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Sheet 0076540 Printer Friendly View
Safety Data Sheet
Date of Issue: |Revision Date: 7/29/2014 |Revision Number:
Imperial Supplies Part Number: 0076540
SECTION 1: IDENTIFICATION
1.1. Product Identifier
Product Form:
Product Name: BMC & SMC Polyester / Vinyl Ester Thermoset Molding Compounds
CAS No:
Synonyms: FibaRoll/FibaClad
1.2. Intended Use of the Product
Use of the substance/mixture:
1.3. Name, Address, and Telephone of the Responsible Party
Company
FTI-US
119 East Main Street, P.O. Box 589
Independence
VA
24348
Phone: (276) 773-2902
1.4. Emergency Telephone Number
Emergency |(276) 773-2902
number |
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
Classification (GHS-US)
|
|
|
2.2. Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) | | | | | |
Signal Word (GHS-US) |
Hazard Statements (GHS-US) |
Precautionary Statements |
(GHS-US) |
2.3. Other Hazards
Other Hazards Not Contributing to the Classification:
2.4. Unknown Acute Toxicity (GHS-US)
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
Name |Product identifier |% |Classification
| | |(GHS-US)
| | |
| | |
| | |
| | |
| | |
Full text of H-phrases: See Section 16
3.2. Mixture
Name |Product identifier |% |Classification
| | |(GHS-US)
FIBERGLASS | |01-65% |
MINERAL FILLERS | |20-80% |
POLYESTER RESIN | |0-40% |
VINYL ESTER RESIN | |10-40% |
POLYETHELENE / POLYSTYRENE | |0-15% |
STYRENE MONOMER |100-42-5 |01-20% |
SECTION 4: FIRST AID MEASURES
4.1. Description of First Aid Measures
First-aid Measures General:
First-aid Measures After Inhalation: Remove To Fresh Air. Administer Oxygen If
There Is Difficulty In Breathing.
First-aid Measures After Skin Contact: WASH WITH SOAP AND WATER.
First-aid Measures After Eye Contact: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES.
First-aid Measures After Ingestion:
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:
Symptoms/Injuries After Inhalation: BREATHING: DIZZINESS, NAUSEA.
Symptoms/Injuries After Skin Contact: IRRITATION, DEFATTING
Symptoms/Injuries After Eye Contact: IRRITATION, BLURRED VISION, TEARING.
Symptoms/Injuries After Ingestion:
Chronic Symptoms:
4.3. Indication of Any Immediate Medical Attention and Special Treatment
Needed
SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media:
Unsuitable Extinguishing Media:
5.2. Special Hazards Arising From the Substance or Mixture
Fire Hazard:
Explosion Hazard: EXTENDED HIGH TEMPERATURES CAN RESULT IN EXOTHERMIC
POLYMERIZATIN, GIVING OFF PEROXIDES. AVOID GENERATING DUST; FINE DUST DISPERSED IN
AIR IN SUFFICIENT CONCERNTRATIONS, AND IN THE PRESENTS OF AN IGNITION SOURCE IS A
POTENTIAL DUSTEXPLOSION HAZARD.
Reactivity:
5.3. Advice for Firefighters
Precautionary Measures Fire:
Firefighting Instructions: RECOMMEND PROTECTIVE CLOTHING, FULL FACE SELF CONTAINED
MSHA/NIOSH APPROVED BREATHING APPARATUS.
Protection During Firefighting:
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
General Measures:
6.1.1. For Non-emergency Personnel
Protective Equipment:
Emergency Procedures:
6.1.2. For Emergency Responders
Protective Equipment:
Emergency Procedures:
6.2. Environmental Precautions
6.3. Methods and Material for Containment and Cleaning Up
For Containment:
Methods for Cleaning Up: WHERE EXPOSURE LEVEL IS NOT KNOWN, WEAR NIOSH APPROVED,
POSITIVE PRESSURE, SELF-CONTAINED RESPIRATOR. WHERE EXPOSURE LEVEL IS KNOWN, WEAR
NIOSH APPROVED RESPIRATOR SUITABLE FOR LEVEL OF EXPOSURE. WEAR SAME PROTECTIVE
CLOTHING / EQUIPMENT AS IN SECTION 8 (EXPOSURE CONTROLS / PERSONAL PROTECTION).
SWEEP UP SPILLS AND PLACE IN A WASTE DISPOSAL CONTAINER. FLUSH AREA WITH WATER.
