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SDS Sheet 0071740

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SECTION 1: IDENTIFICATION                                                       
 


1.1.  Product Identifier
Product Form:                                                                   
 
Product Name: BZ7563 Z FRESH SUBDUE R02001 12QT/CS                              
 
CAS No:                                                                         
 
Synonyms:                                                                       
 


1.2.  Intended Use of the Product
Use of the substance/mixture:                                                   
 


1.3.  Name, Address, and Telephone of the Responsible Party
Company                                                                         
 
Zep Inc.                                                                        
 
1310 Seaboard Industrial Blvd., NW                                              
 
Atlanta, GA 30318                                                               
 
Phone: 404-352-1680                                                             
 


1.4.  Emergency Telephone Number
Emergency     |1-877-428-9937, 877-541-2016, 800-424-9300, 202-483-7616         
 
number        |                                                                 
 

SECTION 2: HAZARDS IDENTIFICATION                                               
 


2.1.  Classification of the Substance or Mixture
Classification (GHS-US)
Flammable     |Category 3    
liquids       |              
Eye irritation|Category 2A   
Skin          |Category 1    
sensitisation |              


2.2.  Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US)   |Flame |Exclamation Mark
        
Signal Word (GHS-US)         |Warning                                           
 
Hazard Statements (GHS-US)   |H226 Flammable liquid and vapour.                 
 
                             |H317 May cause an allergic skin reaction.         
 
                             |H319 Causes serious eye irritation.               
 
Precautionary Statements     |Prevention:                                       
 
(GHS-US)                     |P210 Keep away from heat, hot surfaces, sparks,
open
                             |flames and other ignition sources. No smoking.    
 
                             |P233 Keep container tightly closed.               
 
                             |P240 Ground/bond container and receiving
equipment. 
                             |P241 Use explosion-proof electrical/ ventilating/ 
 
                             |lighting/ equipment.                              
 
                             |P242 Use only non-sparking tools.                 
 
                             |P243 Take precautionary measures against static   
 
                             |discharge.                                        
 
                             |P261 Avoid breathing dust/ fume/ gas/ mist/
vapours/
                             |spray.                                            
 
                             |P264 Wash skin thoroughly after handling.         
 
                             |P272 Contaminated work clothing should not be     
 
                             |allowed out of the workplace.                     
 
                             |P280 Wear protective gloves/ eye protection/ face 
 
                             |protection.                                       
 
                             |Response:                                         
 
                             |P303 + P361 + P353 IF ON SKIN (or hair): Remove/  
 
                             |Take off immediately all contaminated clothing.   
 
                             |Rinse skin with water/ shower.                    
 
                             |P305 + P351 + P338 IF IN EYES: Rinse cautiously
with
                             |water for several minutes. Remove contact lenses,
if
                             |present and easy to do. Continue rinsing.         
 
                             |P333 + P313 If skin irritation or rash occurs: Get
 
                             |medical advice/ attention.                        
 
                             |P337 + P313 If eye irritation persists: Get
medical 
                             |advice/ attention.                                
 
                             |P363 Wash contaminated clothing before reuse.     
 
                             |P370 + P378 In case of fire: Use dry sand, dry    
 
                             |chemical or alcohol-resistant foam for extinction.
 
                             |Storage:                                          
 
                             |P403 + P235 Store in a well-ventilated place. Keep
 
                             |cool.                                             
 
                             |Disposal:                                         
 
                             |P501 Dispose of contents/container in accordance  
 
                             |with local regulation.                            
 


2.3.  Other Hazards
Other Hazards Not Contributing to the Classification:                           
 


2.4.  Unknown Acute Toxicity (GHS-US)
                                                                                
 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS                               
 


3.1.  Substance
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 
                                |                     |        |                
 


Full text of H-phrases: See Section 16
3.2.  Mixture
Name                            |Product identifier   |%       |Classification  
 
                                |                     |        |(GHS-US)        
 
Alcohols, C10-14, ethoxylated   |66455-15-0           |>= 5 - <|                
 
                                |                     |10      |                
 
ethanol                         |64-17-5              |>= 1 - <|                
 
                                |                     |5       |                
 
cinnamyl alcohol                |104-54-1             |>= 0.1 -|                
 
                                |                     |< 1     |                
 
                                |                     |        |                
 
                                |                     |        |                
 


SECTION 4: FIRST AID MEASURES                                                   
 


4.1.  Description of First Aid Measures
First-aid Measures General: Move out of dangerous area. Show this safety data   
 
sheet to the doctor in attendance. Do not leave the victim unattended.          
 
