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SDS Sheet 0071610Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form: Product Name: BZ7399 EMULS SLVT DGRSR R07624 4/1 GAL CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company : Zep Inc. 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 T-404-352-1680 1.4. Emergency Telephone Number Emergency | 1-877-428-9937, 877-541-2016, 800-424-9300, 202-483-7616 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flammable |Category 3 liquids | Skin |Category 2 irritation | Germ cell |Category 1B mutagenicity | Carcinogenicit|Category 1B y | Specific |Category 3 target organ |(Respiratory toxicity |system) -single | exposure | Aspiration |Category 1 hazard | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Flame |Health Hazard |Exclamation Mark Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H226 Flammable liquid and vapour. |H304 May be fatal if swallowed and enters airways. |H315 Causes skin irritation. |H335 May cause respiratory irritation. |H340 May cause genetic defects. |H350 May cause cancer. Precautionary Statements |Prevention: (GHS-US) |P201 Obtain special instructions before use. P202 Do |not handle until all safety precautions have been |read and understood. P210 Keep away from heat, hot |surfaces, sparks, open flames and other ignition |sources. No smoking. P233 Keep container tightly |closed. P240 Ground/bond container and receiving |equipment. P241 Use explosion-proof electrical/ |ventilating/ lighting/ equipment. P242 Use only |non-sparking tools. P243 Take precautionary measures |against static discharge. P261 Avoid breathing dust/ |fume/ gas/ mist/ vapours/ spray. P264 Wash skin |thoroughly after handling. P271 Use only outdoors or |in a well-ventilated area. P280 Wear protective |gloves/ eye protection/ face protection. P281 Use |personal protective equipment as required. |Response: |P301 + P310 IF SWALLOWED: Immediately call a POISON |CENTER or doctor/ physician. P303 + P361 + P353 IF |ON SKIN (or hair): Remove/ Take off immediately all |contaminated clothing. Rinse skin with water/ |shower. P304 + P340 + P312 IF INHALED: Remove victim |to fresh air and keep at rest in a position |comfortable for breathing. Call a POISON CENTER or |doctor/ physician if you feel unwell. P308 + P313 IF |exposed or concerned: Get medical advice/ attention. |P331 Do NOT induce vomiting. P332 + P313 If skin |irritation occurs: Get medical advice/ attention. |P362 Take off contaminated clothing and wash before |reuse. P370 + P378 In case of fire: Use dry sand, |dry chemical or alcohol-resistant foam for |extinction. |Storage: |P403 + P233 Store in a well-ventilated place. Keep |container tightly closed. P403 + P235 Store in a |well-ventilated place. Keep cool. P405 Store locked |up. |Disposal: |P501 Dispose of contents/container in accordance |with local regulation. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) Solvent naphtha (petroleum), |64742-95-6 |>= 50 - | light arom. | |< 70 | Kerosine (petroleum), |64742-81-0 |>= 10 - | hydrodesulfurized | |< 20 | Alcohols, C10-14, ethoxylated |66455-15-0 |>= 5 - <| | |10 | | | | | | | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Symptoms of poisoning may appear several hours later. Do not leave the victim unattended. First-aid Measures After Inhalation: If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. First-aid Measures After Skin Contact: If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. First-aid Measures After Eye Contact: Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. First-aid Measures After Ingestion: Clean mouth with water and drink afterwards plenty of water. Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical. Unsuitable Extinguishing Media: High volume water jet 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Carbon dioxide (CO2). Carbon monoxide. Smoke. Explosion Hazard: Do not allow run-off from fire fighting to enter drains or water courses. Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Protection During Firefighting: Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. 6.2. Environmental Precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid formation of aerosol. Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: No smoking. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid: Keep away from oxidising agents and strongly acid or alkaline materials. Materials to avoid: Keep away from oxidising agents and strongly acid or alkaline materials. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis xylenes 1330-20-7 TWA 100 ppm ACGIH STEL 150 ppm ACGIH 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |The suitability for a specific workplace should be |discussed with the producers of the protective |gloves. Eye Protection |Eye wash bottle with pure water Tightly fitting |safety goggles Skin and Body Protection |impervious clothing Choose body protection according |to the amount and concentration of the dangerous |substance at the work place. Respiratory Protection |In the case of vapour formation use a respirator |with an approved filter. