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Sheet 0077730

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Material Safety Data Sheet | |
Date of issue: July |Revision Date: January 25,   |Revision Number:       
2008                |2012                         |                       
Imperial Supplies Part Number: 0077730                                    
1. PRODUCT AND COMPANY IDENTIFICATION                                     
Manufacturer:                                                             
FOMO PRODUCTS, INC.                                                       
P. O. Box 1078                                                            
Norton, Ohio 44203                                                        
Telephone: 1-800-321-5585                                                 
Emergency  Phone: CHEMTREC 1-800-424-9300                                 
                                                                          
                                                                          
Product Name: ONE-COMPONENT POLYURETHANE FOAM ADHESIVE (HFO-1234ze)       
Product Code(s): A16317                                                   
Recommended Use:                                                          
UN-Number: UN1956                                                         
Product Type:                                                             
                                                                          
2.  HAZARDS IDENTIFICATION                                                
                                                                          
                                                                          
Emergency Overview: Product is a liquid urethane prepolymer mixture that  
is packaged under pressure (Non-Flammable Compressed Gas). Containers     
should not be heated above 120�F (49�C) to avoid excessive pressure       
build-up.                                                                 
Appearance: Viscous  |Physical State: Liquid   |Odor: Slight fluorocarbon 
liquid               |                         |                          
                                                                          
Potential Health Effects: The primary adverse health effects of this      
product are related to the Polymeric Isocyanate (MDI) component, and, to a
lesser degree, the Fluorocarbon (HFO-1234ze) component. Therefore,        
adequate ventilation should be provided to avoid exceeding the exposure   
limits of these components (See Section 8). The likelihood of exceeding   
these limits are low due to the low concentration of vapor produced during
normal use. However, if used indoors, mechanical ventilation or exhaust   
should be provided during use and until product is cured.                 
Principle Routes of Exposure                                              
                                                                          
Acute Effects: Physical Hazards: Since the containers are pressurized,    
storage temperature should not exceed 120 Deg. F (49 Deg. C) in order to  
avoid excessive pressure build-up and possible container rupture. Also,   
the product has strong adhesive-like characteristics and will adhere      
aggressively to skin and other surfaces. If accidental contact occurs,    
follow the appropriate first-aid procedure described in Section 4 of this 
MSDS.                                                                     
Eyes                 |May be irritating to eyes. Foam contact can cause   
                     |physical damage due to adhesive character.          
Skin                 |May cause localized irritation, reddening or        
                     |swelling. Prolonged or repeated exposure may lead to
                     |sensitization and/or contact dermatitis.            
Inhalation           |May irritate mucous membranes with tightness in     
                     |chest, coughing, or allergic asthma-like            
                     |sensitivity. Extensive overexposure can lead to     
                     |respiratory symptoms like bronchitis and pulmonary  
                     |edema. These effects are usually reversible.        
                     |Overexposure to trans-1, 1, 1, 3 -                  
                     |Tetrafluoropropene may cause lightheadedness,       
                     |headaches, or lethargy. Persons with cardiac        
                     |arrhythmia may be at increased risk in severe       
                     |exposure.                                           
Ingestion            |May cause irritation of mucous membranes in the     
                     |mouth and digestive tract.                          
Notes:                                                                    
                                                                          
Chronic Effects:                                                          
Eyes                 |                                                    
Skin                 |                                                    
Inhalation           |                                                    
Ingestion            |                                                    
Notes:                                                                    
                                                                          
