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SDS Sheet 0071880Printer Friendly View
Safety Data Sheet Date of Issue: |Revision Date: 10/22/2014 |Revision Number: 1.0 Imperial Supplies Part Number: 0071880 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: BZ7372 LW FM CLNR DGRSR R03224 4/1GL CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company: Zep Inc. 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Phone: 404-352-1680 1.4. Emergency Telephone Number Emergency | For SDS Information: Compliance Services 1-877-428-9937 number |For a Medical Emergency: 877-541-2016 Toll Free - All Calls |Recorded |For a Transportation Emergency: CHEMTREC: 800-424-9300 - All Calls |Recorded. In the District of Columbia 202-483-7616 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin corrosion|Category 1A Serious eye |Category 1 damage | Skin |Category 1 sensitisation | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Corrosio|Exclamat| | | | |n |ion Mark| | | | Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H314 Causes severe skin burns and eye damage. |H317 May cause an allergic skin reaction. Precautionary Statements |Prevention: (GHS-US) |P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ |spray. |P264 Wash skin thoroughly after handling. |P272 Contaminated work clothing should not be |allowed out of the workplace. |P280 Wear protective gloves/ protective clothing/ |eye protection/ face protection. |Response: |P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT |induce vomiting. |P303 + P361 + P353 IF ON SKIN (or hair): Remove/ |Take off immediately all contaminated clothing. |Rinse skin with water/ shower. |P304 + P340 + P310 IF INHALED: Remove victim to |fresh air and keep at rest in a position comfortable |for breathing. Immediately call a POISON CENTER or |doctor/ physician. |P305 + P351 + P338 + P310 IF IN EYES: Rinse |cautiously with water for several minutes. Remove |contact lenses, if present and easy to do. Continue |rinsing. Immediately call a POISON CENTER or doctor/ |physician. |P333 + P313 If skin irritation or rash occurs: Get |medical advice/ attention. |P363 Wash contaminated clothing before reuse. |Storage: |P405 Store locked up. |Disposal: |P501 Dispose of contents/container in accordance |with local regulation. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) 2-butoxyethanol |111-76-2 |>= 5 - <| | |10 | sodium xylenesulphonate |1300-72-7 |>= 1 - <| | |5 | Alcohols, C10-14, ethoxylated |66455-15-0 |>= 1 - <| | |5 | disodium metasilicate |6834-92-0 |>= 1 - <| | |5 | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. First-aid Measures After Inhalation: If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. First-aid Measures After Skin Contact: Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If on skin, rinse well with water. If on clothes, remove clothes. First-aid Measures After Eye Contact: Small amounts splashed into eyes can cause irreversible tissue damage and blindness. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. First-aid Measures After Ingestion: Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Dry chemical Unsuitable Extinguishing Media: High volume water jet 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Explosion Hazard: Carbon dioxide (CO2). Carbon monoxide. Smoke. Sulphur oxides. Phosphorus compounds. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Firefighting Instructions: Protection During Firefighting: Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Hygiene Measures: 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid: Do not freeze. Do not store near acids. Oxidizing agents 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis 2-butoxyethanol 111-76-2 TWA 20 ppm ACGIH TWA 5 ppm 24 mg/m3 NIOSH REL TWA 50 ppm 240 mg/m3 OSHA Z-1 TWA 25 ppm 120 mg/m3 OSHA P0 Biological occupational exposure limits Component CAS-No. Control parameters Biological specimen Sampling time Permissible concentration Basis 2-BUTOXYETHANOL 111-76-2 111-76-2 Butoxyacetic acid (BAA) Urine End of shift (As soon as possible after exposure ceases) 200 mg/g ACGIH BEI 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |The suitability for a specific workplace should be |discussed with the producers of the protective |gloves. Eye Protection |Eye wash bottle with pure water |Tightly fitting safety goggles |Wear face-shield and protective suit for abnormal |processing problems. Skin and Body Protection |impervious clothing |Choose body protection according to the amount and |concentration of the dangerous substance at the work |place. Respiratory Protection | Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |liquid Odor |strong, characteristic Odor Threshold |no data available pH |> 12.5 Relative Evaporation Rate |1 (butylacetate=1) | Melting Point |no data available Freezing Point |no data available Boiling Point |104.44 Â°C Flash Point |does not flash Auto-ignition Temperature |not determined Decomposition Temperature |no data available Flammability (solid, gas) | Vapor Pressure |0.002 hPa Relative Vapor Density at 20 Â°C |no data available Relative Density | Specific Gravity | Solubility |soluble in cold water, soluble in hot water Partition coefficient: |no data available n-octanol/water | Viscosity |5.3 mm2/s (20 Â°C) Lower Flammable Limit |no data available Upper Flammable Limit |no data available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions No decomposition if stored and applied as directed. 10.4 Conditions to Avoid no data available 10.5 Incompatible Materials Acids 10.6 Hazardous Decomposition Products Carbon oxides. Phosphorus compounds. Sulphur oxides. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Acute oral toxicity: Acute toxicity estimate : 4,623 mg/kg Method: Calculation method Acute inhalation toxicity: Acute toxicity estimate : > 40 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method Acute dermal toxicity: Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: disodium metasilicate: Acute oral toxicity: LD50 rat: 1,153 mg/kg Skin Corrosion/Irritation: Remarks: Extremely corrosive and destructive to tissue. Serious Eye Damage/Irritation: Remarks: May cause irreversible eye damage. Respiratory or Skin Sensitization: Remarks: Causes sensitisation. Germ Cell Mutagenicity: no data available Carcinogenicity: no data available Reproductive Toxicity: no data available Specific Target Organ Toxicity (Single Exposure): no data available Specific Target Organ Toxicity (Repeated Exposure): no data available Aspiration Hazard: no data available Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: no data available 12.2. Persistence and Degradability no data available 12.3. Bioaccumulative Potential Partition coefficient: n-octanol/water: Remarks: no data available 12.4. Mobility in Soil no data available 12.5. Other Adverse Effects no data available SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of in accordance with local regulations. Additional Information: Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Not regulated as a dangerous good Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Not regulated as a dangerous good Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) ethane-1,2-diol 107-21-1 5000 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313: SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA Section 311/312 Hazard Classes |Acute Health Hazard Toxic Substances Control Act (TSCA) |On TSCA Inventory 15.2 US State Regulations <COMPONENT> California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |10/22/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Hazard statements |Causes severe skin burns and eye damage. May -- | |cause an allergic skin reaction. ----|Precautionary statements |Prevention: Avoid breathing dust/ fume/ gas/ -- | |mist/ vapours/ spray. Wash skin thoroughly | |after handling. Contaminated work clothing | |should not be allowed out of the workplace. | |Wear protective gloves/ protective clothing/ | |eye protection/ face protection. ----| |Response: IF SWALLOWED: Rinse mouth. Do NOT -- | |induce vomiting. IF ON SKIN (or hair): | |Remove/ Take off immediately all contaminated | |clothing. Rinse skin with water/ shower. IF | |INHALED: Remove victim to fresh air and keep | |at rest in a position comfortable for | |breathing. Immediately call a POISON CENTER | |or doctor/ physician. IF IN EYES: Rinse | |cautiously with water for several minutes. | |Remove contact lenses, if present and easy to | |do. Continue rinsing. Immediately call a | |POISON CENTER or doctor/ physician. If skin | |irritation or rash occurs: Get medical | |advice/ attention. Wash contaminated clothing | |before reuse. ----| |Storage: Store locked up. -- | | ----| |Disposal: Dispose of contents/container in -- | |accordance with local regulation. Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.