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MSDS Sheet 0076030

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IMPERIAL SUPPLIES LLC MSDS SHEET FOR 7604
                                     BOSTIK

Section 1. Product and Company Identification                                 
Product Name:                          1100 FS Product Series.               
MSDS Name:                             1100 FS Product Series- Various       
                                       Colors.                               
Product Name(s) covered:               See Section 16 for Product Names      
                                       Covered.                              
CAS #:                                 Mixture.                              
Product Use:                           Adhesive and/or Sealant.              
Generic description:                   Moisture Cure Polyurethane Based      
                                       Formulation.                          
Manufacturer:                          Bostik Inc.                           
                                       211 Boston Street                     
                                       Middleton, MA 01949 USA               
24 Hour Emergency Assistance:          Telephone: 1-800-227-0332             
                                       (Outside U.S.) 1-703-527-3887         
General Assistance:                    Telephone: 1-978-777-0100             
MSDS Assistance:                       Telephone: 1-414-607-1347             
                                                                              
Section 2. Hazardous Identification                                           
Emergency Overview:                    Contact with this material can cause  
                                       irritation to the skin, eyes and      
                                       mucous membranes. Thermal             
                                       decomposition/burning may produce     
                                       toxic gases and fumes. Closed         
                                       containers may rupture when exposed to
                                       high temperatures, or when the product
                                       has been contaminated with water.     
                                       Avoid breathing hot mists and vapors. 
                                       This product contains a respiratory   
                                       and skin sensitizer. Causes           
                                       respiratory tract irritation and may  
                                       cause allergic respiratory reaction.  
                                       May cause permanent respiratory       
                                       damage. Product vapors are potentially
                                       irritating to skin. May cause allergic
                                       skin reaction and dermatitis.         
Potential Health Effects:              Eyes: This product may cause          
                                       irritation to the eyes. May cause     
                                       temporary corneal injury.             
                                       Skin: this product may cause          
                                       irritation to the skin. Isocyanates   
                                       may react with skin protein and       
                                       moisture to cause itching, reddening, 
                                       swelling, scaling or blistering.      
                                       Individuals previously sensitized to  
                                       this material may experience these    
                                       symptoms from exposure to very small  
                                       amounts of liquid or vapor.           
                                       Inhalation: This product may cause    
                                       irritation to the respiratory system. 
                                       Single large doses, and/or repeated   
                                       exposures, may lead to sensitization  
                                       to diisocyanates (Asthma or           
                                       asthma-like symptoms), causing an     
                                       individual to experience adverse      
                                       effects at exposure levels well below 
                                       exposure limits or guidelines.        
                                       Symptoms may include chest tightness, 
                                       wheezing, shortness of breath,        
                                       coughing or asthmatic attack and may  
                                       be delayed up to several hours.       
                                       Extreme asthmatic reaction can be life
                                       threatening. Once sensitized, an      
                                       individual may experience adverse     
                                       symptoms upon exposure to dust, cold  
                                       air or other irritants. Sensitization 
                                       can last several months, years or be  
                                       permanent in some cases.              
                                       Ingestion: Ingestion can cause        
                                       gastrointestinal irritation, nausea,  
                                       vomiting and diarrhea. This product   
                                       may produce corrosive damage to the   
                                       gastrointestinal tract if it is       
                                       swallowed.                            
Target Organs:                         The lungs and skin may be targeted and
                                       damaged by components of this product.
Signs and Symptoms:                    Signs and symptoms of overexposure to 
                                       this product include headache,        
                                       breathing difficulty, coughing, sore  
                                       throat, eye irritation, skin          
                                       irritation and/or diarrhea.           
Hazard Statements:                     This product contains Methylene       
                                       Diphenyl Isocyanate (MDI) which is a  
                                       potential skin sensitizer and has been
                                       shown to alter cells in certain       
                                       experiments. Although inconclusive,   
                                       these cellular changes are thought to 
                                       indicate potential carcinogenicity.   
                                       Risk to your health depends on        
                                       duration and concentration of         
                                       exposure.                             
                                                                              
Section 3. Composition / Information on Ingredients                           
Hazardous Components      CAS #                     Percent                  
Xylenes (o-, m-, p-       1330-20-7                 1-5                      
isomers)                                                                     
Methylene Diphenyl        101-68-8                  0.1-1                    
Isocyanate (MDI)                                                             
Phenylethane              100-41-4                  0.1-1                    
Methyl alcohol            67-54-1                   < 0.15                   
                                                                              
