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MATERIAL SAFETY DATAT SHEET 3M Auto Glass Urethane (High Modulus/Non-
Conductive), PN 08667 05/13/2002 | |

3M                                                                      
Material Safety Data Sheet                                              
Copyright, 2002, Minnesota Mining and Manufacturing Company. All rights 
reserved. Copying and/or downloading of this information for the purpose
of properly utilizing 3M products is allowed provided that: (1) the     
information is copied in full with no changes unless prior written      
agreement is obtained from 3M, and (2) neither the copy nor the original
is resold or otherwise distributed with the intention of earning a      
profit thereon.                                                         

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION                           

PRODUCT NAME:                       3M Auto Glass Urethane (High       
                                    Modulus/Non-Conductive), PN 08667  
MANUFACTURER:                       3M                                 
DIVISION:                           Automotive Aftermarket                  
ADDRESS:                            3M CENTER                          
                                    St. Paul, MN 55144-1000            
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)            

Issue Date:                         05/13/2002                         
Supercedes Date:                    07/25/2001                         
Document Group:                     16-2135-8                          
Product Use:                                                           
Specific Use:                       Adhesive for windshield bonding and
                                    stationary glass attachment.       

SECTION 2: INGREDIENTS                                                  

Ingredient              C.A.S. No.              % by Wt                
URETHANE POLYMER        68130-40-5              30-60                  
CARBON BLACK            1333-86-4               10-30                  
PHHALATE PLASTICIZER    68515-51-5              10-30                  
CERAMIC MATERIALS AND   66402-68-4              10-30                  
WARES, CHEMICALS                                                       
POLY (VINYL CHLORIDE)   9002-86-2               5-10                   
P,P'-METHYLENEBIS       101-68-8                <1                     
(PHENYL ISOCYANATE)                                                    

SECTION 3: HAZARDS IDENTIFICATION                                       

3.1 EMERGENCY OVERVIEW                                                  
Specific Physical Form:             Paste                              
Odor, Color, Grade:                 Black, Odorless                    
General Physical Form:              Solid                              
Immediate health, physical, and     May cause allergic skin reaction.  
environmental hazards:              May cause allergic respiratory     
                                    reaction. May cause target organ   
                                    effects.. Contains a chemical or   
                                    chemicals which can cause cancer.  
                                    P, P'-METHYLENEBIS (PHENYL         
                                    ISOCYANATE) (101-68-8): Persons    
                                    previously sensitized to an        
                                    isocyanate, or persons with a      
                                    preexisting, non-specific bronchial
                                    hyper reactivity can respond to    
                                    concentrations below the TLV. These
                                    symptoms, which can include chest  
                                    tightness, wheezing, cough,        
                                    shortness of breath, or asthma     
                                    attack, could be immediate or      
                                    delayed (up to several hours after 
                                    exposure).                         
3.2 POTENTIAL HEALTH EFFECTS                                            
Eye Contact:                                                            
Mild Eye Irritation: Signs/symptoms may include redness, swelling, pain,
tearing.                                                                
During grinding, scraping, sanding:                                     
Mechanical eye irritation: Signs/symptoms may include pain, redness,    
tearing and corneal abrasion.                                           
Skin Contact:                                                           
Mild Skin Irritation: Signs/symptoms may include localized redness,     
swelling and itching.                                                   
Prolonged or repeated exposure may cause:                               
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include  
redness, swelling, blistering and itching.                              
Inhalation:                                                             
Respiratory Tract Irritation: Signs/symptoms may include cough,         
sneezing, nasal discharge, headache, hoarseness, and nose and throat    
pain.                                                                   
Allergic Respiratory Reaction: Signs/symptoms may include difficulty    
breathing, wheezing, cough and tightness of chest.                      
Ingestion:                                                              
Ingestion may cause:                                                    
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, 
nausea, vomiting and diarrhea.                                          
Physical Blockage: signs/symptoms may include cramping, abdominal pain  
and constipation.                                                       
Target Organ Effects:                                                   
Persons previously sensitized to isocyanates may develop a              
cross-sensitization reaction to other isocyanates.                      
Carcinogenicity:                                                        
Contains a chemical or chemicals which can cause cancer.                
Ingredient        C.A.S. No.        Class Description Regulation       
CARBON BLACK      1333-86-4         Group 2B          International    
                                                      Agency for       
                                                      Research on      
                                                      Cancer           