First-aid Measures After Inhalation: If unconscious place in recovery position
and
seek medical advice. If symptoms persist, call a physician.                     
 
First-aid Measures After Skin Contact: If skin irritation persists, call a      
 
physician. If on skin, rinse well with water.  If on clothes, remove clothes.   
 
First-aid Measures After Eye Contact: Immediately flush eye(s) with plenty of   
 
water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while    
 
rinsing.  If eye irritation persists, consult a specialist.                     
 
First-aid Measures After Ingestion: Clean mouth with water and drink afterwards 
 
plenty of water. Keep respiratory tract clear. Do not give milk or alcoholic    
 
beverages. Never give anything by mouth to an unconscious person. If symptoms   
 
persist, call a physician.                                                      
 


4.2.  Most important symptoms and effects, both acute and delayed
Symptoms/Injuries:                                                              
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 


4.3.  Indication of Any Immediate Medical Attention and Special Treatment
Needed
                                                                                
 

SECTION 5: FIRE-FIGHTING MEASURES                                               
 

5.1.  Extinguishing Media
Suitable Extinguishing Media: Alcohol-resistant foam Carbon dioxide (CO2)  Dry  
 
chemical.                                                                       
 
Unsuitable Extinguishing Media: High volume water jet.                          
 


5.2.  Special Hazards Arising From the Substance or Mixture
Fire Hazard: Do not allow run-off from fire fighting to enter drains or water   
 
courses.                                                                        
 
Explosion Hazard: Carbon dioxide (CO2) Carbon monoxide Smoke.                   
 
Reactivity:                                                                     
 


5.3.  Advice for Firefighters
Precautionary Measures Fire:                                                    
 
Firefighting Instructions: Use extinguishing measures that are appropriate to   
 
local circumstances and the surrounding environment.                            
 
Further information: Collect contaminated fire extinguishing water separately.  
 
This must not be discharged into drains. Fire residues and contaminated fire    
 
extinguishing water must be disposed of in accordance with local regulations.
For 
safety reasons in case of fire, cans should be stored separately in closed      
 
containments. Use a water spray to cool fully closed containers.                
 
Protection During Firefighting: Wear self-contained breathing apparatus for     
 
firefighting if necessary.                                                      
 

SECTION 6: ACCIDENTAL RELEASE MEASURES                                          
 


6.1.  Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Use personal protective equipment. Remove all sources of      
 
ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to
form
explosive concentrations. Vapours can accumulate in low areas.                  
 


6.1.1.      For Non-emergency Personnel
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.1.2.      For Emergency Responders
Protective Equipment:                                                           
 
Emergency Procedures:                                                           
 


6.2.  Environmental Precautions
Prevent product from entering drains. Prevent further leakage or spillage if
safe 
to do so. If the product contaminates rivers and lakes or drains inform
respective
authorities.                                                                    
 


6.3.  Methods and Material for Containment and Cleaning Up
For Containment:                                                                
 
Methods for Cleaning Up: Contain spillage, and then collect with non-combustible
 
absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and
place 
in container for disposal according to local / national regulations (see section
 
13).                                                                            
 


6.4.  Reference to Other Sections
See heading  8, Exposure Controls and Personal Protection.                      
 


SECTION 7: HANDLING AND STORAGE                                                 
 


7.1.  Precautions for Safe Handling
Additional Hazards When Processed: Avoid formation of aerosol. Do not breathe   
 
vapours/dust. Avoid exposure - obtain special instructions before use. Avoid    
 
contact with skin and eyes. For personal protection see section 8. Smoking,
eating
and drinking should be prohibited in the application area. Take precautionary   
 
measures against static discharges. Provide sufficient air exchange and/or
exhaust
in work rooms. Open drum carefully as content may be under pressure. Dispose of 
 
rinse water in accordance with local and national regulations. Persons
susceptible
to skin sensitisation problems or asthma, allergies, chronic or recurrent       
 
respiratory disease should not be employed in any process in which this mixture
is
being used.                                                                     
 
Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash 
 
hands before breaks and at the end of workday.                                  
 