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |liquid Odor |solvent-like Odor Threshold |no data available pH |not applicable Relative Evaporation Rate |no data available (butylacetate=1) | Melting Point |no data available Freezing Point |no data available Boiling Point |154.44 Â°C Flash Point |45.0 Â°C |Method: closed cup Auto-ignition Temperature |not determined Decomposition Temperature |no data available Flammability (solid, gas) | Vapor Pressure |not determined Relative Vapor Density at 20 Â°C |no data available Relative Density | Specific Gravity | Solubility | Partition coefficient: |no data available n-octanol/water | Viscosity |Viscosity, kinematic |6.3 mm2/s (20 Â°C) Lower Flammable Limit | Upper Flammable Limit | 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions Vapours may form explosive mixture with air. 10.4 Conditions to Avoid Heat, flames and sparks. 10.5 Incompatible Materials Oxidizing agents 10.6 Hazardous Decomposition Products Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: no data available. Skin Corrosion/Irritation: Remarks: May cause skin irritation in susceptible persons. Serious Eye Damage/Irritation: Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin. Respiratory or Skin Sensitization: no data available Germ Cell Mutagenicity: no data available Carcinogenicity: no data available Reproductive Toxicity: no data available Specific Target Organ Toxicity (Single Exposure): no data available Specific Target Organ Toxicity (Repeated Exposure): no data available Aspiration Hazard: no data available. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Product: Remarks: Solvents may degrease the skin. Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity no data available. Additional ecological information: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Toxic to aquatic life with long lasting effects. 12.2. Persistence and Degradability no data available 12.3. Bioaccumulative Potential Partition coefficient: n-octanol/water: Remarks: no data available 12.4. Mobility in Soil no data available 12.5. Other Adverse Effects no data available Product: Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances. Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Dispose of in accordance with local regulations. Additional Information: Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |FLAMMABLE LIQUID, N.O.S. (ALIPHATIC PETROLEUM NAPHTHA) Hazard Class |3 |UN 1993 Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Flammable liquid, n.o.s. (ALIPHATIC PETROLEUM NAPHTHA) Identification Number|UN 1993 |<PICTOGRAM PHRASE> Hazard Class |3 | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Xylenes 1330-20-7 100 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA Section 311/312 Hazard Classes |Fire Hazard |Acute Health Hazard |Chronic Health Hazard Toxic Substances Control Act (TSCA) |On TSCA Inventory 15.2 US State Regulations <COMPONENT> California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. Ethylbenzene 100-41-4 Cumene 98-82-8 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Toluene 108-88-3 SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |10/20/2014 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----| |Flammable liquid and vapour. May be fatal if -- | |swallowed and enters airways. Causes skin | |irritation. May cause respiratory irritation. | |May cause genetic defects. May cause cancer. ----| |Prevention: Obtain special instructions -- | |before use. Do not handle until all safety | |precautions have been read and understood. | |Keep away from heat, hot surfaces, sparks, | |open flames and other ignition sources. No | |smoking. Keep container tightly closed. | |Ground/bond container and receiving | |equipment. Use explosion-proof electrical/ | |ventilating/ lighting/ equipment. Use only | |non-sparking tools. Take precautionary | |measures against static discharge. Avoid | |breathing dust/ fume/ gas/ mist/ vapours/ | |spray. Wash skin thoroughly after handling. | |Use only outdoors or in a well-ventilated | |area. Wear protective gloves/ eye protection/ | |face protection. Use personal protective | |equipment as required. ----| |Response: IF SWALLOWED: Immediately call a -- | |POISON CENTER or doctor/ physician. IF ON | |SKIN (or hair): Remove/ Take off immediately | |all contaminated clothing. Rinse skin with | |water/ shower. IF INHALED: Remove victim to | |fresh air and keep at rest in a position | |comfortable for breathing. Call a POISON | |CENTER or doctor/ physician if you feel | |unwell. IF exposed or concerned: Get medical | |advice/ attention. Do NOT induce vomiting. If | |skin irritation occurs: Get medical advice/ | |attention. Take off contaminated clothing and | |wash before reuse. In case of fire: Use dry | |sand, dry chemical or alcohol-resistant foam | |for extinction. ----| |Storage: Store in a well-ventilated place. -- | |Keep container tightly closed. Store in a | |well-ventilated place. Keep cool. Store | |locked up. ----| |Disposal: Dispose of contents/container in -- | |accordance with local regulation. Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.