Aggravated Medical Conditions                                             
                                                                          
Environmental Hazard                                                      
                                                                          
3.  COMPOSITION/INFORMATION ON INGREDIENTS                                
                                                                          
Chemical/Ingredient Name |CAS-No     |Weight%   |ACGIH,    |OSHA-PE|Other 
                         |           |          |TLV-TWA   |L      |      
trans-1,1,1,3-           |1645-83-6  |10 to 30  |          |       |      
Tetrafluoropropene       |           |percent   |          |       |      
(Non-Flammable Compressed|           |          |          |       |      
Gas, HFC, Fluorocarbon)  |           |          |          |       |      
HFO-1234ze               |           |          |          |       |      
4,4' - Diphenylmethane   |101-68-8   |5 to 10   |          |       |      
Diisocyanate (MDI)       |           |percent   |          |       |      
Higher Oligomers of MDI  |9016-87-9  |5 to 10   |          |       |      
(Polymeric MDI)          |           |percent   |          |       |      
Urethane Pre-polymer     |Not        |60 to 100 |          |       |      
Blend (Non- Hazardous    |Available  |percent   |          |       |      
Proprietary Blend)       |           |          |          |       |      
                         |           |          |          |       |      
                         |           |          |          |       |      
                         |           |          |          |       |      
Notes                                                                     
                                                                          
4.  FIRST AID MEASURES                                                    
                                                                          
General Advice                                                            
Eyes               |Flush with clean water for at least 15 minutes and   
                   |obtain medical attention.                            
Skin               |Use a rag to remove excess foam from skin and remove 
                   |contaminated clothing. Use of a solvent, such as     
                   |acetone (nail polish remover) or mineral spirits, may
                   |help in removing uncured foam residue from clothing  
                   |or other surfaces (avoid eye contact). Cured foam may
                   |be physically removed by persistent washing with soap
                   |and water. If irritation develops, use mild skin     
                   |cream. If irritation persists, obtain medical        
                   |attention.                                           
Inhalation         |If breathing difficulty is experienced, move to area 
                   |free of exposure. Provide fresh air. If necessary,   
                   |provide oxygen or artificial respiration by trained  
                   |personnel and obtain medical attention.              
Ingestion          |Drink 1 to 3 glasses of water and seek immediate     
                   |medical attention. Never give anything orally to an  
                   |unconscious person.                                  
Notes to Physician |                                                     
Protection of      |                                                     
First-aiders       |                                                     
Notes              |                                                     
                                                                          
5.  FIRE-FIGHTING MEASURES                                                
                                                                          
Flammability/Flammable     |                                              
properties                 |                                              
Flash point                |Approximately 800 Deg. F (426.6 Deg. C)       
Recommended Extinguishing  |Drink 1 to 3 glasses of water and seek        
Media                      |immediate medical attention. Never give       
                           |anything orally to an unconscious person.     
Special  Fire-Fighting     |                                              
Procedures                 |                                              
                           |                                              
Explosion Data             |Contents are not known to be sensitive to     
                           |mechanical impact or static discharge.        
Sensitivity to Mechanical  |                                              
Impact                     |                                              
Sensitivity to Static      |                                              
Discharge                  |                                              
                           |                                              
Specific Hazards from      |                                              
Chemical                   |                                              
                           |                                              
Protective Equipment       |Wear self-contained breathing apparatus to    
                           |protect against toxic decomposition           
                           |by-products, including CO, CO2, NO, and traces
                           |of HCN. Cured foam is organic and, therefore, 
                           |will burn in the presence of sufficient heat, 
                           |oxygen and an ignition source. Main hazards   
                           |associated with burning foam are similar to   
                           |burning of other organic materials (wood,     
                           |paper, cotton, etc.) and precautions against  
                           |exposure should be taken accordingly. Avoid   
                           |welding or other "hot work" in the vicinity of
                           |exposed cured foam.                           
                                                                          
NFPA |Health Hazard: |Flammability: 2|Instability:|Physical Hazard        
     |1              |               |1           |                       
                                                                          
HMIS |Health Hazard: |Flammability: 2|Physical      |PPE:                 
     |1              |               |Hazard: 1     |                     
                                                                          