7.2.  Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures:                                                             
 
Storage Conditions: No smoking. Keep container tightly closed in a dry and      
 
well-ventilated place. Containers which are opened must be carefully resealed
and 
kept upright to prevent leakage. Observe label precautions. Electrical          
 
installations / working materials must comply with the technological safety     
 
standards.                                                                      
 
Materials to avoid: Keep away from oxidising agents and strongly acid or
alkaline 
materials.                                                                      
 


7.3.  Specific End Use(s)
                                                                                
 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION                                
 


8.1.  Control Parameters
Components                                                                      
 
CAS-No.                                                                         
 
Value type (Form of exposure)                                                   
 
Control parameters / Permissible concentration                                  
 
Basis                                                                           
 
                                                                                
 
ethanol                                                                         
 
64-17-5                                                                         
 
TWA                                                                             
 
1,000 ppm                                                                       
 
ACGIH                                                                           
 
                                                                                
 
                                                                                
 
                                                                                
 
TWA                                                                             
 
1,000 ppm                                                                       
 
1,900 mg/m3                                                                     
 
NIOSH REL                                                                       
 
                                                                                
 
                                                                                
 
                                                                                
 
TWA                                                                             
 
1,000 ppm                                                                       
 
1,900 mg/m3                                                                     
 
OSHA Z-1                                                                        
 
                                                                                
 
                                                                                
 
                                                                                
 
TWA                                                                             
 
1,000 ppm                                                                       
 
1,900 mg/m3                                                                     
 
OSHA P0                                                                         
 
                                                                                
 


8.2.  Exposure Controls
Appropriate Engineering      |                                                  
 
Controls                     |                                                  
 
Personal Protective Equipment|                                                  
 
Materials for Protective     |                                                  
 
Clothing                     |                                                  
 
Hand Protection              |Remarks: The suitability for a specific workplace 
 
                             |should be discussed with the producers of the     
 
                             |protective gloves.                                
 
Eye Protection               |Eye wash bottle with pure water. Tightly fitting  
 
                             |safety goggles. Wear face-shield and protective
suit
                             |for abnormal processing problems.                 
 
Skin and Body Protection     |Impervious clothing. Choose body protection       
 
                             |according to the amount and concentration of the  
 
                             |dangerous substance at the work place.            
 
Respiratory Protection       |No personal respiratory protective equipment      
 
                             |normally required.                                
 
Thermal Hazard Protection    |                                                  
 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES                                     
 


9.1.  Information on Basic Physical and Chemical Properties
Physical State                      |                                           
 
Appearance                          |liquid                                     
 
Odor                                |strong, pleasant                           
 
Odor Threshold                      |no data available                          
 
pH                                  |5 - 6                                      
 
Relative Evaporation Rate           |1                                          
 
(butylacetate=1)                    |                                           
 
Melting Point                       |no data available                          
 
Freezing Point                      |no data available                          
 
Boiling Point                       |87.77 °C                                   
 
Flash Point                         |45 °C Method: closed cup                   
 
Auto-ignition Temperature           |not determined                             
 
Decomposition Temperature           |                                           
 
Flammability (solid, gas)           |                                           
 
Vapor Pressure                      |no data available                          
 
Relative Vapor Density at 20 °C     |no data available                          
 
Relative Density                    |0.991 g/cm3                                
 
Specific Gravity                    |                                           
 
Solubility                          |not applicable                             
 
Partition coefficient:              |no data available                          
 
n-octanol/water                     |                                           
 
Viscosity                           |6.7 mm2/s (20 °C)                          
 
Lower Flammable Limit               |12 %(V)                                    
 
Upper Flammable Limit               |2 %(V)                                     
 


9.2.  Other Information
                                                                                
 

