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SDS Sheet 0041240

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: GOJO® NATURAL* ORANGE Pumice Hand Cleaner                         
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture:  Skin-care                                        
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
GOJO Industries, Inc.                                                           
 
One GOJO Plaza, Suite 500                                                       
 
Akron OH 44311                                                                  
 
Phone: 1 (330) 255-6000                                                         
 


1.4.  Emergency Telephone Number
Emergency     | 1-800-424-9300 CHEMTREC                                         
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Eye irritation|Category 2A   
              |              
              |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Exclamation Mark
        
Signal Word (GHS-US)         |Warning                                           

Hazard Statements (GHS-US)   |H319 Causes serious eye irritation.               

Precautionary Statements     |Prevention:                                       
 
(GHS-US)                     |P264 Wash skin thoroughly after handling.         
 
                             |P280 Wear eye protection/ face protection.        
 
                             |Response:                                         
 
                             |P305 + P351 + P338 IF IN EYES: Rinse cautiously
with
                             |water for several minutes. Remove contact lenses,
if
                             |present and easy to do. Continue rinsing.         
 
                             |P337 + P313 If eye irritation persists: Get
medical 
                             |advice/ attention.                                
 
                             |                                                  
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:  None known.              
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
1-Methyl 4-(1-Methylethenyl)    |5989-27-5            |>= 5- < |                
 
Cyclohexene                     |                     |10      |                
 
Alcohols, C12-15, ethoxylated   |68551-13-3           |>= 1- < |                
 
propoxylated                    |                     |5       |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:  In the case of accident or if you feel unwell, seek
 
medical advice immediately. When symptoms persist or in all cases of doubt seek 
 
medical advice.                                                                 
 
First-aid Measures After Inhalation:  If inhaled, remove to fresh air. Get
medical
attention if symptoms occur.                                                    
 
First-aid Measures After Skin Contact:  Wash with water and soap as a
precaution. 
Get medical attention if symptoms occur.                                        
 
First-aid Measures After Eye Contact:  In case of contact, immediately flush
eyes 
with plenty of water for at least 15 minutes. If easy to do, remove contact
lens, 
if worn. Get medical attention.                                                 
 
First-aid Measures After Ingestion:  If swallowed, DO NOT induce vomiting. Get  
 
medical attention if symptoms occur. Rinse mouth thoroughly with water.         
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact: Causes serious eye irritation.             
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
First Aid responders should pay attention to self-protection, and use the       
 
recommended personal protective equipment when the potential for exposure
exists. 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media:                                                   
 
Water spray                                                                     
 
Alcohol-resistant foam                                                          
 
Dry chemical                                                                    
 
Carbon dioxide (CO2)                                                            
 
Unsuitable Extinguishing Media: None known.                                     
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Exposure to combustion products may be a hazard to health.         
 
Explosion Hazard: Carbon oxides                                                 
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:  Use extinguishing measures that are appropriate to  
 
local circumstances and the surrounding environment. Use water spray to cool    
 
unopened containers. Remove undamaged containers from fire area if it is safe to
 
do so. Evacuate area.                                                           
 
Protection During Firefighting: In the event of fire, wear self-contained       
 
breathing apparatus. Use personal protective equipment.                         
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:                                                               
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:  Use personal protective equipment.                       
 
Emergency Procedures: Follow safe handling advice and personal protective       
 
equipment recommendations.                                                      
 


6.2.  Environmental Precautions
 Discharge into the environment must be avoided. Prevent further leakage or     
 
spillage if safe to do so. Prevent spreading over a wide area (e.g. by
containment
or oil barriers). Retain and dispose of contaminated wash water. Local
authorities
should be advised if significant spillages cannot be contained.                 
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Soak up with inert absorbent material. For large spills,
provide 
diking or other appropriate containment to keep material from spreading. If
diked 
material can be pumped, store recovered material in appropriate container.      
 
Methods for Cleaning Up: Clean up remaining materials from spill with suitable  
 
absorbent. Local or national regulations may apply to releases and disposal of  
 
this material, as well as those materials and items employed in the cleanup of  
 
releases. You will need to determine which regulations are applicable. Sections
13
and 15 of this SDS provide information regarding certain local or national      
 
requirements.                                                                   
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid inhalation of vapor or mist. Do not    
 
swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin.
Handle
in accordance with good industrial hygiene and safety practice. Take care to    
 
prevent spills, waste and minimize release to the environment.                  
 
Hygiene Measures: Ensure that eye flushing systems and safety showers are
located 
close to the working place. When using do not eat, drink or smoke. Wash         
 
contaminated clothing before re-use.                                            
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: See Engineering measures under EXPOSURE CONTROLS/PERSONAL   
 
PROTECTION section.                                                             
 
Storage Conditions: Keep in properly labeled containers. Store in accordance
with 
the particular national regulations.                                            
 
Materials to avoid: Do not store with the following product types: Strong       
 
oxidizing agents                                                                
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Contains no substances with occupational exposure limit values.                 
 
