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SDS Sheet 0076360

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: 7636-0 CUTTING TOOL LUBRICANT                                     
 
CAS No:                                                                         
 
Synonyms: None                                                                  
 


1.2.  Intended Use of the Product
Use of the substance/mixture: Air Tool Lubricant.                               
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company:                                                                        
 
Imperial Supplies LLC                                                           
 
789 Armed Forces Drive                                                          
 
P.O. Box 11008                                                                  
 
Green Bay, WI 53407-1038                                                        
 
Phone:                                                                          
 


1.4.  Emergency Telephone Number
Emergency     | 1-800-424-9300                                                  
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Skin          |Category 2    
corrosion/irri|              
tation        |              
Serious eye   |Category 1    
damage/eye    |              
irritation    |              
Carcinogenicit|Category 2    
y             |              
Specific      |Category 2    
target organ  |              
toxicity      |              
(repeated     |              
exposure)     |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Health Hazard |Corrosion
       
Signal Word (GHS-US)         |DANGER                                            
 
Hazard Statements (GHS-US)   |Causes skin irritation                            
 
                             |Causes serious eye damage                         
 
                             |Suspected of causing cancer                       
 
                             |May cause damage to organs (Eyes, Respiratory     
 
                             |System, and Skin) through prolonged or repeated   
 
                             |exposure.                                         
 
Precautionary Statements     |Prevention                                        
 
(GHS-US)                     |Obtain special instructions before use            
 
                             |Wear protective gloves/protective clothing/eye    
 
                             |protection/face protection                        
 
                             |Do not handle until all safety precautions have
been
                             |read and understood                               
 
                             |Wash face, hands and any exposed skin thoroughly  
 
                             |after handling                                    
 
                             |Do not breathe dust/fume/gas/mist/vapors/spray    
 
                             |Response                                          
 
                             |If exposed or concerned: Get medical              
 
                             |advice/attention                                  
 
                             |Specific treatment (see first aid on this label)  
 
                             |IF IN EYES: Rinse cautiously with water for
several 
                             |minutes. Remove contact lenses, if present and
easy 
                             |to do. Continue rinsing.                          
 
                             |Immediately call a POISON CENTER or               
 
                             |doctor/physician.                                 
 
                             |IF ON SKIN: Wash with plenty of soap and water.   
 
                             |Take off contaminated clothing and wash before
reuse
                             |                                                  
 
                             |If skin irritation occurs: Get medical            
 
                             |advice/attention                                  
 
                             |Storage                                           
 
                             |Store locked up                                   
 
                             |Disposal                                          
 
                             |Dispose of contents/container to an approved waste
 
                             |disposal plant                                    
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                           
 


2.4.  Unknown Acute Toxicity (GHS-US)
Harmful to aquatic life with long lasting effects                               
 
0% of the mixture consists of ingredient(s) of unknown toxicity                 
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
DIETHANOLAMINE                  |111-42-2             |5-15    |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


*The exact percentage (concentration) of composition has been withheld as a
trade secret.

SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General: Avoid contact with eyes,skin, and clothing.Avoid    
 
breathing, vapors,mist,or gas.                                                  
 
First-aid Measures After Inhalation: Move to fresh air. If not breathing, give  
 
artificial respiration. If breathing has stopped,                               
 
contact emergency medical services immediately.                                 
 
First-aid Measures After Skin Contact: Wash off immediately with soap and plenty
 
of water. Remove and wash contaminated                                          
 
clothing before re-use. Get medical attention immediately if symptoms occur.    
 
First-aid Measures After Eye Contact: Immediately flush with plenty of water.   
 
After initial flushing, remove any contact lenses and continue flushing for at  
 
least 15 minutes. Seek immediate medical attention/advice.                      
 
First-aid Measures After Ingestion: Do NOT induce vomiting. Call a physician    
 
immediately. Never give anything by mouth to an                                 
 
unconscious person.                                                             
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation: May cause respiratory irritation.           
 
Symptoms/Injuries After Skin Contact: Causes skin irritation.                   
 
Symptoms/Injuries After Eye Contact: Causes eye irritation.                     
 
Symptoms/Injuries After Ingestion: May be harmful if swallowed.                 
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
Notes to physician: Treat symptomatically.                                      
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Use extinguishing measures that are appropriate to
 
local circumstances and the surrounding environment.                            
 
