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SDS Sheet 0075640Printer Friendly View
Safety Data Sheet Date of Issue: |Revision Date: 2015-05-05 |Revision Number: Imperial Supplies Part Number: 0075640 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: Poly - 50 CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: Glass repair resin used in item #410 1.3. Name, Address, and Telephone of the Responsible Party Company Glass Star America, Inc. 15 Frowein Rd. Bldg E-2 Center Moriches, NY 11934 Phone: 631-951-0443 1.4. Emergency Telephone Number Emergency | Emergency number: Poison Control Centers may be available in number |specific member countries. SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Ex. Compressed|H280 gas | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Exclamat|Environme|Corrosi| | | |ion Mark|nt |on | | | Signal Word (GHS-US) |Warning Hazard Statements (GHS-US) |H302 Harmful if swallowed |H314 Can cause skin burns and eye damage |H411 Toxic to aquatic life Precautionary Statements |P280 Wear protective gloves and eye wear (GHS-US) |P273 Avoid release into the environment |P270 Do not eat, drink, or smoke when using this |product |P264 Wash hands with soap and water after handling |P233 Keep container tightly closed |Response: |P310 If in eves: Rinse with water for several |minutes |P303 If contact with skin: Remove all contaminated |clothing |and rinse with generous amounts of soap and water |P361 If contact with skin: Remove all contaminated |clothing |and rinse with generous amounts of soap and water |P352 If contact with skin: Remove all contaminated |clothing |and rinse with generous amounts of soap and water |P301 If swallowed: Rinse mouth. Do not induce |vomiting |P330 If swallowed: Rinse mouth. Do not induce |vomiting |P331 If swallowed: Rinse mouth. Do not induce |vomiting |In case of fire use dry powder, foam, or |extinguisher |Storage: |Store locked up. |Store in well ventilated area |Keep cool |Disposal: |Dispose of contents in hazardous or special waste |collection point 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Isobornyl Acrylate |5888-33-5 |50 - 75 | 2-Hydroxyethyl Methacrylate |868-77-9 |15 - 25 | Urethanc (Meth) Acrylate | |15 - 25 | Oligomer | | | Acrylic Acid |7910-7 |5 - 10 | Photoinitiator |947-19-3 |1 - 5 | Silane coupling agent |2530-85-0 |1 - 5 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Immediately remove any clothing soiled by the product. First-aid Measures After Inhalation: Supply fresh air and be sure to call a doctor. In case of unconsciousness, place patient stably in side position for transportation. First-aid Measures After Skin Contact: Immediately wash with water and soap, rinse thoroughly. First-aid Measures After Eye Contact: Rinse opened eye for several minutes under running water. Then consult a doctor. First-aid Measures After Ingestion: Drink copious amounts of water and provide fresh Immediately call a doctor. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: C02, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Unsuitable Extinguishing Media: 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Please refer to section 8 for more information. Protection During Firefighting: SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Wear protective equipment. Keep unprotected persons away. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/surface or ground water. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Absorb with liquid-binding materials (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Keep away from heat and direct sunlight. Ensure good ventilation/exhaustion at workplace. Prevent formation of aerosols. Hygiene Measures: Keep away from food, beverages and feed. Immediately remove soiled contaminated clothing. Wash hands before breaks and the end of work. Avoid contact with eyes and skin. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store only in original receptacle. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. Protect from exposure to the light. Avoid loss of dissolved air, loss of inhibitor, and contamination with incompatible materials. Maximum storage teperature: <38 Â°C (100Â°F>. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components with limit values that require monitoring at the workplace; 79-10-7 Acrylic acid (5-10%) REL 6 mg/m 3, 2 ppm Skin TLV 5.9 mg/m3, 2 ppm Skin Additional information: The lists were valid during the creation were used as basis. 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Protective glove material has to be impermeable and |resistant to the product/ the substance/ the |preparation.Due to missing tests no recommendation |of glove material can be given for the product/ the |preparation/ the chemical mixture. Selection of |glove material in consideration of the penetration |times, rates of diffusion and the degradation. Eye Protection |Tightly sealed goggles. Skin and Body Protection |The selection of the suitable gloves does not only |depend on the material, hut also on further marks of |quality and varies from manufacturer. As the product |is a preparation of several substances, the |resistance of the glove material cannot be |calculated in advance and should be checked prior to |the application. Respiratory Protection |Breathing equipment: In case of brief exposure or |low pollution use respiratory filter device. In case |of intensive or longer exposure use respiratory |protective device that is independent of circulating |air. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance | Odor | Odor Threshold | pH | Relative Evaporation Rate | (butylacetate=1) | Melting Point | Freezing Point | Boiling Point | Flash Point |214.0 Â°F(101 Â°C) Auto-ignition Temperature | Decomposition Temperature | Flammability (solid, gas) | Vapor Pressure | Relative Vapor Density at 20 Â°C | Relative Density | Specific Gravity | Solubility | Partition coefficient: | n-octanol/water | Viscosity | Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability 10.3 Possibility of Hazardous Reactions 10.4 Conditions to Avoid Material to be avoided: Oxidizers, amines, strong, Lewis acids, mineral acids, and thiosulfates. 10.5 Incompatible Materials 10.6 Hazardous Decomposition Products No decomposition if used according to specifications. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: The product shows the following dangers according to internally approved calculation methods for preparations: Corrosive, Irritant. Swallowing will lead to a strong caustic effect on the mouth and throat and danger of perforation of the esophagus and stomach. Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: Sentization possible through skin contact. Germ Cell Mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific Target Organ Toxicity (Single Exposure): Specific Target Organ Toxicity (Repeated Exposure): Aspiration Hazard: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Caustic effect on skin and mucous membranes. Symptoms/Injuries After Eye Contact: Strong caustic effect. Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Toxic for fish. 12.2. Persistence and Degradability 12.3. Bioaccumulative Potential 12.4. Mobility in Soil 12.5. Other Adverse Effects Water hazard class 2 (Self-assessment): hazardous water. Do not allow product to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or un-neutralized. Danger to drinking water, even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Must be disposed of together with household garbage. Do not allow to reach sewage. Uncleaned packages Recommendations: Disposal must be made according to official regulations. Additional Information: SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |The product is not covered by international regulation on |the transport of dangerous goods. Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |The product is not covered by international regulation on |the transport of dangerous goods. Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> SARA Section 311/312 Hazard Classes | Toxic Substances Control Act (TSCA) | 15.2 US State Regulations <COMPONENT> SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |2015-05-05 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|H302 |Harmful if swallowed. -- | | ----|H312 |Harmful in contact with skin. -- | | ----|H314 |Causes severe skin burns and eye damage. -- | | ----|H315 |Causes skin irritation. -- | | ----|H317 |May cause an allergic skin reaction. -- | | |H319 |Causes serious eye irritation. Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.