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SECTION 1: IDENTIFICATION | |1.1. Product Identifier Product Form: Product Name: PURE CITRUS ORANGE SOLID AIR FRESHENER 8 OZ. CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Solid Air Freshener 1.3. Name, Address, and Telephone of the Responsible Party Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 T 817-645-6088 1.4. Emergency Telephone Number Emergency | CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Not classified| | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |None Signal Word (GHS-US) |None Hazard Statements (GHS-US) |None Precautionary Statements |None (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: None under normal conditions. 2.4. Unknown Acute Toxicity (GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) Fragrance |Mixture |1-3 |Not classified | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid Measures After Inhalation: Assure fresh air breathing. Allow the victim to rest. First-aid Measures After Skin Contact: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid Measures After Eye Contact: Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/Injuries After Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/Injuries After Skin Contact: May cause slight irritation. Itching. Red skin. Skin rash/inflammation. Symptoms/Injuries After Eye Contact: May cause slight eye irritation. Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Symptoms/Injuries After Ingestion: May be harmful if swallowed and enters airways. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed No additional information available SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable Extinguishing Media: Do not use a heavy water stream. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Do not use a heavy water stream. Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Remove ignition sources. 6.1.1. For Non-emergency Personnel Protective Equipment: Safety glasses. Gloves. Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Responders Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area. 6.2. Environmental Precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Dam up the solid spill. Keep in tubing if not used. Methods for Cleaning Up: On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Hygiene Measures: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash affected areas thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Storage Conditions: Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. 7.3. Specific End Use(s) Follow Label Directions. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters 8.2. Exposure Controls Appropriate Engineering |Ensure good ventilation of the work station. Local Controls |exhaust ventilation, vent hoods. Personal Protective Equipment|Avoid all unnecessary exposure. Gloves. Safety |glasses. Materials for Protective | Clothing | Hand Protection |Wear protective gloves. Eye Protection |Chemical goggles or safety glasses. Skin and Body Protection |Wear suitable protective clothing. Respiratory Protection |Wear appropriate mask. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Solid Appearance |Solid Odor |Lemon Odor Threshold |No data available pH |9.2 Relative Evaporation Rate |No data available (butylacetate=1) | Melting Point |110 - 125 �C Freezing Point |No data available Boiling Point |100 �C Flash Point |None Auto-ignition Temperature |No data available Decomposition Temperature |No data available Flammability (solid, gas) |No data available Vapor Pressure |No data available Relative Vapor Density at 20 �C |No data available Relative Density |1 Specific Gravity | Solubility |Poorly soluble in water. Partition coefficient: | n-octanol/water | Viscosity |No data available Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information VOC content : < 3 % SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No additional information available 10.2 Chemical Stability No additional information available 10.3 Possibility of Hazardous Reactions Not established. 10.4 Conditions to Avoid Direct sunlight. Extremely high or low temperatures. 10.5 Incompatible Materials Strong acids. Strong bases. 10.6 Hazardous Decomposition Products Toxic fume. Carbon monoxide. Carbon dioxide. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Not classified Skin Corrosion/Irritation: Not classified Serious Eye Damage/Irritation: Not classified Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): Not classified Specific Target Organ Toxicity (Repeated Exposure): Not classified Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled. Symptoms/Injuries After Skin Contact: May cause slight irritation. Itching. Red skin. Skin rash/inflammation. Symptoms/Injuries After Eye Contact: May cause slight eye irritation. Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Symptoms/Injuries After Ingestion: May be harmful if swallowed and enters airways. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity No additional information available 12.2. Persistence and Degradability PURE CITRUS ORANGE SOLID AIR FRESHENER 8 OZ. Persistence and degradability Not established. Fragrance (Mixture) Persistence and degradability Not established. 12.3. Bioaccumulative Potential PURE CITRUS ORANGE SOLID AIR FRESHENER 8 OZ. Bioaccumulative potential Not established. Fragrance (Mixture) Bioaccumulative potential Not established. 12.4. Mobility in Soil No additional information available 12.5. Other Adverse Effects Other information: Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not Regulated Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not Regulated Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not Regulated Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations SARA Section 311/312 Hazard Classes |Immediate (acute) health hazard Toxic Substances Control Act (TSCA) | 15.2 US State Regulations No additional information available SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |12/10/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer. The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product. Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer /distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.