SECTION 10: STABILITY AND REACTIVITY                                            
 


10.1      Reactivity
Stable.                                                                         
 


10.2      Chemical Stability
Stable under normal conditions.                                                 
 


10.3      Possibility of Hazardous Reactions
Vapours may form explosive mixture with air. No decomposition if stored and     
 
applied as directed.                                                            
 


10.4      Conditions to Avoid
Heat, flames and sparks.                                                        
 


10.5      Incompatible Materials
Oxidizing agents.                                                               
 


10.6      Hazardous Decomposition Products
Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke).              
 

SECTION 11: TOXICOLOGICAL INFORMATION                                           
 


11.1. Information on Toxicological Effects
Acute Toxicity:                                                                 
 
Skin Corrosion/Irritation: Product:                                             
 
Remarks: May cause skin irritation and/or dermatitis.                           
 
Serious Eye Damage/Irritation: Product:                                         
 
Remarks: Irritating to eyes.                                                    
 
Respiratory or Skin Sensitization: Product:                                     
 
Remarks: Causes sensitisation.                                                  
 
Germ Cell Mutagenicity: no data available.                                      
 
Carcinogenicity: no data available.                                             
 
Reproductive Toxicity: no data available.                                       
 
Specific Target Organ Toxicity (Single Exposure): no data available.            
 
Specific Target Organ Toxicity (Repeated Exposure): no data available.          
 
Aspiration Hazard: no data available.                                           
 
Symptoms/Injuries After Inhalation:                                             
 
Symptoms/Injuries After Skin Contact:                                           
 
Symptoms/Injuries After Eye Contact:                                            
 
Symptoms/Injuries After Ingestion:                                              
 
Chronic Symptoms:                                                               
 

SECTION 12: ECOLOGICAL INFORMATION                                              
 


12.1. Toxicity
no data available.                                                              
 


12.2. Persistence and Degradability
no data available.                                                              
 


12.3. Bioaccumulative Potential
Product:                                                                        
 
Partition coefficient: n-octanol/water: Remarks: no data available.             
 
Components:                                                                     
 
cinnamyl alcohol :                                                              
 
Partition coefficient: n-octanol/water: Pow: 1.636.                             
 


12.4. Mobility in Soil
no data available.                                                              
 


12.5. Other Adverse Effects
no data available.                                                              
 
Product:                                                                        
 
Regulation: 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric 
Ozone - CAA Section 602 Class I Substances.                                     
 
Remarks: This product neither contains, nor was manufactured with a Class I or  
 
Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt.
 
A, App.A + B).                                                                  
 
Additional ecological information: no data available.                           
 

SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Waste from residues: Do not dispose of waste
into 
sewer. Do not contaminate ponds, waterways or ditches with chemical or used     
 
container. Dispose of in accordance with local regulations.                     
 
Additional Information:                                                         
 
Contaminated packaging: Empty remaining contents. Dispose of as unused product.
Do
not re-use empty containers. Do not burn, or use a cutting torch on, the empty  
 
drum.                                                                           
 

SECTION 14: TRANSPORT INFORMATION                                               
 


14.1 In Accordance with DOT
Proper Shipping Name |                                                          
 
Hazard Class         |                       |<PICTOGRAM PHRASE>                
 
Identification Number|                       |                                  
 
Label Codes          |                       |                                  
 
ERG Number           |                                                          
 


14.2 In Accordance with IMDG
Proper Shipping Name |Not regulated as a dangerous good                         
 
Hazard Class         |                                                          
 
Identification Number|                                                          
 
Label Codes          |                      |<PICTOGRAM PHRASE>                 
 
ntification Of The   |                      |                                   
 
Substance/m          |                      |                                   
 
EmS-No. (Fire)       |                      |                                   
 
EmS-No. (Spillage)   |                      |                                   
 


14.3 In Accordance with IATA
Proper Shipping Name |Not regulated as a dangerous good                         
 
Identification Number|                       |<PICTOGRAM PHRASE>                
  
Hazard Class         |                       |                                  
  
Label Codes          |                       |                                  
  
ntification Of The   |                       |                                  
  
Substance/m          |                       |                                  
  
ERG Code (IATA)      |                                                          
 

SECTION 15: REGULATORY INFORMATION                                              
 

15.1      US Federal Regulations
<COMPONENT>                                                                     
 
EPCRA - Emergency Planning and Community Right-to-Know Act:                     
 