Section 4. First Aid Measures                                                 
First Aid Procedures:                                                         
Eye Contact:                           Immediately flush eyes with plenty of 
                                       water for at least 15 minutes. Get    
                                       medical attention or advice.          
Skin Contact:                          For skin contact flush with large     
                                       amounts of water while removing       
                                       contaminated clothing. If skin        
                                       irritation persists, call a physician.
                                       For server exposure, immediately get  
                                       under a safety shower and being       
                                       rinsing.                              
Inhalation:                            If inhaled, immediately remove the    
                                       affected person to fresh air. Call    
                                       physician if symptoms develop or      
                                       persist. Administer oxygen or         
                                       artificial respiration as needed.     
Ingestion:                             If the material is swallowed, get     
                                       immediate medical attention or advice.
                                       Do not induce vomiting without medical
                                       advice. Never give anything by mouth  
                                       to a victim who is unconscious or is  
                                       having convulsions.                   
Notes to Physician:                    Provide general supportive measures   
                                       and treat symptomatically. Contact    
                                       Bostik to determine whether any       
                                       additional information is available.  
                                       Eyes: Stain for evidence of corneal   
                                       injury. If cornea is burned, apply    
                                       antibiotic/steroid preparation as     
                                       needed.                               
                                       Skin: This product contains a skin    
                                       sensitizer. Treat symptomatically as  
                                       for contact dermatitis or thermal     
                                       burn.                                 
                                       Ingestion: Treat symptomatically.     
                                       Inhalation: This material contains a  
                                       known pulmonary sensitizer. Any       
                                       individual experiencing dermal or     
                                       pulmonary sensitization should be     
                                       removed from exposure to any          
                                       diisocyanate. May aggravate existing  
                                       heart conditions, particularly those  
                                       with abnormal heart rhythms.          
                                                                              
Section 5 Fire Fighting Measures                                              
Hazardous Combustion products:         Upon decomposition, this product emits
                                       carbon monoxide, carbon dioxide and/or
                                       low molecular weight hydrocarbons.    
                                       Additional decomposition products     
                                       include oxides of nitrogen, amines,   
                                       hydrogen cyanide and                  
                                       isocyanate-containing compounds.      
Extinguishing Media:                                                          
Suitable extinguishing media:          Dry chemical, foam, carbon dioxide,   
                                       water fog.                            
Fire Fighting equipment/instructions:  Firefighters should wear full         
                                       protective clothing including self    
                                       contained breathing apparatus. Avoid  
                                       contact with isocyanates. During a    
                                       fire, isoctanate vapors and other     
                                       irritating and highly toxic gases may 
                                       be produced.                          
Flash Point:                           160 F (71.1 C)                        
                                                                              
Section 6. Accidental Release Measures                                        
Emergency action:                      Wear appropriate personal protective  
                                       equipment. Do not allow product to    
                                       enter sewer or waterways/ Follow all  
                                       Local, State, Federal and Provencial  
                                       regulations for disposal. Regulations 
                                       vary. Consult with local authorities  
                                       before disposal.                      
Spill or Leak procedure:               Scrap up material and place in steel  
                                       drums that are in good condition.     
                                       Thoroughly clean area where spill     
                                       occurred.                             
Containment Procedures:                Isolate area. Stop discharge if safe  
                                       to do so. Stop material from          
                                       contaminating soil or entering sewers 
                                       or water streams. Liquid spills: Cover
                                       spills with absorbent clay or sawdust 
                                       and collect material in open container
                                       and neutralize with a solution        
                                       containing 2% liquid detergent, 3%    
                                       concentrated ammonium hydroxide and   
                                       95% water. Wash spill area clean with 
                                       the neutralization solution. Remove   
                                       container to a safe place, cover      
                                       loosely and allow to stand for 24 to  
                                       48 hours letting evolved carbon       
                                       dioxide escape. Collect and contain   
                                       for disposal.                         
                                       Pellet or chip spill: Collect and     
                                       contain for salvage or disposal.      
                                       Molten adhesive spill: Placard hot    
                                       material, allow to cool and remove. If
                                       material is not cured once cooled,    
                                       follow neutralization directions for  
                                       liquids listed above. Collect and     
                                       contain for disposal.                 
Reporting:                             See federal reporting requirements    
                                       listed in Section 15. We recommend you
                                       contact local authorities to determine
                                       if there may be other local reporting 
                                       requirements.                         
                                                                              
