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MSDS Sheet 0076070Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: SikaflexÂ®-252 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: For further information, refer to the product technical data sheet. 1.3. Name, Address, and Telephone of the Responsible Party Company Sika Corporation 201 Polito Avenue Lyndhurst, NJ 07071 USA Phone: (201) 933-8800 1.4. Emergency Telephone Number Emergency |800-424-9300, 703-527-3887 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Respiratory |Category 1 sensitization | Skin |Category 1 sensitization | Carcinogenicit|Category 2 y | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Health Hazard Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H334 May cause allergy or asthma symptoms or |breathing difficulties if inhaled. |H317 May cause an allergic skin reaction. |H351 Suspected of causing cancer. Precautionary Statements |Prevention: (GHS-US) |P201 Obtain special instructions before use. |P202 Do not handle until all safety precautions have |been read and understood. |P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ |spray. |P272 Contaminated work clothing should not be |allowed out of the workplace. |P280 Wear protective gloves. |P281 Use personal protective equipment as required. |P285 In case of inadequate ventilation wear |respiratory protection. |Response: |P302 + P352 IF ON SKIN: Wash with plenty of soap and |water. |P304 + P341 IF INHALED: If breathing is difficult, |remove victim to fresh air and keep at rest in a |position comfortable for breathing. |P308 + P313 IF exposed or concerned: Get medical |advice/ attention. |P333 + P313 If skin irritation or rash occurs: Get |medical advice/ attention. |P363 Wash contaminated clothing before reuse. |Storage: |P405 Store locked up. |Disposal: |P501 Dispose of contents/ container to an approved |waste disposal plant. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Xylene |1330-20-7 |>= 2 - <| | |5 % | titanium dioxide |13463-67-7 |>= 2 - <| | |5 % | Ethylbenzene |100-41-4 |>= 0 - <| | |1 % | 4,4'-methylenediphenyl |101-68-8 |>= 0 - <| diisocyanate | |1 % | 3-isocyanatomethyl-3,5,5-trimeth|4098-71-9 |>= 0 - <| ylcyclohexyl | |1 % | Isocyanate | | | Aliphatic polyisocyanate |28182-81-2 |>= 0 - <| | |1 % | Carbon black |1333-86-4 |>= 0 - <| | |1 % | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Consult a physician. Show this material safety data sheet to the doctor in attendance. First-aid Measures After Inhalation: Move to fresh air. Consult a physician after significant exposure. First-aid Measures After Skin Contact: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. First-aid Measures After Eye Contact: Remove contact lenses. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. First-aid Measures After Ingestion: Clean mouth with water and drink afterwards plenty of water. Induce vomiting immediately and call a physician. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Asthmatic appearance Allergic reactions See Section 11 for more detailed information on health effects and symptoms. sensitizing effects. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to physician: Treat symptomatically. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Protection During Firefighting: In the event of fire, wear self-contained breathing apparatus. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment. Deny access to unprotected persons. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. Local authorities should be advised if significant spillages cannot be contained. Emergency Procedures: 6.2. Environmental Precautions 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Do not breathe vapors or spray mist. Avoid exceeding the given occupational exposure limits (see section 8). Do not get in eyes, on skin, or on clothing. For personal protection see section 8. Persons with a history of skin sensitization problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Smoking, eating and drinking should be prohibited in the application area. Follow standard hygiene measures when handling chemical products. Hygiene Measures: Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the Product. Remove contaminated clothing and protective equipment before entering eating areas. Wash thoroughly after handling. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store in original container. Keep container tightly closed in a dry and well-ventilated Place. Observe label precautions. Store in accordance with local regulations. Materials to avoid: no data available. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Component CAS-No. Basis ** Value Exposure limit(s)* / Form of exposure Xylene 1330-20-7 OSHA Z-1 TWA 100 ppm 435 mg/m3 ACGIH TWA 100 ppm ACGIH STEL 150 ppm OSHA P0 STEL 150 ppm 655 mg/m3 OSHA P0 TWA 100 ppm 435 mg/m3 titanium dioxide 13463-67-7 ACGIH TWA 10 mg/m3 OSHA P0 TWA 10 mg/m3 Total OSHA Z-1 TWA 15 mg/m3 total dust ethylbenzene 100-41-4 ACGIH TWA 100 ppm ACGIH STEL 125 ppm OSHA Z-1 TWA 100 ppm 435 mg/m3 OSHA P0 TWA 100 ppm 435 mg/m3 OSHA P0 STEL 125 ppm 545 mg/m3 Carbon black 1333-86-4 ACGIH TWA 3.5 mg/m3 OSHA Z-1 TWA 3.5 mg/m3 OSHA P0 TWA 3.5 mg/m3 *The above mentioned values are in accordance with the legislation in effect at the date of the release of this safety data sheet. **Basis: ACGIH. Threshold Limit Values (TLV) OSHA P0. Table Z-1, Limit for Air Contaminat (1989 Vacated Values) OSHA P1. Permissible Exposure Limits (PEL), Table Z-1, Limit for Air Contaminant OSHA P2. Permissible Exposure Limits (PEL), Table Z-2 OSHA Z3. Table Z-3, Mineral Dust 8.2. Exposure Controls Appropriate Engineering |Use of adequate ventilation should be sufficient to Controls |control worker exposure to airborne contaminants. If |the use of this product generates dust, fumes, gas, |vapor or mist, use process enclosures, local exhaust |ventilation or other engineering controls to keep |worker exposure below any recommended or statutory |limits. Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Remarks: Chemical-resistant, impervious gloves |complying with an approved standard should be worn |at all times when handling chemical products if a |risk assessment indicates this is necessary. Eye Protection |Safety eyewear complying with an approved standard |should be used when a risk assessment indicates this |is necessary. Skin and Body Protection |Choose body protection in relation to its type, to |the concentration and amount of dangerous |substances, and to the specific work-place. Respiratory Protection |Use a properly fitted NIOSH approved air-purifying |or air-fed respirator complying with an approved |standard if a risk assessment indicates this is |necessary. The filter class for the respirator must |be suitable for the maximum expected contaminant |concentration (gas/vapor/aerosol/particulates) that |may arise when handling the product. If this |concentration is exceeded, self-contained breathing |apparatus must be used. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Paste Odor |Aromaticq Odor Threshold |no data available pH |no data available Relative Evaporation Rate |no data available (butylacetate=1) | Melting Point |no data available Freezing Point |no data available Boiling Point |no data available Flash Point |Note: not applicable Auto-ignition Temperature |not applicable Decomposition Temperature |no data available Flammability (solid, gas) |no data available Vapor Pressure |no data available Relative Vapor Density at 20 Â°C |no data available Relative Density | Specific Gravity | Solubility |Note: insoluble Partition coefficient: |no data available n-octanol/water | Viscosity |no data available Lower Flammable Limit |no data available Upper Flammable Limit |no data available 9.2. Other Information Volatile organic compounds (VOC) content : 61 g/l SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical Stability The product is chemically stable. 10.3 Possibility of Hazardous Reactions Stable under recommended storage conditions. 10.4 Conditions to Avoid no data available. 10.5 Incompatible Materials no data available. 10.6 Hazardous Decomposition Products SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: no data available. Serious Eye Damage/Irritation: no data available. Respiratory or Skin Sensitization: May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Germ Cell Mutagenicity: no data available Carcinogenicity: Suspected of causing cancer. Reproductive Toxicity: no data available. Specific Target Organ Toxicity (Single Exposure): no data available. Specific Target Organ Toxicity (Repeated Exposure): Reports have associated repeated and prolonged exposure to some of the chemicals in this product with permanent brain,liver, kidney and nervous system damage. Intentional misuse by deliberate concentration and inhalation of vapors may be harmful or fatal. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Aspiration Hazard: no data available Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Other information Do not empty into drains; dispose of this material and its container in a safe way. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Component: Carbon black 1333-86-4 Toxicity to fish: LC50 Species: Brachydanio rerio (zebrafish) Dose: > 1,000 mg/l Exposure time: 96 h SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Not dangerous goods Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not dangerous goods Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not dangerous goods Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> EPCRA - Emergency Planning and Community Right-to-Know: CERCLA Reportable Quantity: This material does not contain any components with a CERCLA RQ. SARA304 Reportable Quantity: This material does not contain any components with a section 304 EHS RQ. SARA 302: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313: The following components are subject to reporting levels established by SARA Title III, Section 313: xylene 1330-20-7 3.54% Clean Air Act: Ozone-Depletion Potential: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): xylene 1330-20-7 3.54% This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). SARA Section 311/312 Hazard Classes |Chronic Health Hazard |Acute Health Hazard Toxic Substances Control Act (TSCA) |All chemical substances in this product are |either listed on the |TSCA Inventory or are in compliance with a |TSCA Inventory exemption. 15.2 US State Regulations <COMPONENT> California Prop 65: WARNING! This product contains a chemical known in the State of California to cause cancer. WARNING: This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |08/26/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.