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SECTION 1: IDENTIFICATION | |1.1. Product Identifier Product Form: Solid Product Name: No. 100/105/107/110/115 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Petroleum lubricating grease 1.3. Name, Address, and Telephone of the Responsible Party Company LUBRIPLATEÂ® Lubricants Co. 129 Lockwood St. Newark, NJ 07105 Phone: 1-973-589-9150 1.4. Emergency Telephone Number Emergency |CHEM-TEL 1-800-255-3924 (24 hour) number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) SKIN |Category 1 SENSITIZATION | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamation Mark Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |May cause an allergic skin reaction. Precautionary Statements |Prevention: Wear protective gloves. Avoid breathing (GHS-US) |dust. Contaminated work clothing should not be |allowed out of the workplace. |Response: IF ON SKIN: Wash with plenty of soap and |water. Wash contaminated clothing before reuse. If |skin irritation or rash occurs: Get medical |attention. |Storage: Not applicable. |Disposal: Dispose of contents and container in |accordance with all local, regional, national and |international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Defatting to the skin. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Distillates (petroleum), |64742-52-5 |60-100 | hydrotreated heavy naphthenic | | | Zinc oxide |1314-13-2 |5-10 | Zinc bis(dibutyldithiocarbamate)|136-23-2 |0.1-1 | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. First-aid Measures After Skin Contact: Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. First-aid Measures After Ingestion: Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: No known significant effects or critical hazards. Over-exposure signs/symptoms: No specific data. Symptoms/Injuries After Skin Contact: May cause an allergic skin reaction. Over-exposure signs/symptoms: Adverse symptoms may include the following: Irritation, redness. Symptoms/Injuries After Eye Contact: No known significant effects or critical hazards. Over-exposure signs/symptoms: No specific data. Symptoms/Injuries After Ingestion: No known significant effects or critical hazards. Over-exposure signs/symptoms: No specific data. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments: No specific treatment. Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use an extinguishing agent suitable for the surrounding fire. Unsuitable Extinguishing Media: Do not use water jet. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: No specific fire or explosion hazard. Explosion Hazard: Decomposition products may include the following materials: Carbon dioxide, carbon monoxide, metal oxide/oxides, sulfur oxides Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Protection During Firefighting: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Emergency Procedures: 6.2. Environmental Precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Small spill: Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust dispersal. Place spilled material in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Large spill: Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Hygiene Measures: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Ingredient name Exposure limits Distillates (petroleum), hydrotreated heavy naphthenic Zinc oxide ACGIH TLV (United States, 4/2014). TWA: 5 mg/mÂ³ 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2013). TWA: 5 mg/mÂ³ 10 hours. Form: Mist STEL: 10 mg/mÂ³ 15 minutes. Form: Mist OSHA PEL (United States, 2/2013). TWA: 5 mg/mÂ³ 8 hours. NIOSH REL (United States, 10/2013). CEIL: 15 mg/mÂ³ Form: Dust TWA: 5 mg/mÂ³ 10 hours. Form: Dust and fumes STEL: 10 mg/mÂ³ 15 minutes. Form: Fume OSHA PEL 1989 (United States, 3/1989). TWA: 5 mg/mÂ³ 8 hours. Form: Fume STEL: 10 mg/mÂ³ 15 minutes. Form: Fume TWA: 5 mg/mÂ³ 8 hours. Form: Respirable fraction TWA: 10 mg/mÂ³ 8 hours. Form: Total dust OSHA PEL (United States, 2/2013). TWA: 5 mg/mÂ³ 8 hours. Form: Fume TWA: 5 mg/mÂ³ 8 hours. Form: Respirable fraction TWA: 15 mg/mÂ³ 8 hours. Form: Total dust ACGIH TLV (United States, 4/2014). TWA: 2 mg/mÂ³ 8 hours. Form: Respirable fraction STEL: 10 mg/mÂ³ 15 minutes. Form: Respirable fraction 8.2. Exposure Controls Appropriate Engineering |Good general ventilation should be sufficient to Controls |control worker exposure to airborne contaminants. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Chemical-resistant, impervious gloves complying with |an approved standard should be worn at all times |when handling chemical products if a risk assessment |indicates this is necessary. Considering the |parameters specified by the glove |manufacturer,check during use that the gloves are |still retaining their protective properties. It |should be noted that the time to breakthrough for |any glove material may be different for different |glove manufacturers. In the case of mixtures, |consisting of several substances, the protection |time of the gloves cannot be accurately estimated. Eye Protection |Safety eyewear complying with an approved standard |should be used when a risk assessment indicates |this is necessary to avoid exposure to liquid |splashes, mists, gases or dusts. If contact is |possible, the following protection should be worn, |unless the assessment indicates a higher degree of |protection: safety glasses with side-shields. Skin and Body Protection |Body Protection: Personal protective equipment for |the body should be selected based on the task being |performed and the risks involved and should be |approved by a specialist before handling this |product. |Other Skin Protection: Appropriate footwear and any |additional skin protection measures should be |selected based on the task being performed and the |risks involved and should be approved by a |specialist before handling this product. Respiratory Protection |Use a properly fitted, particulate filter respirator |complying with an approved standard if a risk |assessment indicates this is necessary. Respirator |selection must be based on known or anticipated |exposure levels, the hazards of the product and the |safe working limits of the selected respirator. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Solid. [grease] Appearance | Odor |Mineral oil Odor Threshold |Not available. pH |Not available. Relative Evaporation Rate |<0.01 (butyl acetate = 1) (butylacetate=1) | Melting Point |Not available. Freezing Point | Boiling Point |>288Â°C (>550.4Â°F) Flash Point |Open cup: 182Â°C (359.6Â°F) [Cleveland.] Auto-ignition Temperature |Not available. Decomposition Temperature |Not available. Flammability (solid, gas) |Not available. Vapor Pressure |Not available. Relative Vapor Density at 20 Â°C |Not available. Relative Density |0.89 to 0.93 [Water = 1] Specific Gravity | Solubility |Insoluble in the following materials: cold |water and hot water. Partition coefficient: |Not available. n-octanol/water | Viscosity |Kinematic (40Â°C (104Â°F)): 0.58 cm2/s (58 cSt) Lower Flammable Limit |Lower: 0.9% Upper Flammable Limit |Upper: 7% | 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No specific test data related to reactivity available for this product or its ingredients. 10.2 Chemical Stability The product is stable. 10.3 Possibility of Hazardous Reactions Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous polymerization will not occur. 10.4 Conditions to Avoid Keep away from heat, sparks and flame. Keep away from all sources of ignition. 10.5 Incompatible Materials Reactive or incompatible with the following materials: oxidizing materials. Chlorine. 10.6 Hazardous Decomposition Products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: May cause an allergic skin reaction. Serious Eye Damage/Irritation: No known significant effects or critical hazards. Respiratory or Skin Sensitization: Not available. No known significant effects or critical hazards. Germ Cell Mutagenicity: Not available. Carcinogenicity: Not available. Reproductive Toxicity: Not available. Specific Target Organ Toxicity (Single Exposure): Name Category Route of Exposure Target organs Zinc bis(dibutyldithiocarbamate) Category 3 Not applicable Respiratory tract irritation Specific Target Organ Toxicity (Repeated Exposure): Not available. Aspiration Hazard: Name Result Distillates (petroleum), hydrotreated heavy naphthenic ASPIRATION HAZARD - Category 1 Symptoms/Injuries After Inhalation: No specific data. Symptoms/Injuries After Skin Contact: Adverse symptoms may include the following: Irritation redness Symptoms/Injuries After Eye Contact: No specific data. Symptoms/Injuries After Ingestion: No specific data Chronic Symptoms: Not available. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Product/ingredient name Result Species Exposure Zinc oxide Zinc bis (dibutyldithiocarbamate) Acute EC50 0.042 mg/l Fresh water Acute LC50 98 ?g/l Fresh water Acute LC50 1.1 ppm Fresh water Chronic NOEC 0.017 mg/l Fresh water Acute EC50 0.74 mg/l Acute LC50 520 mg/l Algae - Pseudokirchneriella subcapitata - Exponential growth phase Daphnia - Daphnia magna - Neonate Fish - Oncorhynchus mykiss Algae - Pseudokirchneriella subcapitata - Exponential growth phase Daphnia - Daphnia magna Fish - Oncorhynchus mykiss 72 hours 48 hours 96 hours 72 hours 48 hours 96 hours 12.2. Persistence and Degradability Not available. 12.3. Bioaccumulative Potential Product/ingredient name LogPow BCF Potential Zinc oxide - 60960 high 12.4. Mobility in Soil Not available. 12.5. Other Adverse Effects No known significant effects or critical hazards. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not regulated. Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (zinc |oxide). Marine pollutant (zinc oxide) Hazard Class |9 Identification Number|UN3077 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | |[pic] [pic] Substance/m | | EmS-No. (Fire) |F-A | EmS-No. (Spillage) |S-F | 14.3 In Accordance with IATA Proper Shipping Name |Environmentally hazardous substance, solid, n.o.s. (zinc |oxide) Identification Number|UN3077 |<PICTOGRAM PHRASE> | |[pic] [pic] | | Hazard Class |9 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Clean Water Act (CWA) 307: zinc oxide; zinc bis(dibutyldithiocarbamate) Clean Water Act (CWA) 311: sodium hydroxide SARA 313 Product name CAS number % Form R - Reporting zinc oxide 1314-13-2 5-10 Requirements zinc oxide 1314-13-2 5-10 Supplier notification SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. SARA Section 311/312 Hazard Classes |Immediate (acute) health hazard Composition/information on ingredients Name % Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Distillates (petroleum), hydrotreated heavy naphthenic Zinc oxide Zinc bis(dibutyldithiocarbamate) 60-100 5-10 0.1-1 No. No. Yes. No. No. No. No. No. No. Yes. Yes. Yes. No. No. No. Toxic Substances Control Act (TSCA) |All components are listed or exempted. 15.2 US State Regulations <COMPONENT> Massachusetts: The following components are listed: ZINC OXIDE FUME New York : None of the components are listed. New Jersey : The following components are listed: MINERAL OIL (HIGHLY REFINED); OIL MIST, MINERAL; ZINC OXIDE Pennsylvania : The following components are listed: ZINC OXIDE (ZNO) California Prop. 65 WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer. Ingredient name Cancer Reproductive No significant risk Maximum level acceptable dosage Level crystalline silica non-respirable Yes. No No No SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |01/22/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.