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IMPERIAL SUPPLIES LLC MSDS SHEET FOR 7604 BOSTIK Section 1. Product and Company Identification Product Name: 1100 FS Product Series. MSDS Name: 1100 FS Product Series- Various Colors. Product Name(s) covered: See Section 16 for Product Names Covered. CAS #: Mixture. Product Use: Adhesive and/or Sealant. Generic description: Moisture Cure Polyurethane Based Formulation. Manufacturer: Bostik Inc. 211 Boston Street Middleton, MA 01949 USA 24 Hour Emergency Assistance: Telephone: 1-800-227-0332 (Outside U.S.) 1-703-527-3887 General Assistance: Telephone: 1-978-777-0100 MSDS Assistance: Telephone: 1-414-607-1347 Section 2. Hazardous Identification Emergency Overview: Contact with this material can cause irritation to the skin, eyes and mucous membranes. Thermal decomposition/burning may produce toxic gases and fumes. Closed containers may rupture when exposed to high temperatures, or when the product has been contaminated with water. Avoid breathing hot mists and vapors. This product contains a respiratory and skin sensitizer. Causes respiratory tract irritation and may cause allergic respiratory reaction. May cause permanent respiratory damage. Product vapors are potentially irritating to skin. May cause allergic skin reaction and dermatitis. Potential Health Effects: Eyes: This product may cause irritation to the eyes. May cause temporary corneal injury. Skin: this product may cause irritation to the skin. Isocyanates may react with skin protein and moisture to cause itching, reddening, swelling, scaling or blistering. Individuals previously sensitized to this material may experience these symptoms from exposure to very small amounts of liquid or vapor. Inhalation: This product may cause irritation to the respiratory system. Single large doses, and/or repeated exposures, may lead to sensitization to diisocyanates (Asthma or asthma-like symptoms), causing an individual to experience adverse effects at exposure levels well below exposure limits or guidelines. Symptoms may include chest tightness, wheezing, shortness of breath, coughing or asthmatic attack and may be delayed up to several hours. Extreme asthmatic reaction can be life threatening. Once sensitized, an individual may experience adverse symptoms upon exposure to dust, cold air or other irritants. Sensitization can last several months, years or be permanent in some cases. Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. This product may produce corrosive damage to the gastrointestinal tract if it is swallowed. Target Organs: The lungs and skin may be targeted and damaged by components of this product. Signs and Symptoms: Signs and symptoms of overexposure to this product include headache, breathing difficulty, coughing, sore throat, eye irritation, skin irritation and/or diarrhea. Hazard Statements: This product contains Methylene Diphenyl Isocyanate (MDI) which is a potential skin sensitizer and has been shown to alter cells in certain experiments. Although inconclusive, these cellular changes are thought to indicate potential carcinogenicity. Risk to your health depends on duration and concentration of exposure. Section 3. Composition / Information on Ingredients Hazardous Components CAS # Percent Xylenes (o-, m-, p- 1330-20-7 1-5 isomers) Methylene Diphenyl 101-68-8 0.1-1 Isocyanate (MDI) Phenylethane 100-41-4 0.1-1 Methyl alcohol 67-54-1 < 0.15 Section 4. First Aid Measures First Aid Procedures: Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention or advice. Skin Contact: For skin contact flush with large amounts of water while removing contaminated clothing. If skin irritation persists, call a physician. For server exposure, immediately get under a safety shower and being rinsing. Inhalation: If inhaled, immediately remove the affected person to fresh air. Call physician if symptoms develop or persist. Administer oxygen or artificial respiration as needed. Ingestion: If the material is swallowed, get immediate medical attention or advice. Do not induce vomiting without medical advice. Never give anything by mouth to a victim who is unconscious or is having convulsions. Notes to Physician: Provide general supportive measures and treat symptomatically. Contact Bostik to determine whether any additional information is available. Eyes: Stain for evidence of corneal injury. If cornea is burned, apply antibiotic/steroid preparation as needed. Skin: This product contains a skin sensitizer. Treat symptomatically as for contact dermatitis or thermal burn. Ingestion: Treat symptomatically. Inhalation: This material contains a known pulmonary sensitizer. Any individual experiencing dermal or pulmonary sensitization should be removed from exposure to any diisocyanate. May aggravate existing heart conditions, particularly those with abnormal heart rhythms. Section 5 Fire Fighting Measures Hazardous Combustion products: Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Additional decomposition products include oxides of nitrogen, amines, hydrogen cyanide and isocyanate-containing compounds. Extinguishing Media: Suitable extinguishing media: Dry chemical, foam, carbon dioxide, water fog. Fire Fighting equipment/instructions: Firefighters should wear full protective clothing including self contained breathing apparatus. Avoid contact with isocyanates. During a fire, isoctanate vapors and other irritating and highly toxic gases may be produced. Flash Point: 