ELIMINATE SOURCES OF IGNITION AND VENILATE. DUST DEPOSITS SHOULD NOT BE ALLOWED TO
ACCUMULATE ON SURFACES, AS THESE MAY FORM AN EXPLOSIVE MIXTURE IF THEY ARE
RELEASED INTO THE ATMOSPHERE IN SUFFICIENT CONCENTRATION. AVOID DISPERSAL OF DUST
IN THE AIR (I.E., CLEARING DUST SURFACES WITH COMPRESSED AIR).
6.4. Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Additional Hazards When Processed: AVOID BREATHING DUST. AVOID CONTACT WITH EYES,
SKIN, AND CLOTHING. WASH THOROUGHLY AFTER HANDLING.
OTHER PRECAUTIONS: MAY CAUSE NUISANCE DUST UPON GRINDING OF MOLDED MATERIAL.
MINIMIZE DUST GENERATION AND ACCUMULATION. ROUTINE HOUSEKEEPING SHOULD BE
INSTITUTED TO ENSURE THAT DUSTS DO NOT ACCUMULATE ON SURFACES. DRY POWDERS CAN
BUILD STATIC ELECTRICITY CHARGES WHEN SUBJECTED TO THE FRICTION OF TRANSFER AND
MIXING OPERATIONS. PROVIDE ADEQUATE PRECAUTIONS, SUCH AS ELECTRICAL GROUNDING AND
BONDING, OR INERT ATMOSPHERES.
Hygiene Measures:
7.2. Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:
Storage Conditions: FOR MAXIMUM STORAGE LIFE AND TO MAINTAIN MOLDABILITY, STORE AT
BELOW 70 �F (22�C). THESE COMPOUNDS ARE PACKAGED IN SPECIAL BAGS IMPERMEABLE TO
STYRENE OR VINYL TOLUENE. DO NOT PUNCTURE BAG. CLOSE TIGHTLY AFTER PARTIAL USE.
7.3. Specific End Use(s)
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
8.2. Exposure Controls
Appropriate Engineering |ENGINEERING CONTROLS ARE NOT USUALLY NECESSARY IF
Controls |GOOD HYGIENE PRACTICES ARE FOLLOWED. BEFORE EATING,
|DRINKING, OR SMOKING, WASH FACE AND HANDS THOROUGHLY
|WITH SOAP AND WATER. AVOID UNNECESSARY SKIN CONTACT.
|IMPERVIOUS GLOVES AND APRON ARE RECOMMENDED TO
|PREVENT SKIN CONTACT. FOR OPERATIONS WHERE EYE OR
|FACE CONTACT CAN OCCUR, WEAR EYE PROTECTION SUCH AS
|CHEMICAL SPLASH-PROOF GOGGLES OR FACE SHIELD. WHERE
|EXPOSURES ARE BELOW THE PERMISSIBLE EXPOSURE LIMIT
|(PEL), NO RESPIRATORY PROTECTION IS REQUIRED. WHERE
|EXPOSURES EXCEED THE PEL, USE RESPIRATOR APPROVED BY
|NIOSH FOR THE MATERIAL AND LEVEL OF EXPOSURE. SEE
|"GUIDE TO INDUSTRIAL RESPIRATORY PROTECTION"
|(NIOSH). SINCE THIS MATERIAL CONTAINS A COMPONENT
|WITH A SKIN NOTATION WITH A PEL AS SHOWN IN THE
|REGULATED COMPONENTS SECTION, ADDITIONAL SKIN
|PROTECTION SUCH AS A PROTECTIVE SUIT OR CLOTHING MAY
|BE REQUIRED. CUTTING, GRINDING, OR SANDING OF PARTS
|FABRICATED AFTER CURING OF THIS MATERIAL MAY CREATE
|RESPIRABLE DUST PARTICLES. RESPIRATORY PROTECTION
|APPROPRIATE FOR THIS DUST MAY BE REQUIRED. REFER TO
|THE REGULATED COMPONENT SECTION FOR POTENTIAL
|HAZARDOUS COMPONENTS IN THE DUST. GLOVES,
|LONG-SLEEVE SHIRT AND SAFETY GLASSES ARE RECOMMENDED
|TO PREVENT CONTACT WITH ANY DUST PARTICLES
|GENERATED.
Personal Protective Equipment|
Materials for Protective |
Clothing |
Hand Protection |
Eye Protection |SAFETY GLASSES/GOGGLES TO PROTECT AGAINST DRY
|PARTICLES.
Skin and Body Protection |IMPERVIOUS AND ABRAISON RESISTANT.
|OTHER PROTECTIVE CLOTHING OR EQUIPMENT: NONE -
|RECOMMEND USING GOOD INDUSTRIAL HYGENE PRACTICES.