SECTION 4: FIRST AID MEASURES                                           

4.1 FIRST AID PROCEDURES                                                
The following first aid recommendations are based on an assumption that 
appropriate personal and industrial hygiene practices are followed.     
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms  
persist, get medical attention.                                         
Skin Contact: Remove contaminated clothing and shoes. Immediately flush 
skin with large amounts of water for at least 15 minutes. If            
signs/symptoms develop, get medical attention. Wash contaminated        
clothing and clean shoes before reuse.                                  
Inhalation: Remove person to fresh air. If signs/symptoms develop, get  
immediate medical attention.                                            
If Swallowed: Do not induce vomiting. Give victim two glasses of water. 
Never give anything by mouth to an unconscious person. Get medical      
attention.                                                              

SECTION 5: FIRE FIGHTING MEASRES                                        

5.1 FLAMMABLE PROPERTIES                                                
Autoignition temperature            [Details: CONDITIONS: Product is   
                                    not self-igniting.] Not Applicable 
Flash Point                         [Details: CONDITIONS: Product is   
                                    not flammable.] Not Applicable     
Flammable Limits-LEL                No Data Available                  
Flammable Limits-UEL                No Data Available                  
5.2 EXTINGUISHING MEDIA                                                 
DO NOT USE WATER                                                        
5.3 PROTECTION OF FIRE FIGHTERS                                         
Special Fire Fighting Procedures: Wear full protective clothing,        
including helmet, self-contained, positive pressure or pressure demand  
breathing apparatus, bunker coat and pants, bands around arms, waist and
legs, face mask, and protective covering for exposed areas of the head. 
Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards
are anticipated.                                                        
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion
and thermal decomposition information.                                  

SECTION 6: ACCIDENTAL RELEASE MEASURES                                  

Accidental Release Measures: Refer to other sections of this MSDS for   
information regarding physical and health hazards, respiratory          
protection, ventilation, and personal protective equipment. Call        
3M-HELPS line (1-800-364-3577) for more information on handling and     
managing the spill. Evacuate unprotected and untrained personnel from   
hazard area. The spill should be cleaned up by qualified personnel.     
Ventilate the area with fresh air. Avoid contact with water. Pour       
isocyanate decontaminant solution (90% water, 8% concentrated ammonia,  
2% detergent) on spill and allow to react for 10 minutes. Or pour water 
on spill and allow to react for more than 30 minutes. Cover with        
absorbent material. Place in a container approved for transportation by 
appropriate authorities, but do not seal the container for 48 hours to  
avoid pressure build-up. Collect as much of the spilled material as     
possible. Collect the resulting residue containing solution. Place in a 
closed container approved for transportation by appropriate authorities.
In the event of a release of this material, the user should determine if
the release qualifies as reportable according to local, state, and      
federal regulations.                                                    

SECTION 7: HANDLING AND STORAGE                                         

7.1 HANDLING                                                            
Keep out of the reach of children. Do not eat, drink or smoke when using
this product. Wash exposed areas thoroughly with soap and water. Avoid  
skin contact. Avoid eye contact. For industrial or professional use     
only.                                                                   
7.2 STORAGE                                                             
Store in a cool place. Store away from heat. Store out of direct        
sunlight. Keep container tightly closed.                                