160 F (71.1 C) Section 6. Accidental Release Measures Emergency action: Wear appropriate personal protective equipment. Do not allow product to enter sewer or waterways/ Follow all Local, State, Federal and Provencial regulations for disposal. Regulations vary. Consult with local authorities before disposal. Spill or Leak procedure: Scrap up material and place in steel drums that are in good condition. Thoroughly clean area where spill occurred. Containment Procedures: Isolate area. Stop discharge if safe to do so. Stop material from contaminating soil or entering sewers or water streams. Liquid spills: Cover spills with absorbent clay or sawdust and collect material in open container and neutralize with a solution containing 2% liquid detergent, 3% concentrated ammonium hydroxide and 95% water. Wash spill area clean with the neutralization solution. Remove container to a safe place, cover loosely and allow to stand for 24 to 48 hours letting evolved carbon dioxide escape. Collect and contain for disposal. Pellet or chip spill: Collect and contain for salvage or disposal. Molten adhesive spill: Placard hot material, allow to cool and remove. If material is not cured once cooled, follow neutralization directions for liquids listed above. Collect and contain for disposal. Reporting: See federal reporting requirements listed in Section 15. We recommend you contact local authorities to determine if there may be other local reporting requirements. Section 7. Handling and Storage Handling: Do not get this material in your eyes, on your skin, or on your clothing. Wash hands after handling and before eating. Do not breathe gas/fumes/vapor/spray. Wear respiratory protection if the material is heated, sprayed, used in a confined space, or if exposure limit is exceeded. This product can produce asthmatic sensitization. Individuals with lung or breathing problems or prior allergic reactions to isocyanates must avoid fumes from this product. Wear appropriate protective equipment to avoid contact with skin and eyes. Storage: Keep in a dry, cool and well ventilated place. Keep away from heat. Keep away from direct sunlight. Empty Container Precaution: Attention! Follow label warnings even after container is emptied since empty containers may retain product residues. Do not reuse empty container without professional cleaning for food, clothing, or products for human or animal consumption, or where skin contact can occur. Section 8. Exposure Controls/Personal Protection Engineering Controls: Provide local and general exhaust ventilation to effectively remove and prevent buildup or any vapors or mists generate from the handling of this product. Personal Protective Equipment: Eye Protection: Wear safety glasses with side shields. Skin and Body Protection: Use impervious gloves. Work clothing sufficient to prevent all skin contact should be worn, such as coveralls and long sleeves. Respiratory Protection: Avoid breathing vapor and/or mists. If airborne concentrations are above the applicable exposure limits, use NIOSH approved respiratory protection. High airborne concentrations may necessitate the use of self-contained breathing apparatus (SCBA) or a supplied air respirator. General: Eye wash fountains and emergency showers should be readily available. Additional Exposure Data: US ACGIH Threshold limit values: Time Weighted Average (TWA): mg/m3 & ppm Phenylethane 100-41-4 Ethyl Benzene 100 PPM Methylene Diphenyl 101-68-8 Methylene Bisphenyl Isocyanate Isocyanate (MDI) 0.005 PPM Xylenes (o-, m-, p- 1330-20-7 Xylene (O, M and P isomers) Isomers) 100 PPM Methyl alcohol 67-56-1 Methanol 200 PPM US NOISH Pocket Guide to Chemical Hazards: Ceiling Limit Value ant Time Period (If specified) Methylene Diphenyl 101-68-8 Methylene Bisphenyl Isocyanate Isocyanate 0.2 MGM3 - 0.020 PPM 10-min US OSHA Table Z-1-A: Time weighted Average (TWA): mg/m3 & ppm Phenylene Diphenyl 100-41-4 Ethylbenzene 435 MGM3 - Isocyanate 100 PPM Xylenes (o-, m-, p- 1330-20-7 Xylene (O-, M-, P- isomers) Isomers) 435 MGM3 - 100PPM Methyl alcohol 67-56-1 Methyl Alcohol 260 MGM3 - 200 PPM Section 9. Physical and Chemical Properties Target Solids: 96% Density: 1.22 g/cc Odor: Solvent Color: Various Physical State: Paste Freeze Point: No VOC (Volatile Organic Compounds) 3.9% Section 10. Chemical Stability and Reactivity Information Hazardous reactions/decomposition Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Additional decomposition products include oxides of nitrogen, amines, hydrogen cyanide and isocuanate- containing chemicals. Hazardous Polymerization: Hazardous polymerization can occur with elevated temperatures or contact with water. Conditions to Avoid: Avoid strong acids. Avoid amines, strong bases, alcohols and metallic hydrides. Stability: This product is stable under normal conditions but will react slightly with water to release some heat and carbon dioxide. The reaction is not violent. Carbon dioxide, carbon monoxide, and in high temperature (800 F) low oxygen atmospheres such as fire situations, hydrogen cyanide may be released. Section 11. Toxicological Information Carcinogenicity: If this product contains any carcinogens, they will be noted below: This product contains Methylene Diphenyl Isocyanate (MDI). MDI is not listed by the NTP, IARC or regulated by OSHA as a carcinogen. However, is has been shown to alter cells in certain experiments. Although inconclusive, these cellular changes are though