6.  ACCIDENTAL RELEASE MEASURES                                           
                                                                          
Personal Precautions                                                      
Environmental Precautions                                                 
Methods for Containment                                                   
Methods for Cleaning Up                                                   
Notes: Read all product instructions before using. Personal protective    
equipment should include (impervious gloves, protective eye wear and      
suitable work clothes). Uncured product is very sticky, so carefully      
remove the bulk of the foam by scraping it up and then immediately remove 
residue with a rag and solvent such as polyurethane cleaner, mineral      
spirits, acetone (nail polish remover), paint thinner, etc. Once the      
product has cured, it can only be removed physically by scraping, buffing,
etc. Dispose as plastic waste (foam plastic) in accordance with all       
applicable guidelines and regulations. Before disposing of containers,    
relieve container of any remaining foam and pressure. Allow product to    
fully cure before disposing. Never discard in a liquid state.             
                                                                          
7.  HANDLING AND STORAGE                                                  
                                                                          
Handling                                                                  
Storage: Store in a cool, dry place. Ideal storage temperature is 60 Deg. 
F to 80 Deg. F (15.5 Deg. C to 26.6 Deg. C). Storage above 90 Deg. F (32.2
Deg. C) will shorten the shelf life. Storage below 55 Deg. F (12.7 Deg. C)
may affect foam quality if chemicals are not warmed before using. Protect 
containers from physical abuse. Protect unused product from freezing.     
                                                                          
8.  EXPOSURE CONTROLS/PERSONAL PROTECTION                                 
Read all product instructions before using. Personal protective equipment 
should include impervious gloves, protective eye wear and suitable work   
clothes. Adequate ventilation should also be employed so that vapor levels
do not exceed recommended guidelines. If vapor levels are expected to     
exceed these guidelines, use NIOSH approved, positive pressure, supplied  
air respirator or a negative pressure half mask with organic vapor        
cartridges and dust/mist pre-filters. Exercise good personal hygiene, wash
thoroughly after each use.                                                
Exposure Guidelines                                                       
                                                                          
Chemical Name    |ACGIH TLV    |OSHA PEL      |NIOSH IDLH     |OTHER      
4,4' -           |0.005 ppm TWA|0.020 ppm     |               |           
Diphenylmethane  |             |ceiling       |               |           
Diisocyanate     |0.051 mg/m3  |0.200 mg/m3   |               |           
(MDI)            |TWA          |ceiling       |               |           
Higher Oligomers |None         |None          |               |           
of MDI           |Established  |Established   |               |           
trans-1,1,1,3 -  |None         |None          |               |           
Tetrafluoropropen|Established  |Established   |               |           
e (Non-Flammable |             |              |               |           
Compressed Gas,  |             |              |               |           
HFC Fluorocarbon |             |              |               |           
HFO-1234 Ze)     |             |              |               |           
                                                                          
Engineering Measures                                                      
                                                                          
Personal Protective Equipment                                             
Eyes/Face          |                                                     
Protection         |                                                     
Skin and Body      |                                                     
Protection         |                                                     
Respiratory        |                                                     
Protection         |                                                     
Ventilation/Other  |                                                     
Hygiene Measures                                                          
                                                                          
9.  PHYSICAL AND CHEMICAL PROPERTIES                                      
                                                                          
Appearance       |Viscous      |Odor                |Slight fluorocarbon 
                 |liquid       |                    |                    
Odor Threshold   |             |Physical State      |                    
Color            |             |Viscosity           |                    
pH               |             |Percent  Volatile,  |                    
                 |             |wt. %               |                    
Flash Point      |Approximately|Auto-ignition       |                    
                 |800 Deg. F   |Temperature         |                    
                 |(426.6 Deg.  |                    |                    
                 |C)           |                    |                    
Decomposition    |             |Boiling Point/ Range|-2.2 Deg. F (-19    
Temp             |             |                    |Deg. C)             
                 |             |                    |Other components:   
                 |             |                    |Greater than 200    
                 |             |                    |Deg. F (93.3 Deg. C)
Melting          |             |Freezing Point      |                    
Point/Range      |             |                    |                    
Flammability     |             |Explosion Limits    |                    
Specific Gravity |Approximately|Water Solubility    |Insoluble,          
                 |1.2 (H2O = 1)|                    |liberating traces of
                 |             |                    |CO2.                
Solubility       |             |Evaporation Rate    |                    
Vapor Pressure   |Greater than |Vapor Density       |                    
                 |50 psig / 345|                    |                    
                 |kPa          |                    |                    
VOC content, wt. |             |                    |                    
%                |             |                    |                    
                 |             |                    |                    
Notes                                                                     
                                                                          