Respiratory Protection |NONE IF TLV /PEL NOT EXCEEDED.
Thermal Hazard Protection |
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
Physical State |
Appearance |FLEXIBLE, SOFT SHEETS OR DOUGHY COMPOUND,
|PUNGENT ODOR. A SOFT, TACKY, FIBROUS MATERIAL
|OF VARIOUS COLORS. PHYSICAL STATE - SOLID.
Odor |CHARACTERISTIC ODOR OF STYRENE OR VINYL
|TOLUENE.
Odor Threshold |
pH |
Relative Evaporation Rate (butyl |0.00
acetate=1) |
Melting Point |N/A
Freezing Point |N/A
Boiling Point |N/A
Flash Point |N/A
Auto-ignition Temperature |N/A
Decomposition Temperature |
Flammability (solid, gas) |
Vapor Pressure |4.5 (STYRENE)
Relative Vapor Density at 20 �C |3.6 (STYRENE)
Relative Density |
Specific Gravity |1.7-2.2
Solubility |NEGLIGIBLE
Partition coefficient: |
n-octanol/water |
Viscosity |
Lower Flammable Limit |1.1%
Upper Flammable Limit |-6.1%
9.2. Other Information
NONE GIVEN
SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity
10.2 Chemical Stability
THE CHEMICAL IS STABLE UNDER NORMAL HANDLING AND STORAGE CONDITIONS.
10.3 Possibility of Hazardous Reactions
10.4 Conditions to Avoid
HIGH TEMPERATURES WILL INDUCE NON-VIOLENT POLYMERIZATION.
10.5 Incompatible Materials
PEROXIDES AND POLYMERIZATION CATALYST. CARBON MONOXIDE & CARBON
10.6 Hazardous Decomposition Products
CO AND HYDROCARBONS
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects
Acute Toxicity: HAZARDS IDENTIFICATION. TOXICOLOGICAL INFORMATION ON THE OSHA
REGULATED COMPONENTS OF THIS PRODUCT ARE AS FOLLOWS: STYRENE HAS AN ACUTE ORAL
LD50 (RAT) OF 5 G/KG. THE INHALATION LC50 (RAT) IS 24 MG/L FOLLOWING A 4-HOUR
EXPOSURE. ACUTE OVEREXPOSURE TO STYRENE VAPOR MAY CAUSE MODERATE EYE AND NASAL
IRRITATION AS WELL AS DROWSINESS, HEADACHE AND CENTRAL NERVOUS SYSTEM DEPRESSION.
STYRENE IS A MODERATE SKIN AND EYE IRRITANT. STYRENE HAS BEEN SHOWN TO CAUSE LUNG
TUMORS IN MICE. EPIDEMIOLOGICAL STUDIES OF STYRENE EXPOSURE IN HUMANS IS NOT
CONCLUSIVE DUE TO THE INADEQUATE CONTROL OF VARIABLES. ACUTE ORAL (RAT) AND DERMAL
(RABBIT) LD (50) VALUES ARE ESTIMATED TO GREATER THAN 5,000 MG/ KG AND GREATER
THAN 2,000 MG/KG, RESPECTIVELY. THE 4-HOUR INHALATION LC 50 (RAT) VALUE IS
ESTIMATED TO BE GREATER THAN 20 MG/L. DIRECT CONTACT WITH THIS MATERIAL MAY CAUSE
MINIMAL EYE AND SKIN IRRITATION. INHALATION OVEREXPOSURE MAY CAUSE IRRITATION OF
THE RESPIRATORY TRACT AND EYES. REFER TO SECTION 11 FOR TOXICOLOGY INFORMATION ON
THE OSHA REGULATED COMPONENTS OF THIS PRODUCT. INHALATION OVEREXPOSURE TO ZINC
STEARATE, ALUMINA TRIHYDRATE, KAOLIN, CALCIUM METASILICATE, GLASS, MICA,
FIBERGLASS, CELLULOSE, IRON OXIDE, CARBON BLACK, AND TALC MAY CAUSE RESPIRATORY
CONGESTION AND IRRITATION.
Skin Corrosion/Irritation:
Serious Eye Damage/Irritation:
Respiratory or Skin Sensitization:
Germ Cell Mutagenicity:
Carcinogenicity:
Reproductive Toxicity:
Specific Target Organ Toxicity (Single Exposure):
Specific Target Organ Toxicity (Repeated Exposure):
Aspiration Hazard:
Symptoms/Injuries After Inhalation:
Symptoms/Injuries After Skin Contact:
Symptoms/Injuries After Eye Contact:
Symptoms/Injuries After Ingestion:
Chronic Symptoms:
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
12.2. Persistence and Degradability
12.3. Bioaccumulative Potential
12.4. Mobility in Soil
12.5. Other Adverse Effects
NO APPLICABLE INFORMATION WAS FOUND.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: THE INFORMATION OF RCRA WASTE CLASSIFICATION AND
DISPOSAL METHODOLOGY PROVIDED BELOW APPLIES ONLY TO THE IDI PRODUCT, AS SUPPLIED.