Section 7. Handling and Storage                                               
Handling:                              Do not get this material in your eyes,
                                       on your skin, or on your clothing.    
                                       Wash hands after handling and before  
                                       eating. Do not breathe                
                                       gas/fumes/vapor/spray. Wear           
                                       respiratory protection if the material
                                       is heated, sprayed, used in a confined
                                       space, or if exposure limit is        
                                       exceeded. This product can produce    
                                       asthmatic sensitization. Individuals  
                                       with lung or breathing problems or    
                                       prior allergic reactions to           
                                       isocyanates must avoid fumes from this
                                       product. Wear appropriate protective  
                                       equipment to avoid contact with skin  
                                       and eyes.                             
Storage:                               Keep in a dry, cool and well          
                                       ventilated place. Keep away from heat.
                                       Keep away from direct sunlight.       
Empty Container Precaution:            Attention! Follow label warnings even 
                                       after container is emptied since empty
                                       containers may retain product         
                                       residues. Do not reuse empty container
                                       without professional cleaning for     
                                       food, clothing, or products for human 
                                       or animal consumption, or where skin  
                                       contact can occur.                    
                                                                              
Section 8. Exposure Controls/Personal Protection                              
Engineering Controls:                  Provide local and general exhaust     
                                       ventilation to effectively remove and 
                                       prevent buildup or any vapors or mists
                                       generate from the handling of this    
                                       product.                              
Personal Protective Equipment:                                                
Eye Protection:                        Wear safety glasses with side shields.
Skin and Body Protection:              Use impervious gloves. Work clothing  
                                       sufficient to prevent all skin contact
                                       should be worn, such as coveralls and 
                                       long sleeves.                         
Respiratory Protection:                Avoid breathing vapor and/or mists. If
                                       airborne concentrations are above the 
                                       applicable exposure limits, use NIOSH 
                                       approved respiratory protection. High 
                                       airborne concentrations may           
                                       necessitate the use of self-contained 
                                       breathing apparatus (SCBA) or a       
                                       supplied air respirator.              
General:                               Eye wash fountains and emergency      
                                       showers should be readily available.  
Additional Exposure Data:                                                     
US ACGIH Threshold limit values: Time Weighted Average (TWA): mg/m3 & ppm     
Phenylethane              100-41-4                  Ethyl Benzene 100 PPM    
Methylene Diphenyl        101-68-8                  Methylene Bisphenyl      
Isocyanate                                          Isocyanate (MDI) 0.005   
                                                    PPM                      
Xylenes (o-, m-, p-       1330-20-7                 Xylene (O, M and P       
isomers)                                            Isomers) 100 PPM         
Methyl alcohol            67-56-1                   Methanol 200 PPM         
US NOISH Pocket Guide to Chemical Hazards: Ceiling Limit Value ant Time Period
(If specified)                                                                
Methylene Diphenyl        101-68-8                  Methylene Bisphenyl      
Isocyanate                                          Isocyanate 0.2 MGM3 -    
                                                    0.020 PPM 10-min         
US OSHA Table Z-1-A: Time weighted Average (TWA): mg/m3 & ppm                 
Phenylene Diphenyl        100-41-4                  Ethylbenzene 435 MGM3 -  
Isocyanate                                          100 PPM                  
Xylenes (o-, m-, p-       1330-20-7                 Xylene (O-, M-, P-       
isomers)                                            Isomers) 435 MGM3 -      
                                                    100PPM                   
Methyl alcohol            67-56-1                   Methyl Alcohol 260 MGM3 -
                                                    200 PPM                  
                                                                              
Section 9.  Physical and Chemical Properties                                  
Target Solids:                         96%                                   
Density:                               1.22 g/cc                             
Odor:                                  Solvent                               
Color:                                 Various                               
Physical State:                        Paste                                 
Freeze Point:                          No                                    
VOC (Volatile Organic Compounds)       3.9%                                  
                                                                              