10. STABILITY AND REACTIVITY                                              
                                                                          
Chemical Stability        |                                               
Incompatible Products     |                                               
Conditions to avoid       |                                               
Hazardous Decomposition   |                                               
Products                  |                                               
Hazardous Polymerization  |                                               
Notes: This product is considered stable under normal and anticipated     
storage and handling conditions. Do not store above 120 Deg. F (49 Deg.   
C). For longest shelf life, avoid storage above 90 Deg. F (32.2 Deg. C).  
Avoid alcohols, strong bases or amines and metal compounds (such as small 
particle metal catalysts).                                                
                                                                          
11. TOXICOLOGY INFORMATION                                                
                                                                          
Acute Toxicity                                                            
                                                                          
Product          |                                                        
Information      |                                                        
Inhalation      |                                                        
Eye Contact     |                                                        
Skin Contact    |                                                        
Ingestion       |                                                        
                                                                          
Chemical Name   |LD50 Oral      |LD50 Dermal       |LC50 Inhalation      
Trans-1,1,1,3-  |NA             |NA                |NA                   
Tetrafluoroprope|               |                  |                     
ne              |               |                  |                     
(Non-Flammable  |               |                  |                     
Compressed Gas, |               |                  |                     
HFC,            |               |                  |                     
Fluorocarbon)   |               |                  |                     
HFO-1234ze      |               |                  |                     
4,4'            |NA             |NA                |NA                   
-Diphenylmethane|               |                  |                     
Diisocyanate    |               |                  |                     
(MDI)           |               |                  |                     
Higher Oligomers|NA             |NA                |NA                   
of MDI          |               |                  |                     
(Polymeric MDI) |               |                  |                     
Urethane        |NA             |NA                |NA                   
Pre-polymer     |               |                  |                     
Blend (Non-     |               |                  |                     
Hazardous       |               |                  |                     
Proprietary     |               |                  |                     
Blend)          |               |                  |                     
                                                                          
Chronic Toxicity|                                                        
                                                                          
Chemical Name   |ACGIH            |IARC      |NTP          |OSHA          
                |                 |          |             |              
                |                 |          |             |              
                                                                          
Target Organ Effects                                                      
                                                                          
12.  ECOLOGICAL INFORMATION                                               
                                                                          
Ecotoxicity                                                               
The Environmental impact of this product has been fully investigated      
                                                                          
Chemical Name|Toxicity to    |Toxicity to  |Tox, to       |Daphnia Magna   
             |Algea          |Fish         |Microorganisms|(water flea)    
             |               |             |              |                
             |               |             |              |                
             |               |             |              |                
                                                                          
Notes                                                                     
                                                                          
13.  DISPOSAL CONSIDERATIONS                                              
                                                                          
Waste Disposal Methods                                                    
                                                                          
Contaminated Packaging                                                    
                                                                          
US EPA Waste number                                                       
                                                                          
Notes                                                                     
                                                                          
                                                                          
14.  TRANSPORTATION INFORMATION                                           
                                                                          
DOT                                                                       
UN-Number           |UN1956                                               
Proper Shipping name|Compressed Gas n.o.s. (Fluorinated Hydrocarbon,      
                    |Nitrogen)                                            
Hazard Class        |2.2 (Non-Flammable Gas Label)                        
Packing Group       |                                                     
Description         |                                                     
Emergency Response  |                                                     
Guide Number        |                                                     
                                                                          
TDG                                                                       
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
MEX                 |                                                     
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
ICAO                                                                      
UN-Number           |                                                     
Proper Shipping name|                                                     
Hazard Class        |                                                     
Packing Group       |                                                     
Description         |                                                     
                                                                          