IF THE MATERIAL HAS BEEN ALTERED OR CONTAMINATED, OR IT HAS EXCEEDED ITS
RECOMMENDED SHELF LIFE, THE GUIDANCE MAY BE INAPPLICABLE, HAZARDOUS WASTE
CLASSIFICATION UNDER FEDERAL REGULATIONS (40 CFR PART 261 ET SEQ) IS DEPENDENT
UPON WHETHER A MATERIAL IS A RCRA "LISTED HAZARDOUS WASTE" OR HAS ANY OF THE FOUR
RCRA "HAZARDOUS WASTE CHARACTERISTICS". REFER TO 40 CFR PART 261.33 TO DETERMINE
IF A GIVEN MATERIAL TO BE DISPOSED OF IS RCRA "LISTED HAZARDOUS WASTE";
INFORMATION CONTAINED IN SECTION 15 OF THIS MSDS IS NOT INTENDED TO INDICATE IF
THE PRODUCT IS A "LISTED HAZARDOUS WASTE" OR HAS A RCRA HAZARDOUS WASTE
CHARACTERISTIC. THERE ARE FOUR CHARACTERISTICS DEFINED IN 40 CFR SECTION
261.21-61.24: IGNITABILITY, CORROSIVITY, REACTIVITY, AND TOXICITY. TO DETERMINE
IGNITABILITY, SEE SECTION 5 OF THIS MSDS (FLASH POINT). FOR CORROSIVITY, SEE
SECTION 9 AND 14 (PH AND DOT CORROSIVITY). FOR REACTIVITY, SEE SECTION 10
(INCOMPATIBLE MATERIALS). FOR TOXICITY, SEE SECTION 2 (COMPOSITION). FEDERAL
REGULATIONS ARE SUBJECT TO CHANGE. STATE AND LOCAL REQUIREMENTS, WHICH MAY DIFFER
FROM OR BE MORE STRINGENT THAN THE FEDERAL REGULATION, MAY ALSO APPLY TO THE
CLASSIFICATION OF THE MATERIAL IF IT IS TO BE DISPOSED. IDI ENCOURAGES THE
RECYCLE, RECOVERY AND REUSE OF MATERIALS, WHERE PERMITED, AS AN ALTERNATE TO
DISPOSED AS A WASTE. IDI RECOMMENDS THAT ORGANIC MATERIAL CLASSIFIED AS RCRA
PROVIDED THE FOREGOING FOR INFORMATION ONLY; THE PERSON GENERATING THE WASTE IS
RESPONSIBLE FOR DETERMINING THE WASTE CLASSIFICATIONS AND DISPOSAL METHOD.
Additional Information:
SECTION 14: TRANSPORT INFORMATION
14.1 In Accordance with DOT
Proper Shipping Name |
Hazard Class | |<PICTOGRAM PHRASE>
Identification Number| |
Label Codes | |
ERG Number |
14.2 In Accordance with IMDG
Proper Shipping Name |
Hazard Class |
Identification Number|
Label Codes | |<PICTOGRAM PHRASE>
ntification Of The | |
Substance/m | |
EmS-No. (Fire) | |
EmS-No. (Spillage) | |
14.3 In Accordance with IATA
Proper Shipping Name |
Identification Number| |<PICTOGRAM PHRASE>
Hazard Class | |
Label Codes | |
ntification Of The | |
Substance/m | |
ERG Code (IATA) |
SECTION 15: REGULATORY INFORMATION
15.1 US Federal Regulations
<COMPONENT>
SARA Section 311/312 Hazard Classes |
Toxic Substances Control Act (TSCA) |THIS PRODUCT IS MANUFACTURED IN COMPLIANCE
|WITH ALL PROVISIONS OF THE TOXIC SUBSTANCES
|CONTROL ACT, 15 U.S.C. 2601 ET. SEQ.
15.2 US State Regulations
<COMPONENT>
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision date |7/29/2014
Other |This document has been prepared in accordance with the SDS
Information |requirements of the OSHA Hazard Communication Standard 29 CFR
|1910.1200.
GHS Full Text Phrases:
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Grainger disclaimer.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance. |