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SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Manus Bond 75-AM UL CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: adhesives / sealant 1.3. Name, Address, and Telephone of the Responsible Party Company Manus Products, Inc. 866 Industrial Blvd. West Waconia, MN 55387 Phone: (952) 442-3323 1.4. Emergency Telephone Number Emergency | (800) 424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Toxic to |Category 2 reproduction | Hazardous to |Category 3 the Aquatic | Environment - | Acute Hazard | Hazardous to |Category 3 the Aquatic | Environment - | Chronic Hazard| 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Health Hazard Signal Word (GHS-US) |WARNING Hazard Statements (GHS-US) |Suspected of damaging fertility or the unborn child |Harmful to aquatic life with long lasting effects Precautionary Statements |Prevention (GHS-US) |Obtain special instructions before use. Do not |handle until all safety precautions have been read |and understood. Wear protective gloves/clothing and |eye/face protection. Avoid release to the |environment. |Response |IF exposed or concerned: Get medical |advice/attention. |Storage |Store locked up. |Disposal |Dispose of contents/container in accordance with |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Calcium Carbonate |1317-65-3 |30-55 | Carbonic acid, calcium salt |471-34-1 |15-25 | (1:1) | | | 1,2-Benzenedicarboxylic acid, |53306-54-0 |5-15 | bis(2-propylheptyl)ester | | | N-[3-(Trimethyoxysilyl)propyl]-1|1760-24-3 |0.5-2 | ,2-ethanediamine | | | Titanium dioxide |13463-67-7 |0.1-1 | Carbon black |1333-86-4 |0.01-0.0| | |9 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: IF INHALED: If breathing is difficult, remove person to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: If a large amount is swallowed, get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Acute: skin irritation and eye irritation. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: skin irritation. Symptoms/Injuries After Eye Contact: eye irritation. Symptoms/Injuries After Ingestion: Chronic Symptoms: reproductive effects 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Treat symptomatically and supportively. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use carbon dioxide, regular dry chemical, regular foam or water. Unsuitable Extinguishing Media: None known. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: May burn, but does not ignite readily. Explosion Hazard: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Move material from fire area if it can be done without risk. Cool containers with water. Avoid inhalation of vapors or combustion by-products. Use extinguishing agents appropriate for surrounding fire. Dike for later disposal. Stay upwind and keep out of low areas Firefighting Instructions: Protection During Firefighting: Firefighters should wear full-face, self-contained breathing apparatus and impervious protective clothing. Firefighters should avoid inhaling any combustion products. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Wear personal protective clothing and equipment, see Section 8. Keep unnecessary people away, isolate hazard area and deny entry. Only personnel trained for the hazards of this material should perform clean up and disposal. Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Ventilate the area. Stop leak if possible without personal risk. Absorb with sand or other non-combustible material. Methods for Cleaning Up: Collect spilled material in appropriate container for disposal. Avoid release to the environment. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Do not handle until all safety precautions have been read and understood. Do not breathe vapor or mist. Avoid contact with skin and eyes. Do not eat, drink, or smoke when using this product. Always wear recommended personal protective equipment. Wear personal protective clothing and equipment, see Section 8. Wash thoroughly after handling. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store and handle in accordance with all current regulations and standards. Keep container tightly closed. Keep separated from incompatible substances. Incompatibilities: strong acids, strong oxidizing materials 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Calcium Carbonate (1317-65-3) OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) NIOSH: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Mexico: 10 mg/m3 TWA LMPE-PPT 20 mg/m3 STEL [LMPE-CT] Carbonic acid, calcium salt (1:1) (471-34-1) NIOSH: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Titanium dioxide (White, Gray, Beige and Neutral only) (13463-67-7) ACGIH: 10 mg/m3 TWA OSHA: 15 mg/m3 TWA (total dust) Mexico: 10 mg/m3 TWA LMPE-PPT (as Ti) 20 mg/m3 STEL [LMPE-CT] (as Ti) Dibutyl tin (818-08-6) ACGIH: 0.1 mg/m3 TWA (as Sn); 0.2 mg/m3 STEL (as Sn) NIOSH: 0.1 mg/m3 TWA (except Cyhexatin, as Sn) Carbon black (*used in Gray and Black ONLY) (1333-86-4) ACGIH: 3 mg/m3 TWA (inhalable fraction) OSHA: 3.5 mg/m3 TWA NIOSH: 3.5 mg/m3 TWA; 0.1 mg/m3 TWA (Carbon black in presence of Polycyclic aromatic hydrocarbons, as PAH) Mexico: 3.5 mg/m3 TWA LMPE-PPT 7 mg/m3 STEL [LMPE-CT] 8.2. Exposure Controls Appropriate Engineering |Provide local exhaust ventilation system. Ensure Controls |compliance with applicable exposure limits. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Glove Recommendations: Wear appropriate chemical |resistant gloves. Eye Protection |Wear splash resistant safety goggles with a |faceshield. Provide an emergency eye wash fountain |and quick drench shower in the immediate work area. Skin and Body Protection |Wear appropriate chemical resistant clothing. Respiratory Protection |Use an approved respirator if exposure limits are |exceeded or if irritation develops or persists. