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Safety Data Sheet | | Date of Issue: 01/09/2015 |Revision Date: 01/05/2015 |Revision Number: 1.0 Imperial Supplies Part Number: 0075100 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Mixture Product Name: HH-66 Thinner CAS No: Synonyms: Solvent Blend 1.2. Intended Use of the Product Use of the substance/mixture: No additional information available. 1.3. Name, Address, and Telephone of the Responsible Party Company Name: RH Products Co., Inc. 308 Old High Street Acton MA USA 01720 Phone: 1-978-897-8000 Supplier: Imperial Supplies LLC 1.4. Emergency Telephone Number Emergency | 1-800-535-5053 INFOTRAC; 1-352-323-3500 INFOTRAC International number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flam. Liq. 2 |H225 Skin Irrit. 2 |H315 Eye Irrit. 2A |H319 Repr. 2 |H361 STOT SE 3 |H336 STOT RE 2 |H373 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Exclamat|Health | | | | |ion mark|hazard | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H225 - Highly flammable liquid and vapor. |H315 - Causes skin irritation. |H319 - Causes serious eye irritation. |H336 - May cause drowsiness or dizziness. |H361 - Suspected of damaging fertility or the unborn |child. |H373 - May cause damage to organs through prolonged |or repeated exposure. Precautionary Statements |P201 - Obtain special instructions before use. (GHS-US) |P202 - Do not handle until all safety precautions |have been read and understood. P210 - Keep away from |heat, hot surfaces, open flames, sparks - No |smoking. P233 - Keep container tightly closed. |P240 - Ground/bond container and receiving |equipment. |P241 - Use explosion-proof electrical, lighting, |ventilating equipment. |P242 - Use only non-sparking tools. |P243 - Take precautionary measures against static |discharge. |P260 - Do not breathe vapors, mist, spray. |P264 - Wash hands, forearms, and exposed areas |thoroughly after handling. |P271 - Use only outdoors or in a well-ventilated |area. |P280 - Wear eye protection, protective clothing, |protective gloves. |P303+P361+P353+P352 - If on skin (or hair): Take off |immediately all contaminated clothing. Rinse skin |with water/shower. Wash with plenty of water. |P304+P340 - IF INHALED: Remove person to fresh air |and keep at rest in a position comfortable for |breathing. |P305+P351+P338 - IF IN EYES: Rinse cautiously with |water for several minutes. |Remove contact lenses, if present and easy to do. |Continue rinsing. |P308+P313 - If exposed or concerned: Get medical |advice/attention. |P312 - Call a poison center if you feel unwell. |P321 - Specific treatment (see Section 4). |P332+P313 - If skin irritation occurs: Get medical |advice/attention. |P337+P313 - If eye irritation persists: Get medical |advice/attention. |P362 - Take off contaminated clothing and wash |before reuse. |P370+P378 - In case of fire: Use dry chemical |powder, alcohol-resistant foam, carbon dioxide (CO2) |to extinguish. |P403+P233 - Store in a well-ventilated place. Keep |container tightly closed. P235+P405 - Keep cool. |Store locked up. |P501 - Dispose of contents/container according to |local, regional, national, and international |regulations. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: Aquatic Acute 3 Aquatic Chronic 3 H412 - Harmful to aquatic life with long lasting effects. P273 - Avoid release to the environment. 2.4. Unknown Acute Toxicity (GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Toluene |(CAS No) 108-88-3 |72 |Flam- Liq. 2, H225 | | |Skin Irrit. 2, | | |H315 Repr. 2, H361 | | |STOTSE 3, H336 | | |STOT RE 2, H373 | | |Asp. Tox. 1, H304 | | |Aquatic Acute 2, | | |H401 Aquatic | | |Chronic 3, H412 Acetone |(CAS No) 67-64-1 |18.6 |Flam- Liq. 2, H225 | | |Eye Irrit. 2A, | | |H319 STOTSE 3, | | |H336 Methyl ethyl ketone |(CAS No) 78-93-3 |9.4 |Flam- Liq. 2, H225 | | |Eye Irrit. 2A, | | |H319 STOTSE 3, | | |H336 | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid Measures After Inhalation: Using proper respiratory protection, immediately move the exposed person to fresh air. Assure fresh air breathing. Call a physician if symptoms occur. First-aid Measures After Skin Contact: Remove contaminated clothing. Gently wash with plenty of soap and water followed by rinsing with water for at least 15 minutes. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. First-aid Measures After Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Causes skin irritation. Causes serious eye irritation. Vapors may cause drowsiness and dizziness. Symptoms/Injuries After Inhalation: High concentration of vapours may induce: headache, dizziness, drowsiness, nausea and vomiting. Symptoms/Injuries After Skin Contact: Causes skin irritation. Repeated exposure may cause skin dryness or cracking. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms: May cause damage to organs through prolonged or repeated exposure. May cause damage to central nervous system, liver, and kidneys. Suspected of damaging fertility or the unborn child. