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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: Manus Bond 75-AM UL                                               
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture: adhesives / sealant                               
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Manus Products, Inc.                                                            
 
866 Industrial Blvd. West                                                       
 
Waconia, MN 55387                                                               
 
Phone: (952) 442-3323                                                           
 


1.4.  Emergency Telephone Number
Emergency     | (800) 424-9300                                                  
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Toxic to      |Category 2    
reproduction  |              
Hazardous to  |Category 3    
the Aquatic   |              
Environment - |              
Acute Hazard  |              
Hazardous to  |Category 3    
the Aquatic   |              
Environment - |              
Chronic Hazard|              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Health Hazard
        
Signal Word (GHS-US)         |WARNING                                           
 
Hazard Statements (GHS-US)   |Suspected of damaging fertility or the unborn
child 
                             |Harmful to aquatic life with long lasting effects 
 
Precautionary Statements     |Prevention                                        
 
(GHS-US)                     |Obtain special instructions before use. Do not    
 
                             |handle until all safety precautions have been read
 
                             |and understood. Wear protective gloves/clothing
and 
                             |eye/face protection. Avoid release to the         
 
                             |environment.                                      
 
                             |Response                                          
 
                             |IF exposed or concerned: Get medical              
 
                             |advice/attention.                                 
 
                             |Storage                                           
 
                             |Store locked up.                                  
 
                             |Disposal                                          
 
                             |Dispose of contents/container in accordance with  
 
                             |local/regional/national/international regulations.
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                           
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Calcium Carbonate               |1317-65-3            |30-55   |                
 
Carbonic acid, calcium salt     |471-34-1             |15-25   |                
 
(1:1)                           |                     |        |                
 
1,2-Benzenedicarboxylic acid,   |53306-54-0           |5-15    |                
 
bis(2-propylheptyl)ester        |                     |        |                
 
N-[3-(Trimethyoxysilyl)propyl]-1|1760-24-3            |0.5-2   |                
 
,2-ethanediamine                |                     |        |                
 
Titanium dioxide                |13463-67-7           |0.1-1   |                
 
Carbon black                    |1333-86-4            |0.01-0.0|                
 
                                |                     |9       |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General:                                                     
 
First-aid Measures After Inhalation: IF INHALED: If breathing is difficult,
remove
person to fresh air and keep at rest in a position comfortable for breathing.
Call
a POISON CENTER or doctor/physician if you feel unwell.                         
 
First-aid Measures After Skin Contact: IF ON SKIN: Wash with plenty of soap and 
 
water. If skin irritation or rash occurs: Get medical advice/attention. Take off
 
contaminated clothing and wash before reuse.                                    
 
First-aid Measures After Eye Contact: IF IN EYES: Rinse cautiously with water
for 
several minutes. Remove contact lenses, if present and easy to do. Continue     
 
rinsing. If eye irritation persists: Get medical advice/attention.              
 
First-aid Measures After Ingestion: If a large amount is swallowed, get
immediate 
medical attention.                                                              
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:  Acute: skin irritation and eye irritation.                  
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact: skin irritation.                          
 
Symptoms/Injuries After Eye Contact: eye irritation.                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms: reproductive effects                                          
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Treat symptomatically and supportively.                                         
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use carbon dioxide, regular dry chemical, regular 
 
foam or water.                                                                  
 
Unsuitable Extinguishing Media: None known.                                     
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: May burn, but does not ignite readily.                             
 
Explosion Hazard: Upon decomposition, this product emits carbon monoxide, carbon
 
dioxide and/or low molecular weight hydrocarbons.                               
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:  Move material from fire area if it can be done    
 
without risk. Cool containers with water. Avoid inhalation of vapors or
combustion
by-products. Use extinguishing agents appropriate for surrounding fire. Dike for
 
later disposal. Stay upwind and keep out of low areas                           
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: Firefighters should wear full-face,
self-contained
breathing apparatus and impervious protective clothing. Firefighters should
avoid 
inhaling any combustion products.                                               
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:                                                               
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment: Wear personal protective clothing and equipment, see
Section
8. Keep unnecessary people away, isolate hazard area and deny entry. Only       
 
personnel trained for the hazards of this material should perform clean up and  
 
disposal.                                                                       
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
                                                                                
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Ventilate the area. Stop leak if possible without personal
risk. 
Absorb with sand or other non-combustible material.                             
 
Methods for Cleaning Up: Collect spilled material in appropriate container for  
 
disposal. Avoid release to the environment.                                     
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Do not handle until all safety precautions
have
been read and understood. Do not breathe vapor or mist. Avoid contact with skin 
 
and eyes. Do not eat, drink, or smoke when using this product. Always wear      
 
recommended personal protective equipment. Wear personal protective clothing and
 
equipment, see Section 8. Wash thoroughly after handling.                       
 