Hazardous components without workplace control parameters                       
 
Ingredients                                                                     
 
CAS-No.                                                                         
 
                                                                                
 
1-Methyl 4-(1-Methylethenyl) Cyclohexene                                        
 
5989-27-5                                                                       
 
                                                                                
 
Alcohols, C12-15, ethoxylated propoxylated                                      
 
68551-13-3                                                                      
 
                                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |Ensure adequate ventilation, especially in
confined 
Controls                     |areas. Minimize workplace exposure concentrations.
 
                             |Dust formation may be relevant in the processing
of 
                             |this product. In addition to substance-specific   
 
                             |OELs, general limitations of concentrations of    
 
                             |particulates in the air at workplaces have to be  
 
                             |considered in workplace risk assessment. Relevant 
 
                             |limits include: OSHA PEL for Particulates Not     
 
                             |Otherwise Regulated of 15 mg/m3 - total dust, 5   
 
                             |mg/m3 - respirable fraction; and ACGIH TWA for    
 
                             |Particles (insoluble or poorly soluble) Not       
 
                             |Otherwise Specified of 3 mg/m3 - respirable       
 
                             |particles, 10 mg/m3 - inhalable particles.        
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Material: Impervious gloves                       
 
                             |Remarks: Choose gloves to protect hands against   
 
                             |chemicals depending on the concentration specific
to
                             |place of work. Breakthrough time is not determined
 
                             |for the product. Change gloves often! For special 
 
                             |applications, we recommend clarifying the
resistance
                             |to chemicals of the aforementioned protective
gloves
                             |with the glove manufacturer. Wash hands before    
 
                             |breaks and at the end of workday.                 
 
Eye Protection               |Wear the following personal protective equipment: 
 
                             |Safety goggles                                    
 
Skin and Body Protection     |Select appropriate protective clothing based on   
 
                             |chemical resistance data and an assessment of the 
 
                             |local exposure potential. Skin contact must be    
 
                             |avoided by using impervious protective clothing   
 
                             |(gloves, aprons, boots, etc).                     
 
Respiratory Protection       |General and local exhaust ventilation is
recommended
                             |to maintain vapor exposures below recommended     
 
                             |limits. Where concentrations are above recommended
 
                             |limits or are unknown, appropriate respiratory    
 
                             |protection should be worn. Follow OSHA respirator 
 
                             |regulations (29 CFR 1910.134) and use NIOSH/MSHA  
 
                             |approved respirators. Protection provided by air  
 
                             |purifying respirators against exposure to any     
 
                             |hazardous chemical is limited. Use a positive     
 
                             |pressure air supplied respirator if there is any  
 
                             |potential for uncontrolled release, exposure
levels 
                             |are unknown, or any other circumstance where air  
 
                             |purifying respirators may not provide adequate    
 
                             |protection.                                       
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |                                           
 
Appearance                          |Liquid                                     
 
Odor                                |Citrus                                     
 
Odor Threshold                      |No data available                          
 
pH                                  |5.0 - 8.0                                  
 
Relative Evaporation Rate           |No data available                          
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No data available                          
 
Freezing Point                      |No data available                          
 
Boiling Point                       |95 °C                                      
 
Flash Point                         |> 100 °C                                   
 
Auto-ignition Temperature           |No data available                          
 
Decomposition Temperature           |The substance or mixture is not classified 
 
                                    |self-reactive.                             
 
Flammability (solid, gas)           |Not applicable                             
 
Vapor Pressure                      |No data available                          
 
Relative Vapor Density at 20 °C     |No data available                          
 
Relative Density                    |                                           
 
Specific Gravity                    |                                           
 
Solubility                          |Soluble                                    
 
Partition coefficient:              |Not applicable                             
 
n-octanol/water                     |                                           
 
Viscosity                           |10,000 - 50,000 mm2/s (20 °C)              
 
Lower Flammable Limit               |No data available                          
 
Upper Flammable Limit               |No data available                          
 


9.2.  Other Information
                                                                                
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
Not classified as a reactivity hazard.                                          
 


10.2      Chemical Stability
Stable under normal conditions.                                                 
 


10.3      Possibility of Hazardous Reactions
Can react with strong oxidizing agents.                                         
 


10.4      Conditions to Avoid
None known.                                                                     
 


10.5      Incompatible Materials
Oxidizing agents                                                                
 


10.6      Hazardous Decomposition Products
No hazardous decomposition products are known.                                  
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity: Not classified based on available information.                  
 
Skin Corrosion/Irritation: Not classified based on available information.       
 
Serious Eye Damage/Irritation: Causes serious eye irritation.                   
 
Respiratory or Skin Sensitization:                                              
 
Skin sensitization: Not classified based on available information.              
 
Respiratory sensitization: Not classified based on available information.       
 
Germ Cell Mutagenicity: Not classified based on available information.          
 
Carcinogenicity: Not classified based on available information.                 
 
Reproductive Toxicity:Not classified based on available information.            
 