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Highly flammable liquid and vapor. Explosion Hazard: May form flammable/explosive vapor-air mixture. Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Reactivity: Reacts violently with oxidants causing fire and explosion hazard. 5.3. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Use water spray or fog for cooling exposed containers. Do not get water inside containers. Do not apply water stream directly at source of leak. Fight fire from safe distance and protected location. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use special care to avoid static electric charges. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not get in eyes, on skin, or on clothing. Do not breathe vapour or mist. 6.1.1. For Non-emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Responders Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Ventilate area. Eliminate ignition sources. Stop leak if safe to do so. 6.2. Environmental Precautions Prevent entry to sewers and public waters. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Absorb and/or contain spill with inert material, then place in suitable container. Do not take up in combustible material such as: saw dust or cellulosic material. Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely. Use only non-sparking tools. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Handle empty containers with care because residual vapors are flammable. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Other Information: When using, do not eat, drink or smoke. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Proper grounding procedures to avoid static electricity should be followed. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep in fireproof place. 7.3. Specific End Use(s) No additional information available SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Toluene (108-88-3) USA ACGIH ACGIH TWA (ppm) 20 ppm USA NIOSH NIOSH REL (TWA) (mg/mÂ³) 375 mg/mÂ³ USA NIOSH NIOSH REL (TWA) (ppm) 100 ppm USA NIOSH NIOSH REL (STEL) (mg/mÂ³) 560 mg/mÂ³ USA NIOSH NIOSH REL (STEL) (ppm) 150 ppm USA IDLH US IDLH (ppm) 500 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm Acetone (67-64-1) USA ACGIH ACGIH TWA (ppm) 500 ppm USA ACGIH ACGIH STEL (ppm) 750 ppm USA NIOSH NIOSH REL (TWA) (mg/mÂ³) 590 mg/mÂ³ USA NIOSH NIOSH REL (TWA) (ppm) 250 ppm USA IDLH US IDLH (ppm) 2500 ppm (10% LEL) USA OSHA OSHA PEL (TWA) (mg/mÂ³) 2400 mg/mÂ³ USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm Methyl ethyl ketone (78-93-3) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 300 ppm USA NIOSH NIOSH REL (TWA) (mg/mÂ³) 590 mg/mÂ³ USA NIOSH NIOSH REL (TWA) (ppm) 200 ppm USA NIOSH NIOSH REL (STEL) (mg/mÂ³) 885 mg/mÂ³ USA NIOSH NIOSH REL (STEL) (ppm) 300 ppm USA IDLH US IDLH (ppm) 3000 ppm USA OSHA OSHA PEL (TWA) (mg/mÂ³) 590 mg/mÂ³ USA OSHA OSHA PEL (TWA) (ppm) 200 ppm 8.2. Exposure Controls Appropriate Engineering |Emergency eye wash fountains and safety showers Controls |should be available in the immediate vicinity of any |potential exposure. Gas detectors should be used |when flammable gases/vapors may be released. Provide |exhaust ventilation or other engineering controls to |keep the airborne concentrations of vapor or mists |below the applicable workplace exposure limits |indicated above. All electrical equipment should |comply with the National Electric Code. Ensure all |national/local regulations are observed. Personal Protective Equipment|Full protective flameproof clothing. Protective |goggles. Gloves. Insufficient ventilation: wear |respiratory protection. Materials for Protective |Wear fire/flame resistant/retardant clothing. Clothing | Hand Protection |Wear chemically resistant protective gloves. Eye Protection |Chemical goggles or safety glasses. Skin and Body Protection |Wear suitable protective clothing. Respiratory Protection |Use NIOSH-approved air-purifying or supplied-air |respirator where airborne concentrations of vapor or |mist are expected to exceed exposure limits. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State |Liquid Appearance |Clear Odor |Strong Aromatic Odor/sharp mint like |fragrance Odor Threshold |No data available pH |No data available Relative Evaporation Rate (butyl |No data available acetate=1) | Melting Point |No data available Freezing Point |No data available Boiling Point |> 35 Â°C (95.00 Â°F) Flash Point |No data available Auto-ignition Temperature |No data available Decomposition Temperature |No data available Flammability (solid, gas) |No data available Vapor Pressure |180 mm Hg at 20 Â°C (68 Â°F) Relative Vapor Density at 20 Â°C |> 1 (heavier than air) Relative Density |0.84 (water = 1) Specific Gravity | Solubility |Insoluble in water. Partition coefficient: |No data available n-octanol/water | Viscosity |No data available Lower Flammable Limit |1 % Upper Flammable Limit |11 % 9.2. Other Information VOC content: 81.4 % (5.8 lbs/gal or 700 g/l) SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Reacts violently with oxidants causing fire and explosion hazard. 