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SDS Sheet 0075200Printer Friendly View
Safety Data Sheet Date of Issue: 27-May-2015 |Revision Date: |Revision Number: 01 Imperial Supplies Part Number: 0075200 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Liquid Product Name: Oatey Clear Cleaner CAS No: Synonyms: Part Numbers: 30766, 30779, 30782, 30795, 30805, 32216, 32217, 32218, 32219 1.2. Intended Use of the Product Use of the substance/mixture: Cleaning PVC, CPVC or ABS pipe and fittings 1.3. Name, Address, and Telephone of the Responsible Party Company: Oatey Inc. 4700 West 160th Street Cleveland, OH 44135 Phone: 216-267-7100 1.4. Emergency Telephone Number Emergency | Chemtrec 1-800-424-9300 (Outside the US 1-703-527-3887) number |Emergency First Aid: 1-877-740-5015 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 2 liquids | Acute |Category 4 toxicity, oral| Skin |Category 2 corrosion/irri| tation | Serious eye |Category 2A damage/eye | irritation | Specific |Category 3 target organ |respiratory toxicity, |tract single |irritation exposure | Specific |Category 3 target organ |narcotic toxicity, |effects single | exposure | Aspiration |Category 1 hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Health |Exclamat| | | | |Hazard |ion Mark| | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |Highly flammable liquid and vapor. Harmful if |swallowed. May be fatal if swallowed and enters |airways. Causes skin irritation. Causes serious eye |irritation. May cause respiratory irritation. May |cause drowsiness or dizziness. Precautionary Statements |Prevention: (GHS-US) |Keep away from heat/sparks/open flames/hot surfaces. |- No smoking. Keep container tightly closed. |Ground/bond container and receiving equipment. Use |explosion-proof electrical/ventilating/lighting |equipment. Use only non-sparking tools. Take |precautionary measures against static discharge. |Avoid breathing mist or vapor. Wash thoroughly after |handling. Do not eat, drink or smoke when using this |product. Use only outdoors or in a wellventilated |area. Wear protective gloves/protective clothing/eye |protection/face protection. | |Response: |If swallowed: Immediately call a poison |center/doctor. If on skin (or hair): Take off |immediately all contaminated clothing. Rinse skin |with water/shower. If inhaled: Remove person to |fresh air and keep comfortable for breathing. If in |eyes: Rinse cautiously with water for several |minutes. Remove contact lenses, if present and easy |to do. Continue rinsing. Call a poison center/doctor |if you feel unwell. Rinse mouth. Do NOT induce |vomiting. If skin irritation occurs: Get medical |advice/attention. If eye irritation persists: Get |medical advice/attention. Take off contaminated |clothing and wash before reuse. In case of fire: Use |appropriate media to extinguish. | |Storage: |Store in a well-ventilated place. Keep container |tightly closed. Keep cool. Store locked up. | |Disposal: |Dispose of contents/container in accordance with |local/regional/national/international regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. May form explosive peroxides. 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Acetone |67-64-1 |75-95 | Cyclohexanone |108-94-1 |1-5 | Methy ethyl ketone |78-93-3 |0-5 | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Take off all contaminated clothing immediately. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. First-aid Measures After Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid Measures After Skin Contact: Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. First-aid Measures After Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid Measures After Ingestion: Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin irritation. May cause redness and pain. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. During fire, gases hazardous to health may be formed. Explosion Hazard: Highly flammable liquid and vapor. This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Specific methods: Use standard firefighting procedures and consider the hazards of other involved materials. Protection During Firefighting: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Avoid discharge into drains, water courses or onto the ground. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Methods for Cleaning Up: Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or divert vapor cloud drift. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original container for reuse. For waste disposal, see sect. 13 of the SDS. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Vapors may form explosive mixtures with air. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Hygiene Measures: When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Occupational exposure limits: US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Components Type Value FORM Acetone (CAS 67-64-1) PEL 2400 mg/m3 1000 ppm Cyclohexanone (CAS 108-94-1) PEL 200 mg/m3 50 ppm Methyl ethyl ketone (CAS 78-93-3) PEL 590 mg/m3 200 pp, US. ACGIH Threshold Limit Values Components Type Value FORM Acetone (CAS 67-64-1) STEL TWA 750 ppm 500 ppm Cyclohexanone (CAS 108-94-1) STEL 50 ppm Methyl ethyl ketone (CAS 78-93-3) STEL TWA 300 ppm 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Type Acetone (CAS 67-64-1) TWA 590 mg/m3 250 ppm Cyclohexanone (CAS 108-94-1) TWA 100 mg/m3 25 ppm Methyl ethyl ketone (CAS 78-93-3) STEL TWA 885 mg/m3 300 ppm 590 mg/m3 200 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time Acetone (CAS 67-64-1) 50 mg/l Acetone Urine * Cyclohexanone (CAS 108-94-1) 80 mg/l 8 mg/l 1,2-Cyclohexanediol, with hydrolysis Cyclohexanol, with hydrolysis Urine * Methyl ethyl ketone (CAS 78-93-3) 2 mg/l MEK Urine * *- For sampling details, see the source document. 