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SDS Sheet 0071570Printer Friendly View
SECTION 1: IDENTIFICATION 1.1. Product Identifier: Product Form: Product Name: BZ7407 HD ALKALINE CLNR R08524 4/1 GAL CAS No: Synonyms: 1.2. Intended Use of the Product Use of the substance/mixture: 1.3. Name, Address, and Telephone of the Responsible Party Company : Zep Inc. 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Phone: 404-352-1680 1.4. Emergency Telephone Number Emergency |1-877-428-9937, 877-541-2016, 800-424-9300, 202-483-7616 number | SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Skin corrosion| Category 1A Serious eye | Category 1 damage | | 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) |Corrosion Signal Word (GHS-US) |Danger Hazard Statements (GHS-US) |H314 Causes severe skin burns and eye damage. Precautionary Statements |Prevention: (GHS-US) |P264 Wash skin thoroughly after handling. |P280 Wear protective gloves/ protective clothing/ |eye protection/ face protection. |Response: |P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT |induce vomiting. |P303 + P361 + P353 IF ON SKIN (or hair): Remove/ |Take off immediately all contaminated clothing. |Rinse skin with water/ shower. |P304 + P340 + P310 IF INHALED: Remove victim to |fresh air and keep at rest in a position comfortable |for breathing. Immediately call a POISON CENTER or |doctor/ physician. |P305 + P351 + P338 + P310 IF IN EYES: Rinse |cautiously with water for several minutes. Remove |contact lenses, if present and easy to do. Continue |rinsing. Immediately call a POISON CENTER or doctor/ |physician. |P363 Wash contaminated clothing before reuse. |Storage: |P405 Store locked up. |Disposal: |P501 Dispose of contents/container in accordance |with local regulation. 2.3. Other Hazards Other Hazards Not Contributing to the Classification: 2.4. Unknown Acute Toxicity (GHS-US) SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Name |Product identifier |% |Classification | | |(GHS-US) | | | | | | | | | | | | | | | Full text of H-phrases: See Section 16 3.2. Mixture Name |Product identifier |% |Classification | | |(GHS-US) 2-butoxyethanol |111-76-2 |>= 1 - <| | |5 | Sodium metasilicate (disodium |6834-92-0 |>= 1 - <| salt) | |5 | sodium dodecylbenzenesulfonate |25155-30-0 |>= 1 - <| | |5 | tetrasodium |64-02-8 |>= 1 - <| ethylenediaminetetraacetate | |5 | Fatty acids, tall-oil, sodium |61790-45-2 |>= 1 - <| salts | |5 | SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. First-aid Measures After Inhalation: If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. First-aid Measures After Skin Contact: Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes. First-aid Measures After Eye Contact: Small amounts splashed into eyes can cause irreversible tissue damage and blindness. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. Rinse immediately with plenty of water for at least 15 minutes. First-aid Measures After Ingestion: Clean mouth with water and drink afterwards plenty of water. Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Take victim immediately to hospital. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/Injuries: Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Dry chemical Water Foam Carbon dioxide (CO2). Unsuitable Extinguishing Media: High volume water jet. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Do not allow run-off from fire fighting to enter drains or water courses. Explosion Hazard: Carbon dioxide (CO2) Carbon monoxide Smoke Nitrogen oxides (NOx). Reactivity: 5.3. Advice for Firefighters Precautionary Measures Fire: Firefighting Instructions: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Protection During Firefighting: Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Use personal protective equipment. 6.1.1. For Non-emergency Personnel Protective Equipment: Emergency Procedures: 6.1.2. For Emergency Responders Protective Equipment: Emergency Procedures: 6.2. Environmental Precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Methods for Cleaning Up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Do not breathe vapours/dust. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations. Hygiene Measures: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid: Oxidizing agents. Do not freeze. Do not store near acids. 7.3. Specific End Use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters Components with workplace control parameters: Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis 2-butoxyethanol 111-76-2 TWA 20 ppm ACGIH TWA TWA 5 ppm 24 mg/m3 50 ppm 240 mg/m3 NIOSH REL OSHA Z-1 TWA 25 ppm 120 mg/m3 OSHA P0 Biological occupational exposure limits: Component CAS-No. Control parameters Biological specimen Sampling time Permissible concentration Basis 2-BUTOXYETHANOL 111-76-2 Butoxyacetic acid (BAA) Urine End of shift (As soon as possible after exposure ceases) 200 mg/g ACGIH BEI Remarks: Creatinine 8.2. Exposure Controls Appropriate Engineering | Controls | Personal Protective Equipment| Materials for Protective | Clothing | Hand Protection |Remarks: The suitability for a specific workplace |should be discussed with the producers of the |protective gloves. Eye Protection |Ensure that eyewash stations and safety showers are |close to the workstation location. Tightly fitting |safety goggles. Skin and Body Protection |Impervious clothing. Choose body protection |according to the amount and concentration of the |dangerous substance at the work place. Respiratory Protection |Use respiratory protection unless adequate local |exhaust ventilation is provided or exposure |assessment demonstrates that exposures are within |recommended exposure guidelines. Thermal