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Sheet 0071900 Printer Friendly ViewSafety Data Sheet Date of Issue: |Revision Date: 04/22/2015 |Revision Number: 1.0 Imperial Supplies Part Number: 0071900 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: BZ7506 BARRIER CREAM R25801 12QT/CS CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company Zep Inc. 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Phone: 404-352-1680 1.4. Emergency Telephone Number Emergency |For SDS Information: Compliance Services 1-877-428-9937 number |For a Medical Emergency: 877-541-2016 Toll Free - All Calls |Recorded |For a Transportation Emergency: CHEMTREC: 800-424-9300 - All Calls |Recorded. In the District of Columbia 202-483-7616 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Not a | hazardous | substance or | mixture. | | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) | | | | | | Signal Word (GHS-US) | Hazard Statements (GHS-US) | Precautionary Statements | (GHS-US) | 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Glycerol |56-81-5 |>= 1 - <| | |5 | propane-1,2-diol |57-55-6 |>= 1 - <| | |5 | | | | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. First-aid Measures After Inhalation: If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. First-aid Measures After Skin Contact: This product is formulated for use on skin but should always be immediately washed off with plenty of water. Discontinue use if irritation and redness develop. If conditions persist for more than 72 hours, condult a physician. First-aid Measures After Eye Contact: Rinse immediately with plenty of water for at least 15 minutes. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. First-aid Measures After Ingestion: Keep respiratory tract clear. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Water spray jet. Unsuitable Extinguishing Media: High volume water jet. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Do not allow run-off from fire fighting to enter drains or water courses. Explosion Hazard: Carbon dioxide (CO2) Carbon monoxide Smoke Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Protection During Firefighting: Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Material can create slippery conditions. Use non-slip safety shoes in areas where spills or leaks can occur. Refer to protective measures listed in sections 7 and 8. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid contact with eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Materials to avoid: No materials to be especially mentioned. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components with workplace control parameters: Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Glycerol 56-81-5 TWA (mist, respirable fraction) 5 mg/m3 OSHA Z-1 TWA (mist, total dust) 15 mg/m3 OSHA Z-1 propane-1,2-diol 57-55-6 TWA 10 mg/m3 US WEEL 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |No special protection is required. Eye Protection |Eye protection is not required while washing with |this product. In the workplace, the use of safety |glasses is recommended to avoid eye exposure during |the handling of containers or during spill clean-up. Skin and Body Protection |No special protection is required. Respiratory Protection |In case of insufficient ventilation, wear suitable |respiratory equipment. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |Cream Odor |Pleasant Odor Threshold |No data available pH |6.5 - 7.5 Relative Evaporation Rate |< 1 (butylacetate=1) | Melting Point |No data available Freezing Point |No data available Boiling Point |104.44 �C Flash Point |No data available Auto-ignition Temperature |Not determined Decomposition Temperature |No data available Flammability (solid, gas) | Vapor Pressure |No data available Relative Vapor Density at 20 �C |No data available Relative Density | Specific Gravity | Solubility |Completely miscible Partition coefficient: |No data available n-octanol/water | Viscosity |No data available Lower Flammable Limit |Not applicable Upper Flammable Limit |Not applicable 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable. 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions Stable under recommended storage conditions. 10.4 Conditions to Avoid No data available. 10.5 Incompatible Materials No data available. 10.6 Hazardous Decomposition Products No data available. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Product: Acute oral toxicity: Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Skin Corrosion/Irritation: Product: Result: No skin irritation Serious Eye Damage/Irritation: Product: Result: No eye irritation Respiratory or Skin Sensitization: No data available. glycerol: propane-1,2-diol: Germ Cell Mutagenicity: No data available. Carcinogenicity: No data available. Reproductive Toxicity: No data available. Glycerol: Propane-1,2-diol: Specific Target Organ Toxicity (Single Exposure): No data available. Specific Target Organ Toxicity (Repeated Exposure): No data available. Aspiration Hazard: No data available. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: No data available. 12.2. Persistence and Degradability No data available. 12.3. Bioaccumulative Potential Product: Partition coefficient: n-octanol/water: Remarks: no data available Components: Glycerol: Partition coefficient: n-log Pow: -1.76 propane-1,2-diol : Partition coefficient: n-: log Pow: -1.07 12.4. Mobility in Soil No data available. 12.5. Other Adverse Effects No data available. Product: Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances. Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Harmful to aquatic life with long lasting effects. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations. Additional Information: Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Vessel: NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS |MATERIAL Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Cargo Air: NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS |MATERIAL |Passenger Air: NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS |MATERIAL Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> EPCRA - Emergency Planning and Community Right-to-Know Act: CERCLA Reportable Quantity: Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) ethane-1,2-diol 107-21-1 5000 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity: This material does not contain any components with a section 304 EHS RQ. SARA 302: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313: SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA Section 311/312 Hazard Classes |No SARA Hazards Toxic Substances Control Act (TSCA) |On TSCA Inventory 15.2 US State Regulations <COMPONENT> California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |04/22/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer. The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance. |