Specific Target Organ Toxicity (Single Exposure): Not classified based on       
 
available information.                                                          
 
Specific Target Organ Toxicity (Repeated Exposure): Not classified based on     
 
available information.                                                          
 
Aspiration Hazard: Not classified based on available information.               
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
1-Methyl 4-(1-Methylethenyl) Cyclohexene:                                       
 
Toxicity to fish:                                                               
 
LC50 (Pimephales promelas (fathead minnow)): 0.72 mg/l                          
 
Exposure time: 96 h                                                             
 
Toxicity to daphnia and other aquatic invertebrates:                            
 
EC50 (Daphnia magna (Water flea)): 0.36 mg/l                                    
 
Exposure time: 48 h                                                             
 
Toxicity to algae:                                                              
 
ErC50 (Desmodesmus subspicatus (green algae)): 150 mg/l                         
 
Exposure time: 72 h                                                             
 
Test substance: Water Accommodated Fraction                                     
 
Remarks: Based on data from similar materials                                   
 
M-Factor (Acute aquatic tox-icity): 1                                           
 
Alcohols, C12-15, ethoxylated propoxylated:                                     
 
Toxicity to fish:                                                               
 
LC50 (Scophthalmus maximus (turbot)): 3.1 mg/l                                  
 
Exposure time: 96 h                                                             
 
Remarks: Based on data from similar materials                                   
 
Toxicity to daphnia and other aquatic invertebrates:                            
 
EC50 (Daphnia magna (Water flea)): 0.14 mg/l                                    
 
Exposure time: 48 h                                                             
 
Remarks: Based on data from similar materials                                   
 
Toxicity to algae:                                                              
 
EC50 (Pseudokirchneriella subcapitata (green algae)): 0.75 mg/l                 
 
Exposure time: 72 h                                                             
 
Remarks: Based on data from similar materials                                   
 
M-Factor (Acute aquatic tox-icity): 1                                           
 
Toxicity to bacteria:                                                           
 
EC50 (Pseudomonas putida): > 10,000 mg/l                                        
 
Exposure time: 16.9 h                                                           
 
Remarks: Based on data from similar materials                                   
 


12.2. Persistence and Degradability
1-Methyl 4-(1-Methylethenyl) Cyclohexene:                                       
 
Biodegradability: Result: Readily biodegradable.                                
 
Biodegradation: 80 %                                                            
 
Exposure time: 28 d                                                             
 
Remarks: Based on data from similar materials                                   
 
                                                                                
 
Alcohols, C12-15, ethoxylated propoxylated:                                     
 
Biodegradability: Result: Readily biodegradable.                                
 
Biodegradation: 80 - 88 %                                                       
 
Exposure time: 28 d                                                             
 
Remarks: Based on data from similar materials                                   
 


12.3. Bioaccumulative Potential
1-Methyl 4-(1-Methylethenyl) Cyclohexene:                                       
 
Partition coefficient: n-octanol/water: log Pow: 4.38                           
 


12.4. Mobility in Soil
No data available                                                               
 


12.5. Other Adverse Effects
No data available                                                               
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations:  Dispose of in accordance with local
regulations. 
Additional Information: Dispose of as unused product. Empty containers should be
 
taken to an approved waste handling site for recycling or disposal.             
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |                                                          
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.       
 
                     |(1-Methyl 4-(1-Methylethenyl) Cyclohexene)                
 
Hazard Class         |9                                                         
 
Identification Number|UN 3082                                                   
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |F-A                   |                                   
 
EmS-No. (Spillage)   |S-F                   |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Environmentally hazardous substance, liquid, n.o.s.       
 
                     |(1-Methyl 4-(1-Methylethenyl) Cyclohexene)                
 
Identification Number|UN 3082                |<PICTOGRAM PHRASE>                
  
Hazard Class         |9                      |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA Section 311/312 Hazard Classes |Acute Health Hazard                        
 
Toxic Substances Control Act (TSCA) |All chemical substances in this product are
 
                                    |either listed on the TSCA Inventory or are
in
                                    |compliance with a TSCA Inventory exemption.
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
Pennsylvania Right To Know:                                                     
 
Water                                               7732-18-5                70
- 
90 %                                                                            
 
Pumice                                             1332-09-8                  5
- 
10 %                                                                            
 
1-Methyl 4-(1-Methylethenyl)    5989-27-5                   5 - 10 %            
 
Cyclohexene                                                                     
 
New Jersey Right To Know:                                                       
 
Water                                               7732-18-5                 70
-
90 %                                                                            
 
Pumice                                                  32-09-8                 
 
5 - 10 %                                                                        
 
1-Methyl 4-(1-Methylethenyl)       5989-27-5                  5 - 10 %          
 
Cyclohexene                                                                     
 
Alcohols, C12-15,                             68551-13-3                1 - 5 % 
 
ethoxylated propoxylated                                                        
 
California Prop 65: This product does not contain any chemicals known to the
State
of California to cause cancer, birth, or any other reproductive defects.        
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |03/02/2015                                                     
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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