Section 10. Chemical Stability and Reactivity Information                     
Hazardous reactions/decomposition      Upon decomposition, this product emits
                                       carbon monoxide, carbon dioxide and/or
                                       low molecular weight hydrocarbons.    
                                       Additional decomposition products     
                                       include oxides of nitrogen, amines,   
                                       hydrogen cyanide and isocuanate-      
                                       containing chemicals.                 
Hazardous Polymerization:              Hazardous polymerization can occur    
                                       with elevated temperatures or contact 
                                       with water.                           
Conditions to Avoid:                   Avoid strong acids. Avoid amines,     
                                       strong bases, alcohols and metallic   
                                       hydrides.                             
Stability:                             This product is stable under normal   
                                       conditions but will react slightly    
                                       with water to release some heat and   
                                       carbon dioxide. The reaction is not   
                                       violent. Carbon dioxide, carbon       
                                       monoxide, and in high temperature (800
                                       F) low oxygen atmospheres such as fire
                                       situations, hydrogen cyanide may be   
                                       released.                             
                                                                              
Section 11. Toxicological Information                                         
Carcinogenicity:                       If this product contains any          
                                       carcinogens, they will be noted below:
                                       This product contains Methylene       
                                       Diphenyl Isocyanate (MDI). MDI is not 
                                       listed by the NTP, IARC or regulated  
                                       by OSHA as a carcinogen. However, is  
                                       has been shown to alter cells in      
                                       certain experiments. Although         
                                       inconclusive, these cellular changes  
                                       are though to indicate potential      
                                       carcinogenicity.                      
US ACGIH Threshold Limit Values: Skin Designation                             
Methyl alcohol            67-56-1                   Can be absorbed through  
                                                    the skin.                
Local Effects:                         Single large doses and/or repeated    
                                       exposures, may lead to sensitization  
                                       to diisocyanates or polyisocyanates   
                                       (asthma or asthma - like symptoms),   
                                       causing an individual to experience   
                                       adverse effects at exposure levels    
                                       well below exposure limits or         
                                       guidelines. Symptoms may include chest
                                       tightness, wheezing, shortness of     
                                       breath, coughing or asthmatic attack, 
                                       and may be delayed up to several      
                                       hours. Extreme asthmatic reactions can
                                       be life threatening. Once sensitized, 
                                       an individual may experience adverse  
                                       symptoms upon exposure to dust, cold  
                                       air or other irritants. Sensitization 
                                       can last several months, years or be  
                                       permanent in some cases. Chronic      
                                       exposure may cause lung damage,       
                                       including fibrosis and decreased lung 
                                       function, which may be permanent.     
                                                                              
Section 12. Ecological Information.                                           
Ecotoxicological Information:          No data available for this product.   
                                                                              
Section 13. Disposal Considerations                                           
It is the obligation of each user of the product mentioned herein to determine
and comply with the requirements of all applicable local, state and federal   
regulations.                                                                  
Waste Disposal:                        Dispose of waste material according to
                                       Local, State, Federal, Provincial     
                                       Environmental Regulations.            
                                                                              
Section 14. Transport Information:                                            
DOT:                                   Not regulated as hazardous goods.     
IATA:                                  Not regulated as hazardous goods.     
IMDG:                                  Not regulated as hazardous goods.     
                                                                              
Section 15. Regulatory Information                                            
This MSDS is prepared and distributed to the Federal Hazard Communication     
Standard, 29 CFR 1910.1200.                                                   
The product(s) covered by this M(SDS) do not include any of the 15 substances 
in the Candidate List of Substances of Very High Concern (SVHC) for           
authorization published by ECHA on October 28, 2008 or the list of 15         
substances proposed on August 31, 2009 above concentration of 0.1% weight by  
weight (w/w).                                                                 
Federal Regulations:                   All components are on the U.S. EPA    
                                       TSCA Inventory List.                  
US CWA Section 311 Reporting Quantities of Hazardous Substances: Reportable   
quantity                                                                      
Phenylethane              100-41-4                  Ethylbenzene 1000 LBS    
Xylenes (o-, m-, p-       1330-20-7                 Xylene (Mixed) 100 LBS   
isomers)                                                                     
US EPCRA (SARA Title III) Section 313- Toxic Chemical: Listed substance       
Phenylethane              100-41-4                  Ethylbenzene US EPCRA    
                                                    (SARA Title III) Section 
                                                    313 - Toxic Chemical:    
                                                    Listed substance         
Methylene Diphenyl        101-68-8                  Methylenebis(Phenylisocya
Isocyanate                                          nate) (MDI) US EPCRA     
                                                    (SARA Title III) Section 
                                                    313-Toxic Chemical:      
                                                    Listed substance.        
Xylenes (o-, m-, p-       1330-20-7                 Xylene (mixed isomers) US
isomers)                                            EPCRA (SARA Title III)   
                                                    Section 313- Toxic       
                                                    Chemical: Listed         
                                                    substance.               
Methyl alcohol            67-56-1                   MEHTANOL US EPCRA (SARA  
                                                    Title III) Section 313-  
                                                    Toxic Chemical: Listed   
                                                    substance.               
State Regulations:                     This product may contain an           
                                       ingredient(s) known to the state of   
                                       California to cause cancer, birth     
                                       defects and/or reproductive harm. If  
                                       any of the ingredients in this product
                                       are subject to the Proposition 65     
                                       regulations they will be listed as    
                                       such on the product label.            
International Regulations:             This product has been classified in   
                                       accordance with the hazard criteria of
                                       the Controlled Products Regulations.  
HMIS Ratings:   Health: 2*      Flammability: 2 Physical        Personal       
                                                Hazard: 0       Protection: X  
SARA 311-312 Hazard Categories:        Immediate Hazard- Yes                 
                                       Delayed Hazard- Yes                   
                                       Fire Hazard- Yes                      
                                       Pressure Hazard- No                   
                                       Reactivity Hazard- No                 
WHMIS status:                          Controlled.                           
WHMIS Labeling:                                                              
WHMIS Classification:                  D2A- Other Toxic Effects- VERY TOXIC  
                                       D2B- Other Toxic Effects- TOXIC       
                                                                              