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                        

8.1 ENGINEERING CONTROLS                                                
Use general dilution ventilation and/or local exhaust ventilation to    
control airborne exposure to below Occupational Exposure Limits and/or  
control dust, fume, or airborne particles.. If ventilation is not       
adequate, use respiratory protection equipment.                         
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)                                 
8.2.1 Eye/Face Protection                                               
Avoid eye contact.                                                      
The following eye protection(s) are recommended: Safety Glasses with    
side shields.                                                           
8.2.2 Skin Protection                                                   
Avoid skin contact.                                                     
Select and use gloves and/or protective clothing to prevent skin contact
based on the results of an exposure assessment. Consult with your glove 
and/or protective clothing manufacturer for selection of appropriate    
compatible materials. Gloves made from the following material (s) are   
recommended: Neoprene, Nitrile Rubber, and Polyethylene.                
8.2.3 Respiratory Protection                                            
Under normal use conditions, airborne exposures are not expected to be  
significant enough to require respiratory protection.                   
8.2.4 Prevention of Swallowing                                          
Do not eat, drink or smoke when using this product. Wash exposed areas  
thoroughly with soap and water.                                         
8.3 EXPOSURE GUIDELINES                                                 
Ingredient       Authority     Type          Limit         Additional   
                                                           Information  
CARBON BLACK     ACGIH         TWA           3.5 mg/m3     Table A4     
CARBON BLACK     CMRG          TWA           0.5 mg/m3                  
CARBON BLACK     OSHA          TWA           3.5 mg/m3     Table Z-1    
FREE ISOCYANATES 3M            TWA           0.005 ppm          
                                                                
FREE ISOCYANATES 3M            STEL          0.02 ppm      Table Z-1    
P,P'-METHYLENEBI ACGIH         TWA           0.0005 ppm                 
S (PHENYL                                                               
ISOCYANATE)                                                             
P,P'-METHYLENEBI OSHA          CEIL          0.02 ppm      Table Z-1    
S (PHENYL                                                               
ISOCYANATE)                                                             
TIN, ORGANIC     ACGIH         TWA- specific 0.1 mg/m3     as Sn; Skin  
COMPOUNDS                      form                        Notation;    
                                                           Table A4     
TIN, ORGANIC     ACGIH         STEL-specific 0.2 mg/m3     as Sn; Skin  
COMPOUNDS                      form                        Notation*    
TIN, ORGANIC     OSHA          TWA-specific  0.1 mg/m3     as Sn; skin  
COMPOUNDS                      form                        Notation;    
                                                           Table Z-1A   
* Substance(s) refer to the potential contribution to the overall       
exposure by the cutaneous route including mucous membrane and eye,      
either by airborne or, more particularly, by direct contact with the    
substance. Vehicles can alter skin absorption.                          

SOURCE OF EXPOSURE LIMIT DATA                                           
ACGIH:                              American Conference of Governmental
                                    Industrial Hygienists              
CMRG:                               chemical Manufacturer Recommended  
                                    Guideline                          
OSHA:                               Occupational Safety and Health     
                                    Administration                     
AIHA:                               American Industrial Hygiene        
                                    Association Workplace Environmental
                                    Exposure Level (WEEL)              


SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                             

Specific Physical Form:             Paste                               
Odor, Color, Grade:                 Black, Odorless                     
General Physical Form:              Solid                               
autoignition temperature:           [Details: CONDITIONS: Product is not
                                    self-igniting.] Not Applicable      
Flash Point                         [Details: CONDITIONS: Product is not
                                    flammable.] Not Applicable          
Flammable Limits-LEL                No Data Available                   
Flammable Limits-UEL                No Data Available                   
Boiling point                       No Data Available                   
Vapor Density                       Not Applicable                      
Vapor Pressure                      Not Applicable                      
Specific Gravity                    1.24 [Ref Std: WATER=1]             
pH                                  Not Applicable                      
Melting point                       No Data Available                   
Solubility in Water                 Nil                                 
Evaporation rate                    Not Applicable
          
Volatile Organic Compounds          0.0 g/l                             
Percent volatile                    No Data Available                   
VOC LESS H2O & Exempt Solvents      0.0 g/l                             
Viscosity                           >=999999 MPa-s                      
                                                                        
