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Sheet 0077740

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Material Safety Data Sheet | |
Date of issue:      |Revision Date: March 1, 2013  |Revision Number:      
Imperial Supplies Part Number: 0077740                                    
1. PRODUCT AND COMPANY IDENTIFICATION                                     
Manufacturer:                                                             
James Alexander Corporation                                               
845 Route 94                                                              
Blairstown,                                                               
NJ 07825                                                                  
Telephone: (908) 362-9266                                                 
Emergency  Phone: (800) 424-9300 (CHEMTREC)                               
                                                                          
                                                                          
Product Name: AMMONIA INHALANT SOLUTION                                   
Product Code(s):                                                          
Recommended Use:                                                          
UN-Number: UN2924                                                         
Product Type:                                                             
                                                                          
2.  HAZARDS IDENTIFICATION                                                
                                                                          
                                                                          
                                                                          
Appearance: Clear,   |Physical State:           |Odor: Pungent odor of    
pink to light red    |                          |ammonia                  
liquid               |                          |                         
                                                                          
Potential Health Effects                                                  
Principle Routes of Exposure: Inhalation, eye contact, skin contact,      
ingestion.                                                                
                                                                          
Acute Effects:                                                            
Eyes                 |Severe irritation or burns, may lead to blindness.  
Skin                 |Local irritation, dry skin, burns.                  
Inhalation           |Irritation or burns of the respiratory system,      
                     |headache, coughing, lung congestion or inflammation,
                     |pulmonary edema, breathing difficulty. Headache,    
                     |dizziness, drowsiness, loss of appetite and an      
                     |inability to concentrate.                           
Ingestion            |Burning pain in mouth, throat, constriction of      
                     |throat, coughing, followed by nausea, vomiting or   
                     |diarrhea. Ingestion may prove fatal.                
Notes:                                                                    
                                                                          
Chronic Effects:                                                          
Eyes                 |                                                    
Skin                 |                                                    
Inhalation           |                                                    
Ingestion            |                                                    
Notes:                                                                    
                                                                          
Aggravated Medical Conditions: Individuals with pre-existing nervous      
system disorders, skin disorders, eye problems, or impaired respiratory   
function may be more susceptible to the effects of overexposure.          
                                                                          
Environmental Hazard                                                      
                                                                          
3.  COMPOSITION/INFORMATION ON INGREDIENTS                                
                                                                          
Chemical/Ingredient Name |CAS-No     |Weight%   |ACGIH,    |OSHA-PE|Other 
                         |           |          |TLV-TWA   |L      |      
Ammonia                  |7664-41-7  |17.5      |TLV/TWA:  |50 ppm |      
                         |           |          |25 PPM;   |       |      
                         |           |          |TLV/STEL: |       |      
                         |           |          |35 PPM    |       |      
Ethyl Alcohol            |64-17-5    |37.5      |TLV/TWA:  |1000   |      
                         |           |          |1000 PPM; |ppm    |      
                         |           |          |          |       |      
                         |           |          |TLV/STEL: |       |      
                         |           |          |Not listed|       |      
                         |           |          |          |       |      
                         |           |          |          |       |      
                         |           |          |          |       |      
                         |           |          |          |       |      
                         |           |          |          |       |      
Notes                                                                     
                                                                          
4.  FIRST AID MEASURES                                                    
                                                                          
General Advice                                                            
Eyes               |Immediately flush eyes with copious amounts of water 
                   |for at least 15 minutes. Eyelids should be held apart
                   |and away from eyeball for thorough rinsing. Do not   
                   |permit victim to rub eyes. Get immediate medical     
                   |attention.                                           
Skin               |Immediately flush skin with copious amounts of water 
                   |for at least 15 minutes while removing contaminated  
                   |clothing and shoes. Do not rub or apply ointment to  
                   |affected area. Obtain medical attention if irritation
                   |persists. Wash clothing before re-use.               
Inhalation         |Remove subject immediately to fresh air. Give        
                   |artificial respiration if victim is not breathing. If
                   |breathing is difficult, give oxygen. Get immediate   
                   |medical attention.                                   
Ingestion          |Contact a Poison Control Center immediately. Do NOT  
                   |induce vomiting. If conscious, have victim swallow   
                   |large amounts of water. Do not give anything by mouth
                   |to an unconscious or convulsing person. Get immediate
                   |medical attention.                                   
Notes to Physician |                                                     
Protection of      |                                                     
First-aiders       |                                                     
Notes              |                                                     
                                                                          