Section 16. Other Information                                                 
Product name(s) covered:               A19200-1100 FS WHITE     L            
                                       A19217-BOST 1100 FS WHITE   24/10.1   
                                       A19221- 100FS WHITE  S/PK    12/20.3  
                                       A19226- BOST 1100FS WHITE  S/P        
                                       24/10.0                               
                                       A25600- 1100 FS BLACK   L             
                                       A25614- BOST 1100 FS BLACK  24/10.1   
                                       A25617- BOST 1100FS BLACK   S/P       
                                       24/10.0                               
                                       A25620- 1100FS BLACK  S/PK   12/20.0  
                                       A26800- 1100 FS STONE    L            
                                       A26810- Bostik 1100FS GRY  S/PK       
                                       24/10.3                               
                                       A26814- BOST 1100 FS GRAY   12/30.0   
                                       A26815- BOST 1100FS GRAY    24/10.1   
                                       A2816- 1100FS GRAY  S/PK    12/20.3   
                                       A44400- 1100FS PUTTY   L              
                                       A46610- BOST 1100FS MM BEIGE          
                                       24/10.1                               
                                       A64411- BOST 1100FS DARK GRAY         
                                       24/10.1                               
                                                                              
Disclaimer:                            The date in this MSDS has been        
                                       compiled from publicly available      
                                       sources. This date relates only to the
                                       designated product and not to the use 
                                       of said product in combination with   
                                       other materials. All materials may    
                                       present unknown hazards and should be 
                                       used with caution. Although certain   
                                       hazards are described herein, we      
                                       cannot guarantee that these are the   
                                       only hazards which exist.             
                                       Responsibility for proper precautions 
                                       and safe use of the product lies with 
                                       the user. All data in this MSDS is    
                                       typical of the product as a whole, and
                                       does not represent any individual lot 
                                       or batch, therefore, Bostik, Inc.     
                                       makes no warranty about the accuracy  
                                       of the data herein and assumes no     
                                       liability for the use of such data. It
                                       is the responsibility of the user to  
                                       comply with all applicable federal,   
                                       state and local laws and regulations. 
                                                                              
Further Information:                   If there are any characters following 
                                       an individual item number, they are   
                                       just designations for the various     
                                       types of packaging that are available 
                                       for this product. For example, a      
                                       product "G12345-XX" is item number    
                                       "G12345" with a packaging destination 
                                       of "XX". These characters do not      
                                       indicate a different product nor a    
                                       different regulatory, health, safety  
                                       and/or environmental status. This     
                                       document covers the item numbers      
                                       listed above for all of their         
                                       packaging types.                      
Issue Date:                            01/19/2010                            
Prepared By:                           Michael Simon                         
Supercedes:                            01/19/2010                            
This date sheet contains changes from  This document has undergone           
the previous version in section(s):    significant changes and should be     
                                       reviewed in its entirety.             
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
                                                                              
    

The information contained in this MSDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'MSDS' shall be created or inferred by any statement in this 'MSDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'MSDS'. The user is responsible for full compliance.

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