CERCLA Reportable Quantity:                                                     
 
Components                                                                      
 
CAS-No.                                                                         
 
Component RQ (lbs)                                                              
 
Calculated product RQ (lbs)                                                     
 
                                                                                
 
pentyl acetate                                                                  
 
628-63-7                                                                        
 
5000                                                                            
 
*                                                                               
 
                                                                                
 
*: Calculated RQ exceeds reasonably attainable upper limit.                     
 
                                                                                
 
SARA 304 Extremely Hazardous Substances Reportable Quantity: This material does 
 
not contain any components with a section 304 EHS RQ.                           
 
                                                                                
 
SARA 302: SARA 302: No chemicals in this material are subject to the reporting  
 
requirements of SARA Title III, Section 302.                                    
 
                                                                                
 
SARA 313: This material does not contain any chemical components with known CAS 
 
numbers that exceed the threshold (De Minimis) reporting levels established by  
 
SARA Title III, Section 313.                                                    
 
SARA Section 311/312 Hazard Classes |Fire Hazard                                
 
                                    |Acute Health Hazard                        
 
Toxic Substances Control Act (TSCA) |On TSCA Inventory.                         
 

15.2      US State Regulations
<COMPONENT>                                                                     
 
California Prop 65: This product does not contain any chemicals known to State
of 
California to cause cancer, birth defects, or any other reproductive harm.      
 
                                                                                
 

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION   
 

Revision date   |11/06/2014                                                     
 
Other           |This document has been prepared in accordance with the SDS     
 
Information     |requirements of the OSHA Hazard Communication Standard 29 CFR  
 
                |1910.1200.                                                     
 
GHS Full Text Phrases:                                                          
 
----|Hazard statements:             |Flammable liquid and vapour. May cause an  
 
--  |                               |allergic skin reaction. Causes serious eye 
 
    |                               |irritation.                                
 
----|Precautionary statements:      |Prevention:                                
 
--  |                               |Keep away from heat, hot surfaces, sparks, 
 
    |                               |open flames and other ignition sources. No 
 
    |                               |smoking. Keep container tightly closed.    
 
    |                               |Ground/bond container and receiving        
 
    |                               |equipment. Use explosion-proof electrical/ 
 
    |                               |ventilating/ lighting/ equipment. Use only 
 
    |                               |non-sparking tools. Take precautionary     
 
    |                               |measures against static discharge. Avoid   
 
    |                               |breathing dust/ fume/ gas/ mist/ vapours/  
 
    |                               |spray. Wash skin thoroughly after handling.
 
    |                               |Contaminated work clothing should not be   
 
    |                               |allowed out of the workplace. Wear
protective
    |                               |gloves/ eye protection/ face protection.   
 
    |                               |Response:                                  
 
    |                               |IF ON SKIN (or hair): Remove/ Take off     
 
    |                               |immediately all contaminated clothing.
Rinse 
    |                               |skin with water/ shower. IF IN EYES: Rinse 
 
    |                               |cautiously with water for several minutes. 
 
    |                               |Remove contact lenses, if present and easy
to
    |                               |do. Continue rinsing. If skin irritation or
 
    |                               |rash occurs: Get medical advice/ attention.
 
    |                               |If eye irritation persists: Get medical    
 
    |                               |advice/ attention. Wash contaminated
clothing
    |                               |before reuse. In case of fire: Use dry
sand, 
    |                               |dry chemical or alcohol-resistant foam for 
 
    |                               |extinction.                                
 
    |                               |Storage:                                   
 
    |                               |Store in a well-ventilated place. Keep
cool. 
    |                               |Disposal:                                  
 
    |                               |Dispose of contents/container in accordance
 
    |                               |with local regulation.                     
 
----|                               |                                           
 
--  |                               |                                           
 
----|                               |                                           
 
--  |                               |                                           
 
    |                               |                                           
 


Grainger disclaimer.
    

The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.

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