particulates Not Otherwise Regulated of 15 mg/m3 -
 
                             |total dust, 5 mg/m3 - respirable fraction; and
ACGIH
                             |TWA for Particles (insoluble or poorly soluble)
Not 
                             |Otherwise Specified of 3 mg/m3 - respirable       
 
                             |particles, 10 mg/m3 - inhalable particles.        
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Material: Impervious gloves.                      
 
                             |Material: Flame retardant gloves.                 
 
                             |Remarks: Choose gloves to protect hands against   
 
                             |chemicals depending on the concentration specific
to
                             |place of work. Breakthrough time is not determined
 
                             |for the product. Change gloves often! For special 
 
                             |applications, we recommend clarifying the
resistance
                             |to chemicals of the aforementioned protective
gloves
                             |with the glove manufacturer. Wash hands before    
 
                             |breaks and at the end of workday.                 
 
Eye Protection               |Wear the following personal protective equipment: 
 
                             |Chemical resistant goggles must be worn. If
splashes
                             |are likely to occur, wear: Face-shield.           
 
Skin and Body Protection     |Select appropriate protective clothing based on   
 
                             |chemical resistance data and an assessment of the 
 
                             |local exposure potential. Wear the following      
 
                             |personal protective equipment: Flame retardant    
 
                             |anti-static protective clothing. Skin contact must
 
                             |be avoided by using impervious protective clothing
 
                             |(gloves, aprons, boots, etc).                     
 
Respiratory Protection       |General and local exhaust ventilation is
recommended
                             |to maintain vapor exposures below recommended     
 
                             |limits. Where concentrations are above recommended
 
                             |limits or are unknown, appropriate respiratory    
 
                             |protection should be worn. Follow OSHA respirator 
 
                             |regulations (29 CFR 1910.134) and use NIOSH/MSHA  
 
                             |approved respirators. Protection provided by air  
 
                             |purifying respirators against exposure to any     
 
                             |hazardous chemical is limited. Use a positive     
 
                             |pressure air supplied respirator if there is any  
 
                             |potential for uncontrolled release, exposure
levels 
                             |are unknown, or any other circumstance where air  
 
                             |purifying respirators may not provide adequate    
 
                             |protection.                                       
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |                                           
 
Appearance                          |gel                                        
 
Odor                                |fruity                                     
 
Odor Threshold                      |No data available                          
 
pH                                  |6.5 - 8.0                                  
 
Relative Evaporation Rate           |No data available                          
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No data available                          
 
Freezing Point                      |                                           
 
Boiling Point                       |No data available                          
 
Flash Point                         |93 °C                                      
 
Auto-ignition Temperature           |No data available                          
 
Decomposition Temperature           |The substance or mixture is not classified 
 
                                    |self-reactive.                             
 
Flammability (solid, gas)           |Not applicable                             
 
Vapor Pressure                      |No data available                          
 
Relative Vapor Density at 20 °C     |No data available                          
 
Relative Density                    |                                           
 
Specific Gravity                    |                                           
 
Solubility                          |                                           
 
Partition coefficient:              |Not applicable                             
 
n-octanol/water                     |                                           
 
Viscosity                           |Viscosity, kinematic: 5,000 - 7,500 mm2/s  
 
Lower Flammable Limit               |No data available                          
 
Upper Flammable Limit               |No data available                          
 


9.2.  Other Information
Explosive properties: Not explosive                                             
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
Not classified as a reactivity hazard.                                          
 


10.2      Chemical Stability
Stable under normal conditions.                                                 
 


10.3      Possibility of Hazardous Reactions
Combustible liquid. Vapors may form explosive mixture with air. Can react with  
 
strong oxidizing agents.                                                        
 


10.4      Conditions to Avoid
Heat, flames and sparks.                                                        
 


10.5      Incompatible Materials
Oxidizing agents                                                                
 


10.6      Hazardous Decomposition Products
No hazardous decomposition products are known.                                  
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity: Not classified based on available information.                  
 
Product:                                                                        
 
Acute oral toxicity: Acute toxicity estimate: > 5,000 mg/kg                     
 
Method: Calculation method                                                      
 
Skin Corrosion/Irritation: Not classified based on available information.       
 
Product: Result: No skin irritation.                                            
 
Serious Eye Damage/Irritation: Causes serious eye damage.                       
 
Respiratory or Skin Sensitization: Skin sensitization: Not classified based on  
 
available information. Respiratory sensitization: Not classified based on       
 
available information.                                                          
 
Germ Cell Mutagenicity: Not classified based on available information.          
 
Carcinogenicity: Not classified based on available information.                 
 
Reproductive Toxicity: Not classified based on available information.           
 