Hygiene Measures:                                                               
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Store and handle in accordance with all current regulations 
 
and standards. Keep container tightly closed. Keep separated from incompatible  
 
substances.                                                                     
 
Incompatibilities: strong acids, strong oxidizing materials                     
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Calcium Carbonate (1317-65-3)                                                   
 
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)              
 
NIOSH: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust)                 
 
Mexico: 10 mg/m3 TWA LMPE-PPT                                                   
 
20 mg/m3 STEL [LMPE-CT]                                                         
 
Carbonic acid, calcium salt (1:1) (471-34-1)                                    
 
NIOSH: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust)                 
 
Titanium dioxide (White, Gray, Beige and Neutral only) (13463-67-7)             
 
ACGIH: 10 mg/m3 TWA                                                             
 
OSHA: 15 mg/m3 TWA (total dust)                                                 
 
Mexico: 10 mg/m3 TWA LMPE-PPT (as Ti)                                           
 
20 mg/m3 STEL [LMPE-CT] (as Ti)                                                 
 
Dibutyl tin (818-08-6)                                                          
 
ACGIH: 0.1 mg/m3 TWA (as Sn); 0.2 mg/m3 STEL (as Sn)                            
 
NIOSH: 0.1 mg/m3 TWA (except Cyhexatin, as Sn)                                  
 
Carbon black (*used in Gray and Black ONLY) (1333-86-4)                         
 
ACGIH: 3 mg/m3 TWA (inhalable fraction)                                         
 
OSHA: 3.5 mg/m3 TWA                                                             
 
NIOSH: 3.5 mg/m3 TWA; 0.1 mg/m3 TWA (Carbon black in presence of Polycyclic     
 
aromatic hydrocarbons, as PAH)                                                  
 
Mexico: 3.5 mg/m3 TWA LMPE-PPT                                                  
 
7 mg/m3 STEL [LMPE-CT]                                                          
 


8.2.  Exposure Controls
Appropriate Engineering      |Provide local exhaust ventilation system. Ensure  
 
Controls                     |compliance with applicable exposure limits.       
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Glove Recommendations: Wear appropriate chemical  
 
                             |resistant gloves.                                 
 
Eye Protection               |Wear splash resistant safety goggles with a       
 
                             |faceshield. Provide an emergency eye wash fountain
 
                             |and quick drench shower in the immediate work
area. 
Skin and Body Protection     |Wear appropriate chemical resistant clothing.     
 
Respiratory Protection       |Use an approved respirator if exposure limits are 
 
                             |exceeded or if irritation develops or persists.   
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                     
 
Appearance                          |Paste                                      
 
Odor                                |Mild                                       
 
Odor Threshold                      |Not available                              
 
pH                                  |Not available                              
 
Relative Evaporation Rate           |Not available                              
 
(butylacetate=1)                    |                                           
 
Melting Point                       |Not available                              
 
Freezing Point                      |                                           
 
Boiling Point                       |Not available                              
 
Flash Point                         |>200 �F                                    
 
Auto-ignition Temperature           |Not available                              
 
Decomposition Temperature           |Not available                              
 
Flammability (solid, gas)           |Not available                              
 
Vapor Pressure                      |Not available                              
 
Relative Vapor Density at 20 �C     |Not available                              
 
Relative Density                    |                                           
 
Specific Gravity                    |1.3-1.7                                    
 
Solubility                          |Slightly soluble                           
 
Partition coefficient:              |                                           
 
n-octanol/water                     |                                           
 
Viscosity                           |Not available                              
 
Lower Flammable Limit               |                                           
 
Upper Flammable Limit               |                                           
 


9.2.  Other Information
VOC: Not available                                                              
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No reactivity hazard is expected.                                               
 


10.2      Chemical Stability
Stable at normal temperatures and pressure.                                     
 


10.3      Possibility of Hazardous Reactions
Will not polymerize.                                                            
 


10.4      Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Avoid contact with    
 
incompatible materials.                                                         
 


10.5      Incompatible Materials
strong acids, strong oxidizing materials                                        
 


10.6      Hazardous Decomposition Products
Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or
low 
molecular weight hydrocarbons.                                                  
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Component Analysis - LD50/LC50                                                  
 
The components of this material have been reviewed in various sources and the   
 
following selected endpoints are published:                                     
 
Carbonic acid, calcium salt (1:1) (471-34-1)                                    
 
Oral LD50 Rat 6450 mg/kg                                                        
 
Titanium dioxide (White, Gray, Beige and Neutral only) (13463-67-7)             
 
Oral LD50 Rat >10000 mg/kg                                                      
 
Skin Corrosion/Irritation:                                                      
 
Serious Eye Damage/Irritation:                                                  
 
Respiratory or Skin Sensitization: No information available for the product.    
 
Germ Cell Mutagenicity: No information available for the product.               
 
Carcinogenicity: Results of a DuPont epidemiology study showed that employees
who 
had been exposed to titanium dioxide pigments were at no greater risk of        
 
developing lung cancer than were employees who had not been exposed to titanium 
 
dioxide pigments. No pulmonary fibrosis was found in any of the employees and no
 
associations were observed between titanium dioxide pigment exposure and chronic
 
respiratory disease or lung abnormalities. Based on the results of this study,  
 
DuPont concluded that titanium dioxide pigment will not cause lung cancer or    
 
chronic respiratory disease in humans at concentrations experienced in the      
 
workplace.                                                                      
 
Reproductive Toxicity: May damage fertility or the unborn child                 
 
Specific Target Organ Toxicity (Single Exposure): No target organs identified.  
 