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Paste Odor |Mild Odor Threshold |Not available pH |Not available Relative Evaporation Rate |Not available (butylacetate=1) | Melting Point |Not available Freezing Point | Boiling Point |Not available Flash Point |>200 �F Auto-ignition Temperature |Not available Decomposition Temperature |Not available Flammability (solid, gas) |Not available Vapor Pressure |Not available Relative Vapor Density at 20 �C |Not available Relative Density | Specific Gravity |1.3-1.7 Solubility |Slightly soluble Partition coefficient: | n-octanol/water | Viscosity |Not available Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information VOC: Not available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No reactivity hazard is expected. 10.2 Chemical Stability Stable at normal temperatures and pressure. 10.3 Possibility of Hazardous Reactions Will not polymerize. 10.4 Conditions to Avoid Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials. 10.5 Incompatible Materials strong acids, strong oxidizing materials 10.6 Hazardous Decomposition Products Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Component Analysis - LD50/LC50 The components of this material have been reviewed in various sources and the following selected endpoints are published: Carbonic acid, calcium salt (1:1) (471-34-1) Oral LD50 Rat 6450 mg/kg Titanium dioxide (White, Gray, Beige and Neutral only) (13463-67-7) Oral LD50 Rat >10000 mg/kg Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: No information available for the product. Germ Cell Mutagenicity: No information available for the product. Carcinogenicity: Results of a DuPont epidemiology study showed that employees who had been exposed to titanium dioxide pigments were at no greater risk of developing lung cancer than were employees who had not been exposed to titanium dioxide pigments. No pulmonary fibrosis was found in any of the employees and no associations were observed between titanium dioxide pigment exposure and chronic respiratory disease or lung abnormalities. Based on the results of this study, DuPont concluded that titanium dioxide pigment will not cause lung cancer or chronic respiratory disease in humans at concentrations experienced in the workplace. Reproductive Toxicity: May damage fertility or the unborn child Specific Target Organ Toxicity (Single Exposure): No target organs identified. Specific Target Organ Toxicity (Repeated Exposure): No target organs identified. Aspiration Hazard: No information available for the product. Symptoms/Injuries After Inhalation: May be harmful if inhaled. Symptoms/Injuries After Skin Contact: May cause irritation of the skin. May cause irritation, redness, itching and burning. Symptoms/Injuries After Eye Contact: May cause irritation of the eyes. Contact may cause tearing, redness, a stinging or burning feeling, swelling, and blurred vision. Symptoms/Injuries After Ingestion: May be harmful if swallowed. Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Component Analysis - Aquatic Toxicity Diisononyl phthalate (28553-12-0) Fish: 96 Hr LC50 Brachydanio rerio: >100 mg/L [semi-static]; 96 Hr LC50 Lepomis macrochirus: >0.14 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: >0.17 mg/L [static]; 96 Hr LC50 Pimephalespromelas: >0.19 mg/L [flow-through]; 96 Hr LC50 Pimephales promelas: >0.14 mg/L [static] Algae: 72 Hr EC50 Desmodesmus subspicatus: >500 mg/L; 96 Hr EC50 Pseudokirchneriella subcapitata: >1.8 mg/L [static Invertebrate: 48 Hr EC50 Daphnia magna: >500 mg/L; 48 Hr EC50 Daphnia magna: >0.06 mg/L [Static] 12.2. Persistence and Degradability No information available for the product. 12.3. Bioaccumulative Potential No information available for the product. 12.4. Mobility in Soil No information available for the product. 12.5. Other Adverse Effects SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose in accordance with all applicable federal, state/regional and local laws and regulations. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not regulated as a hazardous material. Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name | Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name | Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan. SARA Section 311/312 Hazard Classes |Acute Health: No |Chronic Health: Yes |Fire: No |Pressure: No |Reactive: No Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA Calcium Carbonate 1317-65-3 No Yes Yes Yes Yes Titanium dioxide 13463-67-7 No Yes Yes Yes Yes Carbon black 1333-86-4 Yes Yes Yes Yes Yes The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains a chemical known to the state of California to cause cancer. WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects. Component Analysis - Inventory Component CAS US CA EU AU PH JP KR CN NZ Calcium Carbonate 1317-65-3 Yes NSL EIN Yes Yes Yes Yes Yes Yes Carbonic acid, calcium salt (1:1) 471-34-1 Yes DSL EIN Yes Yes Yes Yes Yes Yes 1,2-Benzenedicarboxylic acid, bis(2-propylheptyl)ester 53306-54-0 Yes DSL EIN Yes Yes Yes Yes Yes Yes N-[3-(Trimethyoxysilyl)propyl]-1,2-ethanediamine 1760-24-3 Yes DSL EIN Yes Yes Yes Yes Yes Yes Titanium dioxide 13463-67-7 Yes DSL EIN Yes Yes Yes Yes Yes Yes Carbon black 1333-86-4 Yes DSL EIN Yes Yes Yes Yes Yes Yes SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |05/05/15 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.