Specific Target Organ Toxicity (Single Exposure): Not classified based on       
 
available information.                                                          
 
Specific Target Organ Toxicity (Repeated Exposure): Not classified based on     
 
available information.                                                          
 
Aspiration Hazard: Not classified based on available information.               
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Ingredients:                                                                    
 
Distillates (petroleum), hydrotreated light:                                    
 
Toxicity to fish:                                                               
 
LL50 (Danio rerio (zebra fish)): > 250 mg/l                                     
 
Exposure time: 96 h                                                             
 
Test substance: Water Accommodated Fraction                                     
 
Method: OECD Test Guideline 203                                                 
 
Toxicity to daphnia and other aquatic invertebrates:                            
 
EL50 (Acartia tonsa): > 3,193 mg/l                                              
 
Exposure time: 48 h                                                             
 
Test substance: Water Accommodated Fraction                                     
 
Toxicity to algae:                                                              
 
EL50 (Skeletonema costatum (marine diatom)): > 3,200 mg/l                       
 
Exposure time: 72 h                                                             
 
Test substance: Water Accommodated Fraction                                     
 
NOELR (Skeletonema costatum (marine diatom)): 993 mg/l                          
 
Exposure time: 72 h                                                             
 
Test substance: Water Accommodated Fraction                                     
 
Toxicity to daphnia and other: aquatic invertebrates( Chronic toxicity)         
 
NOELR (Ceriodaphnia dubia (water flea)): > 70 mg/l                              
 
Exposure time: 8 d                                                              
 
Test substance: Water Accommodated Fraction                                     
 
Toxicity to bacteria:                                                           
 
EC50: > 100 mg/l                                                                
 
Exposure time: 3 h                                                              
 
Ethoxylated branched C11-14, C13-rich alcohols:                                 
 
Toxicity to fish:                                                               
 
LC50 (Oncorhynchus mykiss (rainbow trout)): 5.6 mg/l                            
 
Exposure time: 96 h                                                             
 
Remarks: Based on data from similar materials                                   
 
Toxicity to daphnia and other aquatic invertebrates:                            
 
EC50 (Daphnia magna (Water flea)): > 1 - 10 mg/l                                
 
Exposure time: 48 h                                                             
 
Remarks: Based on data from similar materials                                   
 
Toxicity to algae:                                                              
 
EC50: > 1 - 10 mg/l                                                             
 
Exposure time: 96 h                                                             
 
Remarks: Based on data from similar materials                                   
 
Toxicity to fish (Chronic toxicity):                                            
 
NOEC (Lepomis macrochirus (Bluegill sunfish)): > 0.33 mg/l                      
 
Exposure time: 30 d                                                             
 
Remarks: Based on data from similar materials                                   
 
Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity):         
 
NOEC (Daphnia magna (Water flea)): 0.77 mg/l                                    
 
Exposure time: 21 d                                                             
 
Remarks: Based on data from similar materials                                   
 


12.2. Persistence and Degradability
Ingredients:                                                                    
 
Distillates (petroleum), hydrotreated light:                                    
 
Biodegradability:                                                               
 
Result: Readily biodegradable.                                                  
 
Biodegradation: 82 %                                                            
 
Exposure time: 24 d                                                             
 
Method: OECD Test Guideline 301F                                                
 
Ethoxylated branched C11-14, C13-rich alcohols:                                 
 
Biodegradability:                                                               
 
Result: Readily biodegradable.                                                  
 
Biodegradation: 95 %                                                            
 
Exposure time: 28 d                                                             
 
Method: OECD Test Guideline 301F                                                
 
Remarks: Based on data from similar materials                                   
 


12.3. Bioaccumulative Potential
No data available                                                               
 


12.4. Mobility in Soil
No data available                                                               
 


12.5. Other Adverse Effects
No data available                                                               
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations:  Dispose of in accordance with local
regulations. 
Additional Information:   Contaminated packaging: Dispose of as unused product. 
 
Empty containers should be taken to an approved waste handling site for
recycling 
or disposal. Do not burn, or use a cutting torch on, the empty drum.            
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |                                                          
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |Not regulated as a dangerous good                         
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Not regulated as a dangerous good                         
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA Section 311/312 Hazard Classes |Fire Hazard                                
 
                                    |Acute Health Hazard                        
 
Toxic Substances Control Act (TSCA) |All chemical substances in this product are
 
                                    |either listed on the TSCA Inventory or are
in
                                    |compliance with a TSCA Inventory exemption.
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
CERCLA Reportable Quantity                                                      
 
Ingredients                            CAS-No.       Component RQ (lbs)         
 
Calculated product RQ (lbs)                                                     
 
Sodium hydroxide               1310-73-2           1000                         
 
*                                                                               
 
*: Calculated RQ exceeds reasonably attainable upper limit.                     
 
Pennsylvania Right To Know                                                      
 
Water                                                                           
 
7732-18-5           30 - 50 %                                                   
 
Distillates (petroleum), hydrotreated light   64742-47-8         20 - 30 %      
 
Fatty acids, tall-oil                                               61790-12-3  
 
10 - 20 %                                                                       
 
Ethoxylated branched C11-14, C13-rich                                           
 
alcohols                                                                        
 
78330-21-9        5-10%                                                         
 
Pumice                                                                1332-09-8 
 
5-10%                                                                           
 
2-phenoxyethanol                                           122-99-6             
 
0.1-1%                                                                          
 
Sodium hydroxide                                          1310-73-2             
 
0.1-1%                                                                          
 
                                                                                
 
New Jersey Right To Know                                                        
 
Water                                                                           
 
7732-18-5           30 - 50 %                                                   
 
Distillates (petroleum), hydrotreated light   64742-47-8         20 - 30 %      
 
Fatty acids, tall-oil                                               61790-12-3  
 
10 - 20 %                                                                       
 
Ethoxylated branched C11-14, C13-rich                                           
 
alcohols                                                                        
 
78330-21-9        5-10%                                                         
 
Pumice                                                                1332-09-8 
 
5-10%                                                                           
 
                                                                                
 
California Prop 65: This product does not contain any chemicals known to the
State
of California to cause cancer, birth, or any other reproductive defects.        
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |04/08/2015                                                     
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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