10.2 Chemical Stability Stable under recommended handling and storage conditions (see section 7). 10.3 Possibility of Hazardous Reactions Hazardous polymerization will not occur. 10.4 Conditions to Avoid Direct sunlight. Extremely high or low temperatures. Open flame. Ignition sources. 10.5 Incompatible Materials Strong acids. Strong bases. Strong oxidizers. 10.6 Hazardous Decomposition Products Carbon oxides (CO, CO2). SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Not classified Skin Corrosion/Irritation: Causes skin irritation. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified Reproductive Toxicity: Suspected of damaging fertility or the unborn child. Specific Target Organ Toxicity (Single Exposure): May cause drowsiness or dizziness. Specific Target Organ Toxicity (Repeated Exposure): May cause damage to organs through prolonged or repeated exposure. Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: High concentration of vapours may induce: headache, dizziness, drowsiness, nausea and vomiting. Symptoms/Injuries After Skin Contact: Causes skin irritation. Repeated exposure may cause skin dryness or cracking. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms: May cause damage to organs through prolonged or repeated exposure. May cause damage to central nervous system, liver, and kidneys. Suspected of damaging fertility or the unborn child. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecology - General: Harmful to aquatic life with long lasting effects. 12.2. Persistence and Degradability Readily biodegradable in water. 12.3. Bioaccumulative Potential 12.4. Mobility in Soil No additional information available 12.5. Other Adverse Effects Other Information: Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, and international regulations. Additional Information: Handle empty containers with care because residual vapors are flammable. RCRA Waste Number: D001. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name |PAINT RELATED MATERIAL including paint thinning, drying, |removing, or reducing compound Hazard Class |3 |<PICTOGRAM PHRASE> Identification Number|UN1263 | Label Codes |3 | ERG Number |128 14.2 In Accordance with IMDG Proper Shipping Name |PAINT RELATED MATERIAL Hazard Class |3 Identification Number|UN1263 Label Codes |3 |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) |F-E | EmS-No. (Spillage) |S-E | 14.3 In Accordance with IATA Proper Shipping Name |PAINT RELATED MATERIAL Identification Number|UN1263 |<PICTOGRAM PHRASE> Hazard Class |3 | Label Codes |3 | ntification Of The | | Substance/m | | ERG Code (IATA) |3L SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Toluene (108-88-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 RQ (Reportable quantity, section 304 of EPA's List of Lists) : 1000 lb SARA Section 313 - Emission Reporting 1.0 % Acetone (67-64-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. Methyl ethyl ketone (78-93-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes |Fire hazard |Immediate (acute) health hazard |Delayed (chronic) health hazard Toxic Substances Control Act (TSCA) |Toluene 108-88-3 |Acetone 67-64-1 |Methyl ethyl ketone 78-93-3 15.2 US State Regulations <COMPONENT> Toluene (108-88-3) U.S. - California - Proposition 65 - Developmental Toxicity WARNING: This product contains chemicals known to the State of California to cause birth defects. U.S. - California - Proposition 65 - Reproductive Toxicity - Female WARNING: This product contains chemicals known to the State of California to cause (Female) reproductive harm. Toluene (108-88-3) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Acetone (67-64-1) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List Methyl ethyl ketone (78-93-3) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |10/3/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Aquatic Acute 2 |Hazardous to the aquatic environment - Acute -- | |Hazard Category 2 ----|Aquatic Acute 3 |Hazardous to the aquatic environment - Acute -- | |Hazard Category 3 ----|Aquatic Chronic 3 |Hazardous to the aquatic environment - -- | |Chronic Hazard Category 3 ----|Asp. Tox. 1 |Aspiration hazard Category 1 -- | | ----|Eye Irrit. 2A |Serious eye damage/eye irritation Category 2A -- | | |Flam. Liq. 2 |Flammable liquids Category 2 R |Repr. 2 |Reproductive toxicity Category 2 |Skin Irrit. 2 |Skin corrosion/irritation Category 2 |STOT RE 2 |Specific target organ toxicity (repeated | |exposure) Category 2 |STOT RE 3 |Specific target organ toxicity (Single | |exposure) Category 3 |H225 |Highly flammable liquid and vapor |H304 |May be fatal if swallowed and enters airways |H315 |Causes skin irritation |H319 |Causes serious eye irritation |H336 |May cause drowsiness or dizziness |H361 |Suspected of damaging fertility or the unborn | |child |H373 |May cause damage to organs through prolonged | |or repeated exposure |H401 |Toxic to aquatic life |H402 |Harmful to aquatic life |H412 |Harmful to aquatic life with long lasting | |effects Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.