to indicate potential carcinogenicity. US ACGIH Threshold Limit Values: Skin Designation Methyl alcohol 67-56-1 Can be absorbed through the skin. Local Effects: Single large doses and/or repeated exposures, may lead to sensitization to diisocyanates or polyisocyanates (asthma or asthma - like symptoms), causing an individual to experience adverse effects at exposure levels well below exposure limits or guidelines. Symptoms may include chest tightness, wheezing, shortness of breath, coughing or asthmatic attack, and may be delayed up to several hours. Extreme asthmatic reactions can be life threatening. Once sensitized, an individual may experience adverse symptoms upon exposure to dust, cold air or other irritants. Sensitization can last several months, years or be permanent in some cases. Chronic exposure may cause lung damage, including fibrosis and decreased lung function, which may be permanent. Section 12. Ecological Information. Ecotoxicological Information: No data available for this product. Section 13. Disposal Considerations It is the obligation of each user of the product mentioned herein to determine and comply with the requirements of all applicable local, state and federal regulations. Waste Disposal: Dispose of waste material according to Local, State, Federal, Provincial Environmental Regulations. Section 14. Transport Information: DOT: Not regulated as hazardous goods. IATA: Not regulated as hazardous goods. IMDG: Not regulated as hazardous goods. Section 15. Regulatory Information This MSDS is prepared and distributed to the Federal Hazard Communication Standard, 29 CFR 1910.1200. The product(s) covered by this M(SDS) do not include any of the 15 substances in the Candidate List of Substances of Very High Concern (SVHC) for authorization published by ECHA on October 28, 2008 or the list of 15 substances proposed on August 31, 2009 above concentration of 0.1% weight by weight (w/w). Federal Regulations: All components are on the U.S. EPA TSCA Inventory List. US CWA Section 311 Reporting Quantities of Hazardous Substances: Reportable quantity Phenylethane 100-41-4 Ethylbenzene 1000 LBS Xylenes (o-, m-, p- 1330-20-7 Xylene (Mixed) 100 LBS isomers) US EPCRA (SARA Title III) Section 313- Toxic Chemical: Listed substance Phenylethane 100-41-4 Ethylbenzene US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Methylene Diphenyl 101-68-8 Methylenebis(Phenylisocya Isocyanate nate) (MDI) US EPCRA (SARA Title III) Section 313-Toxic Chemical: Listed substance. Xylenes (o-, m-, p- 1330-20-7 Xylene (mixed isomers) US isomers) EPCRA (SARA Title III) Section 313- Toxic Chemical: Listed substance. Methyl alcohol 67-56-1 MEHTANOL US EPCRA (SARA Title III) Section 313- Toxic Chemical: Listed substance. State Regulations: This product may contain an ingredient(s) known to the state of California to cause cancer, birth defects and/or reproductive harm. If any of the ingredients in this product are subject to the Proposition 65 regulations they will be listed as such on the product label. International Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations. HMIS Ratings: Health: 2* Flammability: 2 Physical Personal Hazard: 0 Protection: X SARA 311-312 Hazard Categories: Immediate Hazard- Yes Delayed Hazard- Yes Fire Hazard- Yes Pressure Hazard- No Reactivity Hazard- No WHMIS status: Controlled. WHMIS Labeling: WHMIS Classification: D2A- Other Toxic Effects- VERY TOXIC D2B- Other Toxic Effects- TOXIC Section 16. Other Information Product name(s) covered: A19200-1100 FS WHITE L A19217-BOST 1100 FS WHITE 24/10.1 A19221- 100FS WHITE S/PK 12/20.3 A19226- BOST 1100FS WHITE S/P 24/10.0 A25600- 1100 FS BLACK L A25614- BOST 1100 FS BLACK 24/10.1 A25617- BOST 1100FS BLACK S/P 24/10.0 A25620- 1100FS BLACK S/PK 12/20.0 A26800- 1100 FS STONE L A26810- Bostik 1100FS GRY S/PK 24/10.3 A26814- BOST 1100 FS GRAY 12/30.0 A26815- BOST 1100FS GRAY 24/10.1 A2816- 1100FS GRAY S/PK 12/20.3 A44400- 1100FS PUTTY L A46610- BOST 1100FS MM BEIGE 24/10.1 A64411- BOST 1100FS DARK GRAY 24/10.1 Disclaimer: The date in this MSDS has been compiled from publicly available sources. This date relates only to the designated product and not to the use of said product in combination with other materials. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Responsibility for proper precautions and safe use of the product lies with the user. All data in this MSDS is typical of the product as a whole, and does not represent any individual lot or batch, therefore, Bostik, Inc. makes no warranty about the accuracy of the data herein and assumes no liability for the use of such data. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations. Further Information: If there are any characters following an individual item number, they are just designations for the various types of packaging that are available for this product. For example, a product "G12345-XX" is item number "G12345" with a packaging destination of "XX". These characters do not indicate a different product nor a different regulatory, health, safety and/or environmental status. This document covers the item numbers listed above for all of their packaging types. Issue Date: 01/19/2010 Prepared By: Michael Simon Supercedes: 01/19/2010 This date sheet contains changes from This document has undergone the previous version in section(s): significant changes and should be reviewed in its entirety.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.