5.  FIRE-FIGHTING MEASURES                                                
                                                                          
Flammability/Flammable     |Lower (Unknown)                               
properties                 |Upper(Unknown)                                
Flash point                |Less than 50 degrees F                        
Recommended Extinguishing  |"Alcohol resistant" foam, CO2 or dry chemical.
Media                      |                                              
Special  Fire-Fighting     |Note: Individuals should perform only those   
Procedures                 |fire-fighting procedures for which they have  
                           |been trained. Remove all sources of ignition. 
                           |Move exposed containers from fire area if it  
                           |can be done without risk. Firefighters should 
                           |wear proper protective equipment and          
                           |self-contained breathing apparatus with full  
                           |facepiece operated in positive pressure mode. 
                           |Spray extinguishing media directly into base  
                           |of flames. Water may be used to keep          
                           |fire-exposed containers cool.                 
                           |                                              
Explosion Data             |Unusual fire and Explosion hazard: When       
                           |heated, mixture will give off ammonia gas, a  
                           |strong irritant to eyes, respiratory tract,   
                           |and mucous membranes. Other toxic gases       
                           |produced are oxides of nitrogen, carbon       
                           |monoxide, carbon dioxide and hydrogen. Closed 
                           |containers exposed to heat may develop        
                           |pressure and explode. Alcohol vapors are      
                           |heavier than air and may travel a considerable
                           |distance to a source of ignition and flash    
                           |back. Alcohols burn with a pale blue flame    
                           |which may be extremely hard to see under      
                           |normal lighting conditions. Personnel may be  
                           |able to feel the heat of the fire without     
                           |seeing flames. Extreme caution must be        
                           |exercised in fighting alcohol fires.          
Sensitivity to Mechanical  |                                              
Impact                     |                                              
Sensitivity to Static      |                                              
Discharge                  |                                              
                           |                                              
Specific Hazards from      |                                              
Chemical                   |                                              
                           |                                              
Protective Equipment       |                                              
                                                                          
NFPA |Health Hazard: |Flammability: 3|Instability:|Physical Hazard        
     |3              |               |1           |                       
                                                                          
HMIS |Health Hazard: |Flammability:  |Physical      |PPE:                 
     |               |               |Hazard:       |                     
                                                                          
6.  ACCIDENTAL RELEASE MEASURES                                           
                                                                          
Personal Precautions                                                      
Environmental Precautions                                                 
Methods for Containment                                                   
Methods for Cleaning Up                                                   
Notes: For large spills, stop leak if you can do so without risk.         
Extinguish all sources of ignition. Wear self-contained breathing         
apparatus, chemical safety goggles and full protective clothing. Ventilate
area. Spilled liquids should be contained and not washed into sewers or   
ground water. Contain by diking with non-combustible absorbent materials  
and place residue in DOT approved waste container.  Comply with all       
applicable local, state and federal regulations on spill reporting,       
handling and disposal of waste.                                           
                                                                          
7.  HANDLING AND STORAGE                                                  
                                                                          
Handling: All ignition sources should be eliminated. Remove closure       
carefully; internal pressure may be present. Keep closure up to prevent   
leakage. When contents are being transferred, metallic containers must be 
bonded to the receiving container and grounded to avoid static discharges.
Never use pressure to empty containers. Replace closure carefully after   
each opening.                                                             
Storage: Protect containers from physical damage. Detached or outside     
storage is preferred. Inside storage should be in an NFPA approved        
flammable liquids storage room or cabinet. Store in corrosion-proof area  
at temperatures below 77 degrees F (25oC). Do not store in direct         
sunlight. Isolate from incompatible materials. Keep containers tightly    
closed.                                                                   
                                                                          
8.  EXPOSURE CONTROLS/PERSONAL PROTECTION                                 
                                                                          
Exposure Guidelines                                                       
                                                                          
Chemical Name    |ACGIH TLV     |OSHA PEL      |NIOSH IDLH    |OTHER      
                 |              |              |              |           
                 |              |              |              |           
                 |              |              |              |           
                                                                          