Unsuitable Extinguishing Media: Decomposition by contact with water may generate
 
vapors which can be ignited by heat or                                          
 
open flame.                                                                     
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: No information available.                                          
 
Explosion Hazard: Sensitivity to Mechanical Impact: none.                       
 
Sensitivity to Static Discharge: none.                                          
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions:                                                      
 
Protection During Firefighting: As in any fire, wear self-contained breathing   
 
apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective
gear.                                                                           
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Evacuate personnel to safe areas. Avoid contact with skin,
eyes 
and clothing. Ensure adequate ventilation. Avoid dust formation. Keep people
away 
from and upwind of spill/leak.                                                  
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Beware of vapors accumulating to form explosive concentrations. Vapors can      
 
accumulate in low areas. Prevent further leakage or spillage if safe to do so.
Do 
not allow material to contaminate ground water system. Prevent product from     
 
entering drains. Do not flush into surface water or sanitary sewer system.
Should 
not be released into the environment.                                           
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment: Absorb with earth, sand or other non-combustible material and  
 
transfer to containers for later disposal. Prevent further leakage or spillage
if 
safe to do so.                                                                  
 
Methods for Cleaning Up: Pick up and transfer to properly labeled containers.
Soak
up with inert absorbent material. Clean contaminated surface thoroughly. After  
 
cleaning, flush away traces with water.                                         
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid contact with skin, eyes and clothing.  
 
Handle in accordance with good industrial                                       
 
hygiene and safety practice. Remove and wash contaminated clothing before
re-use. 
Keep away from open flames, hot surfaces and sources of ignition. Wear personal 
 
protective equipment.                                                           
 
Hygiene Measures: Handle in accordance with good industrial hygiene and safety  
 
practice.                                                                       
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: Keep container tightly closed in a dry and well-ventilated  
 
place. Keep away from open flames, hot surfaces and sources of ignition. Keep in
 
properly labeled containers. Keep out of the reach of children. Store locked up.
 
Incompatible products: Strong acids, alkalis, or oxidizing agents.              
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Exposure Guidelines                                                             
 
Chemical Name                                                                   
 
ACGIH TLV                                                                       
 
OSHA PEL                                                                        
 
NIOSH IDLH                                                                      
 
                                                                                
 
DIETHANOLAMINE                                                                  
 
111-42-2                                                                        
 
TWA: 1 mg/m3 inhalable fraction and vapor Skin - potential significant          
 
contribution to overall exposure by the cutaneous route                         
 
(vacated) TWA: 3 ppm                                                            
 
(vacated) TWA: 15 mg/m3                                                         
 
TWA: 3 ppm                                                                      
 
TWA: 15 mg/m3                                                                   
 
                                                                                
 
Other Exposure Guidelines: Vacated limits revoked by the Court of Appeals
decision
in AFL-CIO v. OSHA, 965 F.2d 962                                                
 
(11th Cir., 1992).                                                              
 


8.2.  Exposure Controls
Appropriate Engineering      |Showers, Eyewash stations, Ventilation systems.   
 
Controls                     |                                                  
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |                                                  
 
Eye Protection               |Safety glasses with side-shields.                 
 
Skin and Body Protection     |Chemical resistant apron. Protective gloves.      
 
Respiratory Protection       |If exposure limits are exceeded or irritation is  
 
                             |experienced, NIOSH/MSHA approved respiratory      
 
                             |protection should be worn. Positive-pressure      
 
                             |supplied air respirators may be required for high 
 
                             |airborne contaminant concentrations. Respiratory  
 
                             |protection must be provided in accordance with    
 
                             |current local regulations.                        
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |Liquid                                     
 
Appearance                          |Clear                                      
 
Odor                                |Mild                                       
 
Odor Threshold                      |No information available                   
 
pH                                  |9.5                                        
 
Relative Evaporation Rate           |No information available                   
 
(butylacetate=1)                    |                                           
 
Melting Point                       |No information available                   
 
Freezing Point                      |No information available                   
 
Boiling Point                       |No information available                   
 
Flash Point                         |No information available                   
 
Auto-ignition Temperature           |No information available                   
 
Decomposition Temperature           |No information available                   
 
Flammability (solid, gas)           |No information available                   
 
Vapor Pressure                      |No information available                   
 
Relative Vapor Density at 20 °C     |                                           
 
Relative Density                    |No information available                   
 
Specific Gravity                    |1.02                                       
 
Solubility                          |                                           
 
Partition coefficient:              |No information available                   
 
n-octanol/water                     |                                           
 
Viscosity                           |No information available                   
 
Lower Flammable Limit               |No information available                   
 
Upper Flammable Limit               |No information available                   
 


9.2.  Other Information
VOC Content(%): 10                                                              
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
No data available                                                               
 


