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SDS Sheet 0076360Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: 7636-0 CUTTING TOOL LUBRICANT CAS No: Synonyms: None 1.2. Intended Use of the Product Use of the substance/mixture: Air Tool Lubricant. 1.3. Name, Address, and Telephone of the Responsible Party Company: Imperial Supplies LLC 789 Armed Forces Drive P.O. Box 11008 Green Bay, WI 53407-1038 Phone: 1.4. Emergency Telephone Number Emergency | 1-800-424-9300 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin |Category 2 corrosion/irri| tation | Serious eye |Category 1 damage/eye | irritation | Carcinogenicit|Category 2 y | Specific |Category 2 target organ | toxicity | (repeated | exposure) | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Health Hazard |Corrosion Signal Word (GHS-US) |DANGER Hazard Statements (GHS-US) |Causes skin irritation |Causes serious eye damage |Suspected of causing cancer |May cause damage to organs (Eyes, Respiratory |System, and Skin) through prolonged or repeated |exposure. Precautionary Statements |Prevention (GHS-US) |Obtain special instructions before use |Wear protective gloves/protective clothing/eye |protection/face protection |Do not handle until all safety precautions have been |read and understood |Wash face, hands and any exposed skin thoroughly |after handling |Do not breathe dust/fume/gas/mist/vapors/spray |Response |If exposed or concerned: Get medical |advice/attention |Specific treatment (see first aid on this label) |IF IN EYES: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. |Immediately call a POISON CENTER or |doctor/physician. |IF ON SKIN: Wash with plenty of soap and water. |Take off contaminated clothing and wash before reuse | |If skin irritation occurs: Get medical |advice/attention |Storage |Store locked up |Disposal |Dispose of contents/container to an approved waste |disposal plant 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) Harmful to aquatic life with long lasting effects 0% of the mixture consists of ingredient(s) of unknown toxicity SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) DIETHANOLAMINE |111-42-2 |5-15 | | | | | | | | | | | | | *The exact percentage (concentration) of composition has been withheld as a trade secret. SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Avoid contact with eyes,skin, and clothing.Avoid breathing, vapors,mist,or gas. First-aid Measures After Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing has stopped, contact emergency medical services immediately. First-aid Measures After Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. Get medical attention immediately if symptoms occur. First-aid Measures After Eye Contact: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Seek immediate medical attention/advice. First-aid Measures After Ingestion: Do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: May cause respiratory irritation. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes eye irritation. Symptoms/Injuries After Ingestion: May be harmful if swallowed. Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media: Decomposition by contact with water may generate vapors which can be ignited by heat or open flame. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: No information available. Explosion Hazard: Sensitivity to Mechanical Impact: none. Sensitivity to Static Discharge: none. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Protection During Firefighting: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Evacuate personnel to safe areas. Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Avoid dust formation. Keep people away from and upwind of spill/leak. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Should not be released into the environment. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up: Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Clean contaminated surface thoroughly. After cleaning, flush away traces with water. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Keep away from open flames, hot surfaces and sources of ignition. Wear personal protective equipment. Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition. Keep in properly labeled containers. Keep out of the reach of children. Store locked up. Incompatible products: Strong acids, alkalis, or oxidizing agents. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH DIETHANOLAMINE 111-42-2 TWA: 1 mg/m3 inhalable fraction and vapor Skin - potential significant contribution to overall exposure by the cutaneous route (vacated) TWA: 3 ppm (vacated) TWA: 15 mg/m3 TWA: 3 ppm TWA: 15 mg/m3 Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). 8.2. Exposure Controls Appropriate Engineering |Showers, Eyewash stations, Ventilation systems. Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection | Eye Protection |Safety glasses with side-shields. Skin and Body Protection |Chemical resistant apron. Protective gloves. Respiratory Protection |If exposure limits are exceeded or irritation is |experienced, NIOSH/MSHA approved respiratory |protection should be worn. Positive-pressure |supplied air respirators may be required for high |airborne contaminant concentrations. Respiratory |protection must be provided in accordance with |current local regulations. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Clear Odor |Mild Odor Threshold |No information available pH |9.5 Relative Evaporation Rate |No information available (butylacetate=1) | Melting Point |No information available Freezing Point |No information available Boiling Point |No information available Flash Point |No information available Auto-ignition Temperature |No information available Decomposition Temperature |No information available Flammability (solid, gas) |No information available Vapor Pressure |No information available Relative Vapor Density at 20 Â°C | Relative Density |No information available Specific Gravity |1.02 Solubility | Partition coefficient: |No information available n-octanol/water | Viscosity |No information available Lower Flammable Limit |No information available Upper Flammable Limit |No information available 9.2. Other Information VOC Content(%): 10 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical Stability Stable under recommended storage conditions. 10.3 Possibility of Hazardous Reactions None under normal processing. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Strong acids, alkalis, or oxidizing agents. 10.6 Hazardous Decomposition Products None known based on information supplied. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Irritating to skin. Repeated exposure may cause skin dryness or cracking. Prolonged skin contact may defat the skin and produce dermatitis. Avoid contact with skin. Serious Eye Damage/Irritation: causes serious eye damage. Avoid contact with eyes. Respiratory or Skin Sensitization: Avoid breathing vapors or mists. Vapors may irritate throat and respiratory system. May cause drownsiness and dizziness based on components. May cause irritation of respiratory tract. Germ Cell Mutagenicity: None known. Carcinogenicity: Chemical Name ACGIH IARC NTP OSHA DIETHANOLAMINE 111-42-2 - 2B - x Reproductive Toxicity: This product does not contain any known or suspected reproductive hazards. Specific Target Organ Toxicity (Single Exposure): May cause respiratory irritation. May cause drowsiness and dizziness. Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure. Aspiration Hazard: Not applicable. Symptoms/Injuries After Inhalation: Causes respiratory system irritation. Symptoms/Injuries After Skin Contact: Irritating to skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Symptoms/Injuries After Eye Contact: Irritating to eyes. Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways. Chronic Symptoms: Skin corrosion/irritation: Irritating to skin. Eye damage/irritation: Causes severe eye damage . Irritation: Irritating to respiratory system and skin. Corrosivity: Risk of serious damage to eyes. Sensitization: None known. Germ Cell Mutagenicity: None known. Carcinogenicity: No information available. Reproductive toxicity: This product does not contain any known or suspected reproductive hazards. Specific target organ systemic toxicity (single exposure): May cause respiratory irritation. May cause drowsiness and dizziness. Specific target organ systemic toxicity (repeated exposure): May cause damage to organs through prolonged or repeated exposure. Chronic toxicity: Prolonged skin contact may defat the skin and produce dermatitis. Target Organ Effects: Eyes, Respiratory system, Skin. Neurological effects: Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Aspiration hazard Not applicable. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 6764 mg/kg SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Chemical Name Toxicity to algae Toxicity to fish Toxicity to Microorganisms Toxicity to daphnia and other aquatic invertebrates DIETHANOLAMINE 111-42-2 7.8 mg/L EC50 Desmodesmus subspicatus 72h 2.1 - 2.3 mg/L EC50 Pseudokirchneriella subcapitata 96h 1200 - 1580 mg/L LC50 Pimephales promelas 96h static 4460 - 4980 mg/L LC50 Pimephales promelas 96h flow-through 600 - 1000 mg/L LC50 Lepomis macrochirus 96h static - 55 mg/L EC50 Daphnia magna 48h 12.2. Persistence and Degradability No information available. 12.3. Bioaccumulative Potential No information available. Chemical Name log Pow DIETHANOLAMINE 111-42-2 -2.18 12.4. Mobility in Soil 12.5. Other Adverse Effects No information available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: It must undergo special treatment, e.g. at suitable disposal site, to comply with local regulations. Additional Information: Contaminated packaging: Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |NOT REGULATED FOR SHIPMENT Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |NOT REGULATED FOR SHIPMENT Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |NOT REGULATED FOR SHIPMENT Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA 313 Chemical Name CAS-No Weight %* SARA 313 - Threshold Values % DIETHANOLAMINE - 111-42-2 111-42-2 5-15 1.0 Section 313 of Title III of the Superfund Amendments and Re-authorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQ DIETHANOLAMINE 111-42-2 100 lb RQs RQ 100 lb final RQ RQ 45.4 kg final RQ SARA Section 311/312 Hazard Classes |Acute Health Hazard |Yes |Chronic Health Hazard |Yes |Fire Hazard |no |Sudden Release of Pressure Hazard no |Reactive Hazard |no Toxic Substances Control Act (TSCA) |Chemical Name TSCA |DIETHANOLAMINE X 15.2 US State Regulations <COMPONENT> California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name California Prop. 65 DIETHANOLAMINE - 111-42-2 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania DIETHANOLAMINE 111-42-2 X X X SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |21-May-2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.