Engineering Measures                                                      
                                                                          
Personal Protective Equipment                                             
Eyes/Face          |Not required for product (JAC unit dose inhalant)    
Protection         |use. When handling bulk material, always wear        
                   |gas-tight, splash-proof chemical safety goggles      
                   |meeting OSHA 29CFR 1910.133 specifications.          
Skin and Body      |Skin Protection: Not required for product (JAC unit  
Protection         |dose inhalant) use. Use rubber gloves, protective    
                   |suit, face shield and overshoes when handling bulk   
                   |product.                                             
Respiratory        |                                                     
Protection         |                                                     
Ventilation/Other  |Not required for product (JAC unit dose inhalant)    
                   |use. When handling bulk material, use general or     
                   |local exhaust ventilation to meet TLV requirements.  
                   |Where engineering controls are not feasible or       
                   |sufficient to achieve full conformance with          
                   |acceptable exposure limits, use NIOSH approved       
                   |respiratory protection equipment. Care must be taken 
                   |to assure that any respirator chosen is capable of   
                   |protecting the user from both ammonia and ethyl      
                   |alcohol vapors. In some cases, a self-contained      
                   |breathing apparatus may be advisable.                
Hygiene Measures                                                          
                                                                          
9.  PHYSICAL AND CHEMICAL PROPERTIES                                      
                                                                          
Appearance       |Clear, pink to |Odor               |Pungent odor of     
                 |light red      |                   |ammonia             
                 |liquid         |                   |                    
Odor Threshold   |               |Physical State     |                    
Color            |               |Viscosity          |                    
pH               |Unknown        |Percent  Volatile, |                    
                 |               |wt. %              |                    
Flash Point      |Less than 50   |Auto-ignition      |Ammonia 1204 degrees
                 |degrees F      |Temperature        |F (651 Deg C); Ethyl
                 |               |                   |Alcohol: 685 degrees
                 |               |                   |F (363 Deg C)       
Decomposition    |               |Boiling Point/     |N/A for mixtures    
Temp             |               |Range              |                    
Melting          |Unknown        |Freezing Point     |                    
Point/Range      |               |                   |                    
Flammability     |Lower (Unknown)|Explosion Limits   |                    
                 |Upper(Unknown) |                   |                    
Specific Gravity |0.891 25/25    |Water Solubility   |Very soluble        
Solubility       |               |Evaporation Rate   |Unknown             
Vapor Pressure   |Unknown        |Vapor Density      |Unknown             
VOC content, wt. |               |                   |                    
%                |               |                   |                    
                 |               |                   |                    
Notes                                                                     
                                                                          
10. STABILITY AND REACTIVITY                                              
                                                                          
Chemical Stability        |Stable at room temperature.                   
Incompatible Products     |                                              
Conditions to avoid       |Sunlight, heat (heating above ambient         
                          |temperatures causes the vapor pressure of the 
                          |solution to increase). Avoid mixing with      
                          |acids, most common metals, strong oxidizing   
                          |agents, brass, zinc, chlorine, aluminum,      
                          |copper, bronze, mercury, dimethyl sulfate and 
                          |acetyl chloride.                              
Hazardous Decomposition   |                                              
Products                  |                                              
Hazardous Polymerization  |Hazardous polymerization will not occur.      
                          |However, product will react exothermically    
                          |with acids. Releases ammonia vapor when       
                          |heated. Ammonia component will decompose to   
                          |hydrogen and oxides of nitrogen when heated.  
                          |Carbon monoxide gas may also be produced when 
                          |heated.                                       
Notes                                                                     
                                                                          
11. TOXICOLOGY INFORMATION                                                
None of the components present in this formulation are currently          
classified as carcinogens in the NTP Annual Report on Carcinogens, IARC   
Monographs or by OSHA.                                                    
Acute Toxicity                                                            
                                                                          
Product         |                                                        
Information     |                                                        
Inhalation      |                                                         
Eye Contact     |                                                         
Skin Contact    |                                                         
Ingestion       |                                                         
                                                                          
Chemical Name   |LD50 Oral        |LD50 Dermal      |LC50 Inhalation      
                |                 |                 |                     
                |                 |                 |                     
                                                                          
Chronic Toxicity|                                                         
                                                                          
Chemical Name   |ACGIH             |IARC     |NTP          |OSHA          
                |                  |         |             |              
                |                  |         |             |              
                                                                          
Target Organ Effects                                                      
                                                                          
12.  ECOLOGICAL INFORMATION                                               
                                                                          
Ecotoxicity                                                               
The Environmental impact of this product has been fully investigated      
                                                                          