SECTION 10: STABILITY AND REACTIVITY                                    
Stability: Stable                              
Materials and conditions to Avoid: Amines; Alcohols; Water; Reaction    
with water, alcohols, and amines is not hazardous if container can vent 
to the atmosphere to prevent pressure buildup.                          
Hazardous Polymerization: Hazardous Polymerization will not occur.      
Hazardous Decomposition or by-Products                                  
Substance                           Condition                           
Isocyanates                         Not Specified                       
Carbon Monoxide                     Not Specified                       
Carbon Dioxide                      Not Specified                       
Hydrogen Chloride                   Not Specified                       
Hydrogen Cyanide                    Not Specified                       
Toxic Vapor, Gas, Particulate       Not Specified                       

SECTION 11: TOXICOLOGICAL INFORMATION                                   

Please contact the address listed on the first page of the MSDS for     
Toxicological information on this material and/or its components.       

SECTION 12: ECOLOGICAL INFORMATION                                      

ECOTOXICOLOGICAL INFORMATION                                            
Not determined.                                                         
CHEMCAL FATE INFORMATION                                                
Not determined.                                                         

SECTION 13: DISPOSAL CONSIDERATIONS                                     

Waste Disposal Method: Do not release to surface or ground water or     
sewers. Incinerate in a permitted hazardous waste incinerator in the    
presence of a combustible material. Combustion products will include    
HC1. Facility must be capable of handling halogenated materials.        
Since regulations vary, consult applicable regulations or authorities   
before disposal.                                                        

SECTION 14: TRANSPORT INFORMATION                                       

ID Number(s):                                                           
60-9800-4512-8, LB-K000-1007-0                                          
Please contact the emergency numbers listed on the first page of the    
MSDS for Transportation Information for this material.                  

SECTION 15: REGULATORY INFORMATION                                      

US FEDERAL REGULATIONS                                                  
Contact 3M for more information.                                        
311/312 Hazard Categories:                                              
Fire Hazard-No  Pressure Hazard-No  Reactivity Hazard-No  Immediate     
Hazard-Yes  Delayed Hazard-Yes                                          
STATE REGULATIONS                                                       
Contact 3M for more information.                                        
CHEMICAL INVENTORIES                                                    
The components of this product are in compliance with the chemical      
notification requirements of TSCA.                                      
All applicable chemical ingredients in this material are listed on the  
European Inventory of Existing Chemical Substances (EINECS), or are     
exempt polymers whose monomers are listed on EINECS.                    
Contact 3M for more information.                                        
Additional Information: Part A used with Part B (MSDS Document          
07-5569-4).                                                             
INTERNATIONAL REGULATIONS                                               
Contact 3M for more information.                                        
WHMIS: Hazardous                                                        

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication  
Standard, 29 CFR 1910.1200.                                             

SECTION 16: OTHER INFORMATION                                           

NFPA Hazard Classification                                              
Health: 2 Flammability: 1 Reactivity: 1 Special Hazards: None           
                                                 
National Fire Protection Association (NFPA) hazard ratings are designed 
for use by firefighters, sheriffs, or other emergency response teams    
whoa are concerned with the hazards of burning or exploding materials.  
These NFPA codes are not intended to address the hazards of this product
other than in a fire situation.                                         

No revision information is available.                                   

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is
believed to be correct as of the date issued. 3M MAKES NO WARRANTIES,   
EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED        
WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR      
COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for        
determining whether the 3M product is fit for a particular purpose and  
suitable for user's method of use or application. Given the variety of  
factors that can affect the use and application of a 3M product, some of
which are uniquely within the user's knowledge and control, it is       
essential that the user evaluate the 3M product to determine whether it 
is fit for a particular purpose and suitable for user's method of use or
application.                                                            
3M provides information in electronic form as a service to its          
customers. Due to the remote possibility that electronic transfer may   
have resulted in errors, omissions or alterations in this information,  
3M makes no representations as to its completeness or accuracy. In      
addition, information obtained from a database may not be as current as 
the information in the MSDS available directly from 3M.                 
3M MSDS are available at www.3M.com                                     


    

The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.

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