10.2      Chemical Stability
Stable under recommended storage conditions.                                    
 


10.3      Possibility of Hazardous Reactions
None under normal processing.                                                   
 


10.4      Conditions to Avoid
Extremes of temperature and direct sunlight.                                    
 


10.5      Incompatible Materials
Strong acids, alkalis, or oxidizing agents.                                     
 


10.6      Hazardous Decomposition Products
None known based on information supplied.                                       
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation: Irritating to skin. Repeated exposure may cause skin 
 
dryness or cracking. Prolonged skin contact may defat the skin and produce      
 
dermatitis. Avoid contact with skin.                                            
 
Serious Eye Damage/Irritation: causes serious eye damage. Avoid contact with
eyes.
Respiratory or Skin Sensitization: Avoid breathing vapors or mists. Vapors may  
 
irritate throat and respiratory system. May cause drownsiness and dizziness
based 
on components. May cause irritation of respiratory tract.                       
 
Germ Cell Mutagenicity: None known.                                             
 
Carcinogenicity:                                                                
 
Chemical Name                                                                   
 
ACGIH                                                                           
 
IARC                                                                            
 
NTP                                                                             
 
OSHA                                                                            
 
                                                                                
 
DIETHANOLAMINE                                                                  
 
111-42-2                                                                        
 
-                                                                               
 
2B                                                                              
 
-                                                                               
 
x                                                                               
 
                                                                                
 
Reproductive Toxicity: This product does not contain any known or suspected     
 
reproductive hazards.                                                           
 
Specific Target Organ Toxicity (Single Exposure): May cause respiratory         
 
irritation. May cause drowsiness and dizziness.                                 
 
Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs  
 
through prolonged or repeated exposure.                                         
 
Aspiration Hazard: Not applicable.                                              
 
Symptoms/Injuries After Inhalation: Causes respiratory system irritation.       
 
Symptoms/Injuries After Skin Contact: Irritating to skin.                       
 
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and      
 
vomiting.                                                                       
 
Symptoms/Injuries After Eye Contact: Irritating to eyes.                        
 
Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways.
 
Chronic Symptoms:                                                               
 
Skin corrosion/irritation: Irritating to skin.                                  
 
Eye damage/irritation: Causes severe eye damage .                               
 
Irritation: Irritating to respiratory system and skin.                          
 
Corrosivity: Risk of serious damage to eyes.                                    
 
Sensitization: None known.                                                      
 
Germ Cell Mutagenicity: None known.                                             
 
Carcinogenicity: No information available.                                      
 
Reproductive toxicity: This product does not contain any known or suspected     
 
reproductive hazards.                                                           
 
                                                                                
 
Specific target organ systemic                                                  
 
toxicity (single exposure): May cause respiratory irritation. May cause
drowsiness
and dizziness.                                                                  
 
                                                                                
 
Specific target organ systemic                                                  
 
toxicity (repeated exposure): May cause damage to organs through prolonged or   
 
repeated exposure.                                                              
 
                                                                                
 
Chronic toxicity: Prolonged skin contact may defat the skin and produce         
 
dermatitis.                                                                     
 
Target Organ Effects: Eyes, Respiratory system, Skin.                           
 