Specific Target Organ Toxicity (Repeated Exposure): No target organs identified.
 
Aspiration Hazard: No information available for the product.                    
 
Symptoms/Injuries After Inhalation: May be harmful if inhaled.                  
 
Symptoms/Injuries After Skin Contact: May cause irritation of the skin. May
cause 
irritation, redness, itching and burning.                                       
 
Symptoms/Injuries After Eye Contact: May cause irritation of the eyes. Contact
may
cause tearing, redness, a stinging or burning feeling, swelling, and blurred    
 
vision.                                                                         
 
Symptoms/Injuries After Ingestion: May be harmful if swallowed.                 
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
 
environment.                                                                    
 
Component Analysis - Aquatic Toxicity                                           
 
Diisononyl phthalate (28553-12-0)                                               
 
Fish: 96 Hr LC50 Brachydanio rerio: >100 mg/L [semi-static]; 96 Hr LC50 Lepomis 
 
macrochirus: >0.14 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: >0.17
mg/L
[static]; 96 Hr LC50 Pimephalespromelas: >0.19 mg/L [flow-through]; 96 Hr LC50  
 
Pimephales promelas: >0.14 mg/L [static]                                        
 
Algae: 72 Hr EC50 Desmodesmus subspicatus: >500 mg/L; 96 Hr EC50                
 
Pseudokirchneriella subcapitata: >1.8 mg/L [static                              
 
Invertebrate: 48 Hr EC50 Daphnia magna: >500 mg/L; 48 Hr EC50 Daphnia magna:
>0.06
mg/L [Static]                                                                   
 


12.2. Persistence and Degradability
No information available for the product.                                       
 


12.3. Bioaccumulative Potential
No information available for the product.                                       
 


12.4. Mobility in Soil
No information available for the product.                                       
 


12.5. Other Adverse Effects
                                                                                
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose in accordance with all applicable
federal,
state/regional and local laws and regulations.                                  
 
Additional Information:                                                         
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |Not regulated as a hazardous material.                    
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |                                                          
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |                                                          
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
None of this products components are listed under SARA Section 302 (40 CFR 355  
 
Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR     
 
372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety   
 
plan.                                                                           
 
SARA Section 311/312 Hazard Classes |Acute Health: No                           
 
                                    |Chronic Health: Yes                        
 
                                    |Fire: No                                   
 
                                    |Pressure: No                               
 
                                    |Reactive: No                               
 
Toxic Substances Control Act (TSCA) |                                           
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
The following components appear on one or more of the following state hazardous 
 
substances lists:                                                               
 
Component                                                                       
 
CAS                                                                             
 
CA                                                                              
 
MA                                                                              
 
MN                                                                              
 
NJ                                                                              
 
PA                                                                              
 
                                                                                
 
Calcium Carbonate                                                               
 
1317-65-3                                                                       
 
No                                                                              
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
                                                                                
 
Titanium dioxide                                                                
 
13463-67-7                                                                      
 
No                                                                              
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
                                                                                
 
Carbon black                                                                    
 
1333-86-4                                                                       
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
                                                                                
 
                                                                                
 
The following statement(s) are provided under the California Safe Drinking Water
 
and Toxic Enforcement Act of 1986 (Proposition 65):                             
 
WARNING! This product contains a chemical known to the state of California to   
 
cause cancer.                                                                   
 
WARNING! This product contains a chemical known to the state of California to   
 
cause reproductive/developmental effects.                                       
 
                                                                                
 
Component Analysis - Inventory                                                  
 
Component                                                                       
 
CAS                                                                             
 
US                                                                              
 
CA                                                                              
 
EU                                                                              
 
AU                                                                              
 
PH                                                                              
 
JP                                                                              
 
KR                                                                              
 
CN                                                                              
 
NZ                                                                              
 
                                                                                
 
Calcium Carbonate                                                               
 
1317-65-3                                                                       
 
Yes                                                                             
 
NSL                                                                             
 
EIN                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
                                                                                
 
Carbonic acid, calcium salt (1:1)                                               
 
471-34-1                                                                        
 
Yes                                                                             
 
DSL                                                                             
 
EIN                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
                                                                                
 
1,2-Benzenedicarboxylic acid, bis(2-propylheptyl)ester                          
 
53306-54-0                                                                      
 
Yes                                                                             
 
DSL                                                                             
 
EIN                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
                                                                                
 
N-[3-(Trimethyoxysilyl)propyl]-1,2-ethanediamine                                
 
1760-24-3                                                                       
 
Yes                                                                             
 
DSL                                                                             
 
EIN                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
                                                                                
 
Titanium dioxide                                                                
 
13463-67-7                                                                      
 
Yes                                                                             
 
DSL                                                                             
 
EIN                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
                                                                                
 
Carbon black                                                                    
 
1333-86-4                                                                       
 
Yes                                                                             
 
DSL                                                                             
 
EIN                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
Yes                                                                             
 
                                                                                
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |05/05/15                                                       
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
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Grainger disclaimer.

    

The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.

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