Hazard Protection | SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State | Appearance |liquid Odor |mild Odor Threshold |no data available pH |> 13 Relative Evaporation Rate |1 (butylacetate=1) | Melting Point |no data available Freezing Point |no data available Boiling Point |104.44 Â°C Flash Point |does not flash Auto-ignition Temperature |not determined Decomposition Temperature | Flammability (solid, gas) | Vapor Pressure |not determined Relative Vapor Density at 20 Â°C |no data available Relative Density | Specific Gravity | Solubility |soluble Partition coefficient: |no data available n-octanol/water | Viscosity |Viscosity, kinematic: 5.2 mm2/s (20 Â°C) Lower Flammable Limit |no data available Upper Flammable Limit |no data available 9.2. Other Information SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable. 10.2 Chemical Stability Stable under normal conditions. 10.3 Possibility of Hazardous Reactions No decomposition if stored and applied as directed. 10.4 Conditions to Avoid Extremes of temperature and direct sunlight. 10.5 Incompatible Materials Acids Oxidizing agents. 10.6 Hazardous Decomposition Products Carbon oxides, Nitrogen oxides (NOx). SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on Toxicological Effects Acute Toxicity: Skin Corrosion/Irritation: Serious Eye Damage/Irritation: Respiratory or Skin Sensitization: no data available. Germ Cell Mutagenicity: no data available. Carcinogenicity: no data available. Reproductive Toxicity: no data available. Specific Target Organ Toxicity (Single Exposure): no data available. Specific Target Organ Toxicity (Repeated Exposure): no data available. Aspiration Hazard: no data available. Symptoms/Injuries After Inhalation: Symptoms/Injuries After Skin Contact: Symptoms/Injuries After Eye Contact: Symptoms/Injuries After Ingestion: Chronic Symptoms: SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity no data available. 12.2. Persistence and Degradability no data available. 12.3. Bioaccumulative Potential Product: Partition coefficient: n-octanol/water: Remarks: no data available. 12.4. Mobility in Soil no data available. 12.5. Other Adverse Effects no data available. Product: Regulation: 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information: no data available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste Disposal Recommendations: Waste from residues: Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Additional Information: Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14: TRANSPORT INFORMATION 14.1 In Accordance with DOT Proper Shipping Name | Hazard Class | |<PICTOGRAM PHRASE> Identification Number| | Label Codes | | ERG Number | 14.2 In Accordance with IMDG Proper Shipping Name |Vessel: NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS |MATERIAL Hazard Class | Identification Number| Label Codes | |<PICTOGRAM PHRASE> ntification Of The | | Substance/m | | EmS-No. (Fire) | | EmS-No. (Spillage) | | 14.3 In Accordance with IATA Proper Shipping Name |Cargo Air: NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS |MATERIAL |Passenger Air: NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS |MATERIAL Identification Number| |<PICTOGRAM PHRASE> Hazard Class | | Label Codes | | ntification Of The | | Substance/m | | ERG Code (IATA) | SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations <COMPONENT> EPCRA - Emergency Planning and Community Right-to-Know Act: CERCLA Reportable Quantity: Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) sodium dodecylbenzenesulfonate 25155-30-0 1000 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity: This material does not contain any components with a section 304 EHS RQ. SARA 302: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313: SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. SARA Section 311/312 Hazard Classes |Acute Health Hazard Toxic Substances Control Act (TSCA) |On TSCA Inventory. 15.2 US State Regulations <COMPONENT> California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision date |04/20/2015 Other |This document has been prepared in accordance with the SDS Information |requirements of the OSHA Hazard Communication Standard 29 CFR |1910.1200. GHS Full Text Phrases: ----|Hazard statements: |Causes severe skin burns and eye damage. -- | | ----|Precautionary statements: |Prevention: -- | |Wash skin thoroughly after handling. Wear | |protective gloves/ protective clothing/ eye | |protection/ face protection. | |Response: | |IF SWALLOWED: Rinse mouth. Do NOT induce | |vomiting. IF ON SKIN (or hair): Remove/ Take | |off immediately all contaminated clothing. | |Rinse skin with water/ shower. IF INHALED: | |Remove victim to fresh air and keep at rest | |in a position comfortable for breathing. | |Immediately call a POISON CENTER or doctor/ | |physician. IF IN EYES: Rinse cautiously with | |water for several minutes. Remove contact | |lenses, if present and easy to do. Continue | |rinsing. Immediately call a POISON CENTER or | |doctor/ physician. Wash contaminated clothing | |before reuse. | |Storage: | |Store locked up. | |Disposal: | |Dispose of contents/container in accordance | |with local regulation. ----| | -- | | ----| | -- | | ----| | -- | | Grainger disclaimer.
The information contained in this SDS was obtained from current and reliable sources, however, the data is provided without any warrenty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of Imperial Supplies LLC, Imperial will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this 'SDS' shall be created or inferred by any statement in this 'SDS'. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this 'SDS'. The user is responsible for full compliance.