8.2. Exposure Controls Appropriate Engineering |Explosion-proof general and local exhaust Controls |ventilation. Good general ventilation (typically 10 |air changes per hour) should be used. Ventilation |rates should be matched to conditions. If |applicable, use process enclosures, local exhaust |ventilation, or other engineering controls to |maintain airborne levels below recommended exposure |limits. If exposure limits have not been |established, maintain airborne levels to an |acceptable level. Eye wash facilities and emergency |shower must be available when handling this product. Personal Protective Equipment| Materials for Protective |Wear appropriate chemical resistant clothing. Clothing | Hand Protection |Wear appropriate chemical resistant gloves. Eye Protection |Face shield is recommended. Wear safety glasses with |side shields (or goggles). Skin and Body Protection | Respiratory Protection |If engineering controls do not maintain airborne |concentrations below recommended exposure limits |(where applicable) or to an acceptable level (in |countries where exposure limits have not been |established), an approved respirator must be worn. Thermal Hazard Protection |Wear appropriate thermal protective clothing, when |necessary. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance | Odor |Solvent Odor Threshold |Not available. pH |Not Applicable Relative Evaporation Rate |5.5 - 8 (butylacetate=1) | Melting Point |Not available. Freezing Point |Not available. Boiling Point |151 Â°F (66.11 Â°C) Flash Point |0.0 - 4.0 Â°F (-18 to -15Â°C) Auto-ignition Temperature |Not Available Decomposition Temperature |>150Â°C (>302Â°F) Flammability (solid, gas) | Vapor Pressure |145 mmHg @ 20 C Relative Vapor Density at 20 Â°C | Relative Density |0.82 +/- 0.02 Specific Gravity | Solubility |Negligible (water) Partition coefficient: |Not Available n-octanol/water | Viscosity |Not Available Lower Flammable Limit |2.0 Upper Flammable Limit |13.0 9.2. Other Information Bulk Density: 6.8 lb/gal VOC (Weight %): 20g/L SCAQMD 1168/M24 SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. 10.2 Chemical Stability Material is stable under normal conditions. 10.3 Possibility of Hazardous Reactions No dangerous reaction known under conditions of normal use. 10.4 Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. 10.5 Incompatible Materials Acids. Strong oxidizing agents. Ammonia. Amines. Isocyanates. Caustics. 10.6 Hazardous Decomposition Products No hazardous decomposition products are known. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Respiratory sensitization: Not available. Skin sensitization: This product is not expected to cause skin sensitization. Germ Cell Mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity: IARC Mongraphs. Overall Evaluation of Carcingenicity Cyclohexanone (CAS 108-94-1) 3 Not classifiable as to carcinogenicity to humans. Polyvinyl chloride (CAS 9002-86-2) 3 Not classifiable as to carcinogenicity to humans. Silica, amorphous, fumed (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Polyvinyl chloride (CAS 9002-86-2) Cancer Reproductive Toxicity: This product is not expected to cause reproductive or developmental effects. Specific Target Organ Toxicity (Single Exposure): Narcotic effects. May cause drowsiness and dizziness. Respiratory tract irritation. Specific Target Organ Toxicity (Repeated Exposure): Not Classified. Aspiration Hazard: May be fatal if swallowed and enters airways. Symptoms/Injuries After Inhalation: May be fatal if swallowed and enters airways. Headache. Nausea, vomiting. May cause irritation to the respiratory system. Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Prolonged inhalation may be harmful. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: May be fatal if swallowed and enters airways. Harmful if swallowed. Harmful if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Chronic Symptoms: Prolonged inhalation may be harmful. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Results Acetone (CAS 67-64-1) Aquatic Fish - LC 50 Fathead minnow (Pimephales promelas) >100 mg/l, 96 hours Cyclohexanone (108-94-1) Aquatic Fish - LC 50 Fathead minnow (Pimephales promelas) 481-578 mg/l, 96 hours 12.2. Persistence and Degradability No data is available on the degradability of this product. 12.3. Bioaccumulative Potential No data is available. Partition coefficient n-octanol / water (log Kow) Acetone (CAS 67-64-1) -0.24 Cyclohexanone (CAS 108-94-1) 0.81 Methyl ethyl ketone (CAS 78-93-3) 0.29 12.4. Mobility in Soil Not available 12.5. Other Adverse Effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local, regional, national or international regulations. Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Additional Information: Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |Flammable liquids, n.o.s. (Acetone RQ = 5128 LBS) Hazard Class |3 |<PICTOGRAM PHRASE> Identification Number|UN1993 | Label Codes |3 | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Flammable liquid, n.o.s. (Acetone, Cyclohexanone) Hazard Class |3 Identification Number|UN1993 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-E | EmS-No. (Spillage) |S-E | 14.3 In Accordance with IATA Proper Shipping Name |Flammable liquid, n.o.s. (Acetone, Cyclohexanone) Identification Number|UN1993 |<PICTOGRAM PHRASE> Hazard Class |3 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) |3H SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) LISTED Cyclohexanone (CAS 108-94-1) LISTED Methyl ethyl ketone (CAS 78-93-3) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance: Not Listed SARA 313 (TRI reporting): Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Safe Drinking Water Act (SDWA): Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV Methyl ethyl ketone (CAS 78-93-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Methyl ethyl ketone (CAS 78-93-3) 6714 SARA Section 311/312 Hazard Classes |Immediate Hazard - Yes |Delayed Hazard - No |Fire Hazard - Yes |Pressure Hazard - No |Reactivity Hazard - No Toxic Substances Control Act (TSCA) |Not Regulated 15.2 US State Regulations US. Massachusetts RTK - Substance List Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Methyl ethyl ketone (CAS 78-93-3) US. New Jersey Worker and Community Right-to-Know Act Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Methyl ethyl ketone (CAS 78-93-3) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Methyl ethyl ketone (CAS 78-93-3) US. Rhode Island RTK Acetone (CAS 67-64-1) Cyclohexanone (CAS 108-94-1) Methyl ethyl ketone (CAS 78-93-3) US. California Proposition 65: California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date | Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.