Neurological effects: Intentional misuse by deliberately concentrating and      
 
inhaling contents may be harmful or                                             
 
fatal.                                                                          
 
Aspiration hazard Not applicable.                                               
 
                                                                                
 
The following values are calculated based on chapter 3.1 of the GHS document    
 
ATEmix (oral)      6764 mg/kg                                                   
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
                                                                                
 
Chemical Name                                                                   
 
Toxicity to algae                                                               
 
Toxicity to fish                                                                
 
Toxicity to                                                                     
 
Microorganisms                                                                  
 
Toxicity to daphnia and other aquatic invertebrates                             
 
                                                                                
 
DIETHANOLAMINE                                                                  
 
111-42-2                                                                        
 
7.8 mg/L EC50 Desmodesmus subspicatus 72h 2.1 - 2.3 mg/L EC50
Pseudokirchneriella 
subcapitata 96h                                                                 
 
1200 - 1580 mg/L LC50                                                           
 
Pimephales promelas 96h static 4460 - 4980 mg/L LC50 Pimephales promelas 96h    
 
flow-through 600 - 1000 mg/L LC50 Lepomis macrochirus 96h static                
 
-                                                                               
 
55 mg/L EC50 Daphnia                                                            
 
magna 48h                                                                       
 
                                                                                
 


12.2. Persistence and Degradability
No information available.                                                       
 


12.3. Bioaccumulative Potential
No information available.                                                       
 
Chemical Name                                                                   
 
log Pow                                                                         
 
                                                                                
 
DIETHANOLAMINE                                                                  
 
111-42-2                                                                        
 
-2.18                                                                           
 
                                                                                
 


12.4. Mobility in Soil
                                                                                
 


12.5. Other Adverse Effects
No information available                                                        
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: It must undergo special treatment, e.g. at      
 
suitable disposal site, to comply with local regulations.                       
 
Additional Information: Contaminated packaging: Do not re-use empty containers. 
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |NOT REGULATED FOR SHIPMENT                                
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |NOT REGULATED FOR SHIPMENT                                
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |NOT REGULATED FOR SHIPMENT                                
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
SARA 313                                                                        
 
Chemical Name                                                                   
 
CAS-No                                                                          
 
Weight %*                                                                       
 
SARA 313 - Threshold                                                            
 
Values %                                                                        
 
                                                                                
 
DIETHANOLAMINE - 111-42-2                                                       
 
111-42-2                                                                        
 
5-15                                                                            
 
1.0                                                                             
 
                                                                                
 
                                                                                
 
Section 313 of Title III of the Superfund Amendments and Re-authorization Act of
 
1986 (SARA). This product contains a chemical                                   
 
or chemicals which are subject to the reporting requirements of the Act and
Title 
40 of the Code of Federal Regulations, Part 372:                                
 
                                                                                
 
Clean Water Act                                                                 
 
This product does not contain any substances regulated as pollutants pursuant to
 
the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).                          
 
                                                                                
 
CERCLA                                                                          
 
This material, as supplied, contains one or more substances regulated as a      
 
hazardous substance under the Comprehensive Environmental Response Compensation 
 
and Liability Act (CERCLA) (40 CFR 302):                                        
 
Chemical Name                                                                   
 
Hazardous Substances RQs                                                        
 
Extremely Hazardous Substances                                                  
 
RQ                                                                              
 
                                                                                
 
DIETHANOLAMINE                                                                  
 
111-42-2                                                                        
 
100 lb                                                                          
 
RQs                                                                             
 
RQ 100 lb final RQ                                                              
 
RQ 45.4 kg final RQ                                                             
 
                                                                                
 
SARA Section 311/312 Hazard Classes |Acute Health Hazard                        
 
                                    |Yes                                        
 
                                    |Chronic Health Hazard                      
 
                                    |Yes                                        
 
                                    |Fire Hazard                                
 
                                    |no                                         
 
                                    |Sudden Release of Pressure Hazard   no     
 
                                    |Reactive Hazard                            
 
                                    |no                                         
 
Toxic Substances Control Act (TSCA) |Chemical Name                 TSCA         
 
                                    |DIETHANOLAMINE             X               
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Proposition 65                                                       
 
This product contains the following Proposition 65 chemicals:                   
 
Chemical Name                                                                   
 
California Prop. 65                                                             
 
                                                                                
 
DIETHANOLAMINE - 111-42-2                                                       
 
Carcinogen                                                                      
 
                                                                                
 
                                                                                
 
U.S. State Right-to-Know Regulations                                            
 
Chemical Name                                                                   
 
New Jersey                                                                      
 
Massachusetts                                                                   
 
Pennsylvania                                                                    
 
                                                                                
 
DIETHANOLAMINE                                                                  
 
111-42-2                                                                        
 
X                                                                               
 
X                                                                               
 
X                                                                               
 
                                                                                
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |21-May-2015                                                    
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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