Chemical Name|Toxicity to    |Toxicity to |Tox, to       |Daphnia Magna  
             |Algea          |Fish        |Microorganisms|(water flea)   
             |               |            |              |               
             |               |            |              |               
             |               |            |              |               
                                                                          
Notes                                                                     
                                                                          
13.  DISPOSAL CONSIDERATIONS                                              
                                                                          
Waste Disposal Methods:                                                   
                                                                          
Contaminated Packaging                                                    
                                                                          
US EPA Waste number                                                       
                                                                          
Notes: Other Precautions: Containers, even those that have been emptied,  
will retain product residue and vapors. Handle empty containers as if they
were full.                                                                
                                                                          
                                                                          
14.  TRANSPORTATION INFORMATION                                           
                                                                          
DOT                                                                       
UN-Number           |UN2924                                               
Proper Shipping name|Flammable Liquid Corrosive NOS                       
Hazard Class        |3                                                    
Packing Group       |II                                                   
Description         |                                                     
Emergency Response  |                                                     
Guide Number        |                                                     
                                                                          
TDG                                                                       
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
MEX                 |                                                     
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
ICAO                                                                      
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
IATA                                                                      
UN-Number           |UN2924                                               
Proper Shipping name|Flammable Liquid Corrosive NOS                       
Hazard Class        |3                                                    
Packing Group       |II (Ammonia, Ethanol)                                
ERG Code            |                                                     
Description         |                                                     
                                                                          
IMDG/IMO                                                                  
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
EmS No.            |                                                     
Description        |                                                     
                                                                          
RID                                                                       
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
Classification Code|                                                     
Description        |                                                     
ADR/RID-Labels     |                                                     
                                                                          
ADR                                                                       
UN-Number          |                                                      
Proper Shipping    |                                                      
name               |                                                      
Hazard Class       |                                                      
Packing Group      |                                                      
Classification Code|                                                      
Description        |                                                      
ADR/RID-Labels     |                                                      
                                                                          
ADN                                                                       
UN-Number                                                                 
Proper Shipping name                                                      
Hazard Class                                                              
Packing Group                                                             
Classification Code                                                       
Special Provisions                                                        
Description                                                               
Hazard Labels                                                             
Limited Quantity                                                          
                                                                          
15.  REGULATORY INFORMATION                                               
                                                                          
International Inventories                                                 
TSCA                                                                      
DSL                                                                       
EINECS                                                                    
ENCS                                                                      
IECSC                                                                     
PICCS                                                                     
AICS                                                                      
                                                                          
U.S. Federal Regulations                                                  
SARA 313                                                                  
SARA 311/312 Hazard Categories                                            
Acute Health Hazard                                                       
Chronic Health Hazard                                                     
Fire Hazard                                                               
Sudden Release of Pressure Hazard                                         
Reactive Hazard                                                           
                                                                          
Clean Water Act                                                           
                                                                          
CERCLA                                                                    
                                                                          
U.S. State Regulations                                                    
                                                                          
U.S. State Right-to-Know Regulations                                      
                                                                          
International Regulations                                                 
                                                                          
Canada                                                                    
                                                                          
                                                                          
                                                                          
16.  OTHER INFORMATION                                                    
                                                                          
Prepared By: David Robinson                                               
Revision Date: March 1, 2013                                              
Company: James Alexander Corporation                                      
Revision number                                                           
Telephone number: (908) 362-9266                                          
                                                                          
Notes: This Material Safety Data Sheet is intended only as a guide to the 
appropriate precautionary handling of the material by a person trained in,
or supervised by a person trained in, the safe handling of chemical       
materials. James Alexander Corporation (JAC), expressly disclaims all     
express or implied warranties of merchantability and fitness for a        
particular purpose with respect to the product or information provided    
herein. All information appearing herein is based upon data obtained from 
the manufacturer(s) and/or recognized technical sources. While the        
information is believed to be accurate, JAC makes no representations as to
its accuracy or sufficiency. Conditions of use are beyond JAC's control   
and therefore, users are responsible to verify this data under their own  
operating conditions to determine whether the product is suitable for     
their particular purposes and they assume all risks of their use,         
handling, and disposal of the product, or from the publication or use of, 
or reliance upon, information contained herein. This information relates  
only to the product designated herein and does not relate to its use in   
combination with any other material or in any other process.              
                                                                          
Other Information                                                         
                                                                          
Disclaimer information                                                    
                                                                          
                                                                          
END OF MATERIAL SAFETY DATA SHEET                                         





    

The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.

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