IATA                                                                      
UN-Number           |UN1956                                               
Proper Shipping name|Compressed Gas n.o.s. (Fluorinated Hydrocarbon,      
                    |Nitrogen)                                            
Hazard Class        |2.2 (Non-Flammable Gas Label)                        
Packing Group       |                                                     
ERG Code            |                                                     
Description         |                                                     
                                                                          
IMDG/IMO                                                                  
UN-Number           |UN1956                                               
Proper Shipping name|Compressed Gas n.o.s. (Fluorinated Hydrocarbon,      
                    |Nitrogen)                                            
Hazard Class        |2.2 (Non-Flammable Gas Label)                        
Packing Group       |                                                     
EmS No.             |                                                     
Description         |                                                     
                                                                          
RID                                                                       
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
Classification Code|                                                     
Description        |                                                     
ADR/RID-Labels     |                                                     
                                                                          
ADR                                                                       
UN-Number          |                                                     
Proper Shipping    |                                                     
name               |                                                     
Hazard Class       |                                                     
Packing Group      |                                                     
Classification Code|                                                     
Description        |                                                     
ADR/RID-Labels     |                                                     
                                                                          
ADN                                                                       
UN-Number                                                                 
Proper Shipping name                                                      
Hazard Class                                                              
Packing Group                                                             
Classification Code                                                       
Special Provisions                                                        
Description                                                               
Hazard Labels                                                             
Limited Quantity                                                          
                                                                          
15.  REGULATORY INFORMATION                                               
                                                                          
International Inventories                                                 
TSCA: All ingredients are not currently listed on the TSCA inventory, nor 
on the Canadian Domestic Substances List.                                 
DSL                                                                       
EINECS                                                                    
ENCS                                                                      
IECSC                                                                     
PICCS                                                                     
AICS                                                                      
                                                                          
U.S. Federal Regulations                                                  
SARA 313:                                                                 
SARA Title III: Contains Diphenylmethane Diisocyanate (CAS #101-68-8)     
subject to the reporting requirements of SARA Title III. Applicability    
must be determined by the end user.                                       
SARA 311/312 Hazard Categories                                            
Acute Health Hazard                                                       
Chronic Health Hazard                                                     
Fire Hazard                                                               
Sudden Release of Pressure Hazard                                         
Reactive Hazard                                                           
                                                                          
Clean Water Act                                                           
                                                                          
CERCLA                                                                    
                                                                          
U.S. State Regulations: Proposition 65: Based on information currently    
available, this product is not known to contain detectable amounts of any 
chemicals currently listed under California Proposition 65.               
                                                                          
U.S. State Right-to-Know Regulations                                      
                                                                          
International Regulations                                                 
                                                                          
Canada                                                                    
                                                                          
                                                                          
                                                                          
16.  OTHER INFORMATION                                                    
                                                                          
Prepared By:                                                              
Revision Date: January 25, 2012                                           
Company: FOMO PRODUCTS, INC.                                              
Revision number                                                           
Telephone number: 1-800-321-5585                                          
                                                                          
Notes: Information contained herein is deemed to be reliable, conservative
and accurate. FOMO Products, Inc. reserves the right to change the design,
specifications or any other features at any time and without notice, while
otherwise maintaining regulatory compliance.                              
                                                                          
Other Information                                                         
                                                                          
Disclaimer information: The information and recommendations set forth     
herein are presented in good faith and believed to be correct as of the   
date hereof. The manufacturer makes no representations as to the          
completeness or accuracy there of. Information is supplied upon the       
condition that the persons receiving it will make their own determination 
as to its suitability for their purposes prior to use. In no event will   
the manufacturer be responsible for damages of any nature whatsoever      
resulting from the use of or reliance upon information. No representations
or warranties, either expressed or implied, of merchantability or fitness 
for a particular use are made hereunder with respect to this information  
or the product to which information refers.                               
                                                                          
                                                                          
END OF MATERIAL SAFETY DATA SHEET                                         







    

The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.

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