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Material Safety Data Sheet ZEP Zep Inc. Section 1. Chemical Product and Company PROFESSIONAL 1310 Seaboard Identification Industrial Blvd. Atlanta, GA 30318 1-877-793-7776 Product name HEAVY DUTY CITRUS DEGREASER Product use Industrial Solvent Degreaser Product code R077 Date of issue 08/11/08 Supersedes Emergency Telephone Numbers For MSDS Information: Compliance Services 1-877-793-7776 For Medical Emergency INFOTRAC: (877) 541-2016 Toll Free - All Calls Recorded For Transportation Emergency CHEMTREC: (800) 424-9300 - All Calls Recorded In the District of Columbia (202) 483-7616 Prepared By Compliance Services 1420 Seaboard Industrial Blvd. Atlanta, GA 30318 Section 2. Hazards Identification Emergency overview *Hazard Determination System (HDS): Health, Flammability, Reactivity CAUTION! 1 2 0 COMBUSTIBLE. CAUSES EYE IRRITATION. NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all prescribed safety precautions, including the use of proper personal protective equipment. Acute Effects Routes of Entry Inhalation. Skin contact. Eye contact. Eyes Causes eye irritation. Inflammation of the eye is characterized by redness, watering and itching. Skin May cause skin irritation. May cause skin sensitization. May cause allergic reactions in certain individuals. Skin inflammation is characterized by itching, scaling, or reddening. Inhalation Avoid breathing vapors, spray or mists. Over-exposure by inhalation may cause respiratory irritation. Ingestion May be harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage. Chronic effects Prolonged or repeated contact may dry skin and cause irritation. Contains material which may cause damage to the following organs: kidneys, lungs, liver. Carcinogenicity Additional Information: See Toxicological Information (Section 11) Section 3. Composition/Information on Ingredients Name of Hazardous Ingredients CAS number % by Weight OSHA's Hazard Communication Standard (29 CFR 1910.1200) does not require the listing of any ingredient for this product. Section 4. First Aid Measures Eye Contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately. Skin Contact Wash contaminated skin with soap and water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Wash clothing before reuse. Get medical attention if irritation develops. Inhalation Move exposed person to fresh air. If irritation persists, get medical attention. Ingestion If swallowed, do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Get medical attention immediately. Section 5. Fire Fighting Measures National Fire Protection Association (U.S.A.) Health - 1, Flammability - 1, Reactivity - 0 Flash Point Closed cup: 62.7�C (144.9�F) [Tagliabue.] Flammable Not determined. Limits Flammability COMBUSTIBLE. Fire hazard Combustible liquid and vapor. Keep away from heat, sparks and flame. Fire-Fighting Use dry chemical, CO2, water spray (fog) or foam. Procedures Fire-fighters should wear appropriate protective equipment. Do not release runoff from fire to sewers or waterways. Section 6. Accidental Release Measures Spill Clean up Eliminate all ignition sources. Put on appropriate personal protective equipment (see section 8). Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Section 7. Handling and Storage Handling Put on appropriate personal protective equipment (see section 8). Store and use away from heat, sparks, open flame or any other ignition source. Avoid contact with eyes, skin and clothing. Avoid breathing vapors, spray or mists. Use only with adequate ventilation. Do not ingest. Observe label precautions. Wash thoroughly after handling. Empty containers retain product residue and can be hazardous. Do not reuse container. Storage Keep away from heat and direct sunlight. Avoid all possible sources of ignition (spark or flame). Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Keep away from food, drink and animal feeding stuffs. Keep out of the reach of children. Section 8. Exposure Controls/Personal Protection Product name Exposure limits No exposure limit value known. Personal Protective Equipment (PPE) Eyes Safety glasses. Body For prolonged or repeated handling, use gloves. Recommended: Neoprene gloves. Nitrile gloves. Rubber gloves. Respiratory Use with adequate ventilation. Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective occupational exposure limits. Section 9. Physical and Chemical Properties Physical State Liquid. Color Clear. Orange. pH Not applicable Odor Citrus Boiling Point Not determined. Vapor Pressure 0.04 kPa (0.3 mm Hg) Specific 0.88 Vapor Density >1 [Air=1] Gravity Solubility Emulsifies in Evaporation Rate Not determined. water. VOC (Consumer) 202 (g/l). 1.68 lbs/gal (23.0%) Section 10. Stability and Reactivity Stability and The product is stable. Reactivity Incompatibility Combustible materials should be stored away from extreme heat and away from strong oxidizing agents. Incompatible with some strong acids. Reactive with acidic clay (i.e. clay absorbent) Reactive or incompatible with the following materials: oxidizing materials. Hazardous Will not occur. Polymerization Hazardous carbon oxides Decomposition Products Section 11. Toxicological Information Acute Toxicity Product/ingredient name Result Species Dose Exposure d-Limonene LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - Nonylphenoxypoly(Ethyleneoxy)Eth LD50 Dermal Rabbit 2000 mg/kg - ano LD50 Oral Rat 3310 mg/kg - Section 12. Ecological Information Environmental No known significant effects or critical hazards. Effects Aquatic Ecotoxicity Not available. Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities for additional information. Waste Stream Classification: - [Non-hazardous waste] Section 14. Transport Information Regulatory UN number Proper shipping name Classes PG* Label Information DOT Classification Not applicable. Not a DOT controlled - - material (United States). IMDG Class Not determined. NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to the Bill of Lading with your shipment. PG*: Packing group Section 15. Regulatory Information U.S. Federal Regulations SARA 313 toxic chemical notification and release reporting: No products were found. Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. All Components of this product are listed or exempt from listings on TSCA Inventory. State Regulations California Prop No products were found. 65 Section 16. Other Information To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. *NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although these ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to relay the meanings of this scale.
The information contained in this was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this '' shall be created or inferred by any statement in this ''